1 MOST IMP QUESTIONS-JR .CHEMISTRY @LAQ Ss Chemical Bonding 1. What do you understand by Hybridisation? Explain different types of hybridization involving s and p orbitals. 2.Give an account of VSEPR Theory, and its applications 3.Give the Molecular Orbital Energy Diagram of (a) N. . and (b) 0,. Calculate the respective bond order. Write the magnetic nature of N2 and O, molecules. Periodic Table [define 1E1 and IE,. Why is IE2 > 1E1 for a given atom? Discuss the factors that effect IE of an element? 5.What is a periodic property? How the following properties vary ina group and in a period? Explain(a) Atomic radius (b) IE (c) EN (d) Electron gain enthalpy or electron affinity (e) Nature of oxides. 6.Write an essay on s,p,d and f- block elements. Atomic Structure 7. What are the postulates of Bohr's model of hydrogen atom? Discuss the importance of this model to explain various series of line spectra in hydrogen atom? 8.How are the quantum numbers n,| and m,s arrived at? Explain the significance of these quantum 9.Define atomic orbital. Explain the shapes of s, p and d orbitals with the help of diagrams.? Organic chemistry 10. Describe the methods of preparationof ethane .Explain the chemical properties of ethane with equations. 11..Describe the methods of preparation of ethylene. How it reacts with i)ozone ii)hypohalous acid iii)cold.dil.alk.KMnO4_ iv)O2 12.Give two methods of preparation of acetylene, how does it react with water and ozone? 13.Give any two preparation methods of Benzene ,and explain i)halogenation ii)alkylation iii)accylation iv)Nitration v)SulphonationChemical Bonding -SAQ'S 1.State Fajan's rules with suitable examples. 2.What is Hydrogen bond? Explain the different types of Hydrogen bonds. 3.Explain the structure of PCI5 molecule - sp?d hybridisation. 4.Explain the structure of SF6 molecule -sp?d? hybridisation. 5.Explain the formation of Coordinate Covalent bond with one example. States of matter 6.Derive the ideal gas equation from gas laws. 7.Give the important postulates of kinetic molecular theory of gases. 8.Deduce (a) Boyle's law (b) Charle's law (c)Dalton’s law(d).Graham's law from kinetic gas equation. 9.State and explain Graham's law of diffusion. 10.Find kinetic energy of 5 moles of an ideal gas in calories at 27°C. 11.Calculate kinetic energy of 2 moles of Nitrogen at 27° C. 12.Calculate the ratio of kinetic energies of 3g of hydrogen and 4g of oxygen. THERMODYNAMICS 13.State and explain'Hess law of constant heat summation" with exp. 14. Define heat capacity. What are Cp and Cv.Show that Cp-Cv=R. CHEMICAL EQUILIBRIUM 15. Define Le Chatelier principle and mention the conditions for the preparation of the ammonia(NH3) by Haber's process. 16. Discuss the application of Le-Chatelier's principle for the industrial synthesis of Sulphur trioxide (S03) by Contact process. 17. Explain Lewis acid-base theory with examples. 18.Explain the Bronsted-Lowry acid-base theory with example. 19.Calculate the pH of 0.001 M HCI solution. 20 Calculate pH of a 10-8 M solution of HCl. 21.Calculate the pH of 0.05M H2S04 solution. 22.Calculate the pH of 0.001 M NaOH HYDROGEN & ITS COMPOUNDS 23. Write a few lines on the utility of hydrogen as a fuel. 24. Explain the terms hard water and soft water. How is hardness of water removed by Calgon method? 25. Write any two oxidising & reducing properties of hydrogen peroxide. on the basis of their structures.26.Explain, with suitable examples, the following: i) Electron deficient ii) Electron-precise P-BLOCK ELEMENTS(GROUP-13&14) 27. Explain Borax bead test with a suitable examples. 28. Explain the structure of diborane. 29. Explain the differences in properties of diamond and graphite. 30.How does diborane reacts with i)CO ii)NH3 iii)N(CH3)3 iv)H20. STOICHIOMETRY 31.Calculate the oxidation numbers of oxygen in (i) O2F2 (ii) OF2 32.Calculate the oxidation number of chromium (Cr) in Cr,07(-2) ion 33.Calculate the oxidation number of Cr in K2Cr207. 34.Calculate the oxidation number of Mn in KMn04, MnO4(-2) 35.How many number of moles of glucose are present in 540 grams of glucose. 36.Calculate the weight of 0.1 mole of Sodium carbonate. 37.The empirical formula of a compound is CH20.Its molecular weight is 90 .Calculate the molecular formula of the compound. 38.Balance the following redox equation in acidic medium by ion-electron method: —_ > Fe(+2) (aq) + Cr207(aq)-------->Fe(+3)(aq)+Cr(+3).(aq) 39.Balance the following redox reactions by ion-electron method. Cr,07(-2) (aq)+ SO3(-2)(aq) —— >Cr(+3)aq +S04(-2)(aq). 40.A compound contains 4.07% hydrogen, 24.27% carbon and 71.65% chlorine. Its molar mass is 98.96 g. What are its empirical and molecular formulas? 41.A carbon compound contains 12.8% carbon, 2.1% hydrogen, 85.1% bromine. The molecular weight of compound is 187.9. Calculate the molecular formula.VSAQ'S If A&B are two different atoms when does AB molecule become Covalent @? 1. Why H20 has higher BP than HF? 2. What type of bonds are present in NH4Cl?write its structure. 3. Give two chemical equilibrium reactions for which kp=kc. 4. What's are Lewis acids ? Give example. 5. What is the effect of pressure on gaseous reactions. 6. What is dynamic equilibrium? 7. Why does BF3 behaves as Lewis acid? 8. Why the gas constant "R'is called universal gas constant? 9. Which of the gases diffuses faster among N2,02,and CH4. 10. What is Boltzman's constant?Give its value. 11. What is compressibility factor?What is surface tension? 12. Write the effect of temperature on surface tension and viscosity. 13. What is an ideal gas? 14. Write completely the electronic configurations of K and Rb 15. Lithium reacts with water less vigorously than sodium. Give your reasons 16. Explain the biological importance of Magnesium & Calcium 17. What happens when magnesium metal is burnt in air? 18. Write a balanced equation for the formation of ammoniated II A metal ions from the metals in liquid ammonia. 19. Why ko2 is paramagnetic and calculate oxdation state of K? 20. Whay does the solubility of alkaline earth metal carbonates and sulphates in water decreases down the group? 21. Why does potassium carbonate can't be prepared in solvay process? 22. Write any two uses of Mg metal. 23. Lithium salts are mostly hydrated. why? 24. What are the characterstic colours imparted by the IIA elements? 25. What happens, When Mg(NO,)2 is heated ?Give the balanced equation. 26. Describe the important uses of caustic soda. 27. Describe the important uses of sodium carbonate 28. Describe the important uses of quick lime 29. Why are alkali metals not found in the free state in nature30. Which is called milk of magnesia?Give its uses? 31. Write the properties of Washing soda. 32. Why are IA group elements called as alkali metals 33. Why is gypsum added to cement? 34. What is chemical oxygen demand (COD)? 35. a) What is Bio chemical oxygen demand (BOD)? b) Give the possiable BOD values for clean water and poluted water. 38. Define Receptor? 39. What is Green house effect? It is caused by. the harmful effects caused by Global warming. 39.Which oxides cause acid rain ? and what is its pH value? Name two adverse effects caused by acid rains. 40. What is classical smog? and what is its chemical character . 41. What is photo chemical smog? and what is its chemical character 42 What is PAN? What effect is caused by it. 43.What agrochemicals are responsible for water pollution? 44.Define the terms Sink, TLV ,Receptor 45.Mention the harmful effects caused due to depletion of ozone layer. 46 Name the common components of photochemical smog. 47.How many no of moles of glucose are present in 540 gms of glucose 48.Calculate the weight of 0.1 mole of sodium carbonate 49 What is a redox concept ? Give an example 50.What do you mean by significant figures? 51.The empirical formula of compound is CH,0. Its molecular weight is 52. Calculate the molecular formula of the compound. 53.What are the disproportionation reactions? Give examples. 54.What are comproportionation reactions? Give examples 55.What volume of CO, is obtained at STP by heating 4g of CaCO,? 56.1 Define molarity, molality and molefraction 57.Calculate the volume of 0, at STP required to completely burn 100m! of acetylene. 58.Calculate the oxidation number to the under lined elements. (a) H,S04 (b) H,S,08 (c) Cro5 (d) Br,08 (e) K.Mn04(f) NaH,PO4 59.A solution is prepared by adding 2gm of a substance A to 18gm of water. Calculate the mass percent of the solute. .and...gases.Mention60.Calculate the molarity of NaOH in the solution prepared by dissolving 4gm enough water to form 250ml of the solution. 61.How many numbers of CaCO, moles present in 200grams of CaCO,? 62.Calculate the oxidation number of 'Cr' in K2Cr207 63.Calculate the oxidation number of Maganese (Mn) in KMn04, 64.Calculate the amount of carbon dioxide that could be produced when one mole of carbon is burnt in 16 g of dioxygen. 65.Calculate the pH of 0.05M NaOH solution. 66.Calculate the pH of 0.05M H,SO, solution 67.Find the pH of 0.05 M Ba(OH), aqueous solution 68.Calculate the PH of 0.1M HCI solution? 69.Calculate the PH of 10-8 M HCI solution? 70.Write the reagents required for conversion of benzene to methyl benzene 71.How is nitrobenzene prepared 72.Write the structures of: Trichloroethanoic acid, Neopentane, Pp nitrobenzaldehyde 73.Discuss Lassaigne's test 74.Write the IUPAC names of (a) CHy-CHy-CH,-CH=CH, (b FO © AC @ WM St Ws Ug w cr ~ we 75.Write the structural formula of the given compounds - (a) 3,4,4,5-Tetramethyl heptane (b) 3-Ethyl-4,4-dimethylheptane (C) 2,4 dimethylpentane 76.Write a short notes on a) Wurtz reaction (Mar-17) b)Fridel craft alkylation