Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Sr.Super60, Elite,Target & LIIT BT's Paper -2(Adv-2024-P2-Model) Date: 11-05-2025
Time: 02.00Pm to 05.00Pm GTA-34 ^ Max. Marks: 180

KEY SHEET
MATHEMATICS
1 B 2 A 3 D 4 C 5 BC 6 AD

7 AC 8 7 9 2 10 8 11 2 12 2

13 4 14 5 15 7 16 1.57 17 1.57

PHYSICS
18 A 19 A 20 B 21 A 22 AB 23 A

24 ABC 25 2 26 4 27 6 28 9 29 4
1.66-
30 8 31 32 2400 33 585 34 65
1.67

CHEMISTRY
35 D 36 A 37 B 38 C 39 AC 40 AB

41 A 42 0 43 2 44 5 45 8 46 5
5.31- 2.95-
47 5 48 49 50 116 51 206
5.37 3.10
 Sri Chaitanya IIT Academy 11-05-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-34_Key& Sol’s

SOLUTIONS
MATHEMATICS
 1 
1. m1m2  1 a 2  11a  3 m12    220
 m 2
 1 
D C

m2 M

A B
Eq. of AC
AC  (cos   sin  )  (sin   cos  ) y  10
BD  (sin   cos  ) x  (sin   cos  ) y  0
(10(cos  sin  ),10(sin   cos  ))
 sin   cos  
Slope of AC     tan   M
 sin   cos  
Eq. of line making an angle  4 with AC

m  tan m 1 m 1
m1, m2  4  or
 1 m 1 m
1  m tan
4
sin   cos  sin   cos 
1 1
sin   cos  , sin   cos 
 sin   cos   1  sin   cos 
1  
 sin   cos   sin   cos 
m1, m2  tan  ,cot 
Mid point of AC & BD  M (5(cos   sin  ),5(cos   sin  ))
B (10(cos   sin  ),10(cos   sin  ))
a  AB  2 BM  2(5 2)  10
 1 
a = 10  a 2  11a  3  m12    220
 m1 2 
100  110  3(tan 2   cot 2  )  220
1  
Hence tan 2   3, tan 2      or
3 3 6
9 1
Now 72     100  30  13
 16 16 
9 1 5
 72     100  30  13  72    83  45  83  128
 16 16  8

Sec : Sr.Super60, Elite,Target & LIIT BT's Page 2

 Sri Chaitanya IIT Academy 11-05-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-34_Key& Sol’s
2.

D E Akshara Bhavan
C
A B

The required paths are

i) Hostel to A to B to AKSHARA BHAVAN
ii) Hostel to C to AKSHARA BHAVAN
iii) Hostel to D to E to AKSHARA BHAVAN
1 1
3. f  x  k  1  f  x  k   f  x .
2 k 1
2
n n 1 k 1 n 1 1
an   f  x  dx 
0  k f  x  dx   0 f  x  k  dx 
k 0 k 0
n 1 n 1 
1 1 1 1 1 1
  2k 0 f  x  dx 
k
   f  x  dx 
0 k
 2  f  x  dx, n  .
0
k 0 k 0 2 k 0 2
4. 10  113  16 ......  3 K 1 for K  3
11  9  14  17 ......  3K  2
12  3  15  18 ......  3 K
500  9,  400  1, 300  3
5. B) Select 6 planes out of 11 and arrange A, B, C, D, E, F remaining X, X, X, Y, Y gets
arranged in X Y X Y X pattern only at remaining places 11 P6 .
5!
C) 11C 1  4620
6 3!2!
n n
(1) r nCr
6. P (n)   (1) Cr  
r n
r 0 r 0
r 1
1 n n 1 1
P ( n)  
n  1 r 0
Cr 1( 1) r P ( n)  
n 1
7.

P (t )
Q( ,  )
A
B

SOL-
Sec : Sr.Super60, Elite,Target & LIIT BT's Page 3
 Sri Chaitanya IIT Academy 11-05-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-34_Key& Sol’s
Equation of chord of contact
x   y  4 .....(1)
Also, Equation of tangent at P(t)
Is ty  x  2t 2
Also t     2t 2 .....(2)
From (1) & (2)
(t   2t 2 ) x   y  4
 (tx  y )  (2t 2 x  4)  0  tx  y  0 & 2t 2 x  4  0
y y2
t  2.  x  4  0 y2  2x  0
x 2
x

(1 / 2,0)


Area bounded by S = 0 & the line 2x+1=0

2 1 2
 2 
3 2 3
2 x  y  1  0 is a focal chord
Hence angle is 90
8.
xi fi fi xi fi x 2i
A 2 2A 2A2
2A 1 2A 4A2
3A 1 3A 9 A2
4A 1 4A 16 A2
5A 1 5A 25A2
6A 1 6A 36A2
Total 7 22A 92A2
2
 2

 fi x 2i   fi xi 
   160 
92 A2  22 A 
 
2

 fi   fi  7  7 
92 A2 484 A2 92  7 A2  484 A2
 160    160 
7 49 49
Sec : Sr.Super60, Elite,Target & LIIT BT's Page 4
 Sri Chaitanya IIT Academy 11-05-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-34_Key& Sol’s

 160  49  644 A2  484 A2  160 A2  7840

7840
A2   A2  49  A  7
160
A = 7 as A is a positive integer
a
9. Given set is {  I  : 2a 2  3b2  35, a, b  Z }
b
We can see that, 2(2)2  3(3) 2  35
And 2(4)2  3(1) 2  35
 (2,3),(2, 3),( 2, 3),( 2,3),(4,1),(4, 1),(4, 1),(4,1)
10. f ( m  1)  f (m)  3(4m  1)
f (2)  f (1)  3(4  1)
f (3)  f (2)  3(8  1)
---------------------------------
---------------------------------
f (19)  f (18)  3(4.18  1)
–––––––––––––––––––––––––
f (19)  3[4(9.19  18]  3.18[37]  1998

(4  1)(6  3)(12  1) 13
11. Volume  
2 2 1 7
2 1 1
3 4 12
x 1/ x
1
12. F ( x)   f (t )dt  xF    x  f (t ) dt
0
 x 0
1
Let  nT  E
x
2T  E
1 1
lim xF    lim
x 0  x  x  nT  E
 f (t )dt
0
nT nT  E 
n 
 lim   f (t )dt   f (t )dt 
x  nT  E  
0 nt
T E T
n 1 1 1
 lim
x  nT  E
 f (t ) dt 
nT  E  f (t )dt 
T  f (t )dt  3  6  2
0 0 0
13. 7cos 2   3sin   2cos 2 2  2
2

4cos 2   3cos 2  2cos 2 2  2

2(1  cos 2 )  3cos 2  2cos2 2  2

Sec : Sr.Super60, Elite,Target & LIIT BT's Page 5

 Sri Chaitanya IIT Academy 11-05-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-34_Key& Sol’s

2cos 2 2  5cos 2  0
cos 2 (2cos 2  5)  0

cos 2  0 2  (2n  1)
2
   3 5 7 
  (2n  1) S , , , 
4 4 4 4 4 
For all four values of 
x 2  2(tan 2   cot 2  ) x  6sin 2   0  x 2  4 x  3  0
Sum of roots of all four equations  4  4  16 .

14&15. Let cot A  a then a 3  a 2 a  x  a 2 x  1  1

  
a3  a 2 x  a 2 x  1  a 2 x  1  a 2 x  a3 
 1 1 
Finally we get, a   , 5    , 
 5 6
Re  z   0 is ___
16.&17. Sol- w lie on 11z10  10iz 9  10iz  11  0  w  1

z3

(-1, 0) (1, 0)
 z3  1  
arg  
 z3  1  2
 
Locus of z3 will be in I, II quadrant and lie on a unit circle

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 Sri Chaitanya IIT Academy 11-05-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-34_Key& Sol’s

PHYSICS
18. APPLY BERNOILLLIS EQUATION
19. CONCEPTUAL
V1 V
20. V12  V22  V 2  1 i
X L XC
 1   Li V2  iR
V1    C   i V1 
 L  1   2 LC
L
i R i
V1
V2
C


V  Vrms
 2 L2 V2 V
 R2  i
 
2
1   2 LC i2  2 L2
R2 
 
2
1   2 LC
21.

N1 v1 N1 v1
mg mg

(a) (b)
F.B.D in two cases is as shown in case (b) normal will be less and incase (b) work done
by magnetic field is zero so height in two cases will be same.
23.
r1

ice
r l

r2
dr n2
Req   k.2 r  k.2 
r1
Ts  Tice 40
 Heat current   k 2   80 J / sec
Req n2
Sec : Sr.Super60, Elite,Target & LIIT BT's Page 7
 Sri Chaitanya IIT Academy 11-05-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-34_Key& Sol’s
dmice dmice 80 
Also, L f  80    kg / sec
dt dt 80  4.2  1000 4200
23. CONCEPTUAL
24. CONCEPTUAL
25.
B
VMR
60

A

VMR
Resultant


VR  VMR sin 
SOL-
V MR cos 
tan   ;  30
V R  VMR sin 
VR
On solving  VMR
3 cos   sin 
VMR will be minimum when denominator is maximum. That is at   30 .
100 3
And time   200 2
VMR cos
26. Since BC is shorted, potential difference across BC is zero.
Voltmeter reading  VAB VBC  VAB  8Volt (given)
Since length CD  2  length AB, VCD  2VAB 16Volt
Therefore emf of cell  VAB  VBC  VCD  8  0  16  24 Volt
On removing the resistance less wire connecting B and C.
VAC  2VCD
VAC  VCD  24
VAC  16
27. u = 5.0 cm
v = 10.0 cm
uv 10
f   cm
uv 3
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 Sri Chaitanya IIT Academy 11-05-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-34_Key& Sol’s

df  du dv 
 f  
f  u 2 v2 
df  1 1
 f (du)   
f  u 2 v2 
% error in focal length
 1 1 5
 f (du)   100 
 u 2 v2  3
2I1.dA.sin 2 
28. dFR 
C
2.I r 3 2 r.dx.sin 2  .sin 
 0 .
R3 C
4 I0r 4dr sin 2 

R3.C
4 I0.R2.sin 2 
FR 
5C
dx
x
r dr

21A sin 3
C


29. Conceptual
30. Let the velocity at highest point be v and R + h=r
Applying conservation of angular momentum between P and Q, we have
mvr  mv0 R cos 30 
3v0 R
Or v 
2r

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 Sri Chaitanya IIT Academy 11-05-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-34_Key& Sol’s

Applying conservation of mechanical energy between P and Q, we have:

1 2 GMm 1 2 GMm
mv0   mv 
2 R 2 r
Substituting the value of v from equation (1), we get
1 2 GMm 1  3v02 R 2  GMm
mv0   m 
2 R 2  4r 2  r
2 2
2 2GM 3v0 R 2GM
Or v0   
R 2 r
4r
1.5GM 2GM 3  1.5GM  R 2 2GM
Or     
R R 4  R  r2 r
 1.5GM 
 v0  is given 
 R 
1 9 R2 2
Or   . 
2 R 8R r 2 r
Or 4r 2  9R2  16Rt
Or 4r 2  16 Rr  9R2  0
16 R  256 R 2  144 R 2
Or r 
8
16 R  10.58 R
   3.323R or 0.677 R
8
But r < R
Hence r = 3.323 R
Or h = r – R = 2.323 R
C  VR
31. f  f0
C  VR
f 2VR 2V 2  0.1
  R C   5  106  1666.66 m / s
f 0 C  VR C 600

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 Sri Chaitanya IIT Academy 11-05-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-34_Key& Sol’s
C  VR f 2VR
32. f ' f0 
C  VR f 0 C  VR
Velocity is 4 times  f  4f 0  2400 Hz
33.& 34.
P0 ,V0 ,T0 P0 ,V0 ,T0 P0 ,V0 ,T0 P ,V1 ,T1 P ,V, 9T0 P ,V, 9T0
4 4
A1 A2 A3 A1 A2 A3

Initial condition final equilibrium

Considering chamber A2 and A3 ,
P0 2V0 P 2V
No. of moles = constant 
2 RT0 2 9T0
4
9
PV  P0V0
4
Apply adiabatic condition
3
2
P0 (2V0 )  P (2V ) V V0
3
8
P0 (V0 ) 2  P 2 v V  V0
27
P0V0  PV 

 P0V0 16V0
V  V1  3V0  2V  3V0 
P 27
 P0V0 81V0  16V0
V  
9 P0V0 27
4 V
4 65V0
V  1  V0 1 V1 
9 27
4
V 2/3  V02/3 From above volume we can calculate the final pressure.
9
3
4 243
V    V02
2
Final pressure P  P0 and
9 32
4 3/2 585
V V0 Final temperature T  T0
9 32

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 Sri Chaitanya IIT Academy 11-05-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-34_Key& Sol’s

CHEMISTRY
143 K
35. XeF4  O2 F2  XeF6  O2
36. CO2 115 pm 
Normal C=O bond length is: 121pm
37. KW  1013
d  0.9 gm / ml
1000 ml water = 900 gram water
900  1000
Molarity 
18  1000
= 50
 H   OH [ K a ]
H 2O 
C (1 ) C C

[ H  ][OH  ] 1013
Ka  
[ H 2O] 50
 2  1015
38.

1) O

 
3 
2) Zn.H 2O C O
COOH C=O
H
CH3

NH 3

CH3
39. Cu 2 , Pb 2 , Hg 2 , Bi 3 :IIA group
Zn 2 , Co 2 : IV group
40.

41.

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 Sri Chaitanya IIT Academy 11-05-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-34_Key& Sol’s

1
PV 5/2  K 2
PV 3  K1
1  Initial state
2'
P 2  Final state of the 1st process
2'  Final state of the IInd process
2

V
Work done in 2nd process is more than 1st process.
42. X   Ni  CO 4  and Y  ZrI 4

43. 4 3 5
ClO2  NaOH  NaClO2  NaClO3
44.
45. Conceptual
46. amount of Ag deposited  (675  0.0004)  10 gram
w it

E 96500
(675  0.0004)  10 96.5  t
 [ Eq. wt of Ag  108]
108 2  96500
t = 50 sec
x

10
50
 5
10
47. For 1st line of Balmer
Series of He
E  E3  E2
13.6  (2)2 13.6  (2) 2
 
(3) 2 (2) 2
 7.55 eV
For Li 2
13.6  (3) 2
E5 
(5)2
 4.896 eV

Sec : Sr.Super60, Elite,Target & LIIT BT's Page 13

 Sri Chaitanya IIT Academy 11-05-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-34_Key& Sol’s

13.6  (3)2
E4   7.65 eV
(4)2
So electron is emitted out from n  5
48 & 49
7k
 rate constant at 310 K  k   1.07 k
100
k E f T  T 
Using, 2.303log 2  a  2 1 
k1 R  T1T2 
1.07 k Eaf  310  300 
2.303log 
k 8.314  310  300 
Eaf  5.34kJ
Now equilibrium constant at 300 K  K c
3K
 equilibrium constant at 310 K  K c  c  1.03K c
100
K H  T2  T1 
Using, 2.303log 2   
K1 R  T1 
1.03K c H  310  300 
2.303log 
Kc 8.134  310  300 
H  2.31kJ
Since, H  Eaf  Eab
Eab  3.03kJ
50 & 51
LAH
COOH OH HBr Br
COOEt

COOEt
COOEt
H 3O  ,
COOH 
CO2

P1 COOEt

Ph Cl COOH
COOH LDA COO


P2 Ph

Sec : Sr.Super60, Elite,Target & LIIT BT's Page 14