: ‫الدرجه‬ : ‫االسم‬

1 ‫امتحان‬ : ‫المجموعه‬

1)When acetylene gas is passed through water and the reaction conditions are applaied.
a compound is initially formed that is characterized by all of the following except …………….
a)unstable compound b)isomer of acetaldehyde
c)mono-hydroxy alcohol d)saturated alcohol

2)The compound 1,1,2-tri methyl cyclo propane is an isomer of each of the following except ………….
a)hexane b)propyl cyclo propane
c)Benzene d)Ethyl cyclo butane

3)Which of the following is not a use of alkanes or their Derivatives ...........

a)Protecting Preparing metals from rust b)dry cleaning compounds
c)freon manufacturing d)Preparing cooking utensils material

4)Which of the following is correct for acetic acid CH3COOH ……………

a)reacted with caustic soda then dry distillation for it we obtain ethane
b)produced by the reduction of acetaldehyde
c)Iupac name is called ethanoic acid d)aromatic organic acid

5)an hydrocarbon with a molar mass 106g/mol contains 4 bonds.

*What is the formula of the final compound when it reacts with an excess of bromine water ……………
a)C6H8Br6 b)C6H8Br4
c)C8H10Br8 d)C8H8Br8

6)Alkyne has 6 carbon atoms and not contain methylene group It may be ………...
a)4-methyl , 2-pentyne b)2,2-dimethyl , 3-butyne
c)a and d together d)3,3-dimethyl , 1-butyne

7)all of the following is a scientific name for the compound C4H8 except …….........
a)1-Butene b)2-Methyl Propene
c)Cyclo butene d)Methyl cyclo propane

8)The radical resulting from the dehydrogenation of ethene is called ………….

a)alkyl radical b)phenyl radical
c)vinyl radical d)aryl radical

9)When 2 moles of hydrogen are added to 6,6-di methyl , 3-heptyne it can form ..............
a)6,6-dimethyl heptane b)6,6-dimethyl heptene
c)2,2-dimethyl heptane d)3-Methyl hexane

10)The number of possible isomers for C4H9Br is ……...........

a)3 b)2
c)6 d)4

11)The following compound (CH3)2CHCH3 is called ……….........

a)Tri methyl methane b)2,2-Di methyl ethane
c)2-Methyl propane d)1-Methyl propane

12)Coal mines may explode if methane gas mixed with the air due to …….........
a)the heat absorbed as a result of combustion reduces the reaction rate
b)the heat absorbed as a result of combustion increases the reaction rate
c)the heat released as a result of combustion reduces the reaction rate
d)the heat released as a result of combustion doubles the size of the products
13)What are the steps required to obtain ethylene glycol from calcium carbide ……..…….
a)Dripping water then catalytic hydration then reduction
b)Dripping water then catalytic hydration then oxidation
c)Dripping water then partial hydrogenation then oxidation
d)Dripping water then catalytic hydration then catalytic hydrogenation

14)………………. Is the gas that can be prepared industrially in an impure form and mixed with a gas with an bad odor.
a)CH4 b)C2H6
c)C2H4 d)C2H2

15)The yellowish white substance that has high molecular weight and not affected by concentrated acids may be .............
a)CH2=CH2 b)CH≡CH
c)(CH2-CH2-)n d)CH4

16)In the catalytic hydration reaction of ethene , the function of sulfuric acid ……........
a)Breaking the Pi-bond and removing a water molecule
b)Removal of one water molecule because concentrated sulfuric acid is a dehydrator
c)Breaking the Pi-bond because water is a weak electrolyte
a)react by itself with ethene forming ethyl alcohol

17)It is possible to distinguish between ethene and ethyne gases by using …...........
a)KMnO4 solution in alkaline medium b)Bromine dissolved in CCl4
c)Hydrogen present in nickel d)Ammoniacal AgNO3

18)The number of sigma bonds between carbon atoms in the following compound : CH3C(CH3)2CH2CH3 is equal to .............
a)The number of methyl and methylene groups in the compound
b)The number of hydrogen atoms in the compound
c)The number of isomers of the alkane with molar mass is 58g/mol
d)The number of methyl groups in the compound

19)The substance {X} in the following reaction 3CCl4 + 2SbF3 → 3X + 2SbCl3 represents …………....
a)safe anaesthetic b)unsafe anaesthetic
c)laundry detergent d)Freon

20)By reducing the following compound CH3CH(CH3)CHO then removing water and then hydrogenating it.
we can get ………….....
a)alkane has molar mass 58g b)liquid alkane at room temperature
c)alkene has molar mass 42g d)an alkane polymerizes to give P.P

21)the method for preparing PVC polymer , it is preferable to use …….........

a)Calcium carbide / H2O / HCl b)Methane / H2O / HCl
c)Benzaldehyde / H2O / HCl d)Ethylene / H2O / HCl

22)Hydrogen propyl sulfate decomposes thermally to form …………….... and sulfuric acid.
a)propane b)propanol
c)Ethylene d)Propene

23)Which of the following properties increases with the thermal cracking of an alkane with no more than 8 carbon atoms …………
a)Boiling point b)Volatility
c)Molar mass d)Viscosity

24)Which compound gives a ketone when it is catalytically hydrated ……………

a)Ethene b)Propene
c)Ethene d)Propane

25)By oxidizing the isomer of vinyl alcohol and reacting the product with sodium hydroxide , compound (A) is formed.
*Which of the following choices is correct …………………
a)dry distillation of salt (A) give two carbon atoms alkane
b)A may be sodium acetate CH3COONa
c)Solution (A) is acidic to litmus paper
c)By passing (A) through a heated nickel tube benzene is formed
26)The molar mass of the alkane is 128 g/mol , When a thermal cracking process is performed , it produces X,Y and Z.
(X is simplest alkene ) and (Y is simplest alkane forming isomer)
*what is the number of Isomer for Z …………..
a)3 b)2
c)0 d)1

27)The correct order of the following compounds according to the number of sigma bonds …………..
a)C > A > B > D
b)D > A > C > B
c)A > C > D > B
d)A > C > B > D

28)When water is dropped on calcium carbide , compounds A and B are formed.

*Which expressions fit both A and B ...........
B A Choice
An acid that dissolve in Its complete hydrogenation a
water produces ethene
An acid that not dissolve It not react additionally b
in water
turbid lime water Reacts by substitution c
)‫(مطف‬
‫ي‬ Slake lime water Its polymerization produces d
benzene

29)What is the iupac name for the monomer of this polymer ………
a)1,1-Dimethyl ethene
b)2,2-Dimethyl ethene
c)1,2-Dimethyl ethene
d)2-Methyl propene

30)Catalytic reformation of methyl cyclo pentane by expanding the ring , we obtain ….........
a)C6H10 b)C6H8 ‫توسيع الحلقه‬
c)C6H12 d)C6H6

31)Ethylene glycol can form ............... bonds and their number is ........... when it dissolve in water.
a)Ionic / 2 b)Hydrogen / 2
c)Covalent / 2 d)Hydrogen / 4

32)The correct order for obtaining an alkane from an alkyne is ……………..

a)Neutralization - dry distillation - catalytic hydration - oxidation
b)Catalytic hydration - oxidation - neutralization - dry distillation
c)Dry distillation - neutralization - catalytic hydration - oxidation
d)Oxidation - neutralization - dry distillation - catalytic hydration

33)Ethylene glycol is prepared from methane in the following steps ……........

a)Halogenation - hydrolysis - oxidation
b)Heating and cooling - hydrogenation - catalytic hydrolysis
c)Heating and cooling - hydrogenation - oxidation
d)Heating and cooling - halogenation - hydrolysis

34)Non-alkyl and poly methylene hydrocarbons are consider .............

a)Cyclic alkanes b)Alkenes
c)Alkanes d)Alkynes

35)By applying Bayer addition reaction for 2-methyl , 1-propene it produce …............
a)Ethylene glycol b)Propylene glycol
c)1,2-dihydroxy , 2-methyl propane d)Pentylene glycol

36)Alkene has 3 carbon atoms and chlorine atom and bromine atom.
*How many isomers can form without contain a methylene group (CH2) ……………
a)3 b)2
c)5 d)1
37)The IUPAC nomenclature for the following compound is ….........
a)3-iodo , 5,5,4-trimethyl hexane
b)4-iodo , 1,1,3-trimethyl hexane
c)4-iodo , 2,2,3-trimethyl hexane
d)4-iodo , 2,2-dimethyl hexane

38)From the following reaction:

*What is compound A ..............
a)CH3CHO b)CH3CH2CHO
c)C2H5OH d)CH3COOH

39)When the simplest alkene containing ethyl branching is hydrogenated, it gives an isomer of ………......
a)pentane b)3-methyl pentane
c)normal hexane d)2,2-dimethyl propane

40)When 3 moles of HBr are added to vinyl acetylene CH2CHCCH ............... is formed.
a)The same product as adding a mole of bromine water then a mole of HBr to the compound 1-butyne
b)The same product as adding 2 moles of HBr to the compound 2-butyne
c)The same product as adding a mole of bromine water then a mole of HBr to the compound 2-butyne
d)The same product as adding a mole of H2 then a mole of bromine water to the compound 2-butyne

41)Paraffin has Number of Sigma bonds is equal to 19

*which of the following compounds is considered an isomer for it ……………….
a)2-ethyl butane b)2-methyl hexane
c)2-methyl pentane d)1,2-dimethyl butane

42)When pressure , heat and catalyst are applied to the monomer (C 6H5)2CCHCH3 it converted into the polymer ..............

43)The ratio between the number of moles of CO 2 produced from the combustion of the simplest branched alkene to the number of
moles of CO2 produced from the combustion of the simplest branched alkyne is equal to ………......
a)2:2 b)4:5
c)5:4 d)3:4

44)What is the IUPAC name for the corresponding compound …………….

a)Acetal
b)Methanal
c)Ethanal
d)Acetaldehyde

45)When butene gas is passed through dilute sulfuric acid at a temperature of 60°C and in the presence of HgSO 4.
*The compound …………………. Can be produced.
a)1-Butanonl b)1-Butanal
c)2-Butanone d)2-Butanol

46)The fifth member in the alkene contains ……………..

a)5 carbon atoms b)10 hydrogen atoms
c)2 pi bonds d)6 carbon atoms
 Essay Questions

1)Vinylacetylene is an unsaturated aliphatic hydrocarbon characterized by the presence of a double and a triple bond in the structure
represented in the following figure:

a)Calculate the number of sigma and pi bonds present in vinylacetylene.

b)How many moles of hydrogen are needed to convert it into a saturated compound.

c)What is the name of the saturated compound that it turns into when hydrogen is added.

2)How do you practically distinguish between each of the following:

a)Ethanol and dimethyl ether.

b)an organic compound and an inorganic compound.

3)Study the following steps and then answer :

a)Dehydration at 180oC then oxidation.
b)Dehydration then addition of HBr.
a)Oxidation then neutralization then dry distillation.
*Explain from the following reactions what the expected product is if we begin with ethanol for the three reactions.

4)from the compound in the figure :

a)State the name of the alkane resulting from the dry distillation of this compound.
b)what is molecular formula of the product.
c)what is the number of isomers of the product.