21-07-2025

2001CJA101021250018 JA

PHYSICS

SECTION-I

1) Which of the following correctly represents the variation of electric potential (V) of a charged
spherical conductor of radius (R) with radial distance (r) from the centre?

(A)

(B)

(C)

(D)

2) A small object of mass M and charge Q is connected to an insulating massless string in a vaccum
on Earth. A uniform electric field exists throughout the region of the vaccum as indicated. The mass
remains in static equilibrium at an angle of θ with the vertical as shown in the figure. When the
string is cut, which of the illustrated paths best indicates the trajectory of the mass?

(A) I
(B) II
(C) III
(D) IV
3) Figure shows the capacitors in steady state, with S open. When S is closed :-

(A) Both batteries supply energy & heat is lost.

(B) Both batteries supply energy to increase the energy of both the capacitors separately
(C) One battery supplies & other absorbs energy and no heat loss takes place.
(D) One battery supplies energy, other absorbs and heat is lost in the process.

4) Find the potential difference across AB. If voltage of ideal battery 5 Volt is :

(A) 4 V
(B) 2 V
(C) 1 V
(D) None of these

5) A parallel plate air capacitor has a capacitance C (figure-1). When it is half filled with a dielectric
of dielectric constant 5 (figure-2), the percentage increase in the capacitance will be :-

(A) 400%
(B) 33.3%
(C) 66.6%
(D) 200%

6) The potential difference between the points A and B in the given figure is:

(A) +9V
(B)
(C) +3V
(D) +6V

7) For a uniformly charged ring of radius R, the electric field on its axis has the largest magnitude at
a distance h from its centre. Then value of h is :

(A)

(B) R

(C)

(D)

8) Full scale deflection current for galvanometer is 1mA. What should be the value of shunt
resistance (approximately) so that galvanometer shows half scale deflection. (Shown figure)

(A) 1.5 mΩ
(B) 3 mΩ
(C) 10 mΩ
(D) 15 mΩ

9) Masses of three wires of copper are in the ratio of 1 : 3 : 5 & their lengths are in the ratio 5 : 3 : 1.
The ratio of their electrical resistance are :-

(A) 1 : 3 : 5
(B) 5 : 3 : 1
(C) 1 : 15 : 125
(D) 125 : 15 : 1

10) Six identical light bulbs are connected to a battery to form the circuit shown. Which light bulb

(s) glow the brightest?

(A) 1, 2, and 3
(B) 5 and 6
(C) 1, 2, 3 and 4
(D) 4 only

11) A current is flowing in a straight conductor of length L. The magetic induction at a point at a
distance L/4 from its centre on perpendicular bisector is :

(A) Zero

(B)

(C)

(D)

12) A cube is placed inside an electric field, . The side of the cube is 0.5 m and is placed
in the field as shown in the given figure. The charge inside the cube is :

(A) 3.8 × 10–11 C

(B) 8.3 × 10–11 C
(C) 3.8 × 10–12 C
(D) 8.3 × 10–12 C

13) The magnetic field at point P, is :-

(A)

(B)

(C)

(D)

14) Four capacitors are connected as shown in figure to a 30 V battery. The potential difference
between points b and a is :

(A) 5 V
(B) 9 V
(C) 10 V
(D) 13 V

15)

Find the magnetic field induction at 'O' due to the given current carrying wire in diagram :

(A)

(B)

(C)

(D)

16) An isosceles right angle triangle of side d is placed in a horizontal plane. A point charge q is
placed at a distance d vertically above from one of the corner as shown in the figure. Flux of electric
field passing through the triangle is:-

(A)

(B)

(C)

(D)

17) AB represents a segment of infinite uniformly charged wire of density λ. Now a charge q0 is
taken from point P to Q slowly as shown in fig. then work done by the external forces

(A)

(B)

(C)

(D)

18) A parallel plate capacitor has plates of area A separated by distance 'd' between them. It is filled
with a dielectric which has a dielectric constant that varies as k(x) = K(1 + αx) where 'x' is the
distance measured from one of the plates. If (αd) <<1, the total capacitance of the system is best
given by the expression :

(A)

(B)

(C)

(D)

19) A wire of length L is bent into a semi-circular arc. If the two equal halves of the arc were one
side to be uniformly charge +Q and another side to be uniformly charge –2Q, the net electric field at
the centre O of the semi-circular arc would be (where ε0 is the permittivity (in SI units) of free

space),

(A)

(B)

(C)

(D) None of these

20) In wheat stone's bridge shown in the adjoining figure galvanometer gives no deflection on

pressing the key, the balance condition for the bridge is :-

(A)

(B)

(C)

(D)

SECTION-II

1) A point charge Q and an electric dipole of dipole moment P are placed as given in figure. The

force on dipole due to point charge is . The value of N is :-

2)

In the circuit shown in figure equivalent capacitance across AB is (all capacitance in μF)

3) Adjoining figure shows a conductor carrying a current i. The magnitude of magnetic field at the

origin is . Find value of K.

4) Two identical capacitors are charged to E = 1 Volt and then connected to a battery of the same
EMF of 1 Volt as shown in figure (1). After steady state the capacitor with less charge is replenished
to voltage E = 1 Volt again. This capacitor and the other are connected as in figure (2) (such that the
positive terminal of the battery is connected to the negative plate of the capacitor with a larger
magnitude of charge.) What is the final potential drop (in Volts) across the capacitor that carries a
higher charge after a long time?

5) In the given figure if α > β, then the net electric field will be in the direction :

CHEMISTRY

SECTION-I

1)

The donor sites of (EDTA)4– are ?

(A) O atoms only

(B) N atoms only
(C) Two N atoms and four O atoms
(D) Three N atoms and three O atoms

2) Co-ordination number of platinum [Pt(NH3)4Cl2]2+ ion is :

(A) 4
(B) 2
(C) 8
(D) 6

3) The formula of complex tris (ethylenediamine) cobalt (III) sulphate is :

(A) [Co(en)2SO4]
(B) [Co(en)3SO4]
(C) [Co(en)3]2SO4
(D) [Co(en)3]2(SO4)3
4) In which of the following coordination entities, the magnitude of Δ0 will be maximum ?

3–
(A) [Co(CN)6]
3–
(B) [CoF6]
3+
(C) [Co(H2O)6]
3+
(D) [Co(NH3)6]

5) Effective atomic number of [V(CO)6] is 35, hence it is less stable. It attains stability by

(A) Oxidation of V
(B) Reduction of V
(C) Oxidation & reduction
(D) Both (2) & (3)

6) The two compounds pentaamminesulphatocobalt (III)bromide and

pentaamminesulphatocobalt(III) chloride represent :

(A) Linkage isomerism

(B) Ionization isomerism
(C) Co-ordination isomerism
(D) No isomerism

7) The number of hydroxyl (OH) group present in phosphorus acid is :

(A) One
(B) Two
(C) Three
(D) Four

8) Ratio of σ & π bond in P4O10 is :-

(A) 4
(B) 3
(C) 2
(D) 1

9) Which of the following is not known

(A) NCl5
(B) NI3
(C) SbCl3
(D) NCl3

10) Correct order of spin only magnetic moment of the following complex ions is:
(Given At. No. Fe: 26, Co:27)
(A)
(B)
(C)
(D)

11)

Correct IUPAC name of given compound is

(A) 3-Methylcyclohexanecarbaldehyde
(B) 3-Methylcyclohexanal
(C) 5-Methylcyclohexane carbaldehyde
(D) 3-Methylcyclohexanol

12) IUPAC name of is:

(A) 4–Bromo–6–chloro–2–ethyl–1–methylcyclohex–1–ene
(B) 5–Bromo–1–chloro–3–ethyl–2–methylcyclohex–2–ene
(C) 5–Bromo–3–chloro–1–ethyl–2–methylcyclohex–1–ene
(D) 1–Bromo–5–chloro–3–ethyl–4–methylcyclohex–3–ene

13) Find out correct order of acidity of the following compounds :-

(A) R > Q > P > S

(B) P > Q > R > S
(C) R > Q > S > P
(D) P > S > Q > R

14) The most basic nitrogen in the following compound is

(A) I
(B) II
(C) III
(D) IV

15) 10 gm of is dissolved in water to make 100 ml soution. It is kept in 30 cm

polarimeter tube. It produced an optical rotation of –3.6º. Calculate [α] specific angle of rotation for

under identical circumstances of temperature.

(A) –12º
(B) +12º
(C) 0
(D) –36º

16) Which of the following is correct fisher projection of following Newman's projection

(A)

(B)

(C)
(D)

17) Correct order of leaving group nature is :

(A) F > Cl > Br >I

(B) H2O > H2S

(C)

(D)

18) Which one of the following has maximum nucleophilicity in P.P. solvent?

(A)

(B)

(C) Et3N
(D)

19) Product ; Product is :

(A)

(B)

(C)
(D)

20)
X and Y are respectively :

(A)

(B)

(C)

(D)

SECTION-II

1) The number of S–S bonds in sulphur trioxide trimer (S3O9) is _________

2)
X is highly poisonous gas with rotten fish smell. It is absorbed in mercuric chloride solution to form
HgaPb. What is the value of (a + b)

3) How many hydrides of group no: 15 have higher boiling point more than ammonia?
PH3, ASH3, SbH3, BiH3

4)

In the given reaction :

Total number of possible alkenes formed will be :

5) If total number of alkenes possible by dehydrobromination of 3-bromo-3-cyclopentylhexane using

alcoholic KOH is x then value of is

MATHEMATICS

SECTION-I

1) If then x is equal to -

(A)

(B)

(C)

(D)

2) has the value equal to -

(A) e–1/12
(B) e–1/6
(C) e–1/4
(D) e–1/3

3) The value of the limit is equal to :

(A)

(B)

(C) 0
(D)

4) If the function ƒ defined on by is continuous, then k is equal

to

(A)

(B) 1

(C)

(D) 2

5) Let the function f, g and h be defined as follows -

,
and h(x) = |x|3 for –1 ≤ x ≤ 1
Which of these functions are differentiable at x = 0 ?

(A) f and g only

(B) f and h only
(C) g and h only
(D) None of these

6) Let α and β be real numbers. Consider a 3 × 3 matrix A such that A2 = 3A + αI. If A4 = 21A +
βI, then

(A)
(B)
(C)
(D)

7) If A is a 3 × 3 matrix and |A| = 2, then is equal to

(A) 311 . 610

(B) 312 . 610
(C) 310 . 611
(D) 312 . 611

8) If , , C = ABAT and X = ATC2A, then det X is equal to :

(A) 243
(B) 729
(C) 27
(D) 891

9) If , then is equal to (where I is identity matrix)

(A)

(B)

(C)

(D)

10)

(A)

(B)

(C)

(D)

11) is equal to (where C is an arbitrary constant)

(A)

(B)

(C)

(D) – sin2x + C

12) If = ln(f(x)) + g(x) + C where C is the constant of integration and f (x)

is positive, then f (x) + g (x) can be

(A) ex + sin x + 2x
(B) ex + sin x
(C) ex – sin x
(D) ex + sin x + x

13) Let f(x) = x +3 ln(x – 2) & g(x) = x + 5 ln(x - 1), then the set of x satisfying the inequality f'(x) <
g'(x) is -

(A)

(B)

(C) (2, ∞)

(D)

14) If y = , then the value of dy/dx is -

(A)

(B)

(C)

(D)

15) If AAT = I (where I is an identity matrix) and det(A) = 1, then -

(A) Every element of A is equal to it's co-factor.

(B) Every element of A and it's co-factor are additive inverse of each other.
(C) Every element of A and it's co-factor are multiplicative inverse of each other.
(D) None of these

16)
(where C is an arbitrary constant)

(A)

(B)

(C)

(D) None of these

17) equals -
(where C is an arbitrary constant)

(A)

(B)

(C)

(D)

18) equals-
(where C is an arbitrary constant)

(A)

(B)

(C)

(D)

19) Let P(x) be a quadratic polynomial such that P(1) = –1 , if

where C is constant of integration and f(x) is a rational function such that then the
absolute value of f(1) is :

(A) 1
(B) 2
(C) 3
(D) 4

20) If f(x) = f(0) = 0 then the value of f(1) is :

(A)

(B)

(C)

(D)
 SECTION-II

1) If then x is _____.

2) If f is a real-valued differentiable function satisfying |f(x) – f(y)| ≤ (x – y)2, ∀x,y ∈ R and f(0) = 0,
then f(1) equals

3) The matrix is not invertible then the value of 'a' is

4) Let f(x) = dx. If = –4, then [–f(1)] is equal to, where [x] is greatest integer
function

5) Let the matrix A and B be defined as and then the absolute value of
Det.(2A9B–1), is -
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C B D C D A C A D A B B B D A D A A B B

SECTION-II

Q. 21 22 23 24 25
A. 3.00 9.00 4 1.75 2.00

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C D D A B D B A A A A C A C C B C A B A

SECTION-II

Q. 46 47 48 49 50
A. 0.00 5.00 2.00 6.00 12.50

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D A A A C D A B A C B B D C A A A A B A

SECTION-II

Q. 71 72 73 74 75
A. 1985.00 0.00 1.00 1.00 2.00
 SOLUTIONS

PHYSICS

1) Conceptual

2)

3)
Hence work done by one battery will be + and other will be – & since
(work by battery 1) + (work by battery) + ΔU ¹ 0

4)

∴ 1V

5) Now
if C =
Ceq = 3C
ΔC = 3C – C
% ΔC = 200%

6)

7) Electric field on axis of ring

for maximum electric field

8) mA (30) = S [10 – mA]

S= = 1.5 mΩ

9) R = =

R1 : R2: R3 = : :

= : : = : :
= 25 × 5 : 15 : 1
= 125 : 15 : 1
10) No current in bulb 4, 5 and 6.

11)

12) As electric field is in y-direction so electric flux is

only due to top and bottom surface
Bottom surface y = 0
⇒E=0⇒ϕ=0
Top surface y = 0.5 m

⇒ E = 150 (.5)2 =

Now flux ϕ = EA =

By Gauss’s law

× 10–11 C
Option (2)

13) By using formula for finite length wire

B= (sinθ1 + sinθ2)

At point P, due to horizontal part B = 0 & due to vertical part B =

14)

15)

16)

flux =

17) W = q ΔV = q0(VQ – VP)

0 0
= – q (VP – VQ) = – q 2Kλ ℓn

0
= 2Kλq ℓn

18) As K is variable we take a plate element of Area A and thickness dx at distance x

Capacitance of element
Now all such elements are is series so equivalent capacitance

19)

20) For zero deflection.

21)

Force on dipole due to point charge is same as force on point charge due to dipole so
so N = 3

22)

23)

Where

(Since, wire 3 passes through origin)

24)

Let the battery supply a charge q. By KVL:

Hence one capacitor gets a final charge of and the other is replenshed. In the next
 circuit, let the battery supply a charge q'

Final charge

25)

Since α > β, field due to upper part of the line charge will be greater than field due to lower
part. So vertical component will be in – direction and horizontal component for both the parts
is in ( ) direction. So resultant will be in direction.

CHEMISTRY

26)

(EDTA)4– have two N-atoms and 4 O-atoms as donor

27)

NH3, Cl– → monodentate ligand

Hence coordination number of Pt = 6

28)

[Co(en)3]3+ SO42–
Hence formula = [Co(en) ] (SO )
3 2 4 3

29) Gernally chelation effect is more dominant as compair to strength of ligand but absent in
presence of synergic bonding.

30)

[V(CO)6] + e– → [V(CO)6]–
EAN = 35 EAN = 36
31)

32)

The structure contains two P – OH bonds

33)

Number of σ - bonds = 16
Number of π - bonds = 4
σ/π = 4

34) NCl5 is not known because of absence of d-orbitals in nitrogen.

35) → Fe3+ - d5 F– → WFL, 5 unpaired electron

→ Co3+ - d6 F– → WFL, 4 unpaired electron
→ Co3+ - d6 0 unpaired electron

36)

3-methylcyclohexanecarbaldehyde

37) Lowest locant rule is followed.

38) Acidic strength stability of anion formed after removal of H+

39)

Basicity of N-atom having localised LP is greater than that of N-atom which has delocalised LP.

40)

(C) Meso comp. is optically inactive

41)

42)

Leaving group ability ∝ Stability of conjugate base Leaving group order :

> >

44)

45) Question Explanation:

Question is asking the major elimination products obtained by two different bases.

Concept:
In E2 elimination β-H removed by strong base.

Solution:
Highly crowded base (like t-BuOK or Et3COK) prefers removal of less hindered β-H while
normal or small size bases prefer removal of most hindered β-H in order to get the most stable
alkene.
Final Answer:
The correct option is (1)

46)

No S - S bonds in S3O9

47)

X = PH3, Y = NaH2PO2
PH3 + HgCl2 → Hg3P2 + HCl
a = 3, b = 2 ⇒ a + b = 5

48) The melting point increases upto arsenic and then decreases upto bismuth.

49)
 50) Question Explanation:
Question is asking for the total alkenes formed in the given reaction.

Concept:
This question is based on E2 elimination reaction.

Solution:
Number of E2 elimination products depend upon type of β-H and stereoisomers of product.

Total number of alkenes (x) = 5

Final Answer:
The correct answer is 12.5

MATHEMATICS

51)

∴
∴

52)

53)

54) ∴ function should be continuous at

55)
D.N.E.

56)
57)

58)

Now C = ABAT ⇒ det(C) = (dct (A))2 x det(B)

Now |X| = |ATC2A|

= |AT| |C|2 |A|
= |A|2 |C|2
= 9 × 81
= 729

59)

60)

61)
62)

= ℓn(ex + sinx + x) –x + C

63)

f(x) = x + 3 ln (x – 2) this is valid if x > 2 ... (1)

g(x) = x + 5 ln (x – 1) this equation is valid if x > 1 ... (2)
differentiate f(x) w.r.t. x

…(3)
& differentiate g(x) w.r.t. x

g′(x) ... (4)

ATθ f′(x) < g′(x) ⇒

from equation (1), (2) & (5)

64)
Take log and differentiate

65) AAT = I
(AAT)T = IT
A . AT = I ⇒ every element of A is equal to its co-factor.

66)

67)
let 1 + log |x| = t

68) ;

let

69)
f(x) is rational function.
B = D = 0 and P(x) = λ (2x – 3) (3x –2)
P(1) = – l = – 1 ⇒ λ = 1

=|f (1)| = 2
70)

71)

L.H.S.

72)
|f′(y)| ≤ 0;
⇒ f′(y) = 0;
⇒ f(y) = constant
as f(0) = 0;
⇒ f(y) = 0;
⇒ f(1) = 0

73)

Step 1: ( singular matrix does not posses inverse matrix)

Step 2: If matrix A is not invertible,
74) Let 3 – x2 = t2
+x dx = –t dt

f(x) =

f(x) =

75) then obtain 2A9 . B–1 = C and |C| = –2