Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec:Sr.Super60_NUCLEUS & STERLING_BT Paper -2(Adv-2021-P2-Model) Date: 27-08-2023
Time: 02.00Pm to 05.00Pm CTA-03 Max. Marks: 180

KEY SHEET
PHYSICS
1 BC 2 ABCD 3 ABCD 4 AB 5 AD 6 AD

7 4 8 18 9 1.33 10 189 11 2.4 12 32

13 B 14 C 15 D 16 A 17 2 18 2

19 2

CHEMISTRY
20 ABC 21 AC 22 A 23 ABC 24 ACD 25 ABC

26 58.50 27 35.20 28 1.50 29 0.80 30 52.80 31 2

32 B 33 C 34 D 35 D 36 4 37 3

38 5

MATHEMATICS
39 BD 40 ACD 41 BD 42 BC 43 AC 44 A
1.33
45 6.00 46 - 47 3.00 48 1.00 49 0.10 50 0.40
1.34
51 A 52 D 53 A 54 B 55 3 56 8

57 0
 Sri Chaitanya IIT Academy 27-08-2023_Sr.Super60_NUCLEUS&STERLING_BT_Jee-Adv(2021-P2)_CTA-03_Key& Sol’s

SOLUTIONS
PHYSICS
1. The P-V graph of the process is shown.
Equation of the process 3  1

3 3  PV 
V  T  140 V     140
10 10  nR 
2. QAB  U AB
Write equation of straight line BC and the ideal gas equation
U AB  CV TB  TA 
P0
Equation of straight line BC is P   V  4 P0
V0
PV PV
3. 1 1
 2 2
T1 T2
P1  1105 Nm 2 T1  300 K
Kx
V1  2.4 | 102 m3 P2  P1  , V2  V1  Ax
A
R  PV  R
dU  n dT  n dT   1 1  dT
 1  RT1    1
100   80 
2 2
D2  d 2
4. f  
4D 400
10000  6400
f   9 cm
400
D  d 100  80 180
m1    9 m1.m2  1
D  d 100  80 20
5. For minima

x1  x2  x1  D 2  d 2  D
2
1
 d 2 2 d2
 D 1  2   D 
 D  2D
d2 d2  2d 2 D
   d
2D 2D 2 D 2
For maxima
d2 d2
 
2D 2D
d  D

6. When d   path difference
4
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 Sri Chaitanya IIT Academy 27-08-2023_Sr.Super60_NUCLEUS&STERLING_BT_Jee-Adv(2021-P2)_CTA-03_Key& Sol’s
2    
Phase difference  
  4  2
Intensity

 2    
When d    
6   6  3

Anet  2 A0 cos 30

3
Anet  A  2  3 A0
2
lnet  3l0
7 & 8. Average of change in velocity is same in magnitude but opposite in direction.
ud
Find the equation of trajectory and use simple kinematic relations y 2  x
v0

9 & 10.
Let the cross sectional area be a.
Then the work done from a displacement of x to
xadx is  P2  P1  dV
P1 V0  ax   P2 V0  ax   PV
0 0

PV PV
P1  0 0
, P2  0 0
V0  ax V0  ax
 V0  ax  V0  ax  2axPV
P2  P1  PV
0 0  2
0 0

 V 0
2
 a 2 2
x  V0  a 2 2
x
W    P2  P1  dV    P2  P1  adx
2a 2 PV
0 0 xdx

V0  a 2 x 2
2

V02  a 2 x 2  b   a 2 2 xdx  db
a 2 PV
0 0  ln V0  a x  
db
2 
0 0
  PV  2 2 2

a b
 V02 
0 0 ln 
PV 2 2 
 V0  a x 
2

al al
ax  and  V0
4 2

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 Sri Chaitanya IIT Academy 27-08-2023_Sr.Super60_NUCLEUS&STERLING_BT_Jee-Adv(2021-P2)_CTA-03_Key& Sol’s
V0 4
ax  W  PV
0 0 ln  
2 3
Since dU  0, d  dW  Q  W  nRT ln  
4
3
If walls are insulated but piston is conducting the temperature of gas in both the chambers
remains the same. Let the rise in temperature be dT.
U  nCV dT
dU  dW but dW  Negative since work is done on the gas
db
2nCV dT  dU  nRT 
b
T 
T2
C dT db C 3
2 V   dU     2 V ln  2    ln
R T1 T b R  T1  4
2 CV
 T2  R 4
   , CV  2 R
 T1  3
T2 4 2 3
  T2  T1  1.154 T1
T1 3 3
T2  1.154  400   461.6
U  2nCV T2  T1   2nR  62   124nR
11. As the collision is elastic
 Range of the projectile, R  12  3  15m
Now using y  x tan  1  
x
 R
x  12m or   45 R  15m
we get y = 2.4 m.
1
12. Using y  u sin  t  gt 2 for vertical direction motion
2

y  7 m u sin   12m /s g  10m /s 2

we get t = 1 & or 1.4 s
But ball will collide for the first time at t  1.0s x  u cos  t  16m
Now after collision the ball will flow the path which is mirror image of the motion that
would have taken place after 2nd collision if the wall were absent.
 Desired range, R  2  16  32m
1 a 
13. r  
1 a 
r  1  a   1  a  a a a 1  a  1  a 
    
r 1  a  1  a  1  a  1  a  1  a 1  a 

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 Sri Chaitanya IIT Academy 27-08-2023_Sr.Super60_NUCLEUS&STERLING_BT_Jee-Adv(2021-P2)_CTA-03_Key& Sol’s
2a 2a
r  
1  a 1  a 1  a  1  a 2
14. N=N 0e-λt lnN=lnN 0 -λt
dN
=-dλt
N
Converting to error,
ΔN 40
=Δλt  Δλ= =0.02 (N is number of nuclei left undecayed)
N 2000×L
400
15 & 16. Vr   30  4km / hr
3
80  30
Vmr   2.4km / hr
1000
To travel minimum distance
Vmr  Vmg
  37 0
400
d 0  80 sec  530   m
3

2
5  5 
 3   x  x 
2
17. 2
9 2  x 2    x
2  2 
25 11 2 11
9 2   2  5 x   5 x x 
4 4 20
1
18. L.C   0.01mm
50  2
 Diameter  3  35  0.01  0.03
 38 
 3.38mm  3  mm
 100 
19. D  1000 1m
Vrms  1000 m / s
3RT 3  25  T
Vrms   106 
M 3  4  10 3
 1000 
T    4  160
 25 
 x  02

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 Sri Chaitanya IIT Academy 27-08-2023_Sr.Super60_NUCLEUS&STERLING_BT_Jee-Adv(2021-P2)_CTA-03_Key& Sol’s

CHEMISTRY
20. Neither the lone pair of oxygen nor the pi-bonds are in conjugation in (D).
21.
22.

23. A) are chain isomers

B) intramolecular hydrogen bonding

C) Enantiomer pair

D)

24.

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 Sri Chaitanya IIT Academy 27-08-2023_Sr.Super60_NUCLEUS&STERLING_BT_Jee-Adv(2021-P2)_CTA-03_Key& Sol’s
25. Stereospecific syn addition takes place in case of (A), (B) and (C). (D) is the reagent for
hydration (HBO) not hydrogenation.
26.

27.

28 & 29.

C is artificial number (polymerization, free radical)

30.

Molecular weight of S = 132.

 WL of compounds S formed  132  0.4  52.8g

31.

32.
33.

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 Sri Chaitanya IIT Academy 27-08-2023_Sr.Super60_NUCLEUS&STERLING_BT_Jee-Adv(2021-P2)_CTA-03_Key& Sol’s
34 & 35

I)
It is stereo specific and stereo selective but not regioselective.

II)
Stereo specific, stereo selective but not regeoselective

III)
It is regeoselective, neither stereo selective not stereo specific.

IV)
It is regeoselective, stereo specific, stereo selective.

The product are CH 3CH 2CH 2 NO 2 , CH 3CHCH 3 , CH 3CH 2 NO 2 and CH 3 NO 2 because C -C

NO 2
36.
And C – H bond cleavage takes place in this reaction.
37. Use concept of conformational analysis of given organic compound.
38. a, b, c, g and h give carbocation more Stable than isopropyl cation.

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 Sri Chaitanya IIT Academy 27-08-2023_Sr.Super60_NUCLEUS&STERLING_BT_Jee-Adv(2021-P2)_CTA-03_Key& Sol’s

MATHEMATICS
f  x  2

2 x 2  2 x 12 12  2
2  x 1 1
2
  22 x1 2
2
1
39.  a  22 
4
1 1 1 3
g  x  1  1  g  x  1   g  x  2
cos x  2 2 1 2
 1 
 2sin x ; x  1
2

 
40. f  x   x ; x 2  1 Now verify
 2sin1  1 
 ; x 2  1
 2 
 2 a 2 ln  cos  x  2   
  a  1  
 x  2
2
41. Lim 
  1

  x  2   2 ln cos  x  2   4
x 2 2

 
 
  a  1  a 2  1
2

  
 1  1  4
a 2  a  1  1  a 2  a  1  1  a  0,  1
a 2  a  1  1  a 2  a  2  0   a  2  a  1  0  a  2,1
Reject a = 0, -1
42. a) Denominator only integer real values
2  2 2
b) Fundamental period =  2 3
2
c) clear from graph
43. (A) is true
f (c  h)  f (c)  f (c)  f (c  h)
lim
h0 h
f (c  h)  f (c) f (c  h)  f (c)
 lim  lim
h0 h h 0 h
= f '(c)  f '(c) = 2f '(c)
(f is differentiable)
(B) is false. Existence of limit is no guarantee for differentiability
(C) is true
(D) is false
44. If n > 1, sin x >sinnx. If 0 < n < 1, sin x <sinnx.
2  sin x  sin n x    sin x  sin n x 
 if n  1, f  x    3.
2  sin x  sin n x    sin x  sin n x 
2  sin x  sin n x    sin x  sin n x 
1
if 0  n  1, f  x    .
2  sin x  sin x    sin x  sin x  3
n n

 if n  1, g  x   3, x   0,  

 g(x) is continuous and differentiable at x .
2
     
If 0  n  1, g  x   0, x   0,    ,   3, x  .
 2 2  2

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      
Then g   0   0, g   0   0, g    3. So, g(x) is not continuous at x . Hence, g(x) is
2  2  2 2

also not differentiable at x .
2
45. abc 6
52. g  f 1 and f  g  x    x
d
dx
 
g  x    g  x    g  x .x 
d
dx
 x. g '  x  g  x 
atx  4, the derivative
1
 4. g '  x   g  x   4.  0
3
1
Hence f 1  4   0  g  x  and g '  x  
f 1
0
46. abc 6
52. g  f 1 and f  g  x    x
d
dx
 
g  x    g  x    g  x .x 
d
dx
 x. g '  x  g  x 
atx  4, the derivative
1
 4. g '  x   g  x   4.  0
3
1
Hence f 1  4   0  g  x  and g '  x  
f 1
0
47.   1  f  x   cos2 x  2 x
f '  x   0  f is increasing
 3x 2  2 x  1  x 2  2 x  9
 2  x  2  x  1,0,1
48. f is increasing x  R  f '  x   2sin 2 x  2 2   2  1   1 / 2 x  0
1
at   , f '  x   0  this is valid only at   1
2
1 t3  t2  t 1
y 2  t  f  x 
2   t  1 t 4  t 3  t 2  t  1
49. dt
 
1  A Bt  Ct  Dt  E 
3 2
   4 3 2
2  t  1 t  t  t  t  1 
 dt

4 4 3 2 1
Clearly A   , B  , C   , D  , E  
5 5 5 5 5
1 4  1 2
 f  x    ln t  1   ln t 4  t 3  t 2  t  1  C  B  
2 5  5 5
1 t3  t2  t 1
y 2  t  f  x 
2   t  1 t 4  t 3  t 2  t  1
50.

dt


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 Sri Chaitanya IIT Academy 27-08-2023_Sr.Super60_NUCLEUS&STERLING_BT_Jee-Adv(2021-P2)_CTA-03_Key& Sol’s

1  A Bt 3  Ct 2  Dt  E 
2   t  1 t 4  t 3  t 2  t  1 
  dt

4 4 3 2 1
Clearly A   , B  , C   , D  , E  
5 5 5 5 5
1 4  1 2
 f  x     ln t  1   ln t 4  t 3  t 2  t  1  C  B  
2 5  5 5
51. f '  sin x   0 and f "  sin x   0x   0, / 2
g  x   f  sin x   f  cos x 
g '  x   f '  sin x  cos x  f '  cos x   sin x 
g "  x   f "  sin x  .cos 2 x  sin x   sin x 
   
g "  x   0  g "  x  is increasing
    
52. g '    0  g '  x   0, for x   , 
4 4 2
 
and g '  x   0 for x   0, 
 4
  
g is increasing in  , 
4 2
 
g is decreasing in  0, 
 4
2x
53. f(x)=e
54. g(x)=x2
55.  f  f  f  x  3  f  f  x  2
1
f  x   3; f  x  ; f  x   3;
2
Zero solutions 2 solution One solution
Total solutions = 3
tan 4 x  1 1
56. I  dx   dx
1  tan x2
1  tan 2 x
cos 2 x 1 1  cos 2 x
 
   1  tan 2 x ln  
cos 2 x
dx   tan x 
2  cos 2 x
dx
1 1 1 1
  tan x   sec 2 xdx   dx   tan x  ln sec 2 x  tan 2 x  x  D
2 2 4 2
1 1
A  1, B  , C   GE  8
4 2

57.
 1
f  x    
1 
 1  x 2 1  x 
2
dx  
 ln x  1  x 2  tan 1 x  C

f  0  0  C  0

f 1  ln  2 1  4
 0,1  G.E  0

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