In Situ Preservation of A Deep-Sea Wreck Site Sinop D in The Black Sea
In Situ Preservation of A Deep-Sea Wreck Site Sinop D in The Black Sea
To cite this article: Dennis Piechota, Robert D. Ballard, Bridget Buxton & Michael Brennan
(2010) IN SITU PRESERVATION OF A DEEP-SEA WRECK SITE : SINOP D IN THE BLACK SEA,
Studies in Conservation, 55:sup2, 6-11, DOI: 10.1179/sic.2010.55.Supplement-2.6
                              Fig. 1    Map of the Black Sea showing the location of the Sinop D wreck site off the north coast
                                        of Turkey.
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Fig. 2   To the left, the engineers in the control room of the RV Alliance drive the robotic vehicle. To the right, the robotic arm begins to insert a proxy
         artifact decay test, called a ‘kebab’ into the sediment; two ‘twinkie’ decay test boxes and the tops of two previously inserted kebabs can be seen
         on the sea floor.
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to be the result of its descent to the seabed rather than in situ
deterioration. Fluid drag may have ripped off the sails, associated
rigging and any upper gunwale extensions. After initial mapping
and limited excavation in 2003 a comprehensive program of
archaeological research and preservation was planned.
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From the standpoint of anticipating potential in situ preservation               map of the site to show the slope and relief of the wreck and
problems it is best to think of a wreck site not as a collection of              surrounding seabed.
artifacts or of ship construction materials but as a concentrated                   Important to site characterization and conservation in gen-
mass of organic and inorganic boundary surfaces. Each surface,                   eral is the ROV’s onboard environmental datalog. Data that are
whether that of a ship’s timber or artifact can then be thought                  generated routinely by sampling equipment that runs constantly
of as representing a relatively stable physico-chemical barrier                  whenever the ROV is deployed record parameters of the water
[14]. As excavation destroys these barriers the relationship of the              column including water temperature, conductivity and dissolved
materials across them also changes and potential physical and                    oxygen content.
chemical instabilities are created. The conservator’s role then is                  In addition to the streaming ROV-based data, a number of
to try to anticipate the degree to which excavation will disrupt                 discrete data collection operations were designed and per-
the stable barrier surfaces.                                                     formed. Local water sampling was conducted and analyzed
                                                                                 for dissolved element composition using inductively coupled
Materials and Methods                                                            plasma mass spectrometry (ICPMS). Water samples were also
In deep-water archaeology, site characterization requires the                    analyzed for dominant bacterial class using simple bacterial
active participation of the engineers, archaeologists and marine                 activity testers [15]. Wood samples were collected to identify
scientists, many of whom collect data sets that can be essential                 the ship construction materials and estimate the degree of
to the work of the conservator. Specialized data sets include                    preservation.
the digital time-stamped ROV operations logs. This stream                           The physico-chemistry of the sediment, the shipwreck’s
of information forms the backbone of all deep-water archaeo-                     supporting matrix, was sampled using eight sediment cores
logical activities. The data sets include the ‘navlog’ and the                   taken from various locations around the wreck, Fig. 6. Two pre-
‘eventlog’. The navlog functions like an airliner’s black box;                   disturbance cores (C1003-02PC and C1003-04PC) were taken to
it records the position of the ROV at all times. The eventlog is                 document the very easily disturbed fluffy sediment layer at the
also a time-stamped log synchronized to the navlog. It allows                    sediment/water interface and the remaining six cores were taken
all participants, the ROV operators, archaeologists, conservator                 during excavation, several from the bottoms of two targeted
and other scientists, to make text-based observations and to                     excavation pits, approximately 30 and 100 centimeters below
attach video and still photographs of all operations using the                   the seabed. This allowed sampling down to approximately 128
ROV’s imaging equipment. Taken together, the logs allow the                      centimeters of sediment depth.
participants to reconstruct in minute detail all archaeological                     Ongoing analysis of these cores focuses on characterizing the
activities.                                                                      properties of the sediment environment in terms of its capabili-
   A specialized form of imaging carried out at the beginning and                ties to preserve cultural remains and looks for any alterations
end of the deep-water work was the construction of photomosa-                    to the natural conditions caused by the presence of the wreck
ics of the site. Before any site disturbance occurred at Sinop D,                itself. Selected cores were immediately analyzed for redox and
the ROV was programmed to fly over the site taking hundreds                      pH trends in the upper sediment and flock layer. After their
of overlapping close-up images that were then stitched together                  return to the laboratory they were X-rayed; their physical prop-
to form a detailed photographic image of the site, Fig. 6. Data                  erties were measured; and samples were prepared for sediment
from this operation were also used to create a microbathymetric                  micromorphology.
Fig. 6   Pre-disturbance photomosaic of the Sinop D wreck site showing the location of each cataloged timber (e.g., ‘FA35s’) and the eight sediment cores
         (e.g., ‘C1003-02PC’). The locations of the four ‘twinkie’ and eight ‘kebab’ proxy artifact decay tests can be seen in the lower left corner.
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                                                                                   left 500 m east of Sinop D at the same depth as the wreck. The
                                                                                   second was positioned in shallower waters (106 m) in the suboxic
                                                                                   zone. These allowed seasonal variability in the waters around the
                                                                                   wreck to be examined and it was possible to monitor whether the
                                                                                   depth of the upper edge of the anoxic waters, called the suboxic
                                                                                   layer, of the Black Sea varies over time.
                                                                                      Surrogate artifact decay experiments were also designed
                                                                                   and deployed at the site. These devices were inspired by work
                                                                                   conducted in the waters off northern Europe [16]; these mate-
                                                                                   rial packages will be retrieved serially over the coming years
                                                                                   to estimate the types and aggressiveness of various modes of
                                                                                   deterioration at this site. Two sets of surrogate artifact decay
                                                                                   experiments were deployed near the wreck site to achieve two
                                                                                   goals. First, to determine the mechanics and rates of long-term
                                                                                   decay that might be expected for artifacts and ship construction
                                                                                   materials in the sediment and open water environments of the
                                                                                   site. Second, to explore whether it would be safe to expose and
                                                                                   display selected artifacts, including organics, on the anoxic
                                                                                   seabed in a future underwater museum.
                                                                                      The first set of experiments uses so-called ‘kebabs’; these are
                                                                                   based on 65 centimeter-long titanium rods that were inserted
                                                                                   into the sediment near the wreck site. Four rods were fitted
                                                                                   with mild steel test cylinders. Each metal sample was electri-
                                                                                   cally insulated from the rod and adjacent samples with Teflon
                                                                                   washers and sleeves. Four kebabs were fitted with modern wood
                                                                                   samples of pine and oak, Fig. 7. Over the coming years one rod
                                                                                   of each type, wood and steel, will be recovered for analysis.
                                                                                   Taken together, the decay patterns for the samples will be used
                                                                                   to describe a trend line that will help to anticipate the likelihood
                                                                                   of retrieving particular ancient artifact classes and the condition
                                                                                   in which they might be preserved.
                                                                                      A second type of decay rate experiment, called a ‘twinkie’,
                                                                                   was designed as a way to test additional material types and to
                                                                                   look at the differences in decay patterns between open water and
                                                                                   sediment surface. Here, the test samples were attached to panels
                                                                                   within open crates measuring 20 (height) × 30 (width) × 40 cm
                                                                                   (length), which were simply placed on the seafloor. One panel of
Fig. 7   The wood and steel ‘kebab’ proxy artifact decay tests. On the
         wood kebab (left) 2.1 cm high white pine and red oak samples
                                                                                   samples was affixed to the bottom of the crate so that the samples
         alternate. In the second kebab (right) 1.25 cm high mild steel            faced downward and were in direct contact with the sediment.
         samples alternate with Teflon electrical insulators. The kebabs           Duplicate test samples were contained within the open crate in
         that were deployed were double the length shown.                          a manner that exposed them to the open water just above the sea
                                                                                   floor. The wider variety of modern test samples on the twinkies
                                                                                   includes rawhide, bone, pine, oak, copper, lead, steel and barley,
  Two environmental dataloggers, containing conductivity,                          Fig. 8. These will be recovered serially over multiple expeditions
temperature, depth, dissolved oxygen and current sensors, were                     to the site to study how materials may decay differently above
deployed to record seasonal variations around the site. One was                    and below the sea floor. They will be critical to the exploration
Fig. 8   To the left is an overview of the ‘twinkie’ proxy artifact decay test. Samples in the open crate are exposed to seawater. To the right the downward-
         facing panel that is affixed to the bottom of the twinkie in contact with the seabed can be seen. The panel contains the same samples as those in
         the crate: red oak, white pine, barley grains held in a net bag, rawhide and bone as well as duplicate samples of lead, copper and mild steel.
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of whether Sinop D can become an underwater museum with                            4 Smit, A., Van Heeringen, R.M. and Theunissen, E.M., Archaeologi-
formerly buried artifacts left exposed to open water.                                cal Monitoring Standard: Nederlandse Archaeologische Rapporten
                                                                                     33, Rijksdienst voor archeologie, cultuurlandschap en monumenten,
                                                                                     Amersfoort (2006).
EXPEDITION COSTS                                                                   5 Palma, P., ‘Monitoring of Shipwreck Sites’, International Journal
The cost of deep-water archaeology deserves comment because                          of Nautical Archaeology 34(2) (2005) 323–331.
it is so much greater than terrestrial or diver-based underwater
                                                                                   6 Tomalin, D., Simpson, P. and Bingeman, J.M., ‘Excavation versus
archaeology. In 2007, using a large oceanographic ship to access                     sustainability in situ’, International Journal of Nautical Archaeol-
Sinop D along with advanced robotic and telepresence technol-                        ogy 29(1) (2000) 3–42.
ogy and a team to operate it, the cost was about US$30000 per                      7 Satchell, J. and Palma, P., Managing the Marine Cultural Heritage:
day. Seven days were spent on site at Sinop D so the expedition                      Defining, Accessing and Managing the Resource, Council of British
cost was approximately US$240000 including a day of transit                          Archaeology, London (2007).
to the site. In the fields of oceanography, marine biology and                     8 Warren, D., ‘ROV Investigations of the DKM U-166 Shipwreck
marine geology this is considered routine, and research in those                     Site to Document the Archaeological and Biological Aspects of the
fields goes forward in the United States because the appropri-                       Wreck Site: Final Performance Report’, http://www.pastfoundation.
                                                                                     org/U166/U166_final.pdf (accessed 16 January 2010).
ate national funding agencies expect such costs. The cost of
conducting deep-sea archaeology is comparable with the cost                        9 Piechota, D. and Giangrande, C., ‘Conservation of archaeological
of deep-sea biology, geology, chemistry or any other oceano-                         finds from deep-water wreck sites’, in Archaeological Oceanogra-
                                                                                     phy, ed. R.D. Ballard, Princeton University Press, Princeton (2008)
graphic research. The difference is that the latter communities                      65–91.
of researchers have convinced the US National Academy of
                                                                                  10 Ward, C. and Ballard, R., ‘Deep-water archaeological survey in
Sciences to persuade the US National Science Foundation to                           the Black Sea: 2000 season’, International Journal of Nautical
fund at that level. Access to ships, technology and the teams                        Archaeology 33(1) (2004) 2–13.
to operate them are given to scientists who have submitted a                      11 Friedman, Z. and Zoroglu, L., ‘Kelenderis Ship — Square or Lateen
proposal to their various research divisions within the National                     Sail?’, International Journal of Nautical Archaeology 35(1) (2006)
Science Foundation. Archaeologists (and conservators) need                           108–116.
to argue that their research is as important as these other                       12 Fairbanks, R.G., Mortlock, R.A., Chiu, T.-C., Cao, L., Kaplan,
disciplines.                                                                         A., Guilderson, T.P., Fairbanks, T.W., Bloom, A.L., Grootes, P.M.
                                                                                     and Nadeau, M.-J., ‘Radiocarbon Calibration Curve Spanning
                                                                                     0 to 50,000 Years B.P. Based on Paired 230Th/234U/238U and 14C
CONCLUSION                                                                           Dates on Pristine Corals’, Quaternary Science Reviews 24(2005)
Deep-water archaeology is so new that every activity, including                      1781–1796.
excavation itself, is liable to require rethinking and fresh devel-               13 UNESCO, Convention on the Protection of Underwa-
opment. That is the spirit in which the team approached the Sinop                    ter Cultural Heritage (2001), http://unesdoc.unesco.org/
D wreck site. In this setting the deep-water conservator has a                       images/0012/001260/126065e.pdf (accessed 16 January 2010).
unique position between the engineers charged with developing                     14 Emelyanov, E., The Barrier Zones in the Oceans, Springer, Berlin
and implementing technologies for exploration, mapping, and                          (2005).
excavation and the archaeologists charged with directing the                      15 BART User Manual, Droycon Bioconcepts Inc., Regina,
progress of excavation and interpreting the site. While in the                       Saskatchewan (2004), http://www.dbi.ca/BARTs/Docs/Manual.pdf
future these early efforts may be seen as crude technologies,                        (accessed 16 January 2010).
it is nonetheless hoped that the explorations in this new field                   16 Bergstrand, T. and Godfrey, I. (eds), Reburial and Analyses of Ar-
described here will serve as a model in the implementation of                        chaeological Remains: Studies on the effect of reburial on archaeo-
the principles of sustainable archaeology and in situ preservation                   logical materials performed in Marstrand, Sweden 2002–2005,
                                                                                     http://www9.vgregion.se/vastarvet/svk/reburial/the_proj/RAAR2.
in deep-sea site archaeology.
                                                                                     pdf (accessed 16 January 2010).
ACKNOWLEDGEMENTS
The authors wish to thank the engineers, scientists, students, administra-        AUTHORS
tors, husbands, wives and friends who made this collaboration possible            Dennis Piechota is adjunct professor of history and chief conservator
including Katherine Croff, Roland Arsenault, Robert Bogucki, Kathleen             for the Black Sea field program of the Center for Ocean Exploration
Cantner, Alexis Catsambis, Julia Cudahy, Daniel Davis, Mark DeRoche,              and Archaeological Oceanography, University of Rhode Island and
Michael Durbin, Sarah Fuller, Domenico Galletti, Fatma Goletlioglu,               archaeological conservator at the Fiske Center for Archaeological Re-
Todd Gregory, Gabrielle Inglis, David Linstrom, David Lovalvo, Eric               search, Address: Fiske Center for Archaeological Research, University
Martin, Stephanie Nebel, Mary Nichols, Brennan Phillips, Jane Drake               of Massachusetts at Boston, Boston, MA 02125, USA. Email: dennis.
Piechota, Webb Pinner, Brian Raynes, Christopher Roman, Nicola                    [email protected]
Samuelson, Adam Skarke and Mark Talkovic, as well as the captain and
crew of the RV Alliance. We also want to thank David Gregory of the               Dr Robert D. Ballard is a professor of oceanography, the director of the
National Museum of Denmark for his advice on decay rate experiments               Center for Ocean Exploration and Archaeological Oceanography in the
and for the ‘kebab’. This research project was funded through a grant             Graduate School of Oceanography at the University of Rhode Island
from the NOAA Office of Ocean Exploration.                                        and explorer-in-residence at the National Geographic Society. Address:
                                                                                  Graduate School of Oceanography, University of Rhode Island, Nar-
                                                                                  ragansett, RI 02882 USA. Email: [email protected]
REFERENCES
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   shipwrecks in the Black Sea’, paper presented at the Geological                field program of the Center for Ocean Exploration and Archaeological
   Society of America, Denver (2007) (unpublished).                               Oceanography. Address: Department of History, University of Rhode
 2 Camidge, K., Canti, M., Dungworth, D., Jones, M. and Precious,                 Island, Kingston, RI 02881, USA. Email: [email protected]
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   http://www.cismas.org.uk/docs/colossus_stab_trial_final.pdf (ac-               at the University of Rhode Island. Address: as for Ballard. Email: ml-
   cessed 16 January 2010).                                                       [email protected]
 3 Oxley, I. and O’Regan, D., The Marine Archaeological Resource,
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