Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Jr.Super60_STERLING BT JEE-ADV-2023_P1 Date: 08-06-2025
Time: 09.00Am to 12.00Pm WTA-02 Max. Marks: 180

KEY SHEET
MATHEMATICS

1 ABD 2 A 3 ABC 4 B 5 B 6 D

7 B 8 0 9 0 10 54 11 14 12 12

13 9 14 A 15 B 16 B 17 A

PHYSICS

18 CD 19 AC 20 AD 21 D 22 D 23 B

24 A 25 2 26 56 27 15 28 2 29 3

30 29 31 A 32 A 33 A 34 C

CHEMISTRY

35 ABC 36 ABCD 37 ABCD 38 A 39 A 40 C

41 B 42 5 43 3 44 56 45 7 46 75

47 33 48 D 49 A 50 C 51 D
 Sri Chaitanya IIT Academy 08-06-2025_Jr.Super60_STERLING& BT_Jee-Adv(2023-P1)_WTA-02 _Key & Sol’s

SOLUTIONS
MATHEMATICS
1. log 2 ( x  2)  log 22 ( x  2)  log 2 ( x  2)2  log 2 ( x  2)
 ( x  2) 2  ( x  2)  ( x  2)( x  3)  0  x  (2, 3)
x 1
1  1 1
2. 1 x 2  
1 x 2
1 x  2
x 1
x  [1, 1]
3. Conceptual
4. 3  (n1  1)  4  1  (n2  1)  5 = 3  4n1  4  1  5n2  5
4n1  5n2  4  1 = 4n1  5n2  3 = n1  8 n2  7
First common term is 31
x x x 15 x  10 x  6 x 31x
5.    
2 3 5 30 30
x is LCM of (2, 3, 5)
6. ( abc) a b c  1  (abc) 0
a  b  c  0  a 3  b3  c 3  3abc
a 3 b 3  c3 )
Now, L.H.S. = 5log (abc  5log (3abcabc ) .........(1)
 1  log 3abc   1  log 33abc 
And R.H.S = 3  abc   3  abc 
 log 3   log 3 
 log 33abc 
 3 log abc  3 log abc  ............(2)
3 abc 
 3 
3 abc
abc 
From (1) & (2)
 log 3 
5log abc   3 log abc 
3 abc 3 abc

5 m
 
3 n
m  5; n  3  m  n  m  n  8  2  10
 x  3  x  1  x  9 
2 3 5

7.  0 is same as
( x  5)2
 x  3  x  1  x  9 
2 3 5
( x  5)2  0 and x  5

log 32 log 32
8. 2 3

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 Sri Chaitanya IIT Academy 08-06-2025_Jr.Super60_STERLING& BT_Jee-Adv(2023-P1)_WTA-02 _Key & Sol’s

9. 3x  8  0 so no solution
10. x  5 x  6  ( x  2)( x  3)
4

 f (2)  0  16  24  20  66  k  0
k  54
1
11. Given, , a, b are in G.P  16a 2  b
16
1 1 2 1 2 1 1 1
Also, , ,6 are in A.P.    6  2
 6 2  60
a b b a 16a a 8a a
1 8 1 1 1
 2   48  0   12,  4  a  ,
a a a 12 4
2
1  1 1  1 1
But a  0  a   b  16     72( a  b)  72     14
12  12  9  12 9 
12. G.M  ab
log ax log ab
13. x
 x
a
 log ab
a  log aa  log ba  1  log ba  4  3  log ba
log ab log x
k  3  k 2  9
14. I  x  0 x  6  0  x  (6, )
II  2  x  1  2
3  x  1  1  x  1
III  x  4, 2
( x  1)( x  2)( x  2)  0

IV 
2x 1
 3 
2 x  1  3  3x

 4  x   0   x  4  0  1  x  4
1  x  1 x 1  x   x  1
15. I) f ( x)  x 4  3 x  5
Remainder is f (2)  15
II) ( x  3 x  x  2)(2 x  x  3 x  1)
3 2 3 2

Coefficient of x 4 is -1
III) f (3)  0

   2.3x .3x 6   3x 6   0
2 2
x2 2
IV) 3

 
2 2
3x  3x 6  0  x2  x  6  0
Sum of solutions = 1
16. (I) b  c  a  d  2 10
a  b  c  d  40
(II) ( ar )  a  a r where a  2
2 2 2 2 2

r4  1 r2
r4  r2 1  0
Let r  t
2

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 Sri Chaitanya IIT Academy 08-06-2025_Jr.Super60_STERLING& BT_Jee-Adv(2023-P1)_WTA-02 _Key & Sol’s
t2  t 1  0
a  1, b  5

a 2  b 2  1  25  26 Ans.

(III) a, ar , ar G.P. r  1
2

a  ar  ar 2  70
10ar  4a  4ar 2
10r  4  4r 2
2 r 2  5r  2  0
2 r 2  4r  r  2  0
(2r  1)(r  2)  0
r  2 ( reject ) or r  1 / 2
For r  1 / 2
a  40
Series is 40, 20, 10
First term of G.P. is 40 Ans.
(IV) Conceptual

17. Conceptual

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 Sri Chaitanya IIT Academy 08-06-2025_Jr.Super60_STERLING& BT_Jee-Adv(2023-P1)_WTA-02 _Key & Sol’s

PHYSICS
18. Conceptual
19. Conceptual
1
20. s  ut  at 2
2
s 1 2u  at u  (u  at ) uv
Average velocity  vav   u  at  vav    vav 
t 2 2 2 2
Hence, (A) and (D) are correct
A  B  A.B  A2 B 2 sin 2   A2 B 2 cos 2   A2 B 2  sin 2   cos 2    A2 B 2
2 2
21.
Hence, the correct answer is (D)   
22. From the property of vector product, C is perpendicular to A as well as B . Also
    
 
A  B vector must lie in the plane formed by vector A and B . Thus C must be
    
   
perpendicular to A  B also but the cross product A  B gives a vector C which cannot
be perpendicular to itself. So, the last statement is wrong.
t t
v1  v2
23. v 2 2  v1  v2
t 2
2
u u2
v2  u 2 u 2
0
15
24. a  4  4 = s  5 cm
2s 2  15 2 s 3
25. In 40S, body completes 2 revolutions in 5S it covers 1 / 4th of the circle
Displacement  2R
v  u 6.9  4.1 2.8
26. a    0.56m / s 2
t 5 5
sx u2 4u 2 s
27.   = 3s  3 x  4 s = x 
s u 2 3u 2 3
u2 
4
28. Let the vector a make angle  ,  and  with x, y and z axis respectively. Then
2  2
iˆ  a  iˆ a sin 2   iˆ  a  a 2 sin 2 
2 2
Similarly  ˆj  a  a 2 sin 2  and kˆ  a  a 2 sin 2 
2 2 2
Now iˆ  a  ˆj  a  kˆ  a  a 2  sin 2   sin 2   sin 2   .........(1)
Now since cos 2   cos 2   cos 2   1
 1  sin 2    1  sin 2    1  sin 2    1  sin 2   sin 2   sin 2   2..........(2)
2 2 2
From (1) and (2) we get iˆ  a  ˆj  a  kˆ  a  2a 2

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 Sri Chaitanya IIT Academy 08-06-2025_Jr.Super60_STERLING& BT_Jee-Adv(2023-P1)_WTA-02 _Key & Sol’s
 
29. Displacement ( s )  ( 2iˆ  3 ˆj  4kˆ)  (iˆ  2.5kˆ)  s  (3iˆ  3 ˆj  1.5kˆ)m

F  (iˆ  4kˆ) N
 
Work done = F .s  W  ( 3iˆ  3 ˆj  1.5kˆ).(iˆ  4kˆ )  W  3  0  6  3 J
30. Since the last five steps covering 5 m land the drunkard fell into the pit, the displacement
prior to this is (11-5)m = 6m. time taken for first eight steps (displacement in first eight
6
steps = 5-3=2m) = 8s. then time taken to cover first 6m of journey =  8  24s
2
Time taken to cover last 5m = 5s
Total
  time = 24+5 = 29 s  
31. A  B is a new vector perpendicular to A as well as B .
        
 
So, A  B . A  0 Also, A  A  0 and 0  A  0
32. Resultant of two ordered vectors is given by triangle law of vector addition and is
commutative in nature. Dot product of two vectors is a scalar and is also commutative in
nature
So, we have (A)  (r, s) and (B)  (s)
   
Further A.B  0 and A  B  0 is satisfied only when either of the two vectors is a null
vector. So, (C)  (t).
As done already,
         
  
A B C  B  A C  C  A B  0   So, (D)  (p)
Now
 forthree  vectors
 to form  a closed
  polygon,
   we
 must have
A B C  
0  A  B  C  A.C  B.C  C.C
 A.C  B.C  C 2 ..............(1)
      
Similarly A  C   B  A.B  B.C   B 2 ..............(2)
      
Again B  C   A  A.B  A.C   A2 ..............(3)
Adding (1), (2) and (3), we get
           
 
2 A.B  B.C  C. A    A  B  C 
2 2 2

1
A.B  B.C  C. A    A2  B 2  C 2 
2
     
Hence A.B  B.C  C. A  Negative So, ( E )  (q)
33. Conceptual
34.  
(i) 2iˆ  iˆ  ˆj  2iˆ  iˆ  2iˆ  J  2kˆ
(ii) 4iˆ   2iˆ  ˆj   4iˆ  2iˆ  4iˆ  ˆj  0  4kˆ  4kˆ
(iii) 3iˆ   3iˆ  4 ˆj   3iˆ  3iˆ  12(iˆ  ˆj )  0  12kˆ  12kˆ
(iv) 2  iˆ  ˆj   2iˆ  4  iˆ  ˆj   4(iˆ  ˆj )  0  4kˆ   4kˆ
Hence, (i)  (a), (ii)  (c), (iii)  (d), (iv)  (c)

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 Sri Chaitanya IIT Academy 08-06-2025_Jr.Super60_STERLING& BT_Jee-Adv(2023-P1)_WTA-02 _Key & Sol’s
CHEMISTRY
35. Conceptual
36. Conceptual
37. Conceptual
38. 2Mg  O2  2MgO
48 gm ____ 32 gm
0.75 gm ____ 0.5 gm
 Mg remaining  1  .075  0.25 gm
39. 3Ca (OH ) 2  2 H 3 PO4  Ca3 ( PO4 ) 2  6 H 2O
5 / 3  1.66 4 / 2  2
Limiting reagent in Ca (OH ) 2
40. 2 moles of A produce one moles of ‘C’ 8 moles produce 4 moles of ‘c’.
41. Only NaHCO3 undergo decomposition
2 NaHCO3  Na2CO3  H 2O  CO2
168 g 22400 ml

22400ml CO2 obtained from 168 g

448 ml CO2 produced from
448  168
WNaHCO3   3.36 g
22400
WNaHCO3  4  3.369  0.64 g
0.64
% Na2CO3   100  16
4
42. V .D  70
M .W  140
140
x  5
28
43. 54mL  54 g
54
 moles  3
18
44. Molar mass of Fe2O3  160 g / mol
160g contains 112g Fe
 80g contains 56g Fe
45.   300nm  300  109 m
hc6.626  1034  3  108
E  hv    6.626  1019 J
 300  10 9

So answer is 7
46. Formula weight of sodium chloride  23  35.5  58.5
35.5
Weight percentage of chlorine in pure sodium chloride   100  60.6
58.5
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 Sri Chaitanya IIT Academy 08-06-2025_Jr.Super60_STERLING& BT_Jee-Adv(2023-P1)_WTA-02 _Key & Sol’s
60.6 parts of Cl (100% pure) has 45.5 parts of Cl percentage purity of sodium chloride
45.5
  100  75.08
60.6
47. CaCO3  CaO  CO2
14  100
 25 g
56
Percentage purity is only 75%
25
So,  100  33.33
75
48. Conceptual
49. ( I  R) 2 H 2  O2  2 H 2O
1.0 g 1.0 g
1 1
mol mol
2 32
O2 is the limiting reagent: 1mol O2  2 mol H 2O
1 1 18
 mol O2  mol H 2O  g of H 2O  1.125 g
32 16 16
( II  S ) N 2  3H 2  2 NH 3
1.0 g 1.0 g
1 1
mol mol
28 2
N 2 is the limiting reagent,
1 1 1
 mol N 2  mol NH 3   17 g  1.214 g
28 14 14

( III  P) CaCO3   CaO  CO2
1.0g
1 1 1 1
mol mol mol   56 g CaO  0.56g
100 100 100 100
( IV  Q ) C  2 H 2  CH 4
1.0 g 1.0 g
1 1
mol mol
12 2
C is the limiting reagent,
1 1 16
 mol C  mol CH 4  g  1.333 g
12 12 12

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 Sri Chaitanya IIT Academy 08-06-2025_Jr.Super60_STERLING& BT_Jee-Adv(2023-P1)_WTA-02 _Key & Sol’s
50. (A) 0.5 mole of SO2 ( g )  32 g
Weight  1.5 N A atoms
= 11.2L at 1 atm and 273k
(B) 1 g of H 2 ( g )  0.5 mole
H 2  11.2 L at 1 atm and 273k
 N A atoms
(C) 0.5 mole of O3  1.5 N A atoms  11.2 L at 1
Atom and 273k = 24g weight
(D) 1g molecules of O2  1mole of O2  2 N A
Atom = 22.4L at 1 atm
And 273k = 32g weight
44
51. (A) Moles of CO2 ( g )  1
44
1 mole CO2 ( g )  1g  moleculeCO2 ( g )
35.2
(B) Moles of CH 4 ( g )   2.2 moles
16
V  2.2  22.4  49.28 L at 1atm and 273k
48
(C) Moles of O3 ( g )  1
48
44
(D) Moles of N 2O ( g )  1
44
Number of O atoms = N A  1  N A

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