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TEST (EQUILIBRIUM)
DATE :- 23/07/25
TIME 1.5 hrs
SECTION-1 | Type A
TEN
This section contains Siiis{@6) questions. Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of
these four options is the answer. For each question, choose the option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks +3 IFONLY the correct option is chosen;
Zero Marks 0 Ifnone of the options is chosen (Le. the question is unanswered);
Negative Marks | :-1 In all other cases.
‘ld)
For a reversible change in a closed system doing non-expansion work,
() dU = Tds-pdv
(\) dU in a process is independent of path in both reversible and irreversible process for a given
system.
(Ill) For reversible dQ = Tds but dQ = Tds in irreversible process.
(IV) AG < ©, the criteria for spontaneity applies at constant P, T.
Which of the above statements are correct?
(a), Ul (8) 1, WV
Ol (O11, tv
2)
Which of the following are incorrect?
(I) BH, and BeH, both have banana bonds
(II) Single N—N bond is weaker than P-P bond
(II) Solubility order of Sulphate BaSO, < MgSO, 0 when aniline is mixed with phenol
(IV) Entropy change in process depend on heat enthalpy and temperature
(A), HUN, IV (8) I, i, IV
(C) 1m, (0) Hi, II
4.)
Two moles of an ideal monoatomic gas undergoes
a cyclic process ABCA as shown in the figure.
What is the ratio of temperature at B and A?
3 Po
(@) 121 (b) 3;
(c) 27:4 (d) 9:
Vo
2
2 5.)
Which of the following species is not having perfect octahedron structure?
(a) XeF, (b) Sif?
(©) PCle (d) Xeog
6) cc
+ “Hybridisation of central atom does not always change due to back bonding”. This statement is
valid for v" ‘ch of the following compounds ?
@ cdl; qi) cc, Giii) (SiH1,)20 (iv) N(SiH3)3
@ @, Gi &) @, Gi) © @, Gd @ all
7)
Which of the following molecule has weakest (px —dx) back bonding?
(@) ocl, (b) N(SiH)5 (© SiF, (d) O(SiH3).
8.)
What is the heat capacity of the ideal monoatomic
gas undergoing the process shown in the
figure?
P (atm)
2 V (in L)
(a) 1.5R (b) 2.5R
(c) 3.5R (d) 1.33R
9)
The equation of state for one mole of a gas is
PV=RT+ BP, where B is a constant, independent
of temperature. The internal energy of fixed
amount of gas is the function of temperature
only. If one mole of the above gas is isothermally
expanded from 12 L to 22 Lat a constant external
pressure of 1 bar at 400 K, then the change in
enthalpy of the gas is approximately (B = 2 L/mol)
(a) 0 (b) -3.32J
(c) -332J (d) -166 3 10.)
From the following data, calculate the enthalpy
change (in kJ/mol) for the combustion of
cyclopropane(g) at 298 K. The enthalpy of
formation of CO,(g), H,O(I) and propene(g)
are —394, -286 and 20 kJ/mol, respectively. The
enthalpy of isomerization of cyclopropane(g) to
propene(g) is —33 kJ/mol.
(a) —2073 (b) —2093
(c) —2060 (d) —2027
SECTION-1 | Type B
sevi
‘hs secon contains SBS) questns. Each qlsion hes FOUR options (, (), (Can (©). ONE OR
MORE THAN ONE of these four option(s) is (are) correct answer's).
For each question, choose the option(s) corresponding to (al the correct answer(s)
‘Answer to each question will be evaluated according to the following marking scheme:
Full Marks, +4 tfonly (all) the correct option(s) is(are) chosen:
Partial Marks: +3 Ifallthe four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct;
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option;
Zero Marks 0 ifunanswered;
Negative Marks :-2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers,
then
choosing ONLY (A), (8) and (D) will get +4 marks; choosing ONLY (A) and (0) will get +2 marks;
choosing ONLY (A) will get +1 mark:
choosing no option(s) (ie. the question is unanswered) will get 0 marks and
choosing any other option(s) will get -2 marks.
1)
Which of the following are correct?
(A)
(B)
©
(@)
R
When 2 moles of an ideal gas (cv = &) is heated from 300 K to 600 K at constant pressure,
change in entropy of gas is SRIn2
An ideal gas undergoes a change in state as shown in figure, Work done for process A ~ B and A ~
C will be equal
U = constant
Entropy change when an ideal gas expands isothermally is positive
Entropy change is positive for an adiabatic free expansion of an ideal gas, Yaa)
fall bond angles in AX molecule are the same, then which of the following conclusions is correct about
AX;?
a) AX
(B) AX must be planar
nust be polar
(©) AXgmust have at least 5 valence electrons
©) _X must connect from central atom with either single bond or double bond. 3.)
In thermodynamics, the P-V work done is given by
Ex faw = -fav Part
For a system undergoing a particular process, the work done is,
RT a
Ez: [dw =-[av| ~—-=
= j J (= b v2 }
This equation Ez is not applicable to a :
(A) System that satisfies the van der Waal’s equation of state
(B) Process that is irreversible and isothermal
(C) Process that is irreversible and isobaric
(D) Process that is reversible and adiabatic
4.)
The standard enthalpies of formation of CO2(g) and HCOOH () are ~393.7 kJ mot and —409.2 kJ mol-t
respectively at standard conditions. Some statements are given related to the given information. Which of
the following statement(s) is/are correct?
(A) Enthalpy change for the reaction C(s) + O2(g) > COa(g) is (-393.7) kJ mole’, where C(s) is graphite
solid
(B) Enthalpy change for the reaction CO2(g) + Ha(g) +» HCOOH()) is (~15.5) kJ mob?
(C) Enthalpy change for the reaction H20(g) + CO(g) -» HCOOH(|) is (-409.2) kJ mol
(D) Enthalpy change for the reaction Ha(g) + CO2(g) + HeO(l) + CO(g) is (-409.2) kJ mol-!
5)
We are given with some order with respect to some properties indicated in bracket. Identify which order(s)
isfare correct,
(A) NHs > NFs (dipole moment) (B) H2O2 > O2F2 ((- 0 = 0 ~) bond length)
(C) PF2Cls > PFaClz (dipole moment) (D) Fe > Cle > Bre > le (bond energy)
6)
A volume of 100 ml of 0.5 N-H,SO, solution is
neutralized with 200 ml of 0.2 M-NH,OH in
a constant pressure calorimeter which resulted
1.4°C rise in temperature. The heat capacity of
the calorimeter system is 1.5 kJ/°C. Some useful
thermochemical equations are as follows:
HCI + NaOH —> NaCl + H,0 + 57 kJ
CH,COOH + NH,OH > CH,COONH, + H,0 +
48.1 kJ
Which of the following statements are correct?
(a) Enthalpy of neutralization of HCl vs. NH,OH
is -52.5 kJ/mol.
(b) Enthalpy of dissociation (ionization) of
NH,OH is 4.5 kJ/mol.
(c) Enthalpy of dissociation (ionization) of
CH,COOH is 4.6 kJ/mol.
(d) AH for 2H,O(l) > 2H*(aq) + 20H” (aq) is
114 kJ. From the following data at 25°C, which of the
following statement(s) is/are correct?
Y4H,(g) + 20,(g)> OH(g): AH® = 42 kJ
H,(g) + %20,(g) > H,O(g): AH® = —242 kJ
H,(g) > 2H(g): AH® = 436 kJ
O,(g) >20(g): AH® = 495 kJ
(a) A,H° for the reaction H,O(g) > 2H(g) + O(g)
is 925.5 kJ.
(b) A,H® for the reaction OH(g) > H(g) + O(g) is
502 kJ.
(c) Enthalpy of formation of H(g) is —218 kJ/mol.
(d) Enthalpy of formation of OH(g) is 42 kJ/mol.
TEN aueteengn?
© This section contains ~THREE—(0a)-Raragraphe ‘There _are TWO (02)_questions-corresponding-to-Bach
Paragraph. The answer to each question is a NUMERICAL VALUE. For each question, enter the correct.
numerical value of the answer. If the answer is a decimal numerical value, then round-off the value to
TWO decimal places. If the answer is an Integer value, then do not add zero in the decimal places. In the
OMR, do not bubble the @ sign for positive values. However, for negative values, © sign should be
bubbled. (Example: 6, 81, 1.50, 3.25, 0.08)
‘© Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct Integer value is entered. There is NO negative marking.
Tero Marks: _ 0 Inall other cases.
1)
The total number of compounds having at least one bridging oxo group among the molecules given
below is
N2Os, NeOs, ClO7, HsP3O10, H2S207, PaOs, HeS2Os, HoN2O2
2)
Consider the following compounds in their liquid form
No, HCI, OF 2, NFs, F2Oz, CFs, CHF, CeHsCl, CoHsCle (para-isomer), CeH«Cle (meta-isomer),
cl cl
1
©. ; oe + CO, . CH,Cl,
cl cl cl
When a charged comb is brought near their flowing stream, how many of them show deflection as per
the following figure?
°6 iT 3.)
The figure below is the plot of potential energy versus internuclear distance (d) of Hz molecule in the
electronic 1 excited state. The magnitude of the net potential energy Eo (as indicated in the figure) in
kJ/mol is ‘K’ x 108, for d = do at which the electron-electron repulsion and the nucleus-nucleus repulsion
energies are absent. Find the value of K. As reference, the potential energy of H atom is taken as zero
when its electron and the nucleus are infinitely far apart. [Use : Na = 6 x 10% molt}
t
ui
a
E,
4)
Tin is obtained from cassiterite by reduction with coke. Use the data given below, if the minimum
temperature (in K) at which the reduction of cassiterite by coke would take place is ‘x’, then ia is
At 298K: AiH°(SnO2(s)) = — 670.0 kJ mot"
AH*(COZ(s)) = ~ 314.0 kJ mol
S*(Sn0,(s)) = 66.0 JK-' mot
's*(Sn(s)) = 58.0 JK mot
s*(C(s)) = 4.0JK' mol"
S*(COxAS))_— = 190.0 JK" mor
Assume that the enthalpies and the entropies are temperature independent.
5.)
A closed tank has two compartments A and B, both filled with He (assumed to be an ideal gas). The
partition separating the two compartments is fixed and is a perfect heat insulator. If the old partition is
replaced by a new partition which can slide and conduct heat but does not allow the gas to leak across,
the volume (in m4) of the compartment A after the system attains equilibrium is :- (Round off to nearest
integer)
2m’, 5 bar 6m’, 2 bar
800 K 600 K
A B
Initial
A * * B
6)
1 mole of an ideal gas initially present in a 2L insulated cylinder at 300 K is allowed to expand
against vaccum to 8 L, then |AG,,, in calories will be [In2 = 0.7] 7)
+ Total number of species among following, in which bond angle is equal to or less than 109°28'
and also they act as lewis base :
NH3, NMe, O(SiH)2, ICl;, XeO3, BF,Cl, SiF,, ASH, SO ,F,
8)
Consider the following species
O(Me) 2, N(SIH5)3, CO, O(SIH 3), CCl, (Singlet), CCl; , H SiO ,, OCl,, MeNCS
Then calculate total number of species which have (p, ~ p,
bond. ) back bond or (p, —d,) back
9)
» Consider the following compounds:
@ IF Gi) Cy (ii) Xe0,F, (iv) NH3
(v) BC, (vi) BeCly (vii) ASCL; (viii) BOOK) g
(ix) NOZ () ClO}
Then, calculate value of “x + y—2” ,here x,y and z are total number of compounds in given
compounds in which central atom used their all three p-orbitals, only two p-orbitals and only
one p-orbital in hybridisation respectively =
10.)
. Total number of species which has/have symmetrical electronic distribution in their HOMO
and also paramagnetic.
N3,0},Cz,03,B2,C3,N2
