CHEMISTRY

MEMORY CARD
CHAPTER - 1 : BASIC PRINCIPLES & TECHNIQUES IN
ORGANIC CHEMISTRY
CHAPTER - 2 : HYDROCARBONS

for
NEET UDAAN
Challenger Batch & Prime Batch

Dr. Jyotsana | Dr. Ashwani | Dr. Rajat | Dr. Praveen | AMAN TILAK | dr. piyush | er. nikhil | sudhir SIR | NIKUNJ SONI
CHAPTER: BASIC PRINCIPLES AND TECHNIQUES IN ORGANIC CHEMISTRY
Which and from which inorganic compound Urea from Ammonium cyanate
organic compound was first synthesized?
Name two synthesis which showed (i) Acetic acid
conclusively that organic compounds could be (ii) Methane
synthesized from inorganic sources.
What is the principle of crystallization? Difference in the solubilities of the compound
and the impurities in a suitable solvent.
What is distillation used for? Used to separate
(i) volatile liquids from nonvolatile impurities
(ii) The liquids having sufficient difference in
their boiling points.
Give actual example of application of Chloroform and aniline
distillation
In fractional distillation, each successive Theoretical plate
condensation and vaporisation unit in
fractionising column called -
Give one technological application of Crude oil in petroleum industry
fractional distillation.
Give one technological application of Glycerol separated from spent-lye in soap
distillation under reduced pressure. industry
Give one technological application of steam Aniline from aniline-water mixture
distillation.
If the organic compound is less soluble in the Continuous extraction
organic solvent, a very large quantity of
solvent would be required to extract even a
very small quantity of the compound. What is
employed in such cases?
Name two types of chromatography based on (i) Adsorption chromatography
principle involved (ii) Partition chromatography
Name two types of adsorption (i) Column chromatography
chromatography (ii) Thin layer chromatography
Name two commonly used adsorbents Silica gel and Alumina
Give the formula of retardation factor
What is the thickness of adsorbent in TLC? 0.2 mm
At what distance above one end of TLC plate 2 cm
is small spot of mixture applied?
How are spots of colourless compound which Putting plate under ultraviolet light
produce florescence detected?
How are spots of colourless compound which Place plate in jar containing few crystals of
absorb iodine detected? iodine, appear as brown spots
What is the colour of spots of compunds Brown
absorbing iodine in TLC?
How are amino acids detected in TLC? Ninhydrin solution
REFER CLASSES CHART FOR QUALITATIVE
ANALYSIS
In case of compounds containing both S and If sodium fusion is carried out with excess of
N. what happens when sodium fusion is sodium, the thiocyanate decomposes to yield
carried in excess of sodium? cyanide and sulphide. These ions give their
usual tests.
NaSCN + 2Na → NaCN+Na2S
Give the general reaction of complete CxHy + (x + y/4) O2 x CO2 + (y/2) H2O
oxidation of hydrocarbons
In estimation of carbon and hydrogen, where In Platinum boat in U-tube containing anh. CaCl2
is the sample kept?
𝑎𝑡𝑜𝑚𝑖𝑐𝑖𝑡𝑦 𝑜𝑓 𝑒𝑙𝑒𝑚𝑒𝑛𝑡 𝑖𝑛 𝑐𝑜𝑚𝑝𝑑 × 𝑎𝑡𝑜𝑚𝑖𝑐 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑒𝑙𝑒𝑚𝑒𝑛𝑡 × 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑠𝑎𝑚𝑝𝑙𝑒 × 100
What is the general formula for quantitative %=
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑐𝑜𝑚𝑝𝑜𝑢𝑛𝑑 × 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑐𝑜𝑚𝑝𝑜𝑢𝑛𝑑

analysis of organic compound

To what compounds is Kjeldahl method not Nitro, Azo, nitrogen in ring
applicable? Give reason As nitrogen in these compounds does not
change to ammonium sulphate
Where is carius method performed? Hard glass tube known as carius tube
Molar mass of BaSO4 233 g
In what form is phosphorus estimated in (i) Ammonium phosphomolybdate
quantitative analysis? Give molar mass (NH4)3PO4.12MoO3 – 1877 g
(ii) Mg2P2O7 – 222 g
In what form is oxygen estimated in CO
quantitative analysis? How is it analysed? Using I2O5
What is the modern technique to analyse C, CHN elemental analyser
H, N in organic compounds?
What is the required quantity of sample for 1-3 mg
elemental analyser?

CHAPTER: HYDROCARBONS
How is coal gas obtained? Destructive distillation of coal
Where is natural gas found? Upper strata during drilling of oil wells
Which is the domestic fuel with least LPG
pollution?
Name other domestic fuel. What is its Kerosene.
drawback? Causes pollution
Which vehicle fuels cause less pollution? Petrol and CNG
In alkane, what is C-C bond length? 154 pm
In alkane, what is C-H bond length? 112 pm
How many isomers does C6H14 have? 5
How many isomers does C7H16 have? 9
How many isomers does C10H22 have? 75
Comment on physical states of alkanes C1 to C4 : gases
C5 to C17: liquids
Remaining gases
Give the conditions for halogenation of alkanes Higher temperature (573-773K) or in presence
of diffused sunlight or UV light
What is the heat of combustion for methane? -890 kJ mol-1
What is the heat of combustion for butane? -2875.84 kJ mol-1
What is formed during incomplete combustion Carbon black
of alkanes? Give its use. Manufacture of ink, printer ink, black pigments
and as filters
Give the conditions for following:

What is the reagent used for isomerisation of Anh. AlCl3 / HCl

alkanes?
What is the condition of aromatization of Alkane with six or more carbons
alkanes? Heating to 773 K at 10-20 atm pressure in
presence of Cr2O3 or V2O5 or Mo2O3
At what temperature does methane react with 1273 K, Ni
steam? What is the catalyst product? Water gas
What is the highest energy difference between 12.5 kJ mol-1
conformers?
What is the earlier name of alkanes? Paraffins
What is the earlier name of alkenes? Why are Olefins.
they called so? First member ethene forms oily liquid on
reaction with chlorine
What is C=C bond length? 134 pm
What are bond energies of σ and π bonds in 397 kJ mol-1 and 284 kJ mol-1 respectively
alkene?
What is the dipole moment of cis-But-2-ene? 0.33 D
What are temperatures required for
dehydration of alkanes using Al2O3?
What are concentrations required for
dehydration of alkanes using H2SO4?
What is Anti-markownikoff’s rule also known Kharash-Mayo effect/ Peroxide effect
as?
What is the C≡C bond length? 120 pm
Comment on physical states of alkynes C2 to C4 : gases
C5 to C12: liquids
Remaining gases
What is the condition of addition of water to 333 K, REFER LMRN FOR PERCENTAGE OF Hg2+
alkene/ alkyne?
What are kekulenes? Polybenzenoid compounds
What is the C=C reduced double bond length 140 pm
(as in benzene)?
What are naphthalene balls used for? Why? In toilets and preservation of clothes; Because
of unique smell and moth repellant properties
Comment on combustion of aromatic Burn with sooty flame
compounds