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Measurements in Chemistry Chapter 2

Problem-Set Solutions
2.1 It is easier to use because it is a decimal unit system.

2.2 Common measurements include mass, volume, length, time, temperature, pressure,
and concentration.

2.3 a. The metric prefix giga, abbreviated as G, has a value of

10 9. b. The metric prefix nano, abbreviated as n, has a value
of 10-9. c. The metric prefix mega, abbreviated as M, has a
value of 106. d. The metric prefix micro, abbreviated as μ, has
a value of 10-6.

2.4 a. kilo-, 103 b. M, 106 c. pico-, p d. d, 10–1

2.5 a. A kilogram, abbreviated as kg, measures mass.

b. A megameter, abbreviated as Mm, measures
length. c. A nanogram, abbreviated as ng, measures
mass.
d. A milliliter, abbreviated as mL, measures volume.

2.6 a. centimeter, length b. volume, dL c. picometer, length d. mass, kg

2.7 The meaning of a metric system prefix is independent of the base unit it modifies. The
lists, arranged from smallest to largest are:
a. nanogram, milligram, centigram b. kilometer, megameter,
gigameter c. picoliter, microliter, deciliter d. microgram,
milligram, kilogram

2.8 a. microliter, milliliter, gigaliter b. centigram, decigram,

megagram c. picometer, micrometer, kilometer d. nanoliter,
milliliter, centiliter

2.9 a. Measure the thickness of a chemistry textbook in

centimeters. b. Measure the mass of a cantaloupe seed in
milligrams.
c. Measure the capacity of a car’s gasoline tank in
liters. d. Measure the length of a man’s tie in
decimeters.
2.10 a. centimeter b. meter c. milliliter d. kilogram

2.11 60 minutes is a counted (exact number), and 60 feet is a measured (inexact) number.

2.12 27 people is a counted (exact number), and 27 miles per hour is a measured (inexact)
number.

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2.13 An exact number has no uncertainty associated with it; an inexact number has a
degree of uncertainty. Whenever defining a quantity or counting, the resulting number
is exact. Whenever a measurement is made, the resulting number is inexact.
a. 32 is an exact number of chairs.
b. 60 is an exact number of seconds.
c. 3.2 pounds is an inexact measure of
weight. d. 323 is an exact number of words.

2.14 a. exact b. inexact c. inexact d. exact

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9 Problem-Set Solutions Chapter Problem-Set Solutions Chapter 9
2 2

2.15 Measurement results in an inexact number; counting and definition result in exact
numbers. a. The length of a swimming pool is an inexact number because it is
measured.
b. The number of gummi bears in a bag is an exact number; gummi bears are
counted. c. The number of quarts in a gallon is exact because it is a defined
number.
d. The surface area of a living room rug is an inexact number because it is calculated from
two inexact measurements of length.

2.16 a. exact b. exact c. inexact d. inexact

2.17 The last digit of a measurement is estimated.

a. The estimated digit is the 4. b. The estimated digit is the
zero. c. The estimated digit is the 4. d. The estimated digit is
the 4.
2.18 a. the 7 b. the zero c. the zero d. the 7

2.19 The magnitude of the uncertainty is indicated by a 1 in the last measured

digit. a. The magnitude of the uncertainty is ±1
b. The magnitude of the uncertainty is ±0.1
c. The magnitude of the uncertainty is ±0.001
d. The magnitude of the uncertainty is ±0.00001

2.20 a. 1 b. 0.1 c. 0.001 d. 0.0001

2.21 Only one estimated digit is recorded as part of a measurement.

a. Temperature recorded using a thermometer marked in degrees should be recorded to
0.1 degree.
b. The volume from a graduated cylinder with markings of tenths of milliliters should
be recorded to 0.01 mL.
c. Volume using a volumetric device with markings every 10 mL should be recorded to
1 mL.
d. Length using a ruler with a smallest scale marking of 1 mm should be recorded to 0.1
mm.

2.22 a. 0.1 cm b. 0.1o c. 0.01oF d. 1 mL

2.23 a. 0.1 cm; since the ruler is marked in ones units, the estimated digit is
tenths b. 0.1 cm; since the ruler is marked in ones units, the estimated digit
is tenths

2.24 a. 0.01 cm; since the ruler is marked in tenths units, the estimated digit is
hundredths b. 1 cm; since the ruler is marked in tens units, the estimated digit is
ones

2.25 a. 2.70 cm; the value is very close to 2.7, with the estimated value being 2.70
b. 27 cm; the value is definitely between 20 and 30, with the estimated value being 27

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10 Problem-Set Solutions Chapter Problem-Set Solutions Chapter 10
2 2

2.26 a. 2.7 cm; the value is definitely between 2 and 3, with the estimated value being
2.7 b. 27.0 cm; the value is very close to 27, with the estimated value being 27.0

2.27 a. ruler 4; since the ruler is marked in ones units it can be read to tenths
b. ruler 1 or 4; since both rulers are marked in ones units they can be read to
tenths c. ruler 2; since the ruler is marked in tenths units it can be read to
hundredths
d. ruler 3; since the ruler is marked in tens units it can be read to ones

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11 Problem-Set Solutions Chapter Problem-Set Solutions Chapter 11
2 2

2.28 a. ruler 1 or 4; since both rulers are marked in ones units they can be read to
tenths b. ruler 2; since the ruler is marked in tenths units it can be read to
hundredths
c. ruler 3; since the ruler is marked in tens units it can be read to
ones d. ruler 3; since the ruler is marked in tens units it can be read
to ones
2.29 Significant figures are the digits in a measurement that are known with certainty plus one
digit that is uncertain. In a measurement, all nonzero numbers, and some zeros, are
significant.
a. 0.444 has three significant figures. b. 0.00444 has three significant
figures. c. 0.04040 has four significant figures. d. 0.00004 has one
significant figure.

2.30 a. 3 b. 3 c. 5 d. 5

2.31 a. 275.00 has 5 significant figures. Trailing zeros are significant when a decimal
point is present.
b. 27,500 has 3 significant figures. Trailing zeros are not significant if the number lacks
an explicit decimal point. .
c. 6,720,000 has 3 significant figures. Trailing zeros are not significant if the number
lacks an explicit decimal point.
d. 6,720,100 has 5 significant figures. Trailing zeros are not significant if the number
lacks an explicit decimal point. Confined zeros are significant

2.32 a. 5 b. 3 c. 4 d. 6

2.33 a. 11.01 and 11.00 have the same number (four) of significant figures. All of the zeros
are significant because they are either confined or trailing with an explicit decimal
point.
b. 2002 has four significant figures, and 2020 has three. The last zero in 2020 is not
significant because there is no explicit decimal point.
c. 0.000066 and 660,000 have the same number (two) of significant figures. None of the
zeros in either number are significant because they are either leading zeros or trailing
zeros with no explicit decimal point.
d. 0.05700 and 0.05070 have the same number (four) of significant figures. The trailing
zeros are significant because there is an explicit decimal point.
2.34 a. different b. different c. different d. same
2.35 a. Yes, 11.01 and 11.00 have the same uncertainty.
b. No, 2002 and 2020 do not have the same uncertainty.
c. No, 0.000066 and 660,000 do not have the same
uncertainty. d. Yes, 0.05700 and 0.05070 have the same
uncertainty.

2.36 a. no b. no c. no d. no

2.37 a. For 5371: number of significant figures is 4; estimated digit is 1; uncertainty is ±1.

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12 Problem-Set Solutions Chapter Problem-Set Solutions Chapter 12
2 2

b. For 0.41: number of significant figures is 2; estimated digit is 1; uncertainty is

±0.01. c. For 3200: number of significant figures is 2; estimated digit is 2;
uncertainty is ±100.
d. For 5050: number of significant figures is 3; estimated digit is last 5; uncertainty is ±10.

2.38 a. 2, the last 0, ±0.001 b. 2, the 1,

±100 c. 4, the 5, ±1 d. 3, the 3,
±0.01

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13 Problem-Set Solutions Chapter Problem-Set Solutions Chapter 13
2 2

2.39 The estimated number of people is 50,000.

a. If the uncertainty is 10,000, the low and high estimates are 40,000 to
60,000. b. If the uncertainty is 1000, the low and high estimates are 49,000
to 51,000.
c. If the uncertainty is 100, the low and high estimates are 49,900 to
50,100. d. If the uncertainty is 10, the low and high estimates are 49,990
to 50,010.
2.40 a. 30,000-50,000 b. 39,000-41,000 c. 39,900-40,100 d. 39,990-40,010
2.41 When rounding numbers, if the first digit to be deleted is 4 or less, drop it and the following
digits; if it is 5 or greater, drop that digit and all of the following digits and increase the
last retained digit by one.
a. 0.350763 to four s.f. is 0.3508 b. 13.43 to three s.f. is 13.4
c. 22.4555 to two s.f. is 22 d. 0.030303 to three s.f. is 0.0303
2.42 a. 340.3 b. 133 c. 0.045 d. 0.357
2.43 To obtain a number with three significant figures:
a. 3567 becomes 3570 b. 323,200 becomes 323,000
c. 18 becomes 18.0 d. 2,345,346 becomes 2,350,000
2.44 a. 1230 b. 25,700 c. 7.20 d. 3,670,000
2.45 Rounding:
a. 1.8828: to four significant figures is 1.883; to two significant figures is 1.9
b. 24,233: to four significant figures is 24,230; to two significant figures is
24,000 c. 0.51181: to four significant figures is 0.5118; to two significant
figures is 0.51 d. 7.4500: to four significant figures is 7.450; to two significant
figures is 7.5
2.46 a. 0.5373; 0.54 b. 34.41; 34 c. 25,550; 26,000 d. 7.101; 7.1
2.47 In multiplication and division, the number of significant figures in the answer is the
same as the number of significant figures in the measurement that contains the fewest
significant figures. (s.f. stands for significant figures)
a. 10,300 (three s.f.) 0.30 (two s.f.) 0.300 (three s.f.) Since the least number of
significant figures is two, the answer will have two significant
figures.
b. 3300 (two s.f.) 3330 (three s.f.) 333.0 (four s.f.) The lowest number of
significant figures is two, so the answer will have two significant figures.
c. 6.0 (two s.f.) 33.0 (three s.f.) The answer will have two significant
figures. d. 6.000 (four s.f.) 33 (two s.f.) The answer will have two
significant figures.

2.48 a. 1 b. 1 c. 2 d. 1
2.49 In multiplication and division of measured numbers, the answer has the same number
of significant figures as the measurement with the fewest significant figures. (s.f. stands
for significant figures.)

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14 Problem-Set Solutions Chapter Problem-Set Solutions Chapter 14
2 2

a. 2.0000 (five s.f.) × 2.00 (three s.f.) × 0.0020 (two s.f.) = 0.0080 (two s.f.)
b. 4.1567 (five s.f.) × 0.00345 (three s.f.) = 0.0143 (three s.f.)
c. 0.0037 (two s.f.) × 3700 (two s.f.) × 1.001 (four s.f.) = 14 (two s.f.)
d. 6.00 (three s.f.) 33.0 (three s.f.) = 0.182 (three s.f.)
e. 530,000 (two s.f.) 465,300 (four s.f.) = 1.1 (two s.f.)
f. 4670 (four s.f.) × 3.00 (three s.f.) 2.450 (four s.f.) = 5720 (three s.f.)

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15 Problem-Set Solutions Chapter Problem-Set Solutions Chapter 15
2 2

2.50 a. 0.080 b. 0.1655 c. 0.0048 d. 0.1818 e. 36,000 f. 1.44

2.51 In addition and subtraction of measured numbers, the answer has no more digits to the
right of the decimal point than are found in the measurement with the fewest digits to the
right of the decimal point.
a. 12 + 23 + 127 = 162 (no digits to the right of the inferred decimal point)
b. 3.111 + 3.11 + 3.1 = 9.3 (one digit to the right of the decimal point)
c. 1237.6 + 23 + 0.12 = 1261 (no digits to the right of the inferred decimal point)
d. 43.65 – 23.7 = 20.0 (one digit to the right of the decimal point)
2.52 a. 281 b. 12.20 c. 309 d. 1.04
2.53 a. The uncertainty of 12.37050 rounded to 6 significant figures is
0.0001 b. The uncertainty of 12.37050 rounded to 4 significant figures
is 0.01
c. The uncertainty of 12.37050 rounded to 3 significant figures is
0.1 d. The uncertainty of 12.37050 rounded to 2 significant figures
is 1
2.54 a. 0.0001 b. 0.001 c. 0.01 d. 1
2.55 Scientific notation is a numerical system in which a decimal number is expressed as the
product of a number between 1 and 10 (the coefficient) and 10 raised to a power (the
exponential term). To convert a number from decimal notation to scientific notation, move
the decimal point to a position behind the first nonzero digit. The exponent in the
exponential term is equal to the number of places the decimal point was moved.
a. 0.0123 expressed in scientific notation is 1.23 10–2. Negative exponent.
b. 375,000 expressed in scientific notation is 3.75 105. Positive
exponent. c. 0.100 expressed in scientific notation is 1.00 10–1.
Negative exponent. d. 68.75 expressed in scientific notation is 6.875
101. Positive exponent.
2.56 a. positive b. positive c. negative d. positive
2.57 To convert a number from decimal notation to scientific notation, move the decimal point
to a position behind the first nonzero digit. The exponent in the exponential term is equal
to the number of places the decimal point was moved.
a. For 0.0123 move the decimal 2 places to the right.
b. For 375,000 move the decimal 5 places to the
left. c. For 0.100 move the decimal 1 place to the
right.
d. For 68.75 move the decimal 1 place to the left.
2.58 a. 1 b. 5 c. 1 d. 2
2.59 In scientific notation, only significant figures become part of the
coefficient. a. For 0.0123 there will be 3 significant figures in the
scientific notation.
b. For 375,000 there will be 3 significant figures in the scientific notation.

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16 Problem-Set Solutions Chapter Problem-Set Solutions Chapter 16
2 2

c. For 0.100 there will be 3 significant figures in the scientific

notation. d. For 68.75 there will be 4 significant figures in the
scientific notation.

2.60 a. 5 b. 5 c. 4 d. 3

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17 Problem-Set Solutions Chapter Problem-Set Solutions Chapter 17
2 2

2.61 To convert a number from decimal notation to scientific notation, move the decimal point
to a position behind the first nonzero digit. The exponent in the exponential term is equal
to the number of places the decimal point was moved.
a. 120.7 expressed in scientific notation is 1.207 102
b. 0.0034 expressed in scientific notation is 3.4 10–3
c. 231.00 expressed in scientific notation is 2.3100 102
d. 23,100 expressed in scientific notation is 2.31 104

2.62 a. 3.722 101 b. 1.02 10–3 c. 3.4000 101 d. 2.34 105

2.63 To convert a number from scientific notation to decimal notation, move the decimal point
in the coefficient to the right for a positive exponent or to the left for a negative exponent.
The number of places the decimal point is moved is specified by the exponent.
a. 2.34 102 expressed in decimal notation is 234
b. 2.3400 102 expressed in decimal notation is
234.00 c. 2.34 10–3 expressed in decimal notation is
0.00234
d. 2.3400 10–3 expressed in decimal notation is 0.0023400

2.64 a. 3721 b. 372.10 c. 0.0676 d. 0.067600

2.65 To multiply numbers expressed in scientific notation, multiply the coefficients and add the
exponents in the exponential terms. To divide numbers expressed in scientific notation,
divide the coefficients and subtract the exponents.
a. (3.20 107) (1.720 105) = 5.504 1012 = 5.50 1012 The coefficient in
the answer is expressed to three significant figures because one of the numbers
being multiplied has only three significant figures.
b. (1.00 103) (5.00 103) (3.0 10–3) = 15 103 = 1.5 104 To express the
answer in correct scientific notation, the decimal point in the coefficient was moved
one place to the left, and the exponent was increased by 1.
c. (3.0 10–5) (1.5 102) = 2.0 10–7
d. (2.2 106) (2.3 10–6) (1.2 10–3) (3.5 10–3) = 1.2 106

2.66 a. 5.3 × 1012 b. 8.1 × 10−2 c. 2.0 × 10−8 d. 1.3 × 105

2.67 a. 102; the uncertainty in the coefficient is 10−2 and multiplying this by the power of ten
gives
10−2 × 104 = 102
b. 104; 10−2 × 106 = 104
c. 104; 10−1 × 105 = 104
d. 10−4; 10−1 × 10−3 = 10−4
2.68 a. 10−4; the uncertainty in the coefficient is 10−2 and multiplying this by the power of ten
gives
10−2 × 10−2 = 10−4
b. 10−4; 10−3 × 10−1 = 10−4
c. 102; 10−1 × 103 = 102

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