Student's Solution Copy [Code - 31552]

12th_ Batch 25(Astar A0 to A11Dhruv DA-Star) Anushasan 25ALA1 to 25ALA7_P-1_English _ [Mains

Pattern]
12th JEE (M) - Phase 1
KOTA

Date: 11-Aug-2025 Duration: 3 Hours Max Marks: 300

Maths - Section A

1. Answer: A 2. Answer: B

Sol: Sol:

Substitute u = tan(x) , then du = sec

2
dx
I= ∫
x(x−1)
dx
.
2 3 2
(x +1)(x+1)√x +x +x

The integral becomes du

. Multiply and divide by (x + 1)
I = 100
u(u +1)
2
x(x −1)
I = ∫ dx
Using partial fractions: 1
100
2
(x +1)(x+1) √x +x +x
2
3 2

u(u +1)
99

.
1 u 3 2
= − x (1−1/x )
u 100
u +1 I = ∫ 2
dx
1
3
x (x+1/x)(√x+ )
Integrating yields g(x)= ln(u)
√x

1
.
1
100
√x+
− ln(u + 1) x
+1
100

Reverting to gives
2
(1−1/x )
x g(x)= ln(tan(x))
I = ∫ dx :
.
1 100 1
− ln(tan (x) + 1) (x+1/x)(x+
x
+2)
100

As → ∞, the leading terms

√x+ +1
lim tan(x) x

π
x→
2

cancel and . Let x + + 1 = t2⇒(1 −

1 1
g(x)→ 0 )dx = 2 tdt
x x
2

Final Answer: 0
2 tdt dt dt
∫ 2 2
= ∫ [ 2
– 2
]
(t –1)(t +1)t t –1 t +1

1 t–1
= ℓn ∣ ∣ – tan–1 t + c
2
∣ t+1
∣

So, –1 –1 1
A = tan t= tan √x + + 1
x
3. Answer: C 6. Answer: A

Sol: Sol:

Given integral,
n n−1
dy nsec θtanθ+ncos θsinθ
(i) =
dx secθtanθ+sinθ

Let I = ∫ (x
3
− 2x
2
+ 5)e
3x
dx
dy ntanθ ( sec +cos
n n
θ)

dx
=
tanθ ( secθ+cosθ )
= ∫ x e
3 3x
dx − 2 ∫ x e
2 3x
dx + ∫ 5e
3x
dx
2 2 2n 2n
dy n ( sec θ+cos θ+2 )
3 3x
⇒ ( ) =
=
x e 2 3x 2 3x
−∫ x e dx −2 ∫ x e dx dx sec
2
θ+cos
2
θ+2
3
5 3x
+
3
e + C
Now x2 + 4 = sec2 θ + cos2 θ + 2 and y2
3 3x
+ 4 sec2n θ + cos2n θ + 2
=
x e 2 3x 5 3x
− 3∫ x e dx + e + C
3 3 2

∴ (x2 + 4) = x2(y2 + 4)
dy
3 3x ( )
= – x2e3x +∫ 2xe3x dx+ e3x +C
x e 5 dx

3 3

3 3x (ii) put t = tan θ

= – x2e3x + xe3x + e3x +C
x e 2 13

3 3 9
(iii) x2 + y2 = t − 1

t
Comparing with the given equation, we
get ⇒ x4 + y4 + 2x2y2 = t2 + 1
2
−2
t

A= , B = − 1, C = ;D=
1 2 13
⇒
3 3 9 ⇒ x4 + y4 + 2x2y2 = x4 + y4 − 2

Therefore, the correct answer is (C). x2y2 = −1 ⇒ y2 = −

1
2
t

4. Answer: D
⇒ x 3y
dy dy
2y dx = =1
2

Sol:
3
x dx

(iv) ϕ '(x) = f '(x) g(x) + g'(x) f(x)

Let
cosα +cosx+1
I = ∫ dx
cosα+cosx

ϕ ''(x) = 2f '(x) g '(x) + f''(x) g(x) +

Substitute u = tan
x

2
g''(x) f(x)

⇒ du =
1
sec
2 x
dx ϕ ''(x) = 2c + f ''(x) g(x) + g''(x) f(x)
2 2

1−u
2 divide the whole equation by ϕ (x).
2 ( cosα+ +1 )
2

7. Answer: B
u +1

⇒ I = du
2
1−u
2
( u +1 ) ( cosα+ )
u
2
+1
Sol:
2

⇒ 2∫
u cosα+cosα+2

2
du 2 cos 30° + 2√2 cos75° + 2cos120° + 0
( u +1 )

2 2
( u cosα+cosα−u +1 )
( √3−1 )
√3 1
= 2( − )+2√2
1 1 2 2
2√ 2
⇒ 2∫ du + 2 ∫ du
2 2
u ( cosα−1 ) +cosα+1 u +1

1 1
⇒ 2∫ +2 ∫ du
2 2
u ( cosα−1 ) u +1
( cosα+1 ) [ +1 ]
cosα+1

x a

∣ tan +cot ∣
2 2
⇒ cosecα[log∣ x a
∣] + x
tan −cot
∣ 2 2
∣

5. Answer: A
= 2(√3 − 1)= 2√3 − 2
Sol:

gof(x) = x
g'(f(x)) =
1

f '(x)

f'(1) = 5
f(1) = 6
−7

−7 1
g' ( ) =
6 5
8. Answer: B 10. Answer: B

Sol: Sol:
2
Let R(x) = ax + bx + c
1
x
(1+x) +e ( x−1 )
L : Lim −1
=
195 135 85 15 x→0 e (sin x)
x + x − x + x + 1
ln (1+x)

X
e +e ( x−1 )
=(x
3
− x)Q(x)+ ax
2
+ bx + c Lim
e⋅x
=
x→0
ln (1+x)

Put x = 0 e X
− 1
+ ( x−1 )
Lim
x
1=c x→0
ln (1+x) − x

=1+
e −1
put x = 1 Lim
x
x→0

a + b + c = 3 ⇒a + b = 2 Let
ln(1+x)−x
= p, as x → 0, p → 0
x
p
p
1+ =1 +
e −1
put x = –1, a – b = – 2 ∴ Lim
p
Lim
x
p→0 x→0

⇒ a = 0, b = 2, c = 1
= 1

∴ R(x) = 2x + 1 Lim
ln(1+x)−x
=1+ (
−1
) =
1
=L
2
x 2 2
x→0
∴ R(10) = 21. 2

M : f(x) = =
2 tan x
2
2 2

9. Answer: A
tan x+(2 tan x+3)

2
2
= 2
2
2

Sol: 1+(2tanx+3 cotx) 13+4 tan x + 9 cot x


min. value =12

A's equation : [As, 4 tan2x + 9 cot2 x = (2 tan

x – 3 cot x)2 + 12 ⇒ 4 tan2 x + 9 cot2 x
a(x + 2) = ax2 + ax + 3a
3 7
(x +
2
)
2
≥ 12]

Greatest value of f(x) = 13+12 = 25

2 2
∴
B's equation: b(x − 2) (x − 3) = bx2 −
5bx + 6b =M
Hence, (L + M–1) = 2 = =
1 25 26
+
But their constant term should be same
2 2

13. Ans. ]
So 3a = 6b

a = 2b

And B's coefficient of x2 is correct and A's

coefficient of x is correct.

So, the equation will be

bx2 + 7

2
ax + 6b

a = 2b

⇒ bx2 + 7bx + 6b = b(x2 + 7x + 6) =

b(x + 6)(x + 1)

∴ Roots will be − 6, and − 1

x1 +x2
P= = =
1 1 7
+ −
x1 x2 x1 x2 6

12P = 12 × = − 14
7
−
6

Absolute value = 14 Ans.

11. Answer: A 13. Answer: A

Sol: Sol:
xy f (x).f (y)
f( 2
) = 6
...(i) tan
−1 x
2
=tan−1 (
x
2
) − tan
−1
6x
3x +1 1−3x

−1 −1 x −1 x
Differentiating partially wrt 'y' tan 6x= tan
1−3x
2
− tan
3x +1
2

3 3
−1 3x +x−x+3x
xy = tan
f'( )
x
= 1 f(x).f'(y) (1−3x )(1+3x )
2 2

2 2 6
taking tan-1 of both sides :
xy f (x)
f'( 2
) = 3x
. f'(y) 3
3x +x−x+3x
3

6x = 2 2
(1−3x )(1+3x )

Put y = 2
1

f (x)
⇒ x = ±
f'(x) = f'(2)
√3
.
3x

Both values satisfy given equation

k.f (x)
f'(x)= (Let K =f'(2))
3x
∴ Sum of values = 0
f '(x)
= 3x
k

f (x)
Therefore, the correct answer is (A)

14. Answer: B
On integrating we get
Sol:
ln |f(x)|= lnx + lnc
k

3
4
e
k

⇒ln(f(x))=ln x3 .c I = ∫ √logx dx
e

⇒f(x)=x .c ...(ii) 3

On putting log(x)= t⇒ dx = 2 te
t
2

dt

Put x=1 in (ii), we get 2

2
t
k I = ∫ t (e . 2t) dt
f(1)=(1) 3
.c ⇒c=3 1

On integrating by parts taking t as first

k

∴ f(x) = x3 .3
function
Put x =1, f'(1) = k = 3⇒ k=3
2 2
2 2 2 2
t t x
I = ∣ ∣
3

∴ f(x) = .3=3x ∣t. e ∣ – ∫ e dt (∵ ∫ e dx = α)

x 3
1
1 1

f(1–x) = 3(1–x)=3 – 3x
I = 2e4 − e − α
∴ f(x) + (1–x) = 3
Therefore, the correct answer is (B)
Therefore the correct answer is (C)
15. Answer: B
12. Answer: B
Sol:
Sol: 3 x
I = ∫ √ dx
f(x) – f(x/2) = x/2
0 3−x

f(x/2) – f(x/4) = x/4 put 3 – x = t2

f(x/4) – f(x/8) = x/8 – dx = 2tdt

.....
2
0 √3−t
I = −∫ ⋅ 2 tdt
√3 t

adding all these,

√3
2
I = 2∫ √3 − t dt
0
x 1
f (x)−f ( n )= x(1 − n )
2 2
√3
t 2 3 −1 t
I = 2 ⋅ [ √3 − t + sin ]
2 2 √3
x 0
∴ lim (f (x)−f ( n ))= x
2
n→∞
3 π 3π
I = 2( ⋅ − 0)=
2 2 2
16. Answer: D 19. Answer: A

Sol: Sol:
2 cosx cosx
g (x) = f
−1
(x) But y = f (x) = (x + 1) p =
1−sin 2x
=
(cosx−sinx)
2

⇒ x = √y − 1
Domain = x ∈ R

so f
−1
(x) = √x − 1. h (x) = g (x + 3) −{x ∣ x = nπ +
π
, n ∈ I}
4

= √x + 3 − 1 . Now, in (
π
,
5π
), p → ∞ ,
4 4

17. Answer: A +

as
π
x →
4
Sol:
Also p → −∞
I =∫ (sin (100x + x) . sin
99
x) dx
−

as x →
5π

4
sin (100x) cosx
=∫
99
[( )](sinx) dx
∴ p ∈ R
+ cos 100x. sinx
99
= ∫ sin (100x) cosx. (sinx) dx + 20. Answer: A
 
I II Sol:
100
∫ cos (100x) . (sinx) dx
100
sin(100x)(sinx)
= –
100
100
+
100
∫ cos (100x) (sinx) dx
100
100
∫ cos (100x) (sinx) dx

100
sin(100x)(sin x)
= 100
+C
Let the vertices 'B' and 'C' lie on the
18. Answer: C 2√ 2
given line. Then, OD = = 2 ,
Sol:
√2

Equation of OD is
−∫
(x−1)
dx y = x ⇒ x = y = √2 (for point D)
(x+1)⋅x 1
√x+ +1

Also, BD = OD × tan 60° = √3 for

x
2

(Take x2 out of the radial sign from

the coordinates of B and C. Using
denominator as x)
1 1
parametric equation of line, we get
( 1− ) ( 1+ )
x x
dx
= −∫
1 1 x−√2 y−√2
(x+1)⋅ ( 1+ ) √x+ +1
x x
1
= 1
= ±2√3
−
1 √2 √2
( 1− ) dx
2
x
= −∫
1 1
( x+
x
+2 ) √x+
x
+1 ⇒ C =(√2 + √6, √2 − √6)

(Substituting x +
1

x
+ 1 = t ;
2

) and
1
(1 − 2
)dx = 2 tdt B = (√2 − √6, √2 + √6)
x

2t⋅dt −1
= −∫ =−2 tan t + C
2
( t +1 ) ⋅t

−1 1
= −2 tan √x + + 1 + C
x
 Maths - Section B

21. Answer: 6 23. Answer: 3

Sol: Sol:

A(x
4
+ x
3
+ 1)+(Bx + C)(4x
3
+ 3x )
2
g (f (x)) = x

4 3 2 h(g(x)) = x2 + 6x + 8
= 4x − 2x − 3x − 4

⇒ A = −4,B = 2,C = −1
⇒ h (x) = (f (x))2 + 6 (f (x)) + 8

3 2
dx
(2x−1) ( 4x +3x ) ⇒ f (x) = √h(x) + 1 − 3
f (x) =−4 ∫ +∫
4 3 3/2
√x +x +1 4
( x +x +1 )
3

(f (x) − √h(x) + 1 − 3 not possible

dx 4 dx
= −4 ∫ −+ ∫
√x +x +1
4 3 4
( x +x +1 )
3
1/2 because f(5) > 0)
′
h (x)
2(2x−1) ′
⇒ f (x)=
= − + c 2√h(x)+1
1/2
4 3
( x +x +1 )

′
h (3) 12
′
2(2×0−1)
⇒ f (3)= = = 3
F (0) = − + C 2√h(3)+1 2√3+1
0+0+1

2 = 2 + C 24. Answer: 7

C=0 Sol:
2(2×−1−1) Continuity at x = 2 gives
F (−1) =− +1
1/2
4 3
( (−1) +(−1) +1 )
1
64 ⋅ a + b =
−6 8
F(−1) = +1
1/2
( 1−1+1 )
Differentiability at x = 2 requires
F (−1) = −6
matching derivatives:

−3
22. Answer: 2 192 ⋅ a =
16
Sol:
From the second equation,
Differentiating f (x)= x
8
− x
6
+ x +
4

and hence
−3 −1
a = =
1
x − 2012 gives 192⋅16 1024
1 −1 3
2011
b = − 64 ⋅ =
8 1024 16
′
f (x) = 8x
7
− 6x +4x
5 3
+
1
and
2011
Evaluating the required expression:
1
′ 7 5 3 1 ∣ + 48 ⋅ b ∣= 7
f (−x) = −8x +6x − 4x + ∣ 64⋅a
2011

Final Answer: 7
Summing gives ′ ′ 2
f (x) + f (−x) =
2011

25. Answer: 02
Hence the integral becomes
2011 2011
2

2 2011 1
Sol:
∫ x
dx = ∫ x
dx
−2011 2011 +1 2011 −2011 2011 +1
− cosx
∫ √1 + sinxdx = ∫ dx
2011 √1−sinx
Denote the integral .
1
J ∫ x
dx
−2011 2011 +1

= 2√1 − sinx + c
Under the substitution x → −x , one
shows J satisfies J + J = ∫
2011
dx
∴ k = 2 .
−2011

= 2 × 2011 so J = 2011 .

Therefore the given integral equals

× 2011 = 2.
2

2011

Final Answer: 2
 Physics - Section A

1. Answer: B 5. Answer: A

Sol: Sol:

Displacement ; as we know the line integral for magnetic

field around
→
2 2 ˆ
S = at î + bt ĵ + 0k
current carrying wire is ∮ B. dl = μ0 i
→
→
Velocity ; v =
d S
putting the values
dt
−7 1
∮ B. dl = 4π × 10 ×
4π
→
v = 2 at î + 2 bt ĵ
that gives
−7
→ 2 2 ∮ B. dl = 10 weber/metre
∣ ∣
v = √(2 at) + (2 bt)
∣ ∣

6. Answer: B
2 2
v = 2t√(a + b )
Sol:
2. Answer: A
Magnetic field due to straight wire at 'R'
Sol: is

mg sinθ < μmg cosθ B0 =

μ0 I

4πR

so static friction = mg sinθ = 9.8 N

∵ Current flows from both wires.
Therefore, the correct answer is (A) μ0 I μ0 I
∴ B1 = 2 × B0 = 2 × =
3. Answer: C
4πR 2πR

In the given question, wire is wound in

Sol:
such a way that a disc is formed then
Speed of sphere does not change while from other side of wire, current can
string hits the nail. travel.

By conservation of energy, h1 =(h2 + h3 ) This can be done by passing currrent

from full wire than half circle.

∴ Magnetic field due to full circle of

radius R is-
μ0 I
B2 =
2R

& magnetic field due to half circle is -

L cos θ = ℓ cos(ϕ) + (L − ℓ) cos(ψ)
μ0 I
Lcosθ−ℓcosϕ B3 =
4R
cosψ =
L−ℓ

∴ Total magnetic field is

4. Answer: B
B = B1 + B2 + B3
Sol:
μ0 I μ0 I μ0 I
B = + +
COM of combined System of 3 sphere will 2R 4R 2πR

MP xP +MQ xQ +MR xR
be at = 3μ0 I 2μ0 I
( MP +MQ +MR ) ⇒ B = +
4R 4πR

(1×0)+(1×PQ)+(1×PR) μ0 I
= 3
⇒ B = [3 +
2
]
4R π

PQ+PR
= 3
7. Answer: A 14. Answer: A

Sol: Sol:

For Imax , Rh is minimum which is zero . Magnetic field will be added.

5.5
Imax = Amp.
20 μ0 k
B = 2( )
for Imin , Rh is maximum which is 30 . 2

5.5 5.5
Imin = = Amp. q
50
20+30
= μ0 (
a
2
. ν)
Imin 5.5 20 2
= × = Amp. 2
Imax 50 5.5 5 ε0 a
= μ0 [(
d
) V]
ν

a
2

8. Answer: A
μ 0 ε0 Vν
Sol: = d

Q
V = = 500 volt
C

15. Answer: D
9. Answer: C
Sol:
Sol:
Consider system of two disks to be short
After along time, charge on
3C∈
A =
2
dipole
2k 2k
Charge on
3C∈
B = − E = 3
∫ dp = 3
ℓσA
2 r r

10. Answer: B
2
2ℓ 2 σℓR
E = 3
σπR = 3
4πε0 r 2ε0 r

Sol:
16. Answer: B
As the magnetic field is uniform and the
particle is projected in a direction Sol:
perpendicular to the field, it will describe Given
a circular path. The particle will not hit
the y-z plane, if the radius of the circule Charge density,
is smaller than d. For the maximum value σ = 2 μ
C
= 2 × 10
−6 C

of v the radius is just equal to d. Thus

2 2
m m

mv Bqd Radius, r = 6 mm = 6 × 10
−3
m
= d ∴ v =
Bq m

Excess pressure, Pin − Pout = 0

⇒ Pin = Pout
11. Answer: C 2
4T σ
⇒ =
Sol: r 2ϵ0

PE = 2(TE) ⇒ U = 2E0
rσ
⇒ T =
8ε0

12. Answer: D ( 6×10

−3
) ( 2×10
−6
)
2

−3
T = = 0. 33 × 10 N/m
Sol:
−12
8 ( 8.854×10 )

Power p =
V
2
17. Answer: C
R

1
Sol:
∴ p ∝
R
Using,
V
R = –G
ig
p1 R2 2
∴ = =
p2 R1 1

We have,
10
R = – 20 = 9980Ω
–3
10
p1 : p2 = 2 : 1

Thus, a resistance of 9980Ω is to be

13. Answer: C
connected in series with the
Sol: galvanometer to convert it into the
voltmeter of desired range.
R' = R0[1 + ∝R ΔT ]

and ℓ' = ℓ[ 1+ ∝E ∆T]

18. Answer: A 20. Answer: A

Sol: Sol:

magnetic force on electron Fm = evB

sin 90º

electric force on electron Fe = eE

electron moves uneffected so

Fe = Fm
Applying Gauss law
⇒ eE = evB → →
∮ E ⋅ d s = 4πGmin
E V
⇒ B = =
v vd
→ →
600 −1 Where E is gravitational field at d s
⇒ B = = 10 tesla
6 −3
(2×10 )(3×10 )
Computing over colsed surface given
19. Answer: A
E2s = 4πG(ρsh)

Sol: 4πGρh
E =
2
......(1)
τ = MB sin θ ⇒ τ = (mL)B sin θ

On the surface of earth with radius

⇒ 25×10–6 =(m×5×10–2)×5×10–2×sin 4 3

30°
G(ρ πR )
3

R, E = 2
R

⇒ m = 2 × 10–2 Am
= Gρ
4

3
πR .....(2)

Equating (1) and (2)

4πGρh
4
= Gρ πR
2 3

2R
h =
3
 Physics - Section B

21. Answer: 2 23. Answer: 0

Sol: Sol:

v = speed with which the block leaves

the surface at B 2 mV = mgRcosθ
1 2

v2 = 2gR cos θ ...(1)

Range of the projectile released from B is

( 240−x )
x
v
2
sin 2θ +20 − + = 0
12 6
x = = 2Rcosθ ⋅ sin 2θ [ from (1)]
g
x x
20 − 20 + + = 0
cos2θ.
12 6
=4R sin θ

x=0
x is maximum when
There is no transfer of charge through
–2 cos sin2 + cos3 =0
dx

dθ
= 0 ⇒ θ θ θ the battery

⇒ cos θ [cos2 θ – 2 sin2 θ] = 0 24. Answer: 4

cosθ = 0 is not acceptable [it will give Sol:

zero range]

∴ cos2 θ – 2 sin2 θ =0
1
tan θ = so, x = 2
√2

22. Answer: 45.00

Sol:

2 2
Fnet = √4 + 4 + 2 × 4 cos 120°

Fnet = 4 N

25. Answer: 4

Sol:
using equation of kinematic
1
gt2 = R + h
2

Using Pythagoras theorem

h2 + (5t)2 = R2
Using work energy theorem
1

2
mv2 – 12 m52 = mg (R + h)
v2 = 52 + 2g (R + h)
v2 = 52 + 2g ( 12 gt2 ) 2
2
AB = 1/2g(T/2) = 1/8 gT
v2 = 25 + 100t2
v2 = 25 + 4 [R2 – h2] 2

5t2 = R + h
CD = 1/2 gT

25t2 = R2 – h2 CD
1/2 gT
2

5=R–h ∴
AB
=
2

v2 = 25 + 4R2 – 4 [R – 5]2
1/8 gT

25 + 4 (3)2 – 4 (3 – 5)2 ⇒ T = 4 sec

= 25 + 36 – 4 × 4
25 + 20 = 45.00
 Chemistry - Section A

1. Answer: C 5. Answer: A

Sol: Sol:

Therefore, the correct answer is (A).

6. Answer: D

Sol:

[Cr (NH3 ) ][Co(CN)6 ]

6
and
[Co (NH3 ) ][Cr(CN)6 ]
6

in coordination isomerism both cationic

and anionic past must be complex

2. Answer: D 7. Answer: D

Sol: Sol:

Depression in freezing point is a

colligative property which depends
upon the amount of the solute.

Δ Tf = i× Kf × m

Δ Tf α i but F.P. α 1/i

8. Answer: B
i(C6H12O6) = 1
Sol:
i(KI) = 2
The expression for the depression in the
i(K2SO4) = 3 freezing point and the molality is
i [Al2(SO4)3] = 5 Kf =
ΔTf

Therefore, the correct answer is (D).

For a solution which freezes at −0.2 oC,
3. Answer: B ( molality ) =
x×1000
=
0. 2

100 Kf
f
Sol: ___________(1)
linkage isomerism For a solution which freezes ar −0.25 oC,
4. Answer: A ( molality ) =
x×1000
=
0. 25

Kf
W
f

Sol: ____________(2)

Concentration increases boiling point On dividing equation (1) by equation (2),

increases we get
0. 2 W
=
0. 25 100

Hence, W = 80 g

The grams of ice that would have

separated 100 − 80 = 20 g

Therefore, the correct answer is (B).

9. Answer: B 14. Answer: C

Sol: Sol:

In coordination isomerism both cation & Oleum consists of SO3 and H2SO4.
anionic part must be
complex [CuCl2(NH3)2] [PtCl2(NH3)2] – Let the mass of SO3 in given sample
Coordination isomerism not possible oleum be = xg

10. Answer: A Mass of H2SO4 is given a sample of oleum

= (0.5 – x) g
Sol:
Eq. mass of SO3 =
80
= 40
2

No. of g equivalents of SO3 = x

40

2NaOH + SO3 → Na2 SO4 + H2 O

These are enantiomers 2NaOH + H2 SO4 → Na2 SO4 + 2H2 O

11. Answer: C Eq. mass of H2SO4 =

98
= 49
2

Sol: 0.5−x
No. of equivalents of H2 SO4 =( )
78% 49

12. Answer: A Total no. of g equivalents =

x 0.5−x
+( )
Sol: 40 49

26.7 mL of 0.4 N NaOH contain no. of the

equivalent of NaOH = 1000 × 26 .7
0.4

At equivalence point

No. of g equivalents of NaOH =

x 0.5−x
+( )
40 49

26 – 2 + 12 = 36 49x+(40×0.5−40x)
0.4×26.7
=
13. Answer: A 1000 40×49

0.9328

Sol: x =
9
= 0.1036

\ Hence % of free SO3 =

0.1036
× 100
0.5

= 20.72%

15. Answer: D

Sol:

78 – 4 + 12 = 86
16. Answer: D 19. Answer: D

Sol: Sol:

Reactity for dehydration (E1) reaction ∝ As –ve charge on metal - C–O bond
stability of product of alkene ∝ stability length - & C – O bond order ↓
of C⊕
C – O bond order
Decreasing order of reactivity for
dehydration is- [Ti(CO)4]2– < [V(CO)6]– < [Cr(CO)6] <
[Mn(CO)6]+

20. Answer: C

Sol:

17. Answer: D

Sol:

More is negative charge on complex more

will be the CO bond & lesser will be the
M–C bond

18. Answer: B

Sol:

5 HIO4

Reaction (1) - −−
− →

2HCHO + CO2 + 3HCOOH

5 HIO4

Reaction (2) - −−
− → HCHO

+ 5HCOOH

Ratio of moles of formaldehyde obtained

in the reaction (1) and reaction (2) is = 2
:1

=2
 Chemistry - Section B

21. Answer: 31 23. Answer: 1

Sol: Sol:
SiC 4+4 8
ΔTb = kb . m = = 1
BN 3+5 8

(0.94) = (0.52) m
24. Answer: 5
m =
0.94

0.52
= 1.8 mol/kg Sol:
1 kg H2O contains 1.8 mole urea

moles of H2O = 1000/18

1.8
Xurea = 1000
1.8+
18

Xurea = 0.0314

22. Answer: 4
Methyl-2-methoxy-6-methyl-3-
Sol: cyclohexene carboxylate
W

25. Answer: 6
2
( ) RT
Mw
2
π = CRT =
V
Sol:
Given W2 = 40 g
(A) all H-atoms which are present in
Mw2 = 246 conjugation with are replaced by D.
T = 27°C = 300 K

V=lL

Substituting all the values, we get

40
π = × 0. 082 × 300 = 4 atm
246