Student's Solution Copy [Code - 31848]

11th_ Batch 25(P-star P1 to P13 P2 Dhruv DP-1 DP3)_ Anushaashan_25ALP1 to ALP5_Eng

_Hindi_P-1_[Mains Pattern]
11th JEE (M) - Phase 1
KOTA

Date: 18-Aug-2025 Duration: 3 Hours Max Marks: 300

Maths - Section A
1. Answer: B 2. Answer: D

Sol: Sol:

a, b, c are in G.P. A. M . ≥ H. M .

Let r is common ratio a+2b+3c

2
b = ar, c = ar 3
≥ 1 1 1
+ +
Now are in
a 2b 3c
(a − b), (c − a), (b − c)

H.P. ⇒ (a + 2b + 3c)

1
,
1
,
1
are in A.P. 1 1 1
a−b c−a b−c ( + + )≥ 9
a 2b 3c

⇒ (b − c)(c − a), (a − b)(b − c),

(a − b)(c − a) are in A.P.

3. Answer: B
Now (ar − ar )(ar
2 2
− a), Sol:
2
(a − ar)(ar − ar )
sin2x – 2cosx + 1
= 0
(a − ar)(ar
2
− a) are in A.P. 4

4 sin2x – 8 cosx + 1 = 0
2 2 2
(r − r )(r − 1),(1 − r)(r − r ),
4 – 4 cos2x – 8 cosx + 1 = 0
(1 − r)(r
2
− 1) are in A.P.
⇒ 4cos2x + 8 cosx – 5 = 0
r(1 − r)(r − 1)(r + r),(1 − r) r(1 − r),

(1 − r)(r − 1) (r + 1) are in A.P. ⇒ 4cos2x + 10 cosx – 2 cosx – 5 = 0

⇒2cosx (2 cosx + 5) – 1(2 cosx + 5)

r(1 + r), −r, (r + 1) are in A.P.
=0
Now −2 r = r(1 + r) + (1 + r)
cosx =
5
⇒ −
2

⇒ −2r = (1 + r)(1 + r)
cosx = 1

2
2
⇒ r + 4r + 1 = 0 . . . . . . . . . (i)
Not possible x = 2xπ ±
π

Now value of
3
a + 4b + c

2 2
a + 4(ar) +(ar )= a(1 + 4r + r )

=a×0=0
4. Answer: A 6. Answer: C
Sol: Sol:
|sin x + 3| + |cos x – 1| = sinx + cos 1
,
1
,…….
1
are in A.P.
x+2 a1 a2 an

(sin x + 3)(cos x – 1) > 0 ⇒ cos x = multiply each term by

1 (a1 + a2 + … . +an )

⇒ x = 2nπ, n∈I ⇒
a1 +a2 +…an
,
a1 +a2 +…an
,…,
a1 a2

∴ Solutions are 0, 2π, 4π, ..... 9π, a1 +a2 +…an

100π an
⏐
↓

x in A.P.
a2 +a3 +…an a1 +a3 +…an
∴ Number of solutions in [0, 314] is ⇒ 1 +
a1
,1 +
a2
,…,

50.
a1 +…an−1
1 +
5. Answer: B an

Sol: in A.P.
2 2 a2 +a3 +…+an a1 +a3 +…+an
( a +3a+1 ) ( b +3b+1 ) ⇒ , ,…,
a1 a2
a b

a1 +a2 +…+an−1
2
( c +3c+1 )
an

in A.P.
=
1 1
(a + + 3) (b + + 3) a1 a2
a b
⇒ , ,…,
a2 +a3 +…+an a1 +a3 +a4 +…+an

1
(c + + 3) an
c
a1 +a2 +…+an−1

using A.M. ≥ G.M.

in H.P.
(∵ a + 1

a
≥ 2, a + 1

a
+ 3 ≥ 5)

similarly b + 1
+ 3 ≥ 5,
b

c+ +3≥5
1

= 5 × 5 × 5 = 125
7. Answer: C 9. Answer: D
Sol: Sol:
Since α, β, γ, δ form an increasing √k+1 −√k

G.P., so Tk = 1
=
√k √k+1
√k√k+1[√k+√k+1]

αδ = βγ where α < β < γ < δ. = 1

– 1

√k √k+1

On solving x
2
− 3x + a = 0
360
S =∑k=1 ( =
1 1
∴ − )
Also
1 √k √k+1
x = (3 ± √9 − 4a). α < β
= = 19
2 1 1 18
1 − 1 −
√361 19

Hence
1
α = (3 − √9 − 4a),
1
2
∴ m + n = 37
β = (3 + √9 − 4a)
2
10. Answer: A
Similarly from x
2
− 12x + b = 0 , we
Sol:
get
π π
1 tan ( − α)tan ( − β) =
γ = (12 − √144 − 4b), 4 4
2

1 π π
δ = (12 + √144 − 4b) tan −tanα tan −tanβ
2 4 4
( π
)( π
)
1+tan .tanα 1+tan .tanβ

Substituing these values of

4 4

α, β, γ, δ

in = (
1−tanα
)(
1−tanβ
)
1+tanα 1+tanβ

αδ = βγ and simplifying, we get (∵ tan

π
= 1)
(a,b) = (2,32)
4

sinβ
sinα
1−
Aliter: Check alternatives ; = (
1−
cosα
)(
cosβ

)
sinα sinβ
1+ 1+
cosα

only (C) satisfies the condition

cosβ

cosα−sinα cosβ−sinβ
8. Answer: A = (
cosα+sinα
)(
cosβ+sinβ
)

Sol: cosα.cosβ−cosα.sinβ

2 −sinα.cosβ+sinα.sinβ
(sinx − 2) + 6 =
cosα.cosβ+cosα.sinβ+

sinα.cosβ+sinα.sinβ
2
([−1, 1] − 2) + 6
cos(α−β)−sin(α+β)
=
2 cos(α−β)+sin(α+β)
([−3, −1]) + 6
sin(α+β)
1−
cos(α−β)
[0, 9] + 6 =
sin(α+β)
1+
cos(α−β)

Max = 15
1−m
1−
1+m 1+m−1+m 2m
M = 15 = = = = m
1−m
1+m+1−m 2
1+
1+m
2 2
4 sec x + 36 cosec x − 14

2 2
= 4 + 4 tan x + 36+36 cot x − 14

2 2
= 26 + 4 tan x + 36 cot x

By AM ≥ GM ,
2 2
4 tan x + 36 cot x ≥ 24

m = 24 + 26 = 50

M = 15 ; m = 50
 14. Answer: D
11. Answer: B
Sol:
Sol:

S= + ………
7 13 19
+ +
2 2 2 2 2 2
2 5 5 8 8 11

3S =
21
+
39
+
57
+ …… Or
2 2 2 2 2 2
2 5 5 8 8 11
2 2
(3r+2) −(3r−1)
3S =
10
∑
r=1 2 2
(3r−1) (3r+2)

10
3S =
1 1
∑ ( − )
r=1 2 2
(3r−1) (3r+2)

3S = 1
2
−
1
10
2 2
8

3S =
2 −1

10
2

S= = .
85 m

1024 n
(i) f(1) . f(3) < 0
Hence, (n – 12m) = 4
(3a + 4) (7a + 3) < 0
12. Answer: C
−4 −8
⇒ a ∈ ( , )
Sol: 3 7

S100 = 1 + 3 + 7 + ....... up to 100

terms
= (2 – 1) + (22 – 1) + (23 – 1) + ...
(2100 – 1) (ii)
100
2[2 −1]
= 2−1
− 100

= 2101 – 102 f(1) = 0

13. Answer: D
a=
−4

Sol:
x2 + 2 (
−4 4
− 1)x − + 5 = 0
2 2 2 3 3
2 1 2 2
(1 ) +(2 ) +3 +(3 ) + ……
3 3 3

to 10 terms ⇒ 3x2 – 14x + 11 = 0

5
2
7
2
9
2
11
2 3x2 – 3x – 11x + 11 = 0
= ( ) +( ) +( ) +( ) ……
3 3 3 3
⇒ 3x(x – 1) – 11(x – 1) = 0
to 10 terms
2
5 +7 +9 +11 +…..
2 2 2 x = 1, 11

to terms
3
= 10
9
11
> 3
1 10 2 3
= ∑ (2r + 3)
9 r=1
−4
a ≠
3
1 10 2
= {4 ∑ r + 12
9 r=1
Or
10 10
∑ r + 9∑ 1}
r=1 r=1

1 10×11×21 12×10×11
= {4 × +
9 6 2

+9 × 10}

1 2290
= {1540 + 660 + 90}=
9 9

f(3) = 0
−8
a= 7
 16. Answer: D
x2 + 2
−8 8
( − 1)− + 5 = 0
7 7

Sol:
⇒ 7x2 – 30x + 27 = 0
f(x) = x2−(m−3) x + m = 0
2
7x – 21x – 8x + 27 = 0
one root lie between (1,2)
7x(x – 3) – 9(x – 3) = 0
f(1) f(2) < 0
x= ,x=3
9

7
=(1−m+3+m) (4−2m+6+m)<0
1< <3
9

7
= 4.(10−m)<0

a=
−8 =(m−10)>0
7

= m∈(10,∞)
−4 −8
( , ]
3 7
17. Answer: A
15. Answer: B
Sol:
Sol:
2 2 2 2
1 +2 +3 +……+r
Tr =
Let
3 6
S = 1 + + 2
r(r+1)
4 4
10 15
r(r+1)(2r+1)
+ + +. ...∞. .. (i) 60 60
4
3
4
4
∴ S = ∑ Tr = ∑
r=1 r=1 6r(r+1)

1 1 3 6 1 60
S = + + = ∑ (2r + 1)
4 4 2 3
6 r=1
4 4
10 15 1
+ 4
+ 5
+. ...∞ . .. (ii) = [3 + 5 + 7 + … … . . +121]
4 4 6


Subtracting (i) – (ii) we get, A.P. with a=3, d=2,n=60

[6 + (60 – 1)2] = 5 [6 + 59 ×
60
S 2
⇒ S − = 1 + =
2⋅6
4 4

+
3
+
4
+
5
+. ...∞
2] = 5 [6 + 118] = 620
2 3 4
4 4 4

3S 2 3 4 5
⇒ = 1 + + 2
+ 3
+ 4
. .. (iii)
4 4
4 4 4

Again
3S 1 2 3 4 5

2
= (1 + + 2
+ 3
+ 4
+. ...∞)
4
4 4 4 4 4

3S 1 2 3
⇒ = + 2
+ 3
16 4 4 4
4 5
+ 4
+ 5
+. ...∞. .. (iv)
4 4

Subtracting (iii) – (iv) we get,

3S 3S
⇒ −
4 16
1 1 1
= 1 + + 2
+ 3
+. ...∞
4 4 4

12S−3S 1 1 1
⇒ = 1 + + 2
+ 3
+. ...∞
16 4 4 4

9S 1
⇒ = 1
16
1−
4

9S 4
⇒ =
16 3

4 16
⇒ S = ×
3 9

64
⇒ S =
27
18. Answer: A 19. Answer: D

Sol: Sol:

Given equation f(x) = 4x3 - ax3 + bc2 - cx + 5

2
2
(log √x −4) .
= x 1 x2 x3 x4 =
1/x 5

4
2
log √x −4
x
= 1 x1 x2 x3 x4
log
x
2
√x −4.
2
( ⋅ ⋅ ⋅ )
2 4 5 8
6 2
log 3 √x −4
√x
x1 x2 x3 x4 4
1
= = ( )
x ∈ (2, ∞) − {√5} 320 4

x1+x2+x3+x 4= 4
a

2
2
(log √x −4) .
1/x

2
AM > GM
log √x −4
x
⇒ 1
= 1 x
1 x
2
x
3
x
4
2
log √x −4. + + +
2 |x| 4 5 8
2
3
2
≥
log √x −4 4
3 x

1
1 x1 x2 x3 x4
√x2 − 4 =
4
⇒ log ( ⋅ ⋅ ⋅ )
x 2 2 4 5 8
2
⇒ √x − 4 = √x x1 x2
=
2 4
1±√17
2
⇒ x − x − 4 = 0 ⇒ x = x3 x4
2 = = = r
5 8

∵ x ∈ (2, ∞) − {√5} 1

4 4
4r 1
≥ [( ) ]
4 4
√17+1
⇒ x =
2
1
r ≥
Therefore, correct answer is option 4

(A) r=
1

x1=2r, x2=4r, x3=5r, x4 = 8r

x1= 2 , x2 = 1, x3 = , x4 = 2
1 5

Sum of root =
1 5 19
+ 1 + + 2 =
2 4 4

a = 19

Therefore, the correct answer is (D)

20. Answer: C

Sol:
n
sinx(sinx + cosx)=
4

2 n
2 sinx + 2sinx ⋅ cosx =
2

n
⇒ 1 − cos 2x + sin 2x =
2

2
(∵ cos 2x = 1 − 2 sin x)

n
⇒ sin 2x − cos 2x = − 1 . . . .(1)
2

We know

2 2
−√(1) + (−1) ≤ sin 2x

2 2
− cos 2x ≤ √(1) + (−1)

−√2 ≤ sin 2x− cos 2x ≤ √2

(from 1)
n
−√2 ≤ − 1 ≤ √2
2

n
−√2 + 1 ≤ ≤ √2 + 1
2

2(1 − √2) ≤ n ≤ 2(√2 + 1)

−0. 828 ≤ n ≤ 4. 828

∴ Integral values of
n = {0, 1, 2, 3, 4}

∴ Number of integral values of n are

5
 Maths - Section B

21. Answer: 2 23. Answer: 2

Sol: Sol:

tanx + secx = 2 cosx We have,

n i j
⇒ (1 + sinx) 220 = ∑ ∑ ∑ 1
i=1 j=1 k=1
2 2
= 2 cos x = 2 (1 − sin x)
n i
= ∑ ∑
i=1 j=1
⇒ (sinx + 1) (1 − 2 + 2 sinx) = 0
(1 + 1 + 1+. . . . j times)

1
⇒ sinx = −1, n i
2
= ∑ ∑ (j)
i=1 j=1
π 3π π 5π
⇒ x = , , ,
2 2 6 6 n
= ∑ (1 + 2 + 3+. . . . +i)
i=1
π 5π
⇒ x = ,
6 6
n i(i+1)
π
∵ x ≠ (2n + 1) = ∑ ( )
i=1 2
2

Number of solution is 2 =
1
[∑
n
i
2
+ ∑
n
i]
2 i=1 i=1

22. Answer: 2 n(n+1)(2n+1) n(n+1)

1
= [ + ]
Sol: 2 6 2

Let the four parts be =

1
[
n(n+1) [ (2n+1)+3 ]
]
2 6

(a − 3d), (a − 3d), (a − d), (a + d)

⇒220 × 12= n(n + 1)(2n + 4)

and (a + 3d) . Then,

220 × 6= n(n + 1)(n + 2)

sum=32
6 ⋅ 2 ⋅ 10 ⋅ 11= n(n + 1)(n + 2)
⇒ (a − 3d) + (a − d)+
10 ⋅ 11 ⋅ 12= n(n + 1)(n + 2)
(a + d) + (a + 3d) = 32
⇒ n = 10
⇒ 4a = 32 ⇒ a = 8

Therefore,
n 10
= = 2
It is given that 5 5

(a−3d),(a+3d)
7
24. Answer: 0
=
(a−d),(a+d) 15
Sol:
2 2
a −9d 7
2
a −d
2
=
15
sinα sin β – cosα cos β + 1 = 0
⇒ – cos (α + β) + 1 = 0
2
64−9d
⇒ cos (α + β) = 1 ⇒ sin (α + )
7
⇒ = β
2
64−d 15
=0
2 cos α sin β
⇒ 128d = 512
then 1 + cot α tan β =1+
sin α cos β
2
sinαcosβ+cosαsinβ sin(α+β)
⇒ d = 4 ⇒ d = ±2
= = =0
sinαcosβ sinα cosβ

Thus, the four parts are 2,6,10,14.

Therefore, the smallest part is 2.

25. Answer: 20.15

Sol:
sin(2n−1)α
Tn =
cos(2n−2)α ⋅ cos 2nα

2sinα ⋅ sin(2n−1)α
= 2sinα ·
1

cos(2n−2)α ⋅ cos 2nα

cos(2n−2)α−cos 2nα
= ·
1

2sinα cos(2n−2)α ⋅ cos 2nα

sec 2nα−sec(2n−2)α
= 2sinα

T1 =
sec 2α−1

2sinα

T2 =
sec 4α−sec 2α

2sinα

⋮
sec 2nα−sec(2n−2)α
Tn = 2sinα

sec(2nα)−1
Sn = 2sinα

sec(4030α)−1
∴ S2015 = 2sinα

∴ k = 4030, λ = 2, μ =1
= 2015 Ans.
k

λμ
 Physics - Section A

1. Answer: C 2. Answer: A

Sol: Sol:

At position A balloon drops first

particle

So, uA = 0, aA = – g, t =
3.5 sec.

SA = (
1

2
2
gt ) ...........(i)

Balloon is going upward from A

to B in 2 sec.so distance
travelled by balloon in 2 second.

(SB =
1
aB t )
2
..........(ii)
From the above figure,
2

aB = 0.4 m/s2 , t=2

We can write as:
sec.
→
v o/p = −v2 ĵ S1 = BC = (SB + SA) ...........
(iii)
→ →
v o/g − v p/g = −v2 ĵ

→ →
v o/g = v p/g − v2 ĵ . ..(1)

→ →
v o/g + v2 ĵ = v p/g

from (1)
∣ ∣ 2
→ ∣→ ∣ 2
∣ v o/g ∣ = √ v p/g + v
∣ ∣ 2
∣ ∣

2
∣→ ∣ 2
v1 = √ v p/g + v
Distance travell by second stone
∣ ∣ 2

∣→ ∣
2 which is droped from balloon at
B
2 2
∣ v p/g ∣ = v − v
∣ ∣ 1 2

2 2
vp/g = √v − v
1 2
u2 = uB = aBt = 0.4 × 2 = 0.8
m/s t = 1.5
sec.

(S2 = u2 t −
1

2
2
gt ) ...........(iv)

Distance between two stone

DS = S1 – S2 .
3. Answer: A 5. Answer: C

Sol: Sol:

The height of particle A at any instant

t is given as,
1 2
hA = 10 + uA sin 45°t– gt
2

1 2 1 2
hA = 10 + 10√2 sin 45°t– gt = 10 + 10t– gt
2 2

Similarly, height of particle B at any

instant t is given as, hB = 20– 1 gt2
2
Three masses are hanging on
At the collision, both the heights are frictionless pulleys as shown in
equal. figure. In given question its an ideal
case.
1 2 1 2
∴ 10 + 10t − gt = 20 − gt ⇒ t = 1s
2 2

The accelerations and the tension in

Horizontal distance moved by particle the rope if all the masses are equal
A in 1 second is, to m1 = m2 = m3 = m
xA = uA cos 45° × t = 10√2 cos 45° × 1 = 10m 2 mg
∴ T =
3
, a1 = –g/3, a2 = –g/3, a3
Horizontal distance moved by particle = –g/3 and T = 2m/3
B in 1 second is,
Here if m1 = m3 = m and m2 = 2m
xB = uB × t = 10 × 1 = 10m
i.e. T = m
∴ d = xA + xB = 10m + 10m = 20m
Since, the direction of acceleration
4. Answer: D and mass of B is same.
→ →
Sol:
∴ T . F = cosθ

Suppose a be the downward ∵ θ = 0°

acceleration of the 4 kg mass,
therefore, 2a is the upward → →
T. F = 1
acceleration of the 1 kg mass. Hence,
equations of motion are : So, acceleration of pulley is same as
that of mass.
1 × 2a = T – 1g ...(i)
6. Answer: A
4a = 4g – 2T ...(ii)
Sol:
Adding, after multiplying the equation
(i) by 2, T - mg = ma

360 – 300 = 30 a
2g g g
8a = 2g or a =
8
=
4
or 2a =
2

a = 2 m/s2
Thus, the acceleration of the mass 1
g
kg is 2 up wards. 7. Answer: C

Sol:

Mass of the rope = 8 × 0.5 = 4kg

Acceleration = F 12 −2
= = 3 ms
m 4

Mass upto 4 m or mid-point = 2 kg

Force used to pull 2 kg = 2 × 3 = 6N

So tension at the mid-point = 6 N

8. Answer: C 10. Answer: C

Sol: Sol:

T – mg = ma

here a = 0

T = mg

9. Answer: B

Sol:

just after cut

Let us consider that 5 kg is the mass
and the a be acceleration.

N1 is the normal reaction on 5kg by

the mass 10 kg

The equations are given as:

mg mg g
aB =
m
= g aA =
2m
=
2
N1 − 5g = 5a ........ (1)

⇒ N1 = 5g + 5a

N1 denotes the normal reaction on

the 10 kg by 5 kg.

N2 denotes the normal reaction on

the 10 kg by floor.

The equations are given as :

N2 − N1 − 10g = 10a ....... (2)

⇒ N2 = N1 + 10g + 10a

From equation (ii) and equation (i) :

N2 = 5g + 5a + 10g + 10a

⇒ N2 = 5 × 10 + 5 × 3 + 10 × 10 + 10 × 3

⇒ N2 = 50 + 15 + 100 + 30

⇒ N2 = 195N
11. Answer: B 14. Answer: C

Sol: Sol:

Block is moving horizontally with

respect to ground. So net vertical
force is zero. So force by incline
(normal) in vertical direction will
balance mg.

15. Answer: B

Sol:
h = r − r cos θ F
a =
15
μ mg cosθ = mg sin θ
10F
f =
tan θ = u 15

cos θ =
1 16. Answer: C
2
√1+μ

Sol:
1
h = r (1 − cos θ) = r [1 − ] 1 2
√1+μ2 wA = k A xA
2

Therefore correct option is (B) wB =

1
kB x
2

2 B

12. Answer: A 2
wA kA x
A
=
Sol:
2
wB kB x
B

& kA xA = kB xB

wA kB
So,
1
= =
wB kA 2

17. Answer: C

Sol:
Suppose the roller is pushed as in
figure (B). The force F is resolved The gravitational force is
into two components, horizontal conservative, so the work done by it
component FH which helps the roller is independent of path, hence in both
to move forward, and the vertical cases 2 mv2 = mgh v = √2 gh;
1

component acting downwards adds to

independentofmass
the weight. Thus weight is increased.
But in the case of pull [fig (A)] the So, v1 = v2
vertical component is opposite to its
weight. Thus weight is reduced. So
pulling is easier than pushing the
lawn roller.

13. Answer: B

Sol:

Use work-energy theorem.

WET on system

mA g(1) − (μm g)(2)

B

2 2
+
1 1
= mA (0. 3) = mB (0. 6)
2 2

μ ≈ 0. 12
18. Answer: D 19. Answer: C

Sol: Sol:
→
ˆ
F 1
= 6 î − 6 ĵ + 3k

using equation of motion

→ → 2
→ 1
S = u t − a t
2

→ 2
ˆ
=0+
1
(1 î + 5 ĵ + 4k) a (2)
2

→ →
→ 1 î +5 ĵ +4k̂ F 1+ F 2
a = =
2 8

→
ˆ
F 2 = −2 î + 26 ĵ + 13k
By energy conservation,
→ →
w= F 2
⋅ S = ˆ
(−2 î + 26 ĵ + 13k) · 1 2 3R 1 2
Kx + mg ( ) = mv
2 2 2

ˆ ˆ ˆ
(1 i + 5 j + 4k) = 180 J
2
1 4 mg R 3 mgR 1 2
( )( ) + = mv
Therefore, the correct answer is (D)
2 R 4 2 2

2
gR + 3gR = v ⇒ v = 2√gR

20. Answer: D

Sol:
→ →
work = F . dr = −μN (2πr)

1
= −0.5 × 5 × 2 × π ×
π

=–5J
 Physics - Section B

21. Answer: 8 24. Answer: 40

Sol: Sol:

Time of flight : T =
2usinθ
= 2√2 sec displcement vector
g

Range (along north) =(2 î − 2 ĵ )−( î + ĵ )=( î − 3 ĵ )

2
u sin 2θ
= = 40 m
g
work done
Range (along east)
1 2
= a T = 30 m → →
2
Wg = F g. Δ S = 10 ( î − ĵ ).( î − 3 ĵ )

Range
2 2
∴ = √30 + 40 = 50 m
= 10 + 30 = 40 J
22. Answer: 20
25. Answer: 25.00
Sol:
Sol:
From Newton's third law,
External force will do the work
F = ma against friction and it will increase
net pulling force
the potential energy of rope.
anet =
total mass
m ℓ ℓ mgℓ
∴ ΔPE =( ) g =
F ℓ 2 4 8
a =
m1 +m2 +m3

40
a =
10+6+4

2
a = 2 m/s

By the equilibrium of forces at block

of 10kg
F − T = ma let the rope has shifted by ‘x’ then

40 – T = 10 × 2 m ℓ
fr(x) = μ ( + x)g
T = 20 N ℓ 2

ℓ/2 μmg ℓ
∴ ΔW2 (Against friction) = ∫ ( + x)dx
0 ℓ 2

23. Answer: 0 ℓ/2

2
μmg ℓ x
⇒ Δw2 = ( x + )
Sol: ℓ 2 2
0

Block start when μs mg = 4t μmg 3ℓ

2
3μmgl
= ( )=
ℓ 8 8

t = 9 sec
∴ ΔW = ΔPE + Δω2
At t = 5s block was at rest so answer mgl
= (1 + 3μ)
=0 8

4×10×2 5
⇒ ΔW = × = 25 Joule
8 2
 Chemistry - Section A

1. Answer: D 5. Answer: B

Sol: Sol:

Shortest S–O bond length is present

in -

2-Methyl cyclo pentane

1-carboxamide

Therefore the correct option is (A)

2. Answer: C

Sol:

As the size of the surrounding atom

increases the electronic repulsion
increases bond angle increases.

Bond angle ∝ size of surrounding

atom 6. Answer: B
The correct order of bond angle is : Sol:
PF3 < PCl3 < PBr3 < PI3 211. 6π pm

7. Answer: B
3. Answer: D Sol:

Sol:

Given :- Thershold frequency of

metal (minimum frequency) (υ ) 0

Minimum energy (E) = hυ0 =

6.626×10–34×4×1014 → Aldehyde has higher priority than
hydroxyl group, hence suffix of
= 2.64×10–19 J
aldehyde and prefix of hydroxyl is
Therefore, the correct answer is (D) being used.

4. Answer: B → The correct IUPAC name of the

compound is 2-Bromo-6-
Sol: hydroxybenzene carbaldehyde.

8. Answer: A

Sol:

Therefore, the correct answer is (B)

9. Answer: B 12. Answer: D
Sol: Sol:
Theory based We know, E =
hc
⇒ E∝
1

λ λ

10. Answer: C
and = R×Z2
1 1 1
( 2
– 2
)
λ n n

Sol:
1 2

for lyman series n = 1 and n2 = 2, 3

Answer: .........
Number the cycloalkene so that the

double bonded carbons get numbers

for Lyman series, spectral lines have
1 and 2, and the first substituent
smaller λ and thus higher energy
gets the lowest possible number
because (E∝ 1 )
λ

i.e. 13. Answer: C

If there is a substituent on one of the Sol:
double-bond carbons, it gets to number 1.

(1)

4-Aminomethyl-6-hydroxycyclohex-2-
ene-1-carboxylic acid

6 –Ethyl –1– methyl cyclohexene 14. Answer: C

Sol:

Theory based

15. Answer: A
(2)
Sol:

6 – Bromo – 1,3–dichloro 16. Answer: C

cyclohexene
Sol:

According to Bent’s rule s-character is

minimum in hybrid orbitals being
(3) used in formation of
P–F bonds in POF3 while more s–
character is in P–Br bonds.
Lower the s–character lower will
3– Amino– 5– formyl cyclohexane be the bond angle between two such
carboxylic acid hybrid orbitals. Hence
θ3 < θ1 < θ2 ]
therefore the correct option is option D.

11. Answer: B

Sol:
∙∙

P H3

According to Drago's rule.

17. Answer: C 18. Answer: A

Sol: Sol:

Number of atoms in 1 g of a Given:

substance = (mass / molar mass) ×
Avogadro’s number × (atoms per A M − F in which the
formula unit). electronegativity of electropositive
element (Xe ) ie M is 2. 1
Since metals Au, Na and Li have one
atom per formula unit and Cl₂ has We know, the electronegativity of
two atoms per molecule, compare the Fluorine is 3. 98
quantity
Percentage Ionic Character =
2
[16 × (ΔE. N. )] + [3. 5 × (ΔE. N. ) ]
1
atoms ∝ × α
M
where, ΔE. N.= difference in
where M is the molar mass and α is 1 electronegativity
for Au, Na, Li and 2 for Cl₂. ΔE. N.= 3. 98 − 2. 1 = 1. 88

Calculate 1M for each: Percentage Ionic Character =

2

Au (M = 197 g·mol⁻¹): 1
≈ 0.00508
[16 × (1. 88)] + [3. 5 × (1. 88) ]

197

Percentage Ionic Character =

Na (M = 23 g·mol⁻¹): 1
≈ 0.0435
23 [30. 08)] + [3. 5 × 3. 53]

Li (M = 6.94 g·mol⁻¹):
1

6.94
≈ 0.144
Percentage Ionic Character =
[30. 08)] + [12. 35]
Cl₂ (M = 70.9 g·mol⁻¹; α = 2):
2 ×
1
≈ 0.0282 Percentage Ionic Character =
70.9
42. 45%~ 43. 03%

Comparing these values shows Li(s)

Hence, option (1) is correct.
has the greatest number of atoms
per gram. 19. Answer: D

Sol:

Number of moles of electrons in 1 kg

is given by n = 1
. −31 23
9.108 ×6.023

Combine powers of 10: 10−31+23 =

10−8 moves to numerator as 108:

1
8
n = × 10
9.108 × 6.023

Denominator product 9.108×6.023 ≈

54.89, hence
1 8 6
n ≈ × 10 = 1. 82 × 10
54.89
20. Answer: C

Sol:

In CH3Cl and CH3F, contribution

of three C-H bond toward dipole
moment is comman.So dipole
moment depends only on C-Cl
and C-F bond.

Bond length(d) = C-Cl > C-F

(Because size of Cl is more than the

F)

Charge(q) = C-Cl < C-F

(Because electronegativity of F is
more than the Cl)

Dipole moment, μ =q×d

Product of (q×d) is more for C-Cl

bond than the C-F bond.

Hence dipole moment of CHCl3 is

more than the CHF3.

Correct answer is C.
 Chemistry - Section B

21. Answer: 7 23. Answer: 5

Sol: Sol:

Molecular mass of SO3 = 80

Molecular mass of CH4 = 16

The ratio of the density of a

substance to the density of a
standard is called relative density. It
is directly proportional to molar
mass.

1. This is secondary amine group. The relative density of SO3 gas with
2. This is acyl chloride group. respect to methane =
MSO
3
=
80
=5
3. This is ketone group. MCH
4
16

4. This is aldehyde group.

Answer:5
5. This is primary amine group.
6. This is alcohol group.
7. This is carboxylic acid group.
Answer: 7

22. Answer: 2

Sol:

P = 1 atm
}ST P /N T P
T = 273

Volume of = 22.4 litre

No. of Moles = Volume of gas

1 mole of gas

We also know that

Number of Moles= Weight in gram

Mole of
5.6
SOx = = 0.25
22.4

Mole of
16
SOx ⇒ 0.25 =
32+16x

x = 2;

The gas is SO2.

24. Answer: 3 25. Answer: 5

Sol: Sol:

The polarity of covalent bond can be

conveniently measured in terms of
physical quantity called dipole
moment.

(ii) Cl – Be – Cl BeCl2

(vii) C3 O2

μ ≠ 0

H2O, NH3, and HCl have non-zero

(viii)
dipole moment.

The number of species having the

linear shape is five.