Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec:Sr.Super60_STERLING&NUCLEUS_BT Paper -2(Adv-2021-P2-Model) Date: 06-08-2023
Time: 02.00Pm to 05.00Pm RPTA-01 Max. Marks: 180

KEY SHEET
PHYSICS
1 AC 2 BD 3 AB 4 BD 5 ABCD 6 ACD
4.66 or 8.90 or
7 1.50 8 1.12 9 4 10 8 11 12
4.67 8.91
13 D 14 A 15 C 16 B 17 5 18 3

19 5

CHEMISTRY
20 ABD 21 B 22 BCD 23 ABD 24 C 25 CD

26 14 27 83 28 7 29 5 30 8 31 2020

32 C 33 A 34 C 35 C 36 6 37 5

38 2

MATHEMATICS
39 AB 40 AD 41 ABCD 42 ABC 43 BD 44 BCD

45 15 46 8 47 3 48 3 49 1.5 50 6

51 A 52 C 53 B 54 D 55 2 56 4

57 1
 Sri Chaitanya IIT Academy 06-08-2023_Sr.Super60_STERLING&NUCLEUS_BT_Jee-Adv(2021-P2)_RPTA01_Key& Sol’s

SOLUTIONS
PHYSICS
1. Let the system be water at 1000 C
 L 
Heat released by steam   4     500   4 L  6 L
 1000 
 L  L  L 
Heat required by ice  10     200   10    10   100   5.67 L
 1000  6  500 
Using 0.33 L of available heat 0.33g converts into steam.

2. Let R
KA
3T  T0 2T  T0 T  T0
The resistances will be R, R and 3R   0
R R 3R
16T
T0  which is guator then T and 2T.
7
Heat flows towards the junction in only one rod.
3.  
Volume of the liquid   R 2h 1   

Area of the base   R 2 1  2 

volume  1   
 Height from the bottom   h 
Area  1  2 
Depth from the top  height of the cylinder – height of the liquid
 1   
 H 1     h    H 1     h 1     2  
 1  2 
4. Q  nC T C can be positive or negative depending on the process.
When C is negative, temperature decreases.
1
5. Average KE per degree of freedom  KT
2
5 5
Energies greater than KT and less than KT are possible.
2 2
1 2 3  Mv 2
6.  
nM v  n  R   T  T 
2 2  3R
P T
Pv  nRT  
P T
V0  2V0 3V0 V
7. VM    M  1.50
2 2 V0
8. 2 P0V0  nRT0
Middle point will be at maximum temperature
 3P0  3V0  TM 9
    nRTM  T
  1.12
8
 2  2  0

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 Sri Chaitanya IIT Academy 06-08-2023_Sr.Super60_STERLING&NUCLEUS_BT_Jee-Adv(2021-P2)_RPTA01_Key& Sol’s
9. The outer shell emits power P in both directions.
Sphere has to emit radiation of power P '  P  P  2 P
10. P T 4 and P ' T '4
4 12
P'  T '  T '
     2 and   8
P T  T 
2
2 RT 3RT  u1 
11. u1  v3      4.66 or 4.67
4  103 28  103  v3 
8 RT 2 RT
12. u2  v1 
 4  103 28  103
2
 u2 
   8.90 or 8.91
 v1 
yA 2 y2A 7
13.    x    22  x   x 
 2 3
Ay 10 Ay
14. F    x  
 3
3  3
15. x   R  T  P0V0
2  2
3 y
y   4 P0V0  P0V0   3
2 x
16. Heat is absorbed when the product PV increases.
3
When pressure increases at V0 , Q1   2 P0V0  P0V0 
2
5
When volume increases at 2 P0 , Q2   4 P0V0  2 P0V0 
2
13P0V0
 heat absorbed 
2
P0V0 2
w  P0V0  Efficiency  
 13P0V0  13
 
 2 
T 10 y
17. Mean free path  y  2.5 x  5
P x
3n
18. PV  nRT  R T  T 
4
T
 3
T
 3   5   10  
19. Q    5   R    4   R   3  R   2
 2   2   2 
 65 R  x 5

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 Sri Chaitanya IIT Academy 06-08-2023_Sr.Super60_STERLING&NUCLEUS_BT_Jee-Adv(2021-P2)_RPTA01_Key& Sol’s

CHEMISTRY
20.

H H

; ;

H H Cis Trans
Cis Trans

CH3 CH3
CH3 CH3

C C
CH3 CH3

CH3 CH3
Cis Trans

21.
CONCEPTUAL
22.
H COOH
C 
 no, anhydride
C
HOOC H

H COOH COOH
C B.R

 H OH
C Meso
H OH
H COOH
COOH

COOH COOH
H COOH
C D H D D H
C
2 H D
Ni D H
HOOC H
COOH COOH

23. a , b, d are without any symmetry element.

24. Only salicylic acid is carboxylic acid.
25.
Cl

Cl Cl
has 9 stereoisomers and
only one enantiomeric pair
and 7 meso compounds.
Cl Cl
Cl
26 & 27. Enolizable H 3  14
Chiral centres  5
sp 2 carbons = 25
28. CONCEPTUAL
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 Sri Chaitanya IIT Academy 06-08-2023_Sr.Super60_STERLING&NUCLEUS_BT_Jee-Adv(2021-P2)_RPTA01_Key& Sol’s
29. OPTICALLY ACTIVE = 2 ; MESO COMPOUNDS = 2
30. CONCEPTUAL
31. CONCEPTUAL

32&33. In "13" 
" c " is without symmetry elements.
In "14"  " y " is without symmetry elements.
34 . C is chiral
35. Only three double bonds can exhibit geometrical isomerism.
36.

4 2
37.
C4 H 6 
, , ,

, , , ,

38.

C7 H14 
8
1 1  3  3

C4 H8O 
, , , ,
1  2 1  2 1

 10
3

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 Sri Chaitanya IIT Academy 06-08-2023_Sr.Super60_STERLING&NUCLEUS_BT_Jee-Adv(2021-P2)_RPTA01_Key& Sol’s

MATHEMATICS
39.
y
 1 
 , 2
 2 

1,1
 0,1
x  1

x0 1 x
x x 1
2
 1, 1

Clearly domain of f is  1,1 . Verify all alternatives from graph.

40. f  x  is defined only when
3  e2 x  0  3  e2 x  e 2 x  3  2 x  log e 3
1
is defined only when 3  e2 x  0  3  e 2 x  e2 x  3  2 x  log e 3
f  x
41. Put x  0  y  f  0   0
f  h   f  0 3
f 1  0   lt
h 0 h

 f 1  0 
 
f 1  0   0 or 1  f 1  0   0 
 f  x  k a x  k
 f  x   0 or  f  0   0 
 x  3 x0 2  x x0
 
42. f  x   x  3 0  x 1 g  x   2  x 0  x  2
 x  2  a 1 x  2 1  2 22
 
 1 x0
 1 0  x 1

h x  
0  h  3  x 1 x  2
a  L  1  x
x2
a  L  2  1  a  L   3
  3
1 2 x  3

43.  
R.H .L f 0  Lt 3  cot 
x 0    x2 



  2 x3  3  
 3  LT cot 1  
  2 
x 0   x  
 33 0

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 Sri Chaitanya IIT Academy 06-08-2023_Sr.Super60_STERLING&NUCLEUS_BT_Jee-Adv(2021-P2)_RPTA01_Key& Sol’s

 1
 
L.H .L f 0  Lt
x 0 
 
x 2 cos  e x   0
 
 
44. f  x    tan 2 x 
 
AT x  0 as x  0 tan x  0  tan 2 x  0
x  0 tan x  0  tan 2 x  0

   
f 0   f 0
f  x  at constant at x  0
45 & 46. For domain of g  x  , f  x   0  x  1,5
Sum of integers  1  2  3  4  5  15


 2 2  x  1

 1
47. f  x    1 1  x  
 2
 2 1
2 x  1  2  x  2


f  x   2 x 2  1 2  x  2
 2 2  x  1
 1
 1 1  x  
 2

f  x   1 1
 2

 2 x  1  2  x  2

 2 x2  1 1
  x2
 2
 2 x 2  1 2  x  1

 2 x 2  1 1  x   1
 2

g  x   1 1
 0  x
 2 2
 2 1
ax  2 2
x2

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 Sri Chaitanya IIT Academy 06-08-2023_Sr.Super60_STERLING&NUCLEUS_BT_Jee-Adv(2021-P2)_RPTA01_Key& Sol’s

f  x  is non differentiable at 3 points.

g  x  is non differentiable at 3 points.
48. CONCEPTUAL
49 & 50
Let x 2  4cos 2   sin 2 
Then f  x   3 sin   3 cos
min  3 1  3
max  3 2  6
50. CONCEPTUAL

 x0
51. f  x   2
 0 x  0
 2 
1 sin x  1  x   2
g  x  
0 sin 2 x  1

Range g x  1 is 0,1
1 
2
  
h  x   sin 1  cos  g  x   cos 2  f  x   

Is discontinuous.
52. CONCEPTUAL
 7 7 
53. Since f  x    f   x  x  R
 4 4 
7
So, f  x  is symmetric about x 
4
b 7 b 7
Hence   
2a 4 a 2
Also f  x   7 x  a has only one real solution, so
ax 2  bx  a  7 x  a  ax 2  x  b  7   0 has discriminant zero.
2
  b  7   4  a  0   0  b  7
Putting b  7 in equation (1), we get a  2
So, f  x   2 x 2  7 x  2 Hence,  a  b    2  7   5
54. Clearly from the graph of f  x   2 x 2  7 x  2 ,
y  7 33 
V , 
4 8 

 0,0  O
7 x
 0, 2  x
4

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 Sri Chaitanya IIT Academy 06-08-2023_Sr.Super60_STERLING&NUCLEUS_BT_Jee-Adv(2021-P2)_RPTA01_Key& Sol’s

 3
Minimum value of f  x  in 0,  is Fmin  x  0   2
 2
55. 2  x    x   2 x
 x  x
 x   0   2   x  0,1
2 2
For  x   0  x  0
1 3
 x  1  x  1  
2 2
56.
y  x3
1
3 2 1 O

1
All is not differentiable at 5 points.
57.

cos x
sin x
1
x
4
O  2

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