10-09-2023 SR - Super60 NUCLEUS BT Jee-Adv (2020-P2) CTA-04 Q.Paper
10-09-2023 SR - Super60 NUCLEUS BT Jee-Adv (2020-P2) CTA-04 Q.Paper
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 19 – 24) Questions With Integer Answer Type 3 -1 6 18
Questions with Multiple Correct
Sec – II(Q.N : 25 – 30) 4 -2 6 24
Choice +1 partial marks
Questions with Numerical Value
Sec – III(Q.N : 31 – 36) 4 0 6 24
Answer Type
Total 18 66
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 37 – 42) Questions With Integer Answer Type 3 -1 6 18
Questions with Multiple Correct
Sec – II(Q.N : 43 – 48) 4 -2 6 24
Choice +1 partial marks
Questions with Numerical Value
Sec – III(Q.N : 49 – 54) 4 0 6 24
Answer Type
Total 18 66
2. A tank having cross sectional area A has a hole at the bottom of area of cross section
A1 A / 1000 . Bottom of the tank is a plane mirror. The tank contains water of refractive
index 4/3. At the instant, when height of the water in the tank is h = 5 m, a fish is rising
vertically in the tank with a velocity 3 cm/sec toward the surface. Find the velocity of the
fish as observed by the observer looking directly at the fish (in cm/s). (Take g = 10 m / s 2 )
3.
An object moving along x-axis such that x t 2 4t 6 m find distance travelled by
particle from t = 0 to t = 3sec
5. If the dimensions of length are expressed as G xc y h z ; where G, c and h are the universal
gravitational constant, speed of light and Planck’s constant respectively, then (z – y) is
6. A pendulum is hanging from a peg inserted in a vertical wall. Its bob is stretched in
horizontal position from the wall and is left free to move. The bob hits on the wall the
2
coefficient of restitution is . After how many collisions the amplitude of vibration will
5
become less than 600
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
•This section contains SIX (06) questions.
•Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
•For each question, choose the option(s) corresponding to (all) the correct answer(s).
•Answer to each question will be evaluated according to the following marking scheme:
Full Marks:+4 If only (all) the correct option(s) is(are) chosen; Partial Marks +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks:+2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks:+1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks:0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: -2 In all other cases.
=========================================================================================
7. Block is in equilibrium and the tension in the string AB is 300 N. Then choose the correct
3
option(s). (Take g = 10 m / s 2 , tan 370 and neglect the mass of the rod CD)
4
A) The locus of point on the wall having equal intensity are circle.
B) No. of dark rings will be observed on the wall are 10
C) Radius of 4th bright ring from O is 8/3m (exclude the position of O)
D) Radius of 4th bright ring from of is 21m (exclude the position of O)
9. Fig. shows a double chambered vessel with thermally insulated walls and partitions. On
each side there are n-moles of an ideal mono atomic gas. Initially the pressure, volume
and temperature in each side is P0 , V0 , T0 . The heater in first chamber supplies heat very
slowly till the gas in the first chamber expands such that the pressure, volume and
temperature of the gas on the left side is P1, V1, T1 respectively and on right chamber is
27 P0
P2 , V2 and T2 respectively
8
8 3/5
A) Volume of first chamber is 2 V0
27
2/5
27
B) Temperature in second chamber is T0
8
C) Work done on the gas in second chamber in terms of molar heat capacity at constant
27 2/5
volume and T0 is nCV T0 1
8
D) Work done on the gas in first chamber in terms of molar heat capacity at constant
27 2/5
volume and T0 is nCV T0 1
8
10. Graph represents motion of an object along X–axis for 80s
disc A is set in motion with velocity ‘v’ along the r bisector of line BC. The distance
between disc B and C is n times the diameter of each disc. For which of the following
values of ‘n’ will the disc A continue moving after elastic collision.
A) n 2.5 B) n 2 C) n 1.5 D) n 3
SECTION – III
(NUMERICAL VALUE TYPE)
• This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
Numeric keypad in the place designated to enter the answer. If the numerical value has more than two decimal places, truncate/round-off the value to
TWO decimal places.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered;
Zero Marks: 0 In all other cases..
=========================================================================================
13. A capillary tube made of a material of refractive index 2. The outer radius of the tube is
3R and inner radius is R. The tube is filled with a liquid of refractive index 1.5 A light
ray is incident on the tube at grazing incidence (angle of incidence approximately 900 )
on the outer surface of capillary tube as shown in the fig. The net angle of deviation is k 0 .
Find the value of ‘k’
15. Two uniform rods of same length but different density are arranged as shown in the
diagram. Centre of mass of this arrangement lies on a line ax + by = l. (l is the length of
rod) find a + b = ?
16. A circular ring of mass 3 kg is suspended from an inextensible string, and two beads of
mass ‘m’ slide on it without friction as shown in the figure. The beads are released
simultaneously from the top of the ring and slide down symmetrically with respect to the
vertical as shown. The ring will start to rise when 600 . Then the value of ‘m’ in kg is
n n 1
‘v’ so that the rod becomes vertical is gl . Find the value of ‘n’
n
18. Figure shows two blocks A and B are connected through pulley and spring system. Block
A, on a frictionless surface, has a mass of 2 Kg, Block B, suspended by cables, has a mass
of 3 Kg. The spring has a stiffness of k = 500 N/m and an unstretched length of 400 mm.
the system is released from rest in the position shown (x = 800 mm).The speed of the
block A (rounded off to the nearest higher integer) in m/s when x = 0 mm is
g 10 m / s 2
K Cr O 7 Ca (OH ) D
CH 3CHO ¾¾2 ¾2¾¾ (A ) ¾¾ ¾ ¾ 2¾ (B) ¾¾ (C) (organic product )
22.
Find the value of ‘p’?
23. Find the number of compounds which on reduction with LiAlH 4 give optically inactive?
O
O
O
O O
a) O O b) O c) d)
O
O O
O
Cl H
e) O f)
24. In the following Hofmann’s bromamide reaction, how many different organic products
would be formed?
O O
|| || 15
NaOH
H3C -C - NH 2 + CH3CH 2 -C - N H 2 + Br2 ¾¾¾¾
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
•This section contains SIX (06) questions.
•Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
•For each question, choose the option(s) corresponding to (all) the correct answer(s).
•Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is(are) chosen; Partial Marks +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks:+1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: -2 In all other cases.
=========================================================================================
(i) NaOH
(ii) MeI
H3 C CH3
B)
COOH
(i) AgOH
H3 C
(ii) CH2=CHCH2Br
CH3
C)
COOH
CH2N2
ether
D)
26. Which of the following reaction is/are correctly matched
CHO
CHO Base
OHC heat
A)
SOCl KCN Sn / HCl
B) CH 3CH 2CH 2OH ¾¾ ¾2¾ ¾¾ ¾ ¾¾ ¾ ¾¾ CH 3CH 2CH 2CHO
C)
+2
D) CH CH A
Hg /H 2SO4 Zn-Hg / HCl
C2 H 6
27. Which of the following reactions is/are correct
A)
O
O
MeOH SOCl
[ A ] ¾¾ ¾2¾
O ¾¾ ¾ ¾¾ [ B] H3C Cl
(1 equiv.) O
B) O O
C)
D)
28. Which of the following is true for 3-methyl-2-butanone
A) It may be prepared by CrO3 oxidation of 2-butanol
B) Reaction with NaBH 4 gives a secondary alcohol
C) It may be prepared by acidic HgSO4 / H 2SO4 catalysed hydration of 3-methyl-1-
butyne
D) It forms a silver mirror on treatment with Ag NH 3 2
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Sri Chaitanya IIT Academy 10-09-2023_Sr.Super60_NUCLEUS _BT_Jee-Adv(2020-P2)_CTA-04_Q.P
29. The product(s) obtained in the below reaction is /are
A) B) C) D)
30.
Which of the following is /are correct regarding above sequence of reactions?
A) B)
C) D)
SECTION – III
(NUMERICAL VALUE TYPE)
• This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
Numeric keypad in the place designated to enter the answer. If the numerical value has more than two decimal places, truncate/round-off the value to
TWO decimal places.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered;
Sec: Sr.Super60_ NUCLEUS _BT Space for rough work Page 14
Sri Chaitanya IIT Academy 10-09-2023_Sr.Super60_NUCLEUS _BT_Jee-Adv(2020-P2)_CTA-04_Q.P
Zero Marks: 0 In all other cases..
=========================================================================================
31.
O
EtO- (I) HO (CH 2 )2 OH / HCl OH( )D
-
¾¾ ¾ ¾ ¾ ¾ P1 ¾¾ ¾ ¾ ¾ ¾ ¾ ¾ ¾ ¾ P2 ¾¾ ¾ ¾ P3
H - C- OEt (II) LiAlH 4
||
O (III) H3O+
In the P1, P2 and P3 total number products having -CHO functional group = x
33.
H C H , CH 3 C H , CH 3 C CH 3
, ,
O
CH 3 C CH 3
a) Number of compounds which are more reactive than towards
nucleophile addition is x
b) Number of compounds which give aldol and haloform (both) reaction is y
c) Number of compounds which give Tertiary alcohols reaction with RMgX is z
the answer is x, y, z. if your answer x is 1 y is 2 z is 3. write answer 123 on OMR sheet
35. A carbonyl compound of formula C9 H10O A , which is a benzene derivative gives
orange precipitate with 2, 4-D.N.P and also gives yellow precipitate with I 2 in presence
of aqueous NaOH. The total no. of isomers possible for A are ………
36.
The number of all possible monobromo products (including stereoisomers) are___.
m 1k 1 n 1
37. Find the value of 2l, where l lim . lim
m k 1 k n r 0 1 k .2r
38.
If 1, 1 , 2 , 2 , ........., n , n are the points on the curve
S : y sin x y x 4 , 4 such that the tangents at these points to S are
n
| k | | k |
perpendicular to the line
2 1 x y 0 then the value of k 1
11
is
(where [ . ] denotes greatest integer function)
4 4 tan d 2
39. If 1 tan ln k
w
, find (kw), where k, w N
4
1
the value of
f ' 2 g '' 0 is equal to
f ' x x f x f x x
41. If dx is equal to m tan 1 c, where m, n R
f x x f x x x2 nx
m
and ‘c’ is constant of integration (x > 0) then is equal to
n
43. If f ' x
1
1 x2
; x , 1 1, and f 3 6 , then f 3 can be equal to
5
A) B) C) D)
6 2 6 2
1 1
sin x
cos x
44. Let I
x x
. dx, then
1
x
x
2 2
sin 2 x sin sin 2 x sin
A) I x . dx B) I x . dx
1 1 x2
0 x 0 x
x x
2
sin
sin x x . dx
C) I . dx D) I
0
x 0
x
n 2 1! 2! 3! ..... n!
45. If , R, 0, n N and lim , then
n n
1
A) 2 ln 0 B) 2 4ln 2
3
1 1
C) 2 ln D) 2 4ln 4
3 2
46. Consider the series f x 1 3sin 2 x 5sin 4 x ....., g x cos x cos3 x cos5 x
…..n terms, then
Sec: Sr.Super60_ NUCLEUS _BT Space for rough work Page 18
Sri Chaitanya IIT Academy 10-09-2023_Sr.Super60_NUCLEUS _BT_Jee-Adv(2020-P2)_CTA-04_Q.P
2 tan 3 x
A) f x dx tan x C (where C is constant of integration, x 2n 1 )
3 2
3
cos ec 2 x
B) lim f x g 2 x e n
2
x 0
2 1
C) If I 2n g x dx, then maximum value of I 2n 2 I 2n is 5 for n 1,6 , n N
0
47. Let f : 0,1 be a continuous function on [0, 1]. Which of the following options is/are
1 c
always correct, if f x . dx 0? note that f x dx
0 0
A) There exists at least one c 0, 1 , such that f c
x4 x 1 1 x2 2 x 1
48. dx tan 1
f x 16 2 ln g x C , where
x 1
4 2
A x4 1 8 2
f(1) = 0, then
A) A = 4 B) g 2 5 C) f 2 12 D) f 3
1
9
SECTION – III
(NUMERICAL VALUE TYPE)
• This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
Numeric keypad in the place designated to enter the answer. If the numerical value has more than two decimal places, truncate/round-off the value to
TWO decimal places.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered;
Zero Marks: 0 In all other cases..
=========================================================================================
x 2 1 mx 2 n 1x p, q