Date : 20/08/2025

Bm sir Chapter : 1 & 2

Time : 1 hours Std 11 : Chemistry Total Marks : 65

Mcq

Section A

Choose the correct option. (1 Úke 65 «§ku) [65]

1. °C = °F will be at which temperature?

(A) 40 °C (B) -40 °C (C) 41.25 °C (D) -41.25 °C

2. 0.15 A° = ________ nm
(A) 0.15 (B) 0.015 (C) 1.5 (D) 150

3. 1 amu = ________ gm.

(A) 1.66056 x 1024 (B) 1.66056 x 1022 (C) 1.66056 x 10–24 (D) 1.66056 x 10–22

4. Which of the following are isotopes of carbon?

(A) C11, C15, C16 (B) C12, C16, C18 (C) C12, C14, C20 (D) 12C, 13C, 14C

5. An empirical formula mass of CH2Cl is…. (C=12, H=1, Cl=35.5)

(A) 49.48 gm (B) 40.48 gm (C) 48.49 gm (D) 49.48 kg

6. What would be the mass of 3.01 x 1021 oxygen atoms?

(A) 16 gm (B) 0.16 gm (C) 0.16 amu (D) 16 amu
sir
7. Amount of oxygen in 32.2 g of Na2SO4 ⋅ 10H2O is:
(A) 2.24 (B) 22.5 (C) 18.0 (D) 16
Bm

8. Mass percent of carbon in methanol is….

(A) 38.50 (B) 32.50 (C) 37.50 (D) 32.25

9. Calculate the mass percent of Zn in ZnSO4 7H2O. (Zn = 65, S = 32, O = 16, H = 1 g.mol–1)
(A) 22.65% (B) 32.56% (C) 33.65% (D) 23.65%

10. Calculate the mass percent of H in methanol (CH3OH).

(A) 12.10% (B) 12.5% (C) 21.5% (D) 12.60%

11. Balance the equation: KClO3 → KCl + O2

(A) KClO3 → 3KCl + 6O2 (B) 2KClO3 → 2KCl + O2

(C) 2KClO3 → 2KCl + 3O2 (D) 2KClO3 → KCl + 4O2

12. Balance the equation: Na2CrO4 + H+ → Na2Cr2O7 + Na+ + H2O

(A) 2Na2CrO4 + 2H+ → 2Na2CrO7 + 2Na+ + 2H2O

(B) Na2CrO4 + 2H+ → Na2CrO2O7 + Na+ + H2O

(C) 2Na2CrO4 + 4H+ → 2Na2Cr2O7 + Na+ + H2O

(D) 2Na2CrO4 + 2H+ → Na2Cr2O7 + 2Na+ + H2O

13. How many grams of CO2(g) will be produce by combustion of 24 g methane gas?
(A) 60 g (B) 65 g (C) 66 g (D) 61 g

14. What volume of 96% H2SO4 solution (density 1.83 g/mL) is required to prepare 2 litres of 3 M H2SO4 solution?
(A) 334.82 ml (B) 343.7 ml (C) 3.347 ml (D) 33.47 ml

15. N2(g) + 3H2(g)  2 NH3(g) 28 gm 6 gm ?

(A) 43 (B) 24 (C) 34 (D) 42

Page No.: 1
16. How much CaO will be formed by decomposition of 200 Kg CaCO3 with 95% purity?
(A) 60 kg (B) 109 kg (C) 106 kg (D) 190 kg

17. A hydrated of iron (III) thiocyanate [Fe (SCN)3 ⋅ mH2O], was found to contain 19% water by mass, then m = ____.
(A) 7 (B) 3 (C) 4 (D) 2

18. The total of mole-fraction of all components of the solution will be ___________
(A) 0 (B) 100 (C) 1 (D) 1000

19. x Cu2S + yO2 → Cu2O + SO2, What will be the value of x and y to balance this equation?
(A) x = 3, y = 2 (B) x = 4, y = 2 (C) x = 2, y =3 (D) x = 2, y = 2

20. What amount of oxygen is required for complete combustion of 2.8 kg ethene (C2H4)? (C = 12, H = 1, O = 16 g⋅mol–1)
(A) 9.6 kg (B) 6.4 kg (C) 96 kg (D) 2.8 kg

21. Reaction of liquid benzene (C6H6) is as below: 2C6H6(l) + 15O2(g) → 12CO2(g) + 6H2O(g)
What volume of O2 is required for complete combustion of 39 gm liquid benzene at STP?
(A) 11.2 L (B) 22.4 L (C) 84 L (D) 74 L

22. If 30 mL H2 and 20 mL O2 form H2O on mixing, then what will be left after the reaction?
(A) 5 mL O2 (B) 10 mL H2 (C) 5 mL H2 (D) 10 mL O2

23. What will be the normality of mixture on mixing 10 mL 0.2 N HCl, 40 mL 0.3 N HNO3 and 50 ml 0.5 N H2SO4?
(A) 0.54 N (B) 0.39 N (C) 0.44 N (D) 0.24 N

24. For the reaction A + 2B → C, 5 moles of A and 8 moles of B will produce how much C?
(A) 8 (B) 4 (C) 5 (D) 16

25. The balanced chemical equation for the combustion of methane is…
(A) CH4(g) + O2(g) → CO2(g) + H2O(g) (B) CH4(g) + O2(g) → CO(g) + H2O(g)
sir
(C) CH4(g) + 2O2(g) → CO2(g) + 2H2O(g) (D) None of the given

26. 6.02 × 1022 molecules of urea are present in 200 mL of its solution. The concentration of urea solution is…
Bm

(A) 50 M (B) 0.5 M (C) 0.1 M (D) 0.02 M

27. is the formula of ….

(A) Molarity (M) (B) Molality (m)

(C) Volume percent (% w/v) (D) Mole fraction (X)

28. If the mass ratio of H2 and O2 is 1:4 in a gaseous mixture, what will be the mole ratio of the mixture?
(A) 4:1 (B) 16:1 (C) 2:1 (D) 1:4

29. The highest number of helium atoms is in

(A) 4 u of helium (B) 4 g of helium
(C) 2.271098 L of helium at S.T.P. (D) 4 mole of helium

30. One molal solution contains 0.5 mol of solute where ________.
(A) 100 ml of solvent (B) 1000 g of solvent
(C) 500 ml of solvent (D) 500 g of solvent

31. The quantity which changes with temperature is :

(A) Molality (B) Molarity (C) Mole fraction (D) Mass percentage

32. Which of the given pairs of isotones for mass number (A) and atomic number (Z)?
(A) (i) A = 30, Z = 15, (ii) A = 31, Z = 14 (B) (i) A = 31, Z = 15, (ii) A = 30, Z = 14
(C) (i) A = 32, Z = 15, (ii) A = 30, Z = 14 (D) (i) Z = 31, Z = 16, (ii) Z = 32, Z = 14

33. Write the unit of frequency.

(A) s–1 (B) s–3 (C) s–2 (D) s–4

34. _________ is called the inverse of the wavelength.

Page No.: 2
 (A) Amplitude (B) Velocity (C) Frequency (D) Wavenumber

35. _________ is called the crest height or trough depth of the wave.
(A) Amplitude (B) Wavenumber (C) Frequency (D) Velocity

36. The wavelength of yellow light radiation is 5800 Ao. So find its wave number (write.)
(A) 1.724 × 104 cm–1 (B) 1.724 × 10–4 m (C) 1.724 × 10–4 m–1 (D) 1.724 × 10–8 m

37. If the threshold wavelength for removing an electron from a metal is 470 nm, what is its work function for photo-electric emission? (Velocity
of electrons = 6.4 × 104 ms–1)
(A) 1.2 × 10–18 J (B) 6 × 10–12 J (C) 6 × 10–19 J (D) 4.2 × 10–19 J

38. What is the value of the maximum wavelength of emission in Balmer series?
(A) 565.5 nm (B) 364.7 nm (C) 656.5 nm (D) 556 nm

39. If the frequency of ultraviolet light is 12 × 1016 s–1, find its wavelength. (c = 3 × 108 m s–1) ?
(A) 2.5 × 10–9 m (B) 4.5 × 10–10 m (C) 3.5 × 10–11 m (D) 1.5 × 10–9 m

40. Find the energy of a photon of radiation having a frequency of 6.67 × 1014 Hz.
(A) 4.42 × 10–12 J (B) 4.42 × 10–19 J (C) 4.42 × 10–17 J (D) 4.42 × 10–25 J

41. One Einstein = J mol–1 photon–1 for a photon of radiation of wavelength 400
(A) 2.99263 × 1012 (B) 2.99263 × 106 (C) 2.99263 × 105 (D) 2.99263 × 1014

42. Which of the following radiations has maximum wavelength?

(A) UV (B) Radio waves (C) X-rays (D) IR rays

43. Energy associated with wave-number 10 cm–1 = ----------------

(A) 19.9 × 10–23 J photon–1 (B) 28.6 × 10–3 k cal mol–1 photon–1
sir
(C) 120 × 10–3 kJ mol–1 photon–1 (D) All of the given

44. What will be the maximum number of emission lines when an electron enters the ground state from n = 6?
Bm

(A) 15 (B) 6 (C) 16 (D) 2

45. Write the relationship between a photon’s energy (E) and its frequency (v).
(A) E = hv (B) E = (C) E = (D) E =

46. What is the number of orbitals with same energy in a single orbit in a molecule other than hydrogen?
(A) n2 (B) n (C) 2l + 1 (D) None of these

47. What is h in the de-Broglie equation?

(A) Wavelength (B) mass of the particle
(C) Planck’s constant (D) Velocity of the particle

48. Write an equation that expresses the relationship between the wavelength (λ) and the velocity (p) of a de-Broglie particle.
(A) l = (B) l = (C) l = (D) l =

49. State the mass of a photon of wavelength 3.6 Ao.

(A) 61.35 × 10–10 kg (B) 61.35 × 1019 (C) 6.135 × 10–29 kg (D) 6.135 × 10–19 kg

50. State Heisenberg’s uncertainty principle in mathematical form.

(A) Dx × Dp ≤ (B) Dx × Dp ≥ (C) Dx × Dp = (D) Dx × Dp >

51. What would be the mass of a photon of wavelength 3.6 Ao?

(A) 6.135 × 10–33 gm (B) 6.135 × 10–33 kg (C) 6.135 × 10–26 gm (D) 6.135 × 10–62 kg

52. If an electron travels a distance equal to its wavelength in one second, how fast will it be rotating?
(A) (B) (C) (D)

53. What is the maximum number of electrons that can be filled in a p-orbital?

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 (A) 36 (B) 12 (C) 72 (D) 6

54. Which of the given quantum number orbitals will the electron fill first?
(A) n = 3, l = 1 (B) n = 3, l = 2 (C) n = 3, l = 0 (D) n = 2, l = 1

55. Which of the given energy giving orbitals with which quantum number will the electron be removed first?
(A) n = 4, l = 0 (B) n = 3, l = 2 (C) n = 3, l = 1 (D) n = 2, l = 1

56. What is the number of radial (spherical) nodes in any orbit?

(A) n – 1 (B) l (C) n – l – 1 (D) n + l

57. Which of the given electron configuration for d-orbital is incorrect?

(A) (B) (C) (D)

58. Which of the following rules for electron configuration of p-orbital is incorrect?

(A) Pauli’s Exclusion Principle (B) Hund’s Maximum Multiplicity Rule

(C) Aufbau’s Principle (D) All of the above

59. What is the number of angular nodes in any orbital?

(A) n – 1 (B) l (C) n – l – 1 (D) n + 1

60. For which of the given orbitals the probability of finding an electron in the xy surface is 0?
(A) 2px (B) 2pz (C) 2py (D) 3dxy

61. For which of the given orbitals the probability of finding an electron in the xy surface is not ‘0’?
(A) 3dzx (B) 3dyz (C) 2pz (D) 3dxy

62.
sir
Which of the following cannot be explained by the quantum numbers n, l and m?
(A) Orbit-No (B) Doublets, triplets etc. found in the spectrum
(C) Orbital type (D) The given trio cannot be explained
Bm

63. Which of the given quantum number electrons will be filled last?
(A) n = 4, l = 0, m1 = 0 (B) n = 3, l = 2, m1 = +1
(C) n = 3, l = 0, m1 = 0 (D) n = 3, l = 1, m1 = – 1

64. What would be the minimum possible atomic number of an element with four electrons in ground state m1 = +1?
(A) 18 (B) 14 (C) 12 (D) 16

65. If all the orbitals between the nucleus and O orbit are completely filled with electrons, for how many of these electrons will S = + ?
(A) 60 (B) 30 (C) 32 (D) 16

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 Date : 20/08/2025
Bm sir Chapter : 1 & 2
Time : 1 hours Std 11 : Chemistry Total Marks : 65

Answer Key

Section A

Choose the correct option. (1 Úke 65 «§ku) [65]

1. °C = °F will be at which temperature?

(A) 40 °C (B) -40 °C (C) 41.25 °C (D) -41.25 °C

 Ans. (B)
 -40 °C

2. 0.15 A° = ________ nm
(A) 0.15 (B) 0.015 (C) 1.5 (D) 150

 Ans. (B)
 0.015
 1 A° = 1 × 10–10 m
∴ 0.15 A° = 0.15 × 10–10 m
here now, 1 m = 109 nm
0.15 × 10–10 m = ?
∴ 0.15 × 10–10 × 109
= 0.15 × 10–1
= 0.015 nm

3. 1 amu = ________ gm.

(A) 1.66056 x 1024 (B) 1.66056 x 1022 (C) 1.66056 x 10–24 (D) 1.66056 x 10–22

 Ans. (C)
 1.66056 x 10–24

4. Which of the following are isotopes of carbon?

(A) C11, C15, C16 (B) C12, C16, C18 (C) C12, C14, C20 (D) 12C, 13C, 14C

 Ans. (D)
 12
C, 13
C, 14C

5. An empirical formula mass of CH2Cl is…. (C=12, H=1, Cl=35.5)

(A) 49.48 gm (B) 40.48 gm (C) 48.49 gm (D) 49.48 kg

 Ans. (A)
 49.48 gm

6. What would be the mass of 3.01 x 1021 oxygen atoms?

(A) 16 gm (B) 0.16 gm (C) 0.16 amu (D) 16 amu

 Ans. (B)
 0.16 gm
 mass of 6.022 × 1023 O2 molecules = 32 gm.

\ 3.01 × 1021 O2 molecules = = 16 g. × 10–2

7. Amount of oxygen in 32.2 g of Na2SO4 ⋅ 10H2O is:

Page No.: 1
 (A) 2.24 (B) 22.5 (C) 18.0 (D) 16

 Ans. (B)
 22.5
 molar mass of Na2SO4 ⋅ 10H2O = 322 gm.
322 g Na2SO4 ⋅ 10H2O = 14 (16) g oxygen
\ 32.2 gm N2SO4 ⋅ 10H2O = ?

\ = 22.4 g oxygen

8. Mass percent of carbon in methanol is….

(A) 38.50 (B) 32.50 (C) 37.50 (D) 32.25

 Ans. (C)
 37.50

9. Calculate the mass percent of Zn in ZnSO4 7H2O. (Zn = 65, S = 32, O = 16, H = 1 g.mol–1)
(A) 22.65% (B) 32.56% (C) 33.65% (D) 23.65%

 Ans. (A)
 22.65%
 use formula

Mass percent of element =

10. Calculate the mass percent of H in methanol (CH3OH).

(A) 12.10% (B) 12.5% (C) 21.5% (D) 12.60%

 Ans. (B)
 12.5%
 molar mass of methanol is 32 g mol–1
Mass percent of H in methanol
= × 100 = 12.5%

11. Balance the equation: KClO3 → KCl + O2

(A) KClO3 → 3KCl + 6O2 (B) 2KClO3 → 2KCl + O2

(C) 2KClO3 → 2KCl + 3O2 (D) 2KClO3 → KCl + 4O2

 Ans. (C)
 2KClO3 → 2KCl + 3O2

12. Balance the equation: Na2CrO4 + H+ → Na2Cr2O7 + Na+ + H2O

(A) 2Na2CrO4 + 2H+ → 2Na2CrO7 + 2Na+ + 2H2O

(B) Na2CrO4 + 2H+ → Na2CrO2O7 + Na+ + H2O

(C) 2Na2CrO4 + 4H+ → 2Na2Cr2O7 + Na+ + H2O

(D) 2Na2CrO4 + 2H+ → Na2Cr2O7 + 2Na+ + H2O

 Ans. (D)
 2Na2CrO4 + 2H+ → Na2Cr2O7 + 2Na+ + H2O

13. How many grams of CO2(g) will be produce by combustion of 24 g methane gas?
(A) 60 g (B) 65 g (C) 66 g (D) 61 g

 Ans. (C)
 66 g
 as per equation
CH4(g) + O2(g) → CO2(g) + 2H2O(g)

Page No.: 2
 1 mol 1 mol
16 g 44 g
\ 24 g (?)
\ = 66(g) CO2

14. What volume of 96% H2SO4 solution (density 1.83 g/mL) is required to prepare 2 litres of 3 M H2SO4 solution?
(A) 334.82 ml (B) 343.7 ml (C) 3.347 ml (D) 33.47 ml

 Ans. (A)
 334.82 ml

Molarity =

= = 17.92

Now, M1V1 = M2V2

∴ 17.92 × V1 = 3 × 2000

∴ V1 =

= 334.82 mL

15. N2(g) + 3H2(g)  2 NH3(g) 28 gm 6 gm ?

(A) 43 (B) 24 (C) 34 (D) 42

 Ans. (C)
 34

16. How much CaO will be formed by decomposition of 200 Kg CaCO3 with 95% purity?
(A) 60 kg (B) 109 kg (C) 106 kg (D) 190 kg

 Ans. (C)
 106 kg
 100% → 112 kg
∴ 95% → (?)
(Moles of CaCO3 and CaO are same)

17. A hydrated of iron (III) thiocyanate [Fe (SCN)3 ⋅ mH2O], was found to contain 19% water by mass, then m = ____.
(A) 7 (B) 3 (C) 4 (D) 2

 Ans. (B)
 3
 molar mass of [Fe (SCN)3 ⋅ mH2O]
= 1 (Fe) + 3 [1(S) + 1(C) + 1(N)] + 18m
= 1 (56) + 3 [32 + 12 + 14] + 18m
= 230 + 18m

Now, mass % of H2O =

19 =
∴m=3

18. The total of mole-fraction of all components of the solution will be ___________
(A) 0 (B) 100 (C) 1 (D) 1000

 Ans. (C)
 1

19. x Cu2S + yO2 → Cu2O + SO2, What will be the value of x and y to balance this equation?
(A) x = 3, y = 2 (B) x = 4, y = 2 (C) x = 2, y =3 (D) x = 2, y = 2

Page No.: 3
 Ans. (C)
 x = 2, y =3

20. What amount of oxygen is required for complete combustion of 2.8 kg ethene (C2H4)? (C = 12, H = 1, O = 16 g⋅mol–1)
(A) 9.6 kg (B) 6.4 kg (C) 96 kg (D) 2.8 kg

 Ans. (A)
 9.6 kg
 C2H4 + 3O2 → 2CO2 + 2H2O
28 gm 96 gm
∴ 2.8 gm = (?)
∴

21. Reaction of liquid benzene (C6H6) is as below: 2C6H6(l) + 15O2(g) → 12CO2(g) + 6H2O(g)
What volume of O2 is required for complete combustion of 39 gm liquid benzene at STP?
(A) 11.2 L (B) 22.4 L (C) 84 L (D) 74 L

 Ans. (C)
 84 L
 from the equation
2 mol benzene = 15 mol O2
∴ 0.5 mol benzene = 3.75 mol O2
Now, volume of 1 mol O2 at STP = 22.4 L
∴ volume of 3.75 mol O2 at STP = ?

= = 84 L

22. If 30 mL H2 and 20 mL O2 form H2O on mixing, then what will be left after the reaction?
(A) 5 mL O2 (B) 10 mL H2 (C) 5 mL H2 (D) 10 mL O2

 Ans. (A)
 5 mL O2
 (from the equation 2H2 + O2 → 2H2O)
2 mL H2 reacts with 1 mL O2
∴ 30 mL H2 will react with 15 mL O2
∴ the volume of O2 left after the reaction
= 20 – 15 = 5 mL O2

23. What will be the normality of mixture on mixing 10 mL 0.2 N HCl, 40 mL 0.3 N HNO3 and 50 ml 0.5 N H2SO4?
(A) 0.54 N (B) 0.39 N (C) 0.44 N (D) 0.24 N

 Ans. (B)
 0.39 N
 N1V1 + N2V2 + N3V3 = NxVx
\ 0.2 × 10 + 0.3 × 40 + 0.5 × 50 = N × 100
\ 2 + 12 + 25 = N × 100
\ N = 0.39

24. For the reaction A + 2B → C, 5 moles of A and 8 moles of B will produce how much C?
(A) 8 (B) 4 (C) 5 (D) 16

 Ans. (C)
 5
 5 moles of C will obtain because A is limiting reagent.

25. The balanced chemical equation for the combustion of methane is…
(A) CH4(g) + O2(g) → CO2(g) + H2O(g) (B) CH4(g) + O2(g) → CO(g) + H2O(g)

Page No.: 4
 (C) CH4(g) + 2O2(g) → CO2(g) + 2H2O(g) (D) None of the given

 Ans. (C)
 CH4(g) + 2O2(g) → CO2(g) + 2H2O(g)

26. 6.02 × 1022 molecules of urea are present in 200 mL of its solution. The concentration of urea solution is…
(A) 50 M (B) 0.5 M (C) 0.1 M (D) 0.02 M

 Ans. (B)
 0.5 M
 6.022 × 1023 urea molecules = 1 mole urea
\ 6.02 × 1022 urea molecules = ?

\ moles of urea = = 10–1

Now, molarity = × 1000 = 0.5 M

27. is the formula of ….

(A) Molarity (M) (B) Molality (m)

(C) Volume percent (% w/v) (D) Mole fraction (X)

 Ans. (D)
 Mole fraction (X)

28. If the mass ratio of H2 and O2 is 1:4 in a gaseous mixture, what will be the mole ratio of the mixture?
(A) 4:1 (B) 16:1 (C) 2:1 (D) 1:4

 Ans. (A)
 4:1


29. The highest number of helium atoms is in

(A) 4 u of helium (B) 4 g of helium
(C) 2.271098 L of helium at S.T.P. (D) 4 mole of helium

 Ans. (D)
 4 mole of helium

30. One molal solution contains 0.5 mol of solute where ________.
(A) 100 ml of solvent (B) 1000 g of solvent
(C) 500 ml of solvent (D) 500 g of solvent

 Ans. (D)
 500 g of solvent

m = nB ×

1 = 0.5 ×

WA = 500 g

31. The quantity which changes with temperature is :

(A) Molality (B) Molarity (C) Mole fraction (D) Mass percentage

 Ans. (B)
 Molarity

32. Which of the given pairs of isotones for mass number (A) and atomic number (Z)?
(A) (i) A = 30, Z = 15, (ii) A = 31, Z = 14 (B) (i) A = 31, Z = 15, (ii) A = 30, Z = 14
(C) (i) A = 32, Z = 15, (ii) A = 30, Z = 14 (D) (i) Z = 31, Z = 16, (ii) Z = 32, Z = 14

Page No.: 5
 Ans : (B)
 (i) A = 31, Z = 15, (ii) A = 30, Z = 14

33. Write the unit of frequency.

(A) s–1 (B) s–3 (C) s–2 (D) s–4

 Ans : (A)
 s–1

34. _________ is called the inverse of the wavelength.

(A) Amplitude (B) Velocity (C) Frequency (D) Wavenumber

 Ans : (D)
 Wavenumber

35. _________ is called the crest height or trough depth of the wave.
(A) Amplitude (B) Wavenumber (C) Frequency (D) Velocity

 Ans : (A)
 Amplitude

36. The wavelength of yellow light radiation is 5800 Ao. So find its wave number (write.)
(A) 1.724 × 104 cm–1 (B) 1.724 × 10–4 m (C) 1.724 × 10–4 m–1 (D) 1.724 × 10–8 m

 Ans : (A)
 Wave number ( )
( )=

= 1.724 × 106 m–1

= 1.724 × 104 cm–1

37. If the threshold wavelength for removing an electron from a metal is 470 nm, what is its work function for photo-electric emission? (Velocity
of electrons = 6.4 × 104 ms–1)
(A) 1.2 × 10–18 J (B) 6 × 10–12 J (C) 6 × 10–19 J (D) 4.2 × 10–19 J

 Ans : (D)
 4.2 × 10–19 J
 KE = mv2

= (9.1 × 10–31)(6.4 × 104)2

= 1.86 × 10–21 J
Now E1 = KE + W0
\ W0 = E1 – KE

= – KE

= – 1.86 × 10–21

= 4.24 × 10–19 J

38. What is the value of the maximum wavelength of emission in Balmer series?
(A) 565.5 nm (B) 364.7 nm (C) 656.5 nm (D) 556 nm

 Ans : (C)
 656.5 nm
 For the Balmer series,

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 lmax =

= 6.565 × 10–7 m
= 656.5 nm

39. If the frequency of ultraviolet light is 12 × 1016 s–1, find its wavelength. (c = 3 × 108 m s–1) ?
(A) 2.5 × 10–9 m (B) 4.5 × 10–10 m (C) 3.5 × 10–11 m (D) 1.5 × 10–9 m

 Ans : (A)
 2.5 × 10–9 m
 V=

l= =

= 0.25 × 10–8 m
= 2.5 × 10–9 m

40. Find the energy of a photon of radiation having a frequency of 6.67 × 1014 Hz.
(A) 4.42 × 10–12 J (B) 4.42 × 10–19 J (C) 4.42 × 10–17 J (D) 4.42 × 10–25 J

 Ans : (B)
 4.42 × 10–19 J
 E = hv
= 6.626 × 10–34 J s × 6.67 × 1014 s–1
= 44.19542 × 10–20

= 4.42 × 10–19 J

41. One Einstein = J mol–1 photon–1 for a photon of radiation of wavelength 400
(A) 2.99263 × 1012 (B) 2.99263 × 106 (C) 2.99263 × 105 (D) 2.99263 × 1014

 Ans : (B)
 2.99263 × 106
 One Einstein =

= 2.99263 × 106

42. Which of the following radiations has maximum wavelength?

(A) UV (B) Radio waves (C) X-rays (D) IR rays

 Ans : (B)
 Radio waves

43. Energy associated with wave-number 10 cm–1 = ----------------

(A) 19.9 × 10–23 J photon–1 (B) 28.6 × 10–3 k cal mol–1 photon–1
–3 –1 –1 (D) All of the given
(C) 120 × 10 kJ mol photon

 Ans : (B)
 28.6 × 10–3 k cal mol–1 photon–1

44. What will be the maximum number of emission lines when an electron enters the ground state from n = 6?
(A) 15 (B) 6 (C) 16 (D) 2

 Ans : (A)
 15
 Emitted linear maximum number =

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 =

= 15

45. Write the relationship between a photon’s energy (E) and its frequency (v).
(A) E = hv (B) E = (C) E = (D) E =

 Ans : (A)
 E = hv

46. What is the number of orbitals with same energy in a single orbit in a molecule other than hydrogen?
(A) n2 (B) n (C) 2l + 1 (D) None of these

 Ans : (C)
 2l + 1

47. What is h in the de-Broglie equation?

(A) Wavelength (B) mass of the particle
(C) Planck’s constant (D) Velocity of the particle

 Ans : (C)
 Planck’s constant

48. Write an equation that expresses the relationship between the wavelength (λ) and the velocity (p) of a de-Broglie particle.
(A) l = (B) l = (C) l = (D) l =

 Ans : (A)
 l=

49. State the mass of a photon of wavelength 3.6 Ao.

(A) 61.35 × 10–10 kg (B) 61.35 × 1019 (C) 6.135 × 10–29 kg (D) 6.135 × 10–19 kg

 Ans : (C)
 6.135 × 10–29 kg
 l = 3.6 = 3.6 × 10
–10
m
Photon velocity = Velocity of light
= 3.0 × 108 m s–1
l=

\m=

= 6.135 × 10–29 kg

50. State Heisenberg’s uncertainty principle in mathematical form.

(A) Dx × Dp ≤ (B) Dx × Dp ≥ (C) Dx × Dp = (D) Dx × Dp >

 Ans : (B)
 Dx × Dp ≥

51. What would be the mass of a photon of wavelength 3.6 Ao?

(A) 6.135 × 10–33 gm (B) 6.135 × 10–33 kg (C) 6.135 × 10–26 gm (D) 6.135 × 10–62 kg

 Ans : (B)
 6.135 × 10–33 kg
 l=

m=

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 =

= 0.6135 × 10–32

= 6.135 × 10–33 kg

52. If an electron travels a distance equal to its wavelength in one second, how fast will it be rotating?
(A) (B) (C) (D)

 Ans : (A)

 l= Here, l = υ

\υ=

υ2 =

\υ=

53. What is the maximum number of electrons that can be filled in a p-orbital?
(A) 36 (B) 12 (C) 72 (D) 6

 Ans : (C)
 72
 n = 6 for p-orbital
∴ Total orbitals = n2 = 36
∴ Total electron = 2n2 = 2(36) = 72

54. Which of the given quantum number orbitals will the electron fill first?
(A) n = 3, l = 1 (B) n = 3, l = 2 (C) n = 3, l = 0 (D) n = 2, l = 1

 Ans : (D)
 n = 2, l = 1
 According to Aufbau’s law, since the 2p-orbital has lower energy, the e– orbital will be filled first.

55. Which of the given energy giving orbitals with which quantum number will the electron be removed first?
(A) n = 4, l = 0 (B) n = 3, l = 2 (C) n = 3, l = 1 (D) n = 2, l = 1

 Ans : (A)
 n = 4, l = 0
 As the value of n is higher, the electron in this orbital is more distant from the nucleus and can be easily removed.

56. What is the number of radial (spherical) nodes in any orbit?

(A) n – 1 (B) l (C) n – l – 1 (D) n + l

 Ans : (C)
 n–l–1

57. Which of the given electron configuration for d-orbital is incorrect?

(A) (B) (C) (D)

 Ans : (B)


 According to Hund’s Law of Maximum Spin Multiplier.

58. Which of the following rules for electron configuration of p-orbital is incorrect?

(A) Pauli’s Exclusion Principle (B) Hund’s Maximum Multiplicity Rule

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 (C) Aufbau’s Principle (D) All of the above

 Ans : (B)
 Hund’s Maximum Multiplicity Rule

59. What is the number of angular nodes in any orbital?

(A) n – 1 (B) l (C) n – l – 1 (D) n + 1

 Ans : (B)
 l

60. For which of the given orbitals the probability of finding an electron in the xy surface is 0?
(A) 2px (B) 2pz (C) 2py (D) 3dxy

 Ans : (B)
 2pz

61. For which of the given orbitals the probability of finding an electron in the xy surface is not ‘0’?
(A) 3dzx (B) 3dyz (C) 2pz (D) 3dxy

 Ans : (D)
 3dxy

62. Which of the following cannot be explained by the quantum numbers n, l and m?
(A) Orbit-No (B) Doublets, triplets etc. found in the spectrum
(C) Orbital type (D) The given trio cannot be explained

 Ans : (B)
 Doublets, triplets etc. found in the spectrum

63. Which of the given quantum number electrons will be filled last?
(A) n = 4, l = 0, m1 = 0 (B) n = 3, l = 2, m1 = +1
(C) n = 3, l = 0, m1 = 0 (D) n = 3, l = 1, m1 = – 1

 Ans : (B)
 n = 3, l = 2, m1 = +1
 According to the (n + 1) rule

64. What would be the minimum possible atomic number of an element with four electrons in ground state m1 = +1?
(A) 18 (B) 14 (C) 12 (D) 16

 Ans : (B)
 14

65. If all the orbitals between the nucleus and O orbit are completely filled with electrons, for how many of these electrons will S = + ?
(A) 60 (B) 30 (C) 32 (D) 16

 Ans : (B)
 30

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