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‘Pure’ word means that there is no mixing in a substance. But according to scientific
language all things are mixture of so many substances, not of single one, That's why they
are not pure.
E.g. Milk, water, fat,ete.
+ Puresubstances means that all elements have same chemical properties
+ Apuresubstance is made up ofsame kind of elements.
Substance : A substance is a kind of matter that cannot be separated into other kind of
matter by any physical process. A pure substance is made up of same kind of elements.
Whatisa mixture?
It isa substance in which two ormore substances (clement or compound) are simply mixed
together in any proportion. Examples : The air is a mixture of oxygen, nitrogen, carbon
dioxide and water vapour.
Types of Mixture : Mixture is of two types:
(i) Homogenous mixture
(i) Heterogenous mixture
Homogenous Mixture : These types of mixtures have no visible boundaries of separation
between the various constituents.
Example : Sugar in water, It has auniform composition throughout its mass.
Heterogenous Mixture : These types of mixtures have visible boundaries of separation
between the various constituents.
Example : Mixture of sugar and sand, It does not have a uniform compos
throughout its mass.
Solution : A solution is a homogenous mixture of two or more substances. E.g., Nimboo
pani, soda water.
Solution » A solution has a solvent and a solute as its components. The component of the
solution that dissolves the other component in it is called the solvent. The component of the
solution that is dissolved in the solventis called the solute.
___
Solute mt
(Substance dissolved) 77 Substance in which dissolved)
eg, Sugar + Water = Sugar solution
14Types of Mixtures.
True Colloidal Suspension
1. Size of solute 1. Size of solute particles bigger than | 1. Size of particles
particles is smallest. | true but smaller than suspension. In biggest. > 10° m.
<10°m. between 10” to 10° m.
2. Solute particles 2. Solute particles can't be seen with 2. Can be seen
can't be seen with Naked eye. with naked eye.
naked eye.
3. Heterogenous
mixture.
3. Homogenous
mixture.
4. Particles can't . Particles can't be separated by 4. Can be Separated
be separated by filteration. by filteration,
filteration.
5. Transparent 5. Translucent 5. Opaque
6. Stable solutions | 6. Stable solutions. 6. Unstable
- Le., solute solution — solute
particles settle
upon keeping.
particles do not
settle on keeping,
7. Do not show 7. Show tyndall effect. 7. May or may not
tyndall effect. show tyndall effect.
8. Solution diffuse} 8. Colloid particles pass through filter | 8. Suspension
rapidly through paper but not through parchment paper.} particles do not
filter paper as pass through filter
well as parchment paper as well as
paper. parchment paper.
9. e.g., Sugar in
water.
9. e.g., Sand/mud
in water.
Dispersal Phase
: Type Example
(Solute) (Solvent)
1. | Liquid Gas ‘Aerosol Fog, cloud
2. | Solid Gas Aerosol Smoke
153 Gas Liquid Foam Shaving
Cream,
4, Liquid Liquid Emulsion Milk, face
cream,
emulsion paint
5 Solid Liquid Sol Mud, digene
6. Gas Solid Foam Foam, rubber
sponge
7. | Liquid Solid Gel Jelly, cheese
8. Solid Solid Solid sol Coloured
gemstones,
glass (milky,
coloured)
* Gas in gas is not a colloidal solution — it is called a mixture.
Concentration of Solution
mass of solute
1. Mass by mass percentage —ee
. p es ‘mass of solution
mass of solute
v — —tuss of solute
2. Mass by volume percentage —
Methods of Separation of Mixtures :
(1) Evaporation:
Basic principal : Out of the two components of a mixture one can evaporate [i
less boiling point] and other has higher boiling point.
Example : Mixture of dye [higher boiling point] and water, Out of water and dye,
water evaporates but dye is left behind in petri dish.
Winter evaporates
Ink
has
Dye left
bein
‘Beaker
Mixture
“Tripod stand
Bumer
(2) Centrifugation:
Basie principle : Separation of Substances or particles on the basis of
16their density, when mixture is rotated very fast, then denser particles are forced at the
bottom and lighter particles stay above.
Lightest
Lighter
Densest particle
Example : Separating cream from milk
Can you think what is toned and double toned milk?
Applications
(2) Used indiagnostic labs for blood and urine tests.
(6) Used in dairies and home to separate butter from cream.
(©) Used inwashing machines dryers to squeeze out water from clothes.
Have you seen dust particles from our clothes settle at the bottom of washing tub.
Doyou know why now?
(3) — BySeparating Funnel:
Basic principle : Two immiscible liquids (which do not dissolve in each other) can
be easily separated by putting in a separating funnel.
Example : Water from oil can be separated by first opening the stop cock till water is
removed in one beaker, then afterwards oil can be collected ina separate beaker.
Separating
fe
Kerosene oil
‘Water
StopeackApplications :
(a) Separation of oil from water.
(b) Extraction of iron from its ore. Lighter slag is removed from above the
molteniron,
(4) Sublimation;
Basic principle : Out of the two components, one will sublime (directly converts to
gas from solid) and other will not.
Example: NH,CI (ammonium chloride) and NaC] common salt mixture can be
easily separated by heating so the NH,CI sublimes but common salt remains behind.
apours of
‘montis
‘a a
Applications +
{a) Camphor, naphthalene, anthracene, NH,Cl can sublime.
(5) Chromatography :
Basic principle ; Coloured components of a mixture can be separated by using an
Adsorbent on which they are adsorbed at different rates.
(Adsorption is the process of surface absorption.)
+}— Chromatography
Paper
Ink Spot
(enivtu Line drawn
of colors) bby pencil
Water / Solvent
When water/any suitable solvent moves up the chromatography paper ink with two
different colours separates because both colours are absorbed at different speeds.
18Glass rod
Paper clips
‘Strip of filter, Jar
aaa Strip of filter
Paper
| Line drawn Spot of ink
by pencil aes
©) spot of ink es
Applications :
(a) Toseparate colours ofa dye.
(b) — Toseparate pigments from natural colours like chlorophyll.
(c) Toseparate drugs from blood.
(Can you guess what is done when athletes undergo a doping test for their blood?)
(6) —_ Distillatios
Basic principle : Based on Separating mixture of miscible liquids having different
boiling points, followed by condensation. Out of the two components one has a lower
boiling point and other has higher boiling point. This is used to separate two or more
miscible liquids.
|. ~reseesaeaee
Clamp —~
Distillation
flask
of acetone
and water
Cold water in
Acetone:
Example : When mixture of acetone and water is heated, acetone having lesser
boiling point, boils and moves to delivery tube, within which it condenses back to liquid
with the help of a condenser clamped to it. Thus, acetone is separated out in a beaker and
water is left in the distillation flask.
Note : ifthere are more than two components (liquids) mixed (with different boiling
points) then we use a fractionating column to separate all the components from each other:
This process is done for air, petroleum etc.
19mM
Petroleum is separated into
paraffin wax, lubricating oil, diesel,
kerosene, petrol and petrol gas by
this method.
Fractional Distillation of Air:
Air is also separated by this method.
compressed and <4 9:
(Aig eet Liquid air—e Allowed to warm —+ Gases separated
up slowly ina at different heights
fractionating column
Some of the applications of fractional distillation :
(a) _Inoil refineries to separate crude oil into useful substances (or fractions).
(b) In the separation of oxygen, liquid nitrogen and argon from air.
Crystallisation :
Basic principle ; To remove impurities from a mixture by first dissolving in a
suitable solvent and then crystallising out one component.
For example : Copper sulphate crystals (impure) are first dissolved in sulphuric acid
and then heated to saturated solution. Now, this solution is left overnight. So, only
pure copper sulphate crystals on filter paper.
Why is crystallisation better than evaporation ?
(i) Some solids decompose or get charred upon heating to dryness during
evaporation. e.g., sugar.
(ii) Some impurities remain dissolved in solution after filteration. On
evaporation, these impurities do not evaporate and remain with the mixture.
Applications :
(a) Purification of salt from sea water.
(b) Separation of crystals [e.g., alum (phitkari), copper sulphate]
from their impure crystals.
20Water purification in water treatment plants
Reservoir » Sedimentation tank ___, Loading tank
(Impure water) (Solids setile down) (Sedimentation of
suspended impurities
using alum ete.)
Water supply Chlorination tank Filtration tank
to homes (Addition of chlorine (All impurities filtered)
to kill germs)
Toaliow Tosediment Fine Coarse
sand gravel
Resorvoir solids to the suspended,
settle impurities Water | Gravel
Sedimentation Loading Filtration tank
tank tank
To home
Chionnation to
kill bacteria :
Physical Vs Chemical Changes
Chemical Physical
. Noteasily reversible . Easily reversible
. New Product(s) formed . No new products
. Reactants used up . Often just a state change
. Often heat/light/sound/ | + e.g., ice melting
fizzing occurs
. Electricity may be produced
. Aprecipitate may form
e.g., Wood burning
Elements
Made of same type of atoms
S.No. | Metals Non-metals Metalloids
1, [Lustrous Non-lustrous Metallaoids have
intermediate properties
between metals and
non-metals.
212. Malleable, ductile Non-malleable, non- | E.g., Boron, Germanium,
ductile Silicon
3. Sonorous Non-sonorous |
4. Good conductors of | Bad conductors
heat & electricity
5. e.g., Gold, iron ete. e.g., Oxygen,
Phosphorus
Mixture ‘Compound
1. Elements or compounds are | 1. Substances are reacted together
simply mixed so no new substance with each other to make a new
is formed. substance.
2, Elements do not combine in a | 2, Composition of the components is
fixed ratio. fixed i.e., they combine together
in a fixed ratio according to their
masses.
3. Amixture shows the properties of | 3. Compound doesn't show the
its components. properties of component
elements.
4. Components can be easily | 4. Components can't be separated
separated by any mechanical from each other by simple
method which is suitable. mechanical methods.
5. ¢.g., sugar in water, oil in water 5. e.g., Iron and sulphur react to from
iron sulphide.