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SOIL
ANALYSIS
in
FORENSIC
TAPHONOMY
Chemical and Biological Effects
of
Buried Human Remains
Edited by
Mark Tibbett and David O. Carter
This book contains information obtained from authentic and highly regarded sources. Reprinted
material is quoted with permission, and sources are indicated. A wide variety of references are
listed. Reasonable efforts have been made to publish reliable data and information, but the author
and the publisher cannot assume responsibility for the validity of all materials or for the conse‑
quences of their use.
Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced,
transmitted, or utilized in any form by any electronic, mechanical, or other means, now known or
hereafter invented, including photocopying, microfilming, and recording, or in any information
storage or retrieval system, without written permission from the publishers.
For permission to photocopy or use material electronically from this work, please access www.
copyright.com (http://www.copyright.com/) or contact the Copyright Clearance Center, Inc. (CCC)
222 Rosewood Drive, Danvers, MA 01923, 978‑750‑8400. CCC is a not‑for‑profit organization that
provides licenses and registration for a variety of users. For organizations that have been granted a
photocopy license by the CCC, a separate system of payment has been arranged.
Trademark Notice: Product or corporate names may be trademarks or registered trademarks, and
are used only for identification and explanation without intent to infringe.
RA1063.47.S65 2008
363.25‑‑dc22 2007045309
M.T.
D.O.C.
Preface vii
Editors ix
Contributors xi
Index 317
vii
one third from the last decade of the twentieth century. We hope that this
book will provide a solid foundation for forensic taphonomists, anthropolo-
gists, soil scientists, entomologists, bacteriologists, and mycologists who aim
to use the processes of cadaver decomposition in terrestrial ecosystems to
solve crime.
Mark Tibbett
David O. Carter
ix
xi
Andrew S. Wilson
Archaeological Sciences
School of Life Sciences
University of Bradford
Bradford, West Yorkshire
United Kingdom
Takashi Yamanaka
Forestry and Forest Products Research
Institute
Ibaraki, Japan
Contents
1.1 Introduction................................................................................................... 1
1.2 Nature of Soils Relevant to Forensic Soil Science and Human
Decomposition Processes............................................................................. 3
1.3 Brief History of Forensic Soil Science......................................................... 4
1.4 Soil Origin, Classification, and Distribution............................................. 6
1.5 Spatial Scale and Pedogenic Processes..................................................... 10
1.6 Relationship between Soil Type and Scale: Regional and Global..........11
1.7 Most Favored Techniques Used by Forensic Soil Scientists....................11
1.7.1 Theory of Making Comparisons between Soil Samples............ 12
1.7.2 Approaches and Methods for Making Comparisons
between Soil Samples..................................................................... 12
1.7.2.1 Soil Color.......................................................................... 13
1.7.2.2 Soil Consistence...............................................................14
1.7.2.3 Soil Texture...................................................................... 15
1.7.2.4 Soil Structure................................................................... 20
1.7.2.5 Segregations and Coarse Fragments............................ 20
1.8 Petrographic and Other Advanced Techniques and Instruments....... 21
1.9 Conclusions.................................................................................................. 25
References............................................................................................................... 25
1.1 Introduction
Soils mean different things to different people. Soil scientists view soils as
being made up of differently sized mineral particles (i.e., sand, silt, and clay)
and organic matter. They have complex biological, chemical, physical, and
mineralogical properties that are always changing with time. Agronomists,
farmers, and gardeners, on the other hand, see soil as a medium for growing
crops, pastures, and plants primarily in the top 50 cm of the earth’s surface.
Engineers regard soil as material to build on and excavate and are usually con-
cerned primarily with moisture conditions and the ability of soil to become
compacted to support structures. However, some people regard soil as dirt or
mud because it makes them “dirty” when they make contact with it.
What do soils do for us? Soils provide a physical and chemical setting
for gases, nutrients, and water. They also exchange heat for living organ-
isms. In fact, biological activity, diversity, and productivity depend on the
specific properties of soil. Soils also distribute surface water, causing runoff
or infiltration, storage, and deep drainage. Consequently, water and solute
flow on the earth’s surface is primarily controlled by soils. Soil acts as sinks
and filters, reducing contaminants that affect the quality of water and other
resources. It also provides many construction materials (e.g., bricks) and is
the foundation for urban and recreational facilities. In addition, soils are
usually involved in the burial of human, animal, or plant remains in cem-
eteries or special kinds of landfills. Large-scale cadaver or plant decomposi-
tion processes are typically associated with such burial facilities. According
to Dent, Forbes, and Stuart (2004) the discussion of human decomposition
in soils has been largely untreated in detail, and the fragments available are
often incomplete. The application of approaches and methods developed in
pedology now are recognized by microbiologists, archaeologists, and foren-
sic scientists as crucial to the understanding of human decomposition pro-
cesses, burial site location, and questions relating to soil taphonomy.
Pedology (from the Greek pedon = soil) is the soil science discipline
concerned primarily with understanding the variety of soils and their dis-
tribution and is most directly concerned with the key questions concern-
ing sampling, descriptions, and interpretations of soils from crime scenes.
Pedologists are primarily interested in the way the five soil forming factors
(i.e., parent material, climate, topography, organisms, and time) affect the
properties of present and past (paleopedology) soils in both its natural and
disturbed state. Soil surveyors, on the other hand, are interested in describing
and classifying soils (using different National and International Soil Classifi-
cations Systems) and then mapping them, usually on aerial photographs with
the aid of remote sensing techniques and geographic information systems
(GIS). Forensic soil scientists (or forensic geologists) are more specifically
concerned with disturbed or moved soils (usually by human activity) and
sometimes with comparing them to natural soils or by matching them with
soil databases to help locate the scene of crimes. Forensic soil scientists usu-
ally obtain soil samples from crime or polluted scenes and nearby suspected
control sites from which soil may have been transported, by vehicle, foot,
or shovel. Soil properties are diverse, and this diversity may actually enable
forensic soil scientists to use soils as evidence with more certainty in crimi-
nal and environmental investigations.
No standard forensic soil examination method exists. The main reasons for
this are that examination of soil is concerned with detection of both (1) natu-
rally occurring soils (e.g., minerals, organic matter, soil animals, included
rock fragments); and (2) manufactured materials in soils such as ions and
fragments from different anthropogenic environments (e.g., synthetic fertil-
izers with nitrate, phosphate, and sulfate; artifacts or objects containing lead
from glass, paint chips, asphalt, brick fragments, cinders) whose presence
may impart soil with characteristics that will make it unique to a particular
location. In addition, fine soil material may often only occur in small quanti-
ties, especially in the examination of materials from (1) the crime scene such
as in Figure 1.1a, which shows a very small amount of yellowish-gray soil
adhering to a suspects shoe, and (2) the control site such as in Figure 1.1b,
which shows the complex diversity and in homogeneity of the soil sample
from the bank of a river (Fitzpatrick, Raven, and Forrester 2007). The yellow-
ish-gray soil at the control site comprises a mixture of 95% coarse gravel and
rock fragments and only 5% clay and silt (< 50 µm fraction).
On a Prussian railroad in April 1856, a barrel that contained silver coins was
found on arrival at its destination to have been emptied and refilled with
sand. A soil scientist acquired samples of sand from stations along lines of
railway and used a light microscope to match the sand to the station from
which the sand must have come (Science and Art 1856). This is arguably the
Figure 1.1 A systematic approach to discriminate soils for forensic soil exami-
nations using soil morphology (e.g., thickness, color, consistency, texture, struc-
ture), organic matter, mineralogy, geochemistry (e.g., spectroscopy, magnetic
susceptibility analyses), and wet chemical techniques (x-ray diffraction, XRD;
inductively coupled plasma spectroscopy mass spectroscopy, ICP-MS; Fourier
transform infrared spectroscopy, FTIR; nuclear magnetic resonance, NMR; dif-
ferential thermal analysis, DTA; thermogravimetric analysis, TGA; differential
scanning calorimetry, DSC; cation exchange capacity, CEC. (From Fitzpatrick,
R. W., Raven, M., and McLaughlin, M. J., in R. W. Fitzpatrick (ed.), Proceedings
of the First International Workshop on Criminal and Environmental Forensics,
http://www.clw.csiro.au/cafss/, May 2006. With permission.)
very first documented case where a forensic comparison of soils was used to
help police solve a crime.
Then in 1887 Sir Arthur Conan Doyle (Doyle 1981, p. 22) published sev-
eral fictional cases involving Sherlock Holmes such as “A Study in Scarlet” in
Beeton’s Christmas Annual of London, where Holmes can “tell at a glance dif-
ferent soils from each other … has shown me splashes upon his trousers, and
told me by their color and consistence in what part of London he had received
them.” In 1891 in “The Five Orange Pips,” Holmes observed, “chalk-rich soil”
on boots. This clearly indicates that Conan Doyle (Doyle 1981, p. 217) was
well aware of the key soil morphological properties (e.g., color and consis-
tence) and soil mineralogy (e.g., chalk) in forensic soil comparisons. For the
first time, as stated in Murray and Tedrow (1975), forensic scientist George
Popp successfully examined soil collected from clothing associated with
the murder of a seamstress named Eva Disch. Several recent reviews cover-
ing mainly “forensic geology” have been compiled by Ruffell and McKinley
(2004) and Murray (2004). The issue of human decomposition processes in
soils and the need to take into account the knowledge of soil environmental
factors have been reviewed by several researchers (e.g., Dent et al. 2004; Gar-
rison 2003; Spennemann and Franke 1995).
Forensic soil science is a relatively new activity that is strongly method
oriented because it is mostly a technique-driven activity in the multidisci-
plinary areas of pedology, geochemistry, mineralogy, molecular biology, geo-
physics, archaeology, and forensic science. Consequently, it does not have
an overabundance of past practitioners such as in the older disciplines like
physics and chemistry.
Pedology has two broad purposes: (1) to describe and classify; and (2) to inter-
pret soil differences with respect to their management or use requirements.
An appropriate definition of pedology is the area of earth science responsible
for the quantification of factors and processes associated with soil forma-
tion (Wilding 1994). This includes the analysis of quality, distribution, and
spatial variability of soils from micro- to megascopic scales (Wilding 1994).
This definition introduces the phrase “extent, distribution, spatial variabil-
ity, and interpretation” in a general way. It is fair to presume, though, that
extent, distribution, spatial variability, and interpretation, for the pedologist,
includes primarily the descriptive aspects of the science—the field and labo-
ratory descriptions of soil attributes such as presence and degree of develop-
ment of particular soil features (e.g., soil color, mottling) and the interpretive
aspects of those attributes (e.g., soil in relation to drainage class or wetness).
This description and its interpretation can then be explained in relation to
the forensic comparison of soils. In addressing the questions, “What is the
soil like?” and “Where does it come from?” (i.e., provenance determination),
we are involved in studies relating to characterizing and locating the sources
of soils to make forensic comparisons.
The sophistication and effectiveness of soil classification reflects the level
of scientific maturity and an understanding of the particular area of study
(Simonson 1959). A major aim of classification is to usefully summarize the
natural variability of forms the entity takes and to enhance communication
about that entity. However, soil classification may stimulate or may discour-
age scientists with an interest in soils.
If a classification system proves to be relevant and user friendly, it stimu-
lates and encourages further work because it is recognized for its inherent
capacity to create order and to enhance the useful understanding of soils (e.g.,
USDA 2003). This approach has provided numerous international soil scien-
tists with valuable conceptual understanding of soils in terms of textural dif-
ferentiation of profiles, the relative development of diagnostic horizons (e.g.,
gypsic, calcic, natric, argillic, oxic), subsoil color, and mottle differences.
Many of the concepts in soil classification also provided effective pedotrans-
fer functionality, particularly in terms of soil water attributes (e.g., Bouma
1989). If a soil classification is not useful it hinders transfer of information—
often because of the lack of distinct separation between classes, many soils
were inconsistently classified and distinguished, leading to conceptual con-
fusion and pointless argument of subtle differences. For example, many soil
classification systems are significantly biased toward agricultural soils, the
subject of study for most soil scientists. Consequently, many soils found in
nonagricultural environments are not suitably categorized because they do
not match the central classification concepts (Fitzpatrick et al. 2003).
Soil classification systems are important tools within the context of the
forensic comparison of soils. They are our attempts to bring conceptual order
into the complex world of soils and to allow knowledge gained in one loca-
tion to be used in another, given that we are transferring that knowledge to
similar soil conditions with similar properties. The great variety of soils and
climates makes classification a major task even if soils were changing. To
appreciate the scale of the task we have to recognize that: soils are chang-
ing (e.g., due to erosion, salinization, disturbance, and oxidation of acid sul-
fate soils), their evolutionary history is only partially understood, and they
are used for a range of purposes, all with unique requirements in relation to
soil function and land use. The demands on soil classification are therefore
so diverse that they cannot be satisfied by a single system at any point in
time or for any part of the world. Changes in classification will be made with
advances in data collection, storage, and processing, but their value depends
on how easily class groups can be interpreted in relation to soil functions and
processes. A sound basis for interpreting soils and their use in forensic soil
comparisons resides in an improved understanding of soil processes and the
interpretation of these from soil morphology in soil landscapes.
Soil formation, or pedogenesis, is a major activity for pedologists. The
origins of soil attributes, distinctive horizons, and profiles must be under-
stood to develop conceptual models for soil evolution over both long and
short time periods (e.g., Smeck, Runge, and MacKintosh 1983). Such models
have intuitive, predictive power in the forensic comparison of soils.
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