Sample Paper-02 Class 11th NEET (2024)

CHEMISTRY
ANSWER KEY
1. (2) 26. (2)
2. (2) 27. (3)
3. (2) 28. (4)
4. (1) 29. (1)
5. (1) 30. (3)
6. (2) 31. (2)
7. (3) 32. (1)
8. (2) 33. (4)
9. (1) 34. (4)
10. (2) 35. (1)
11. (1) 36. (1)
12. (4) 37. (4)
13. (3) 38. (4)
14. (2) 39. (2)
15. (1) 40. (4)
16. (4) 41. (2)
17. (2) 42. (4)
18. (1) 43. (3)
19. (4) 44. (4)
20. (1) 45. (1)
21. (2) 46. (4)
22. (4) 47. (3)
23. (4) 48. (3)
24. (4) 49. (3)
25. (3) 50. (3)
 HINTS AND SOLUTION
1. (2) 8. (2)
3Fe(s) + 4H2O(g) → Fe3O4(s) + 4H2(g) Bond order of O+2 (2.5) is more than that of
3 × 56g 4 × 18g
O2(2.0) and is also paramagnetic due to one
= 168g = 72g electron in antibonding molecular orbital.
72 g steam reacts with 168g of iron
18 g steam will react with 42g of iron 9. (1)
5 → 1 represents highest energy.
2. (2) Acidic Character increases with increase in
non-metallic character
10. (2)
The dipole moment of NF3 is less than NH3. In
3. (2)
F NH3 and NF3, the central atom nitrogen has three
σ bonds and one lone pair. Hence, both are sp3
Cl F hybridized and possess trigonal pyramidal shape.
In NH3 and NF3, the dipole moment vectors do not
F 3bp + 2l.p cancel out each other. Hence, both the molecules
are polar in nature. In NH3, the dipole moment
4. (1) vector of the bond and the lone pairs are in the
IF5 same direction. But in NF3, the dipole moment
1 vector of lone pairs and bond pairs are opposite in
H= [V + M – C + A] direction. So, the net dipole moment will be the
2
substractive effect of the two. Hence, the dipole
1
= [7 + 5 – 0 + 0] = 6 ⇒ sp3d2 moment of NH3 is larger than NF3.
2
F
F F
I N N
F F H F
H F

According to sp3d2 hybridisation, geometry will H F

be octahedral, however according to V.S.E.P.R
NH3 NF3
theory, the compound having 5b.p + 1l.p will
show square pyramidal shape. 11. (1)
Only NO– have unpaired electron.
5. (1)
h 12. (4)
Acc. to de-Broglie,  =
mv Equilibrium constant is independent of
nh concentration of reactant or product.
Put mv =
2r
13. (3)
Now, n = 2r
SF4  4.b.p + 1 lp ⇒ S ⇒ sp3d
1
6. (2) % d character =  100
CaCl2 + 2AgNO3 → 2AgCl + Ca(NO3)2 5
= 20%
4.31
moles of AgCl =
143.5 14. (2)
4.31 1 1
∴ mole of CaCl2 =  = 0.015
143.5 2 2
6 CH = CH — CH3
7. (3) 7 8
5 3
Both O22− and F2 have 18 electrons. 4
15. (1) 22. (4)
Enthalpy of formation is the same as the enthalpy
of reaction when 1 mole of product is formed.
O
Hence the enthalpy of formation of HCl(g) is − 22
H H kcal.
16. (4) 23. (4)
If bond energy of various bonds present in the
7N → 1s 2s 2p
2 2 3
reactants and product are given, then H of that
reaction can be calculate as follows: 8O → 1s22s22p4
I.E of N is greater than that of O due to presence
of half-filled atomic orbital.
17. (2)
For burning one mole of methane 880 kJ is 24. (4)
evolved. 2Al + 2NaOH + 6H2O → 2Na[Al(OH)4] + 3H2.
3.2
For moles of methane.
16 25. (3)
880 The structure of diborane is shown in the figure.
Heat evolved = = 176 kJ
5 The four-terminal hydrogen atoms and the two
176 kJ of heat is absorbed boron atoms lie in one plane. Above and below
this plane, there are two bridging hydrogen atoms.
18. (1)
3 The four-terminal B-H bonds are regular two
S(s) + O2(g) → SO3(g) + x kcals ….1 centre-two electron bonds while the two bridge
2
1 (B-H-B) bonds are different and can be described
SO2(g) + O2(g) → SO3(g) + y kcals …..2 in terms of three centre - two e bonds. The
2
Subtract equation 2 from 1 terminal hydrogens do not lie in the same plane as
S + O2 → SO2 + (x – y)k cals the boron hydrogen banana bonds. Each B atom
uses sp3 hybrids for bonding. Out of the four sp3
19. (4) hybrids on each B atom, one is without an
For isothermally process ΔE = 0 electron shown in broken lines.
H H H H H
20. (1) H
The salt of strong acid and strong base does not B
B B B
undergo hydrolysis. So, only CH3COONa (strong
base+ weak acid) will undergo hydrolysis in water H
H H
and gives basic solution. H H H

21. (2) H
The expression for the pH of the acidic buffer H
H
solution is as given below. 120°
97° B
[salt] B
pH = pKa + log10 119 pm
[acid] 134 pm H
H
pH = 7 H
pKa = 5
The structure of dioborane B2H6
[salt]
7 = 5 + log10
[acid]
26. (2)
[salt]
log10 =2 Fluorine has highest electronegativity in
[acid]
periodic table.
[salt]
= 102 = 100
[acid]
27. (3) 36. (1)
When pressure is increased, the equilibrium will C2 = (σ 1s)2 < (σ* 1s)2 < (σ 2 s)2 < (σ * 2 s)2 <
shift to product side (which contains less number (π 2 px)2 = (π 2 py)2
of moles of gaseous species). This nullifies the
Bond order =
effect of increase in pressure. Hence, more and
more product will be formed. According to Le Number of electrons in bonding molecular orbital−
Number of electrons in anti- bonding molecular orbital
Chatelier's principle, when a system at
equilibrium is disturbed, the position of the 2
4
equilibrium shifts in a direction so that the effect Bond order = 8 − = 2
of the change is nullified. Low temperature 2
favours exothermic reaction. Heat is evolved
during the reaction (positive value of enthalpy 37. (4)
change). (a) CH3 – CH2 – CH2 – CH2 – NH2
NH2
28. (4) |
Hydrogen gas is used in the hydrogenation of oils (b) CH3 − CH 2 − CH − CH3
in the presence of Ni catalyst to give vanaspathi. CH3
By hydrogenation of oil, the unsaturated oils are |
converted to saturated vanaspathi. (c) CH3 − CH − CH 2 − NH 2
CH3
29. (1) |
Ionisation energy decreases on moving down (d) CH3 − C − NH 2
|
the group due to increase the distance between CH3
valance electron and nucleus.
(e) CH3-CH2-CH2-NH-CH3
30. (3) (f) CH3-CH2-NH-CH2-CH3
Ostwald's dilution law is valid for weak
CH3
electrolytes. |
(g) CH3 − CH − NH − CH 3
31. (2)
Initial  [OH–] = 10–2 M  pH = 12
0.04 CH3
Final  [OH–] = 10–2 + = 2 × 10–2 |
40  0.1 (h) CH3 − CH 2 − N − CH3
 pH = 12.3
So, change = 12.3 – 12 = + 0.3 The pairs (a) and (b) and (e) and (g) exhibit
position isomerism. The pairs (a) and (c); (a) and
32. (1)
Zeolites are aluminosilicates of sodium and (d); (b) and (c); (b) and (d) exhibit chain
potassium used in softening of hard water. isomerism. The pairs (e) and (f) and (f) and (g)
exhibit metamerism. All primary amines exhibit
33. (4) functional isomerism with secondary and tertiary
Amphoteric means species which can accept as amines and vice-versa.
well as lose H+.
38. (4)
34. (4) As  G   0 , the equilibrium constant K would
ClO3– and SO32– be less than 1 ( G  = − RT lnk).
Hybridization sp3 sp3
Both are pyramidal in shape. 39. (2)
According to VSEPR theory molecules with pH = 6, [H+] = 10–6
three bond pairs have trigonal planar pH = 4, [H+] = 10–4
geometry. Let volume = 1L
New [H+]
35 (1) 10–6 + 10 –4
=
M.wt 2
B.Pt  = 5.05×10–5
Branching pH = –log[H+] = 4.29
B. Pt ⇒ n-Pentane > iso-Pentane > neo-Pentane
40. (4) 45. (1)
CH2Cl Hybridization sp3 sp2 sp
Percentage s-character 25% 33.33% 50%
CH2Cl2 Percentage s-character α electronegativity

AlCl3 46. (4)

In Ne the atoms are held together by vander waals
AlCl3 forces.

47. (3)
H2 Conjugate acid is the protonated form of an anion
or any species which can take up a proton.
C
48. (3)
Molecules Hybridization Shape
(Diphenyl methane) PCl5 sp3d Trigonal
bipyramidal
41. (2) 3
+ SF4 sp d See saw
CH = CH2 is least stable because positive charge 3 2
is present on sp2 hybridized carbon and not getting XeF4 sp d Square planar
stabilized by inductive effect, hyperconjugation BF3 sp2 Trigonal
and resonance. planar
42. (4)
All three reagent except ammonical AgNO3 reacts 49. (3)
with 1, 2 and 4 compounds, the compounds 3 Zeff is higher, because the radius of the cation is
possessing the terminal alkyne only reacts with smaller than the radius of the neutral atom.
ammonical AgNO3 and thus can be distinguished
from 1, 2 and 4 compounds. 50. (3)
They have the same atomic number (17), the same
43. (3) number of electrons (17) and the same number of
The o-Nitrophenols and p-Nitrophenols are protons (17). They have different mass numbers
separated by steam distillation since o-isomer is (35 and 37) and different numbers of neutrons.
steam volatile due to intramolecular H-bonding 17Cl
35
has 35 − 17 = 18 neutrons whereas 17Cl37
while p-isomer is not steam volatile due to has 35 − 17 = 20 neutrons.
association of molecule by Intermolecular
H-bonding.

44. (4)
Since, ionic product of solution,
Ka.Kh = Kw
K
 Kh = w
Ka
Hydrolysis constant, Kh is inversely proportional
to Ka, i.e. more will be Ka less will be its
hydrolysis.
Here, Ka of HD is least (i.e. 4 × 10–10). So, it will
be most hydrolysed.

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