Sri Chaitanya IIT Academy, India 24-08-25_Sr.

Super60_STERLING@ BT_Jee-Main_CTM-01_Key & Sol’s

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_STERLING BT JEE-MAIN Date: 24-08-2025
Time: 02:00PM to 05:00PM CTM-01 Max. Marks: 300

KEY SHEET
MATHEMATICS

1) 2 2 2 3) 3 4) 1 5) 1
6) 2 7) 3 8) 1 9) 2 10) 1
11) 3 12) 3 13) 1 14) 2 15) 2
16) 1 17) 1 18) 2 19) 3 20) 4
21) 4 22) 2 23) 2 24) 4 25) 96

PHYSICS

26 4 27 2 28 1 29 1 30 4
31 1 32 1 33 3 34 1 35 4
36 4 37 4 38 1 39 2 40 1
41 3 42 4 43 3 44 4 45 2
49 30 47 41 48 12 49 2 50 2

CHEMISTRY

51 3 52 2 53 3 54 1 55 1
56 3 57 4 58 2 59 2 60 3
61 2 62 4 63 4 64 4 65 1
66 2 67 4 68 1 69 3 70 4
71 1 72 3 73 3 74 9 75 4

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 Sri Chaitanya IIT Academy, India 24-08-25_Sr.Super60_STERLING@ BT_Jee-Main_CTM-01_Key & Sol’s

SOLUTIONS
MATHEMATICS

 1 
1.  Tan
K 1

1

 2K 
2 


  2 K  1   2 K  1 
Tan 1    Tan  2 K  1  Tan  2 K  1
1 1

1   2 K  1 2 K  1 

S  tan 1   tan 1 1 
4
2. f  x  is discontinuous at x  1 and x  2
 f  f  x   may be discontinuous when f  x   1 or 2
Now 1  x  1  x  0 , where f  x  is continuous
x  2  1  x  1 1, 2 
4  x  1  x  3   2, 4
Now 1  x  2  x  1  0,1
x  2  2  x  0   0, 2
4  x  2  x  2   2, 4
Hence f  f  x   is discontinuous at x  2,3

3.
2sin 2 x  3sin x  4  sin 2 x  6sin x  2  tan 2 x   2sin 2 x  3sin x  4    sin 2 x  6sin x  2 
lim  lim
x cot 2 x x 2sin 2 x  3sin x  4  sin 2 x  3sin x  2
2 2

tan 2 x  sin 2 x  3sin x  2 

 lim

x
2
2sin 2 x  3sin x  4  sin 2 x  6sin x  2
sin 2 x  sin x  1 sin x  2  1 sin x  1 1 1  sin x
 lim   lim  lim
x

cos x 9  9
2
6 x  1  sin x 6 x  1  sin x 1  sin x 
 2 
2 2 2
1 1 1 1 1
 lim  . 
6 x   1  sin x 6 2 12
2

4. lim  h 1  h  1   lim  h 1  h  1 
h 0 h 0

 h 
lim g  2   h     lim  2  h   f  h  
h0
  h  h 0
lim g  2  1  1  lim g  0  1
h 0 h 0

lim g  1  1  lim1

h 0 h 0

5. The period of x   x is 1.
The period of x   x  is 1.
The period of  x   x  is 1.
2


The period of sin  x  1


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 Sri Chaitanya IIT Academy, India 24-08-25_Sr.Super60_STERLING@ BT_Jee-Main_CTM-01_Key & Sol’s
The period of cos  x  1
The period of tan  x  1
Thus each of the above functions is a period 1. Therefore their L.C.M is 1.
Hence the function f  x  is periodic with fundamental period = 1.

6. Given that x 2  y 2  z 2  r 2
 xz 
Now, tan 1    tan 1    tan 1  
xy yz
 zr   xr   yr 
xy yz xz xyz
   3
1 zr xr yr r
 tan
 x2  y2  z2 
1  
 r2 
xy yz xz xyz
  
zr xr yr r 3
 tan 1
r2
1 2
r

 tan 1  
2
 f  x  h  f  x 
7. f '  x   lim  
h 0
 h 
 f  x  h 1 
f '  x   lim f  x   
h 0
 h 
ln f  x   3ln x  C
ln f  x   ln x  C  f  x    x3
3

f 1      1
 f  x   x3 or f  x    x3
But f 1  1
 f  x   x3

8. Min  x   x  ,1  x   x 
h  x   min  x   x  ,1  x   x 
Always continuous in  2, 2 but not differentiable at 7 points

 24 
9. f  x   3 f    4 x, x  0 ...... 1
 x 
24
Replace x by
x
 24   24   24  96
f    3 f    4   ........  2 
 x   24   x  x
3   2   1

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 Sri Chaitanya IIT Academy, India 24-08-25_Sr.Super60_STERLING@ BT_Jee-Main_CTM-01_Key & Sol’s
96.3 36 x
 8 f  x   4x  f  x  
x x 2
 3   36 
f  3   f  8    12      4   11
 2  8 
10. The probable values of x that could cause discontinuities are the roots or specific values
where the integer
Part changes between consecutive integers. The transitions happen when :
 1, 2,3, 4, 5, 6, 7,8
 x  2, 2, 6, 2 2, 10, 2 3, 14, 4
For the term  x  :
The values of x where  x  changes are straightforward. They occur at : x  1, 2
Discontinuity check
By evaluating f  x  at all these potential points, we find the function is indeed
discontinuous at
x  1, 2, 2, 6, 2 2, 10, 2 3, 14
Thus the function f  x  has 8 discontinuities on the interval  0, 4
11. a  sin 1  sin 5  5  2 and b  cos1  cos 5  2  5
 a 2  b 2   5  2    2  5 
2 2

 8 2  40  50
7  19   39   64 
12. cot 1    cot 1    cot 1    cot 1    ........
4  4  4   4 
 4r 2  3 
Tr  cot 1  
 4 
 
 1 
Tr  tan 1  
  3  r2  
4 
 
 1  1
 r  2r  2 
Tr  tan 1     
 1  r 2
 1/ 4 
 
 
  1  1 
 r  2 r  2  
Tr  tan 1      

1 r  1   1 
  r   
  2  2
13. Let x  2  cos  and y  2  sin 
x  y  4  sin   cos   maximum of  x  y  is 4  2
x  y  cos   sin   maximum of x  y is 2
f    xy  4  2  sin   cos    sin  cos 
f '    2  cos   sin    cos 2  0  tan   1 or 2  sin   cos   0 rejected

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 Sri Chaitanya IIT Academy, India 24-08-25_Sr.Super60_STERLING@ BT_Jee-Main_CTM-01_Key & Sol’s
  1
f    42 2 
4 2
x 2  cos 
g      g '   
 2  sin    sin     2  cos    cos 
y 2  sin   2  sin  
2

1
g '    0  2 sin   sin 2   2 cos   cos 2   0  sin   cos   
2
  1   1 
  cos 1   . Let   cos1  
4 2 2 2 2
  7 1   7 1
cos      and sin     
4  4 4  4
x 7 7 4 7
Maximum value of is 
y 7 7 3
f  3x  3 y  f  3x  3 y 
14.   x, y  
sin  2 x  2 y  sin  2 x  2 y 
 2x 
 f  x   k sin  
 3 
2
Therefore f '  0   k  1
3
3
k
2
3  2x 
 f  x   sin  
2  3 

So f '   
3 3
2 4
15. f  x   cos x  x  1
f '  x    sin x  1
f ' is decreasing  x  R
f  x  0
f  0   2, f     
f is strictly decreasing in  0,   and f  0  . f    0
 only one solution of f  x   0
Only S1 is correct
16. The slope of the tangent to y 2  4 x at 16,8 is given by
 dy   4  2 1
m1       
 dx 16,8  2 y 16,8 8 4
The slope of the tangent to x 2  32 y at 16,8 is given by
 dy   2x 
m2      1
 dx 16,8  32 16,8

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 Sri Chaitanya IIT Academy, India 24-08-25_Sr.Super60_STERLING@ BT_Jee-Main_CTM-01_Key & Sol’s
1
1
 tan   4  3    tan 1  3 
1 5  
1 5
4

17. We have, f  x   2 x  cot 1 x  log 1  x 2  x 
1 1  x 
 f '  x  2     1
1 x 2
1 x  x  1 x
2 2

1  2x 2
1
 f '  x  
1 x 2
1  x2
1  2 x2 1  x2
 f '  x  
1  x2 1  x2

 f  x 
'
x2  1  x2  1  x  1  0 for all x
2

1  x2
Hence, f  x  is an increasing function on  ,  
18. Given equation of the curve y  1  x   cos 2  sin 1 x 
2y

At x  0 ; y  2
Hence the equation of normal at  0, 2 
x  4y  8
4
19. Let x be the radius and V be the volume of the sphere. Then, V   x3
3
dV
  4 x 2
dx
We have x  100 and x  x  98
 x   2
dV
Now, V  x
dx
  dV  
 V  4  1002  2     4  1002 
  dx  x 100 
 V  80000
20. Given, y  x 2  x  1
dy
  2x 1
dx
dy
At 1,1 ,  3  m
dx
 Length of tangent,
y1 1  m 2 1 1 9 10
A  
m 3 3
y1 1
Length of subtangent, B  
m 3
Length of normal,
C  y1 1  m 2  1 1  9  10

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 Sri Chaitanya IIT Academy, India 24-08-25_Sr.Super60_STERLING@ BT_Jee-Main_CTM-01_Key & Sol’s
And length of subnormal, D  y1m  3
Now, increasing order is B,A,D,C

1
21. Let x 
y
  1 
 lim  x  x 2 log e 1   
x 
  x 
 1 log e 1  y  
 lim   
y 0 y
 y2 
 y  log e 1  y  
 lim  
y 0
 y2 
  y 
2

 y  y  
 2  1
 lim  
y 0  y 2
 2
 
 

 1  x2   
22. tan 1  
2x
2 
 1 x 
 cot 1    x  tan   tan 1
x   x  tan
 2x  3 12
   
    case-II :   2  0
 4 4 2
    
tan 1  tan 2   cot 1  cot 2   .........  i     2   2    2 
3  2 2 3
 2
Case – 1: 0  2  4  
2 3
  
2  2    tan   
3  6
   2 3  3 1
sum = tan    tan     2  3   
1

12  12  6 3 3
  4 
tan 1 x   2 
12  3
  2

23. If f  x  is not one-one then atleast one horizontal line should intersect it at two points
b
0 1
2
 0  b  2
 b   2, 0 
 2 x, 2  x  1
  x, 1  x  0
24. f  x    clearly f  x  is discontinuous at x  1 also non differentiable.
 0, 0  x 1
 x  1, 1  x  2
 m 1

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 Sri Chaitanya IIT Academy, India 24-08-25_Sr.Super60_STERLING@ BT_Jee-Main_CTM-01_Key & Sol’s
Now for differentiability
1, 2  x  1
1, 1  x  0

f  x   clearly f  x  is non-differentiable at x  1, 0,1
 0, 0  x 1
1, 1  x  2
also f  x  remains same.
n  3
m  n  4
4x  5 
25. f  x   cos 1  
 3x  7 
 4x  5 
 1    1
 3x  7 
 4x  5 
   1
 3x  7 
4 x  5  3x  7
0
3x  7
7x  2
 0
3x  7

2 7
7 3
Domain of f  x  is
 2 2
 12, 7    12,   7
g  x   log 2  2  6log 27  2 x  5  
Domain
2  6log 27  2 x  5  0
 6 log 27  2 x  5   2
1
 log 27  2 x  5 
3
 2x  5  3
 x  1
5
& 2x  5  0  x  
2
Domain is x    , 1
5
 2 
5
   ,   1
2
 2  5 
7      4       7  12    4    1
 7  2 
82  14  96

SEC: Sr.Super60_STERLING BT Page 8

 Sri Chaitanya IIT Academy, India 24-08-25_Sr.Super60_STERLING@ BT_Jee-Main_CTM-01_Key & Sol’s
PHYSICS
26. 10  v 1 R  330
 
5 v n R  3 00

11 1
n 
10 4
m  1  n  28 gm
27. TV  1  constant
7 7
1 1
T1 V 5  T2 (32 V ) 5
T2 1 1
 2/5

T1 (32) 4
T2 1 3
  1  1 
T1 4 4
28.
TV 3/2  Constant
PV 5/2  Constant
R
C  CV
1 n
5
 R
6
29. Conceptual

30.
W  60  100  6000J
QS  ncp T1  nc v T2 f=6
10000 12000
 4R   3R 
R R
 76000 J
6000 3
  
76000 38

31. A) Volume increase so W>0

PV product increases so temperature increase
U  0 so Q  0
B) Volume decrease so W < 0
PV product decreases so temperature decreases
U  0 so Q  0
C) Cycle is antilock wise W<0
Wcycle  Qcycle
(D) Isobaric process with increase in pressure so W  0 & Q  0

32. Conceptual
33. Conceptual

SEC: Sr.Super60_STERLING BT Page 9

 Sri Chaitanya IIT Academy, India 24-08-25_Sr.Super60_STERLING@ BT_Jee-Main_CTM-01_Key & Sol’s
34.
E   A(819) 4 .....(i )
E0 C   A(273) .....(ii )
4

E E
 34  E0 C
Eo0 81
35.
0
TFe A Fe M cuScu
0

TAl A Cu M FeSFe
lcu cu Scu

lFe Fe SFe
2

xy
36.

R  10  5
20  10  5
3

2
37. Principal of reversibility of light rays. You should aim the laser light directly to the
satellite.
38. TIR+ source shifted upwards
60
39. r  30 cm
2

f
 tan C
d
r 3

d 4
4r
d  40 cm
3

SEC: Sr.Super60_STERLING BT Page 10

 Sri Chaitanya IIT Academy, India 24-08-25_Sr.Super60_STERLING@ BT_Jee-Main_CTM-01_Key & Sol’s
40. at minimum deviation, i=e.
 min  2i  A
30  60  A
A  300
 A   min 
sin 
 2  sin 300 2
Now,    
 A sin 150
3 1
sin  
2
41.
1 1 1
 
v u f
1 dv 1 du
 2  0
v dt u 2 dt
 v2 
 v I / M  2 vO/ M
u
42.

F  10cm  R  10cm [ Lens Marks ]

Refraction at 1
lens air lens  air
  .....(i)
V1 u R
liquid lens liquid   lens
  .....(ii)
V V1 ( R)
2 1 1.5  1 2  1.5
   
V 40 10 10
2 1 1 1
  
V 40 20 20
2 1

V 40
V  80 cm

43.

Object is at 2f .So image will also be at ‘2f’ ( I1 ).

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 Sri Chaitanya IIT Academy, India 24-08-25_Sr.Super60_STERLING@ BT_Jee-Main_CTM-01_Key & Sol’s
Image of I1. will be 1m behind mirror.
i.e  I1
Now I 2 will be object for lens.
 u  3m
f  0.5 m
1 1 1
 
v f u
1 1
 
0.5 3
 0.6m from lens and real image.

44.
Q  mS T
T 1 1
 
Q mS capacity
45. Isotropic photographic enlargement
46.
f1 F
U n1 RT  2 n2 RT
2 2
5 3
 (6 RT )   (10 RT )
2 2
U  30 RT

47. 47.
1RT
P1 
M1
 RT
P2  2
M2
8 1 3

3 2 4
1 32

2 9
x  y  32  9  41
48.
100 S w 100  34   M s Lv
100 1 66  M s  540
6600
Ms   12.22 gm
540

SEC: Sr.Super60_STERLING BT Page 12

 Sri Chaitanya IIT Academy, India 24-08-25_Sr.Super60_STERLING@ BT_Jee-Main_CTM-01_Key & Sol’s
49.
1  3  1 1 
   1   f1  80
f1  4   20 
1  3  1 1 
   1    f 2  40
f 2  6    20 
f1 80
 2
f 2 40

50. Using
1  2   1 1 
   1   
f  1   R1 R2 
1  1.5   1 1 
  1   
f  1   R1 R2 
1  1.5   1 1 
  1   
f1  2   R1 R2 
f 0.5
we get 1  2
f 0.25

SEC: Sr.Super60_STERLING BT Page 13

 Sri Chaitanya IIT Academy, India 24-08-25_Sr.Super60_STERLING@ BT_Jee-Main_CTM-01_Key & Sol’s
CHEMISTRY

51. II without charges, all atoms have octet number of electrons.

III is more stable than I
Oxygen with –ve charge, carbon with +ve charge is more stable.
52.  CH 3 3 N : is nucleophile
: CCl2 is an electrophile.
53.

N
In , lone pair on nitrogen is not involved in delocalization
54. Correct order is
COOH , SO3 H ,  COOR,  COCl ,  CONH 2 ,  CN ,  CHO,  C O ,  OH and  NH 2
I

55. Preference of functional groups

56. In ‘A’, saturated to unsaturated
 elimination
In ‘C’ methyl shift takes place

57. In I, II and III products are not correct

58. In statement – II, intra molecular hydrogen bonding is present in ‘ Gauch’ form.

59. In IV peroxide effect

60. RCOOH  C6 H 5  OH  H 2O  ROH  C2 H 2  NH 3  CH 4

61. CF3 being strong  I effect group, addition of H 2O , to form ‘Q’ is not Markownikoff’s
rule.
62.
NO2

CaCO3   CaO s   3C  CaC2 
2 H 2O
 C2 H 2  3 C2 H 2 
Fe
 
Nitration

(X) (A) (B)
1/3 NO2
1 mole 1 mole 1 mole 1/3
D is C6 H 4  NO2 2
Mw of D is 72+4+28+64 = 168
1
 168  56 g
3
63.
H
 ET  E SP 3 is hybridised
+

SEC: Sr.Super60_STERLING BT Page 14

 Sri Chaitanya IIT Academy, India 24-08-25_Sr.Super60_STERLING@ BT_Jee-Main_CTM-01_Key & Sol’s
64.
‘ X’ is
Cl
Cl Cl
(BHC)

Cl Cl
CCl3 Cl

C6 H 6l6
‘Y’ is  291.0
- 195.5
96.5
65.
CH 3
 353 K  373 K  409  417 K

66. Electrophile for sulphonation is SO3

67. Conceptual
68. Stability of the carbocations, ring expansion and Cl  attack on 30 carbon.
69. Oxidation state of ‘Cr’ in the reagent is + 6
70. X is trans alkene + cis addition
Therefore Y is racemic mixture
P is cis alkene + cis addition
Therefore Q is meso compound
 Option 3 is correct, option 4 is incorrect.
71.
O
OH
H
H
Phenol
72. No. of chiral carbons – 2, symmetry exists.
 d, l and meso
73. II, III, VII & VIII
74.
Br
Br Br

 
NBr
 Br + + +
+
Br

+1 Br +1
+1
( enantiomer ) +1

75.  CH 2 and  CH gives CO2

SEC: Sr.Super60_STERLING BT Page 15