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VARUN ADVANCED BATCH

Gaseous State DPP - 03

Single Correct (1 – 7) 6. One mole of each gases A, B, C and D with van der
1. On a certain day, the vapour pressure is 24 mm of Waals constant (atm L2 mol-2) 1.348, 6.823, 4.390
Hg for water vapour in air at 300 K. The saturated and 2.438, respectively, are kept separately in four
different vessels of equal volumes at identical
vapour pressure is 26.463 mm. How many moles of
temperature. Their pressures are observed to be PA,
water vapour per litre of air would be required to PB, PC and PD, respectively. On the basis of this data
saturate the air at this temperature? alone, the order of pressure of gases is (assume
(1) 0.1 (2) 0.0132 other van der Waals constant to be nearly same for
(3) 1.32 × 10-4 (4) 7.60 all gases)
(1) PA < PB < PC < PD
2. In a glass tube of uniform cross section, a mixture (2) PB < PC < PD < PA
(3) PB < PA < PC < PD
of HCl and He gases are sent from one end and a
(4) PC < PB < PD < PA
mixture of NH3 and Ar gases are sent from the
another end at the same time. The white fumes of 7. Under what pressure will carbon dioxide have the
NH4Cl will appear first density of 2.2 g/ litre at 300 K? For CO2, a = 3.6
(1) at the middle of the tube. atmL2 mol–2 and b = 0.05 mol–1 L.
(2) closer to NH3 end. (1) 1.23 atm (2) 1.28 atm
(3) closer to HCl end. (3) 2.46 atm (4) 0.64 atm
(4) at the NH3 end.
8. Gases do not liquefy above the critical temperature
because above the critical temperature,
3. At what temperature does the average translational
(1) the gases become ideal.
K.E. of a molecule in a gas becomes equal to the (2) the intermolecular attraction vanishes.
K.E. of an electron accelerated through a potential (3) the kinetic energy of molecules become so
density of 3 V? large that the attractive forces become unable
(1) 232 K (2) 2320 K to hold the molecules together.
(3) 23,200 K (4) 2,32,000 K (4) the repulsive forces dominatesin the
molecules.
4. The assumptions of the kinetic theory of gases are 9. A gas can never be liquefied at
most likely to be incorrect for gases under which of (1) T = TC and P = PC
the following conditions? (2) T < TC and P = PC
(1) High temperature and high pressure. (3) T < TC and P < PC
(2) High temperature and low pressure. (4) T > TC and P >> PC
(3) Low temperature and low pressure.
One or more than one correct
(4) Low temperature and high pressure.
10. As a gas (insoluble in liquid) is bubbled through a
liquid, part of the liquid vaporizes and these
5. In the case of positive deviation from an ideal gas vapours are carried of with the gas. As a sample of
𝑃𝑉
(1) Interactions in molecules, >1 dry nitrogen gas is bubbled through a liquid, it is
𝑛𝑅𝑇
𝑃𝑉 found that under identical conditions of
(2) Interactions in molecules, <1 temperature and pressure, a defi nite volume of wet
𝑛𝑅𝑇
𝑃𝑉 nitrogen gas weighs more than the equal volume of
(3) Finite size of molecules, >1
𝑛𝑅𝑇 dry nitrogen gas. Hence, the liquid through which
𝑃𝑉
(4) Finite size of molecules, <1 dry nitrogen gas was passed may be
𝑛𝑅𝑇
(1) water (2) benzene
(3) CCl4 (4) heavy water
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11. One mole of helium and one mole of neon are taken 15. The value of d in cm (shown in the figure), as
in a vessel. Which of the following statements are estimated from Graham's law, is :
correct? (1) 8 (2) 12
(1) Molecules of helium strike the wall of vessel (3) 16 (4) 20
more frequently.
(2) Molecules of neon apply more average force 16. The experimental value of d is found to be smaller
per collision on the wall of vessel. than the estimate obtained using Graham's law.
(3) Molecules of helium have greater average This is due to:
molecular speed. (1) larger mean free path for X as compared to that
(4) Helium exerts higher pressure than neon. of Y
(2) larger mean free path for Y as compared to that
12. At very high pressure, the compressibility factor of of X
1 mole of a van der Waals gas can be given as (3) increased collision frequency of Y with the
bP V b inert gas as compared to that of X with the
(1) Z  1  (2) Z  inert gas
RT V
V a (4) increased collision frequency of X with the
(3) Z  (4) Z  1  inert gas as compared to that of Y with the
V b VRT inert gas
13. van der Waals constant ‘a’ can be expressed as Integer Type Questions – Single Digit (0–9)
9 RTCVC 17. A mixture of H2 and O2 in 2 : 1 mole ratio is used
(1) (2) 3PCVC2
8 to prepare water vapour by the following reaction.
3 PV 27 R 2TC2 2H2(g) + O2(g) → 2H2O(g)
(3)  c C (4)  The total pressure of gases in the container is 4.5
8 TC 64 PC
atm at 57°C before the reaction. The final total
14. For a real gas (van der Waals gas), behaving
pressure of gases (in atm) at 127°C after reaction
ideally, the pressure may be
assuming 80% yield of water vapour is
Vm
(1) a·b·Vm (2)
a b 18. What would be the final pressure of O2 in the
a b following experiment? A collapsed polyethylene
(3) (4)
Vm  b a  Vm bag of 30 L capacity is partially blown up by the
addition of 10 L of N2 at 0.9 atm at 298 K.
Comprehension: 1 Subsequently, enough O2 is pumped into the bag so
𝑋 and 𝑌 are two volatile liquids with molar weights of that at 298 K and external pressure of 1.1 atm, the
bag contains full 30 L. If the answer is x atm, then
10 g mol−1 and 40 g mol−1 respectively. Two cotton
the value of 10x is
plugs, one soaked in 𝑋 and the other soaked in 𝑌, are
simultaneously placed at the ends of a tube of length 𝐿 =
19. Pure water vapour is trapped in a vessel of volume
24 cm, as shown in the figure. The tube is filled with an
10 ml. The relative humidity is 40%. The vapour is
inert gas at 1 atmosphere pressure and a temperature of
compressed slowly and isothermally. The volume
300 K. Vapours of 𝑋 and 𝑌 react to form a product which
of vapour (in ml) at which first drop of liquid will
is first observed at a distance 𝑑 cm from the plug soaked
form is
in 𝑋. Take 𝑋 and 𝑌 to have equal molecular diameters
and assume ideal behaviour for the inert gas and the two 20. A container with a volume of 20.0 L holds N2(g)
vapours. and H2O(l) at 300 K. The pressure is found to be
1.0 atm. The water is then split into hydrogen and
oxygen by electrolysis. After the reaction is
complete, the pressure is 1.86 atm. What mass (in
g) of water was present initially in the container?
The aqueous tension of water at 300 K is 0.04 atm.
(R = 0.08 L-atm/K-mol)
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Answer Key

1. (3) 11. (1, 2, 3)

2. (3) 12. (1, 2)

3. (3) 13. (1, 2, 4)

4. (4) 14. (3)

5. (3) 15. (3)

6. (2) 16. (4)

7. (1) 17. (4)

8. (3) 18. (8)

9. (4) 19. (4)

10. (2, 3) 20. (9)

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