SRI CHAITANYA IIT ACADEMY, INDIA 30-08-2025_Sr.

IPL-IC_Jee-Main_WTM-37_Key & Sol's

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr. IPL-IC JEE-MAIN Date: 30-08-2025
Time: 09.00Am to 12.00Pm WTM -37 Max. Marks: 300
KEY SHEET
MATHEMATICS
1 1 2 1 3 4 4 3 5 1
6 4 7 3 8 3 9 4 10 2
11 3 12 4 13 4 14 4 15 1
16 4 17 3 18 4 19 4 20 3
21 18 22 5 23 1 24 269 25 151

PHYSICS
26 2 27 2 28 4 29 3 30 3
31 1 32 4 33 1 34 1 35 2
36 3 37 4 38 3 39 2 40 4
41 2 42 4 43 4 44 4 45 4
46 5 47 1 48 2 49 11 50 2

CHEMISTRY
51 2 52 2 53 1 54 2 55 2
56 2 57 1 58 2 59 4 60 2
61 2 62 3 63 1 64 1 65 2
66 2 67 2 68 2 69 3 70 2
71 148 72 14 73 4 74 7 75 1

Sec: Sr. C-IPL Page 1

 SRI CHAITANYA IIT ACADEMY, INDIA 30-08-2025_Sr.IPL-IC_Jee-Main_WTM-37_Key & Sol's

SOLUTION
MATHEMATICS
dy y 2 y
1. We have,  
dx x 2 x
dy dv dv dv
Putting y  vx and  v  x , we get v  x  v2  v  x   v 2
dx dx dx dx
1 1
  2 dv  dx
v x
1
On integrating, we get  log x  c  x  y  logx  c 
v
2.
dy
x -3y = x 2
dx
dy 3y
 - =x
dx x
-3
 x dx 1
I.F = e = e-3logx =
x3
Solution is y  3  =  2 dx
1 1
x  x
y -1
= + c  y = -x 2 +cx 3
x3 x
If y  2   4
 c =1
 y = x 3 -x 2
3. Mode + 2Mean = 3 Median
⇒ Mode = 3 × 22 – 2 × 21= 66 – 42= 24.
dy dz dy dz
Put x  y  1  z  1     1
dx dx dx dx

 x  y  1  1  z   1  1   1 
dy dz dz 1
dx  dx  dx z
4. z  1 
 dz  dx    1   dz  dx
z 1  z 1 
z  log  z  1  x  c  x  y  1  log  x  y  2   x  c
 y  log  x  y  2   log c
 e y   x  y  z  c  x  y  2  ce y
dy 1 1
 y
dx x log x x log x
5. IF  log x
and solutionis y log x  log x  c

Sec: Sr. C-IPL Page 2

 SRI CHAITANYA IIT ACADEMY, INDIA 30-08-2025_Sr.IPL-IC_Jee-Main_WTM-37_Key & Sol's

6.
dx x   x  
  ln    1
dy y   y  
x
 t  x  ty
y
dx dt dt
t y t y  t  ln t  1
dy dy dy
dt dt dy
y  t ln t  
dy t ln t y
dt dy
 
t ln t y
1
ln t  p  dt  dp
t
dp dy
    ln p  log y  c
p y
  x 
ln  ln     ln y  C
  y 
x  e, y  1
  e 
ln  ln     ln 1  c  C  0
  1 
x
log    y
 y
7. Here, the number of observations is 11, which is odd. Arranging the data into ascending
order we have 3, 3, 4, 5, 7, 9, 10, 12, 18, 19, 21.
th
11  1
Now, median   
 or 6 observation  9
th

 2 
The absolute values of the respective deviations from the median, i.e., |xi−M| are 6, 6, 5,
4, 2, 0, 1, 3, 9, 10, 12.
11
Therefore,  x M
i 1
i  58

1 11 1
and MD  M   
11 i 1
xi  M   58  5.27
11
x  10
8. 63  a  b
x  10  a  b  17
8
Since variance is independent from origin so, we subtract 10
79  ( a  10) 2  (b  10) 2
 2  13.5   (10  10) 2
8
 a 2  b 2  20  a  b   171
 a 2  b 2  169
a= 12 and b = 5

Sec: Sr. C-IPL Page 3

 SRI CHAITANYA IIT ACADEMY, INDIA 30-08-2025_Sr.IPL-IC_Jee-Main_WTM-37_Key & Sol's

9. General equation of all such circles is x 2  y2  2 fy  0  1

Differentiating, we get
dy dy
2x  2y 2f 0
dx dx
 dy 
 x  y dx 
 f  
dy 
 
 dx 
∴Required differential equation is sub f in (1)
 dy 
  x  y dx 
x  y  2
2 2
y0
dy
 
 dx 
dy  dy 
  x 2  y2   2y  x  y 
dx  dx 
dy 2e x
10. Given  dx  0 on integrating,
1  y 2 1  e2 x

tan 1 y  2 tan 1 e x  C , y  0   0  C 
2

 Tan 1 y  2Tan 1e x 
2

 y log 3    1
3
11.
1  x  dy
2

dx
 xy  5 x 2
1 x2

dy x 5x2
 y 
dx 1  x 2 1  x2
 
x 1
 dx log 1 x 2
I .F .  e 1 x  e2  1  x2
2

y 1  x 2   5 x 2 dx
5
y 1  x2  x3  c
3
Given y  0   0 c  0
12. Given D.E is y(1+xy)dx=xdy
xdy  ydx
 xdx
y2
x
d    xdx
y
Integrating on both sides
x
 d     xdx
y
x x2
  c
y 2

Sec: Sr. C-IPL Page 4

 SRI CHAITANYA IIT ACADEMY, INDIA 30-08-2025_Sr.IPL-IC_Jee-Main_WTM-37_Key & Sol's

1
It passes through the point (1,-1) then c 
2
2x  1 3
Hence y   f   
x 1
2
 3 5
 f i xi 4  72  140  112  72
x 
13. N 80
400
x 5
80
M.d. about
 fi xi  x 128 8
mean   
N 80 5
 f i ( xi  x ) 2 22
Variance  
N 5
8 22
M  , σ2 
5 5
8 22 30
M  σ2    6
5 5 5
2 2
 xi2   xi  18000  960 
14. variance         300  256  44
n  n  60  60 
15.
24  a  b
4
8
ab8
4  1  1  0  1  9  (a  4) 2  (b  4) 2
2
8
16  48  a 2  b 2  8a  8b
a 2  b 2  32
32  2ab
ab  16
a  4, b  4
mode = 4
2 11 0 1 3  0  0
mean deviation about mode = 1
8
dy 2  2  1
x y y

16.   0; x, y  0, y 1  1
dx 2x  1
dy 2 x  2 y  1
 y x
dx 2  2  1
2y 2x
 dy    dx
2y 1 2x  1
2 y ln 2 2 x ln 2
 y dy    x dx
2 1 2 1
ln 2 y  1   ln 2 x  1  C
At x  1, y  1  C  0
Sec: Sr. C-IPL Page 5
 SRI CHAITANYA IIT ACADEMY, INDIA 30-08-2025_Sr.IPL-IC_Jee-Main_WTM-37_Key & Sol's

ln 2 y  1   ln 2 x  1
  2 y  1 2 x  1  1
4
sub x  1then 2 y 
3
4
 y  log 2  
3
17.
f  x   x 1
f f  x   f  x  1  x 1  1  x  2

 
g f  f  x    ex 2
dy 1
  e 2 x  e x  2  y
dx x
dy 1
 y  e x  2 x  2 which is L.D.E
dx x
Its solution is
y  e2 x
  e2 x
 ex 2 x 2
dx  c
y  e2 x
  e x  2 dx  c
y  e2 x
 e x 2  c
Given x  0, y  0  0  e 2  c; c  e 2
 y  e2 x
 e x  2  e 2
when x  1, y  e 2  e 1  e 2
1 1

e 1  e 2 e e 2 e 2  e e  1
y   5  4
e2 e2 e e
18.
Cumulative
Class Frequency
frequency
0-4 3 3
4-8 9 12
8-12 10 22
12-16 8 30
16-20 6 36

N 
 2  C.F 
M  L h
 f 
 
18  12
M  8 4
10
 M = 10.4
 20M = 208

Sec: Sr. C-IPL Page 6

 SRI CHAITANYA IIT ACADEMY, INDIA 30-08-2025_Sr.IPL-IC_Jee-Main_WTM-37_Key & Sol's

19. Given that x1 , x2 ,, xn be n observations, and let x be their arithmetic mean and  2 be
their variance.
2
x2
Then    i    i 
2 x
n  n
Variance of
 2 xi   x 2  x 2 
2 2
 2x 
2 x1 , 2 x2 , ., 2 xn      i   4   i    i    4 2
n  n   n  n  
Statement -1 is true.
2 x1  2 x2    2 xn  x  x     xn 
A.M of 2 x1 , 2 x2 , , 2 xn   2 1 2   2x
n  n 
Statement -2 is false.
20.
dy y 
  tan x ; y 1 
dx x 2
 y  x sin x  y  0   0
1

1 1 1 
 y    sin 1 
2 2 2 12
 3 3 1  3  
 y    sin   
 2  2  2  2 3
 1  1  1  
 y  sin 1  
 2 2  2 4 2
21.
 t  1 dx   2x  (t  1) 4  dt
dx 2x  (t  1) 4

dt t 1
dx 2x
  (t  1)3
dt t  1
2
 dt 1
I·F  e t 1
 e 2ln  t 1 
(t  1) 2
x 1
 (t  1)3 dt  c
(t  1) 2
(t  1) 2

x (t)2
 t c
(t  1) 2 2
sub x  3 , t  0
c 3
 t2 
Now x  (t  1) 2   t  3 
2 
subt  1
1 
then x  4   1  3   18
2 

Sec: Sr. C-IPL Page 7

 SRI CHAITANYA IIT ACADEMY, INDIA 30-08-2025_Sr.IPL-IC_Jee-Main_WTM-37_Key & Sol's

dx x 1  y 2
22.  
dy y y
1
  dy 1
Integrating factor  e y

y
1 1 y2
x   2 dy
y y
x 1
  yc
y y
x  1  y 2  cy
x  2  1
1  1  4  2c  c  3
x  1  y 2  3 y
5 x  2   5  1  4  6 
5
23.
dx 2 y
sec 2 x  e tan 2 x  tan x  0
dy
 dx dt 
 Put tan x  t  sec x  
2

 dy dy 
dt
 e2 y  t 2  t  0
dy
dt
 t  t 2  e2 y
dy
1 dt 1
  e 2 y
t 2 dy t
 1 1 dt du 
 Put  u 2  
 t t dy dy 
 du
 u  e 2 y
dy
du
 u  e2 y
dy
I.F.  e   dy  e  y
ue  y   e  y  e 2 y dy
1
 e y  e y  c
tan x

x , y 
3
1 
 e  e  0
3
1
 e 2 
3
 3e 2  1
Sec: Sr. C-IPL Page 8
 SRI CHAITANYA IIT ACADEMY, INDIA 30-08-2025_Sr.IPL-IC_Jee-Main_WTM-37_Key & Sol's

24.
x1  x2  ....... x8  45  50  500
x1  x2  ....... x8  405
x1  x2  ....... x8  20  25  405  20  25
450
μ  45
10
Given σ 2  144
 x i2
 (50) 2  144
10
x12  x 82  452  50 2  144  2500  2644
x12  x 82  26440   452  502   21915
x12  x 82  202  252  21915  400  625  22940
22940
σ2   452  269
10
 fi x i
25. By frequency distribution table x   28
 fi
2  5  3 15  x  25  5  35  4  45
  28
14  x
x6
 f i  x  xi 
2

σ  2

 fi
2  (23) 2  3  (13) 2  6  (3)2  5  (7)2  4  (17) 2
2   151
20

Sec: Sr. C-IPL Page 9

 SRI CHAITANYA IIT ACADEMY, INDIA 30-08-2025_Sr.IPL-IC_Jee-Main_WTM-37_Key & Sol's

PHYSICS
26. A NOR gate is combination of NOT and OR gate. The Boolean expression of NOR gate
is C  A  B

27.
Y  AB  AB
This is XOR GATE
28. Conceptual
29. Statement I:"LED is a heavily doped p-n junction diode usually connected in reverse
bias."
This is incorrect, because: LEDs are forward biased, not reverse biased, to emit light.
They are indeed heavily doped, but the biasing part is wrong.
Statement II: "GaAs is a better material than Si used in solar cells because of its
relatively higher absorption coefficient."
This is correct, because: GaAs has a direct band gap (~1.43 eV), leading to a high
absorption coefficient. This allows thinner cells and better efficiency compared to Si
(indirect band gap).
Statement I is false, Statement II is true.
6.4 9  6.4
i2  , i1 
30. 800 200
iz  i1  i2
31. Conceptual

32.
Pd across Rs
V1  8  5  3 V
Current through the load resistor
5
I  5 mA
1103
Maximum current through Zener diode
P 10
I z max.    2 mA
Vz 5
And minimum current through Zener diodev

Sec: Sr. C-IPL Page 10

 SRI CHAITANYA IIT ACADEMY, INDIA 30-08-2025_Sr.IPL-IC_Jee-Main_WTM-37_Key & Sol's

I z min.  0
 Is max.  5  2  7 mA
V1 3
and R smin   k
I 7
Similarly,
Is min.  5 mA
V1 3
and R s max.   k
Is min. 5
3 3
 k  Rs  k
7 5
33. Conceptual
34. In the diagrams C, V & Ef represents the conduction band, the valence band, and the
Fermi level.
For n - type semiconductor, the Fermi level is near the conduction band.
For p - type semiconductor, the Fermi level is near the valence band.
For intrinsic semiconductor, the Fermi level lies in the middle.
35. For the positive half cycle of input the resulting network is shown below

1 1
 V0 max  Vi max  10  5V
2 2
36. In full wave rectifier ripple frequency is 2n.
37. Conceptual
38. Rectified output = dc voltage.
V
R ac 
i
2.3  0.3
39. 
10 10 3
 0.2 103 

40.
From the circuit diagram,

Sec: Sr. C-IPL Page 11

 SRI CHAITANYA IIT ACADEMY, INDIA 30-08-2025_Sr.IPL-IC_Jee-Main_WTM-37_Key & Sol's

20 1
5i   A
400 20
1
i  A  10mA  Load current
100
Also, VL  5 V
5
RL  Ω  500Ω
10  103
41. At a specific reverse voltage in p-n junction a huge current flows in reverse direction
known as avalanche current.
42. Intrinsic semiconductor, Fermi-level is in the middle of valence and conduction band.
In n-type semiconductor, Fermi-level is near the conduction band.
In p-type semiconductor, Fermi-level is near the valence band.
In metals, Fermi-level is inside the conduction band.
30
43. I A  2mA
 10 
10  
 2
44. These gates are called digital building blocks because using these gates only (either
NAND or NOR) we can compile all other gates also (like OR, AND, NOT, XOR).

45.
Diodes D1 , D 2 conduct current while D 2 doesn't conduct current.
I1
I2  I4 
2
I1
 2
I2
ne nh  ni 2
46. n 2 1.5 10 
16 2

ne  1   5 109
nh 4.5 1022
47. y  A.B  0. 1  1.0  0  1
48.

Sec: Sr. C-IPL Page 12

 SRI CHAITANYA IIT ACADEMY, INDIA 30-08-2025_Sr.IPL-IC_Jee-Main_WTM-37_Key & Sol's

2
I  20mA
100
I  I Z  IL
VL  IL R L
8  10 103  R Lmax
4
103  R Lmax
5
800  R Lmax
I  IZ  IL
IL  10mA
If I Z  0
ILmax  20mA
VL  I Lmax  R Lmin
8
 103  R Lmin
20
400  R Lmin
R Lmax 800
 2
R Lmin 400
49. By using mass action law n i2  n e n h
n i2 10 
16 2

 nh   21
 1011 per m3
ne 10
1
   e  e ne  h nh 

50.
 1.6  1019 0.36  2.5  1019  0.17  2.5  1019  
 2.12Sm 1

Sec: Sr. C-IPL Page 13

 SRI CHAITANYA IIT ACADEMY, INDIA 30-08-2025_Sr.IPL-IC_Jee-Main_WTM-37_Key & Sol's

CHEMISTRY
51. Due to formation of H+
CH COOH  CH COONa  HCl  NaCl
3 3

52.  91  426.16  126.45

 390.71ohm 1  cm 2  mol 1
 90
53.   0m   0.225
 m 400
54. Both are correct statements but R is not explaining A.
Cu 2   e  Cu  ; G1   nFE1o  1 F  E1o
Cu   e   Cu; G2  1 F  0.522
Cu 2   2e   Cu; G3  2  F  0.34
55. Now, G3  G1  G2
2  F 0.34   FE1o  0.522F
E1o  0.158V
 Ecell ox
56. For hydrogen electrode P H 
0.0591
Ecell  P  0.0591
H

Ecell  10  0.0591
E cell  0.591 V
o
As E Cr 3
/ Cr
 0.7 V and E oFe2 / Fe  0.42 V
2Cr  3Fe 2  3Fe  2Cr 3
2
0.0591 Cr 3 
E cell  E o
cell  log  3
6  Fe 2 

 0.1
2
0.0591
57.   0.42  0.72   log
 0.01
3
6

 0.1
2
0.0591
 0.30  log
0.01
3
6
0.0591
 0.30  log104
6
E cell  0.2606 V

58. Cd  2 Ni  OH 3  CdO  2 Ni  OH 2  H 2O
59. Statement I : Corrosion is an example of electrochemical phenomenon.
In which pure metal act as anode and impure metal (rusted metal) act as cathode.
Statement II: Corrosion is more favourable in acid medium than alkaline so rate of
corrosion is high in acid medium than alkaline.
60. The reactions occurring during discharge are:
Anode: Pb  s   SO42  aq   PbSO4  s   2e
At cathode: PbO2  s   4H  aq   SO42  aq   2e  PbSO4  s   2H2O  l 

Sec: Sr. C-IPL Page 14

 SRI CHAITANYA IIT ACADEMY, INDIA 30-08-2025_Sr.IPL-IC_Jee-Main_WTM-37_Key & Sol's

Overall reaction:
Pb  s   PbO2  s   2H 2 SO4  2PbSO4  s   2H2O  l 
Quantity of electricity consumed
=(2A)(30×3600s)=216000C
2 x 96500 coulombs consume H 2 SO4 =2 moles
∴ 216000 coulombs will consume H 2 SO4
1
  216000  2.24 moles.
96500
Therefore, B. 2.24 mole is the right response.
61. β− naphthol does not give coupling reaction in strong acidic medium
62. EAS reactivity order is PhOH  C6 H 6  C6 H 5Cl  C6 H 5 NO2
HBF4 NaNO2
63. C6 H 5  N 2 Cl   C6 H 5 N 2 BF4  C6 H5  NO2
Cu , heat

64. Resonance increases the stability of species.

65. AgCN
66. Conceptual
67. Conceptual
68. Conceptual
69. HCOOH gives a positive test with Tollen's reagent.
70. Conceptual
0.0591 2
E  E0  log  H  
2
 1.30   0.0591 3
71.
 1.30  0.1773
 1.4773V
E  147.7 102  148  102 V
72. m  AgI   m  NaI   m  AgNO3   m  NaNo3   12.7  13.3  12  14
73. The reaction is

So, 4 chiral centers are present in the compound(B).

74.

75. Lucas test is not given by primary alcohols at room temperature

Sec: Sr. C-IPL Page 15

 SRI CHAITANYA IIT ACADEMY, INDIA 30-08-2025_Sr.IPL-IC_Jee-Main_WTM-37_Key & Sol's

Sec: Sr. C-IPL Page 16