GulfSea Gear Oil 68, 100, 150, 220, 320, 460, 680

Gulf Marine Pte. Ltd.

Chemwatch: 5612-46 Issue Date: 27/06/2023
Version No: 3.1 Print Date: 07/05/2025
Safety Data Sheet in accordance with SS 586-3:2022 S.GHS.SGP.EN.E

SECTION 1 Identification of the substance / mixture and of the company / undertaking

Product Identifier
Product name GulfSea Gear Oil 68, 100, 150, 220, 320, 460, 680
Chemical Name Not Applicable
Synonyms Not Available
Chemical formula Not Applicable
Other means of identification 2ME10680-00, 2ME11000-00, 2ME11500-00, 2ME12200-00, 2ME13200-00, 2ME14600-00, 2ME16800-00

Relevant identified uses of the substance or mixture and uses advised against
Gear oil.
Relevant identified uses
Use according to manufacturer's directions.

Details of the manufacturer or importer of the safety data sheet

Registered company name Gulf Marine Pte. Ltd.
Address 37 Tuas Road 638503 Singapore
Telephone +65 6592 0120
Fax Not Available
Website Not Available
Email [email protected]

Emergency telephone number

Association / Organisation Gulf Marine Pte. Ltd.
Emergency telephone
+65 6592 0120
number(s)
Other emergency telephone
Not Available
number(s)

SECTION 2 Hazards identification

Classification of the substance or mixture

Classification Sensitisation (Skin) Category 1

Label elements

Hazard pictogram(s)

Signal word Warning

Hazard statement(s)
H317 May cause an allergic skin reaction.

Precautionary statement(s) Prevention

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P280 Wear protective gloves and protective clothing.

P261 Avoid breathing mist/vapours/spray.
P272 Contaminated work clothing should not be allowed out of the workplace.

Precautionary statement(s) Response

P302+P352 IF ON SKIN: Wash with plenty of water and soap.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.

Precautionary statement(s) Storage

Not Applicable
Precautionary statement(s) Disposal
P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

Other hazards
Possible skin sensitizer*.

*LIMITED EVIDENCE

SECTION 3 Composition / information on ingredients

Substances
See section below for composition of Mixtures

Mixtures
% Chemical
CAS No Name Synonyms
[weight] formula
C28-H44-O3-S.1/2Ca; calcium bis(di C8-C10, branched, C9 rich,
alkylnaphthalenesulphonate) CAS RN: 1474044-79-5; calcium
bis(dinonylnaphthalenesulphonate) CAS RN: 57855-77-3; calcium
calcium bis(di-C8- C28-H44-
bis(dinonylnaphthalenesulfonate); naphthalenesulfonic acid, dinonyl-,
1474044-79-5 <1 10,branched,C9- O3-S .1/2
calcium salt; calcium dinonylnaphthalene sulfonate; calcium bis(2,3-
rich)alkylnaphthalenesulfonate Ca
dinonyl-1-naphthalenesulfonate); naphthalenesulfonic acid, dinonyl-,
calcium salt (2:1); calcium bis(2,3-dinonylnaphthalene-1-sulfonate);
CaDNNSA; CaDINNSA; Na-sul 729
Ingredients determined not to be Not
Not Available balance
hazardous Available

SECTION 4 First aid measures

Description of first aid measures

If this product comes in contact with eyes:
Wash out immediately with water.
Eye Contact
If irritation continues, seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Skin Contact
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Inhalation
Other measures are usually unnecessary.
Immediately give a glass of water.
Ingestion
First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5 Firefighting measures

Extinguishing media
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.
Water spray or fog - Large fires only.

Special hazards arising from the substrate or mixture

Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Advice for firefighters

Fire Fighting Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Prevent, by any means available, spillage from entering drains or water course.
Use water delivered as a fine spray to control fire and cool adjacent area.
Avoid spraying water onto liquid pools.

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DO NOT approach containers suspected to be hot.

Cool fire exposed containers with water spray from a protected location.
If safe to do so, remove containers from path of fire.
Combustible.
Slight fire hazard when exposed to heat or flame.
Heating may cause expansion or decomposition leading to violent rupture of containers.
On combustion, may emit toxic fumes of carbon monoxide (CO).
May emit acrid smoke.
Fire/Explosion Hazard Mists containing combustible materials may be explosive.
Combustion products include:
carbon dioxide (CO2)
sulfur oxides (SOx)
other pyrolysis products typical of burning organic material.
May emit corrosive fumes.

SECTION 6 Accidental release measures

Personal precautions, protective equipment and emergency procedures

See section 8

Environmental precautions
See section 12

Methods and material for containment and cleaning up

Remove all ignition sources.
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Minor Spills Control personal contact with the substance, by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Wipe up.
Place in a suitable, labelled container for waste disposal.
Moderate hazard.
Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water course.
No smoking, naked lights or ignition sources.
Increase ventilation.
Major Spills
Stop leak if safe to do so.
Contain spill with sand, earth or vermiculite.
Collect recoverable product into labelled containers for recycling.
Absorb remaining product with sand, earth or vermiculite.
Collect solid residues and seal in labelled drums for disposal.
Wash area and prevent runoff into drains.
If contamination of drains or waterways occurs, advise emergency services.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 Handling and storage

Precautions for safe handling

Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Prevent concentration in hollows and sumps.
DO NOT enter confined spaces until atmosphere has been checked.
Avoid smoking, naked lights or ignition sources.
Avoid contact with incompatible materials.
When handling, DO NOT eat, drink or smoke.
Safe handling
Keep containers securely sealed when not in use.
Avoid physical damage to containers.
Always wash hands with soap and water after handling.
Work clothes should be laundered separately.
Use good occupational work practice.
Observe manufacturer's storage and handling recommendations contained within this SDS.
Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions.
DO NOT allow clothing wet with material to stay in contact with skin
Store in original containers.
Keep containers securely sealed.
No smoking, naked lights or ignition sources.
Other information Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Protect containers against physical damage and check regularly for leaks.
Observe manufacturer's storage and handling recommendations contained within this SDS.

Conditions for safe storage, including any incompatibilities

Metal can or drum
Suitable container Packaging as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Storage incompatibility Avoid reaction with oxidising agents

SECTION 8 Exposure controls / personal protection

Control parameters

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Occupational Exposure Limits (OEL)

INGREDIENT DATA
Not Available
Ingredient Original IDLH Revised IDLH
calcium bis(di-C8-
10,branched,C9- Not Available Not Available
rich)alkylnaphthalenesulfonate

Exposure controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls
can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that
strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The
design of a ventilation system must match the particular process and chemical or contaminant in use.
Employers may need to use multiple types of controls to prevent employee overexposure.

General exhaust is adequate under normal operating conditions. If risk of overexposure exists, wear SAA approved respirator. Correct fit is
essential to obtain adequate protection. Provide adequate ventilation in warehouse or closed storage areas. Air contaminants generated in
the workplace possess varying "escape" velocities which, in turn, determine the "capture velocities" of fresh circulating air required to
effectively remove the contaminant.

Type of Contaminant: Air Speed:

0.25-0.5 m/s (50-
solvent, vapours, degreasing etc., evaporating from tank (in still air)
100 f/min)
aerosols, fumes from pouring operations, intermittent container filling, low speed conveyer transfers, welding, 0.5-1 m/s (100-
spray drift, plating acid fumes, pickling (released at low velocity into zone of active generation) 200 f/min.)

Appropriate engineering direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas discharge (active 1-2.5 m/s (200-
controls generation into zone of rapid air motion) 500 f/min)
grinding, abrasive blasting, tumbling, high speed wheel generated dusts (released at high initial velocity into zone 2.5-10 m/s (500-
of very high rapid air motion). 2000 f/min.)

Within each range the appropriate value depends on:

Lower end of the range Upper end of the range

1: Room air currents minimal or favourable to capture 1: Disturbing room air currents
2: Contaminants of low toxicity or of nuisance value only 2: Contaminants of high toxicity
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in motion 4: Small hood - local control only

Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity generally
decreases with the square of distance from the extraction point (in simple cases). Therefore the air speed at the extraction point should be
adjusted, accordingly, after reference to distance from the contaminating source. The air velocity at the extraction fan, for example, should be
a minimum of 1-2 m/s (200-400 f/min.) for extraction of solvents generated in a tank 2 meters distant from the extraction point. Other
mechanical considerations, producing performance deficits within the extraction apparatus, make it essential that theoretical air velocities are
multiplied by factors of 10 or more when extraction systems are installed or used.

Individual protection
measures, such as personal
protective equipment

Safety glasses with side shields.

Chemical goggles. [AS/NZS 1337.1, EN166 or national equivalent]
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,
describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of
Eye and face protection lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel
should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye
irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or
irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current
Intelligence Bulletin 59].
Skin protection See Hand protection below
Hands/feet protection Wear chemical protective gloves, e.g. PVC.
Wear safety footwear or safety gumboots, e.g. Rubber
NOTE:
The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other protective
equipment, to avoid all possible skin contact.
Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to
manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in
advance and has therefore to be checked prior to the application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be observed
when making a final choice.
Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be
washed and dried thoroughly. Application of a non-perfumed moisturiser is recommended.
Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:
· frequency and duration of contact,
· chemical resistance of glove material,
· glove thickness and
· dexterity
Select gloves tested to a relevant standard (e.g. Europe EN 374, US F739, AS/NZS 2161.1 or national equivalent).
· When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than
240 minutes according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.

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· When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to
EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.
· Some glove polymer types are less affected by movement and this should be taken into account when considering gloves for long-term
use.
· Contaminated gloves should be replaced.
As defined in ASTM F-739-96 in any application, gloves are rated as:
· Excellent when breakthrough time > 480 min
· Good when breakthrough time > 20 min
· Fair when breakthrough time < 20 min
· Poor when glove material degrades
For general applications, gloves with a thickness typically greater than 0.35 mm, are recommended.
It should be emphasised that glove thickness is not necessarily a good predictor of glove resistance to a specific chemical, as the
permeation efficiency of the glove will be dependent on the exact composition of the glove material. Therefore, glove selection should also
be based on consideration of the task requirements and knowledge of breakthrough times.
Glove thickness may also vary depending on the glove manufacturer, the glove type and the glove model. Therefore, the manufacturers
technical data should always be taken into account to ensure selection of the most appropriate glove for the task.
Note: Depending on the activity being conducted, gloves of varying thickness may be required for specific tasks. For example:
· Thinner gloves (down to 0.1 mm or less) may be required where a high degree of manual dexterity is needed. However, these gloves are
only likely to give short duration protection and would normally be just for single use applications, then disposed of.
· Thicker gloves (up to 3 mm or more) may be required where there is a mechanical (as well as a chemical) risk i.e. where there is abrasion
or puncture potential
Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed
moisturiser is recommended.
Body protection See Other protection below
Overalls.
P.V.C apron.
Other protection Barrier cream.
Skin cleansing cream.
Eye wash unit.

Respiratory protection
Type A Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)

Selection of the Class and Type of respirator will depend upon the level of breathing zone contaminant and the chemical nature of the contaminant. Protection Factors (defined
as the ratio of contaminant outside and inside the mask) may also be important.

Required minimum protection factor Maximum gas/vapour concentration present in air p.p.m. (by volume) Half-face Respirator Full-Face Respirator
up to 10 1000 A-AUS / Class1 -
up to 50 1000 - A-AUS / Class 1
up to 50 5000 Airline * -
up to 100 5000 - A-2
up to 100 10000 - A-3
100+ Airline**

* - Continuous Flow ** - Continuous-flow or positive pressure demand

A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G =
Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic compounds(below 65 degC)

Cartridge respirators should never be used for emergency ingress or in areas of unknown vapour concentrations or oxygen content.
The wearer must be warned to leave the contaminated area immediately on detecting any odours through the respirator. The odour may indicate that the mask is not
functioning properly, that the vapour concentration is too high, or that the mask is not properly fitted. Because of these limitations, only restricted use of cartridge respirators
is considered appropriate.
Cartridge performance is affected by humidity. Cartridges should be changed after 2 hr of continuous use unless it is determined that the humidity is less than 75%, in which
case, cartridges can be used for 4 hr. Used cartridges should be discarded daily, regardless of the length of time used

SECTION 9 Physical and chemical properties

Information on basic physical and chemical properties

Appearance Yellow colored viscous liquid with a characteristic odor; does not mix with water Yellow

Physical state Liquid Relative density (Water = 1) ~ 0.9

Partition coefficient n-octanol
Odour Characteristic Not Available
/ water
Auto-ignition temperature
Odour threshold Not Available Not Available
(°C)
Decomposition
pH (as supplied) Not Applicable Not Available
temperature (°C)
Melting point / freezing point
Not Available Viscosity (cSt) 68.2 – 682.4
(°C)
Initial boiling point and
Not Available Molecular weight (g/mol) Not Applicable
boiling range (°C)
Flash point (°C) 224-255 (ASTM D 92) Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Applicable Oxidising properties Not Available
Surface Tension (dyn/cm or
Upper Explosive Limit (%) Not Available Not Available
mN/m)
Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water Immiscible pH as a solution (1%) Not Applicable
Vapour density (Air = 1) Not Available VOC g/L Not Available

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Heat of Combustion (kJ/g) Not Available Ignition Distance (cm) Not Available
Flame Height (cm) Not Available Flame Duration (s) Not Available
Enclosed Space Ignition Enclosed Space Ignition
Not Available Not Available
Time Equivalent (s/m3) Deflagration Density (g/m3)

SECTION 10 Stability and reactivity

Reactivity See section 7

Unstable in the presence of incompatible materials.
Chemical stability Product is considered stable.
Hazardous polymerisation will not occur.
Possibility of hazardous
See section 7
reactions
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decomposition
See section 5
products

SECTION 11 Toxicological information

Information on toxicological effects

a) Acute Toxicity Based on available data, the classification criteria are not met.
b) Skin Irritation/Corrosion Based on available data, the classification criteria are not met.
c) Serious Eye
Based on available data, the classification criteria are not met.
Damage/Irritation
d) Respiratory or Skin
There is sufficient evidence to classify this material as sensitising to skin or the respiratory system
sensitisation
e) Mutagenicity Based on available data, the classification criteria are not met.
f) Carcinogenicity Based on available data, the classification criteria are not met.
g) Reproductivity Based on available data, the classification criteria are not met.
h) STOT - Single Exposure Based on available data, the classification criteria are not met.
i) STOT - Repeated Exposure Based on available data, the classification criteria are not met.
j) Aspiration Hazard Based on available data, the classification criteria are not met.

The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by EC Directives using animal
Inhaled models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an
occupational setting.
The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because of the lack
Ingestion
of corroborating animal or human evidence.
The liquid may be able to be mixed with fats or oils and may degrease the skin, producing a skin reaction described as non-allergic contact
Skin Contact
dermatitis. The material is unlikely to produce an irritant dermatitis as described in EC Directives.
Although the liquid is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce transient
Eye
discomfort characterised by tearing or conjunctival redness (as with windburn).
Chronic Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population.

TOXICITY IRRITATION
GulfSea Gear Oil 320
Not Available Not Available

TOXICITY IRRITATION

Dermal (rabbit) LD50: >20000 mg/kg[2] Eye (Rodent - rabbit): 0.1mL

calcium bis(di-C8-
[1]
10,branched,C9- Inhalation (Rat) LC50: >4.5 mg/l4h Eye: adverse effect observed (irritating)[1]
rich)alkylnaphthalenesulfonate
Oral (Rat) LD50: >2500 mg/kg[2] Skin (Rodent - rabbit): 0.5mL - Moderate

Skin: adverse effect observed (irritating)[1]

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2. Value obtained from manufacturer's SDS. Unless otherwise
specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

CALCIUM BIS(DI-C8-10,BRANCHED,C9- The following information refers to contact allergens as a group and may not be specific to this product.
RICH)ALKYLNAPHTHALENESULFONATE Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The
pathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic
skin reactions, e.g. contact urticaria, involve antibody-mediated immune reactions. The significance of the contact allergen is not
simply determined by its sensitisation potential: the distribution of the substance and the opportunities for contact with it are
equally important. A weakly sensitising substance which is widely distributed can be a more important allergen than one with
stronger sensitising potential with which few individuals come into contact. From a clinical point of view, substances are
noteworthy if they produce an allergic test reaction in more than 1% of the persons tested.
For alkaryl sulfonate petroleum additives:
Acute toxicity: Existing data indicates relatively low acute toxicity. Animal testing suggested diarrhea and reduced food intake,
which is consistent with the detergents in an oil-based vehicle having an irritating effect on the gastrointestinal tract.
Subchronic toxicity: Existing data suggests minimal toxicity after chronic exposure by mouth. Repeated skin contact and
inhalation in animals caused injury to the skin and the lungs, respectively.
Reproductive and Developmental Toxicity: Existing data did not show this group of substances to cause reproductive or
developmental toxicity. There was low concern for mutation-causing potential.
For dinonylnaphthalenesulfonic acid (DNNSA) and its salts:

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In general, a compound needs to be dissolved before it can be taken up from the gastro-intestinal tract after oral administration .
Calcium bis( di C8-C10, branched, C9 rich, alkylnaphthalene sulphonate) (CaDNNSA) has a measured water solubility of 0.266
mg/L and therefore it is expected to dissolve into the gastrointestinal fluids to a very limited extent. Uptake by passive diffusion
is possible, but limited due to the high molecular weight of the salt (average MW 959) and its dissociation product DNNSA (MW
461). CaDNNSA has a high log Pow 6.6), which makes the compound relatively hydrophobic. This characteristic will enable
micellular solubilisation by bile salts in the gastro-intestinal tract which allows some crossing of lipid biomembranes. The
structure contains an ionizable group (SO3H), which might hamper diffusion across biological membranes. In addition, the
molecular size of the molecule of 19 Å does not favor uptake across the biological membranes.
In the 90-day study on CaDNNSA in the highest dose group 6/10 females died showing alterations in the gastro-intestinal tract,
a small thymus and bone marrow atrophy. The surviving females at 1000 mg/kg bw showed similar effects and a reduced body
weight (gain). The effects on the gastro-intestinal tract also became apparent in males at 300 and 1000 mg/kg bw. These
animals also had a reduced body weight (gain). Other effects included changes in numbers of white blood cells, lymphocytes,
platelets as well as effects on several biochemical parameters. Macroscopy and histopathology indicated that next to the GI-
tract mainly the thymus and bone marrow could be considered as potentially affected in males at 300 mg/kg bw and above and
in females at 1000 mg/kg bw. The effects on blood and blood forming organs as well as on the immune system are indicative for
some absorption of the substance. This absorption may be enhanced due to the effects on the gastro intestinal tract lining.
The metabolism of DNNSA salts is mainly contingent on both the nature of the alkyl groups and the nature and extent of
naphthalene ring substitutions. There are currently no metabolism studies of CaDNNSA, however, the US EPA has evaluated
the metabolism of analogs in in the sodium alkyl naphthalenesulfonate cluster (SANS), a group of sodium salts of
naphthalenesulfonic acids . In a US EPA final rule for SANS, it was stated that “the 1- or 2-sulfonic acid sodium salt moieties on
the naphthalene ring may provide a handle by which these compounds can be readily conjugated and eliminated.” Though the
available information is not definitive for CaDNNSA, where the alkyl chains are much larger than for the naphthalenesulfonic
acids evaluated by EPA, it is expected that the metabolism of the substance will be a factor, enhancing elimination.
If absorbed, wide distribution of the CaDNNSA throughout the body is not expected based on its molecular size ( 18 Å). In
general, molecules of this size do not pass readily through cell membranes, thus limiting wide distribution. Excretion of
CaDNNSA and its potential metabolites will occur via the bile (high molecular weight) or the urine (low molecular weight).
Irritation:
Calcium bis( di-C8-10, branched, C9 rich, alkylnaphthalenesulphonate) is irritating to skin and eyes. It is not corrosive.
Sensitisation:
In the Buehler assay the substance was shown to be a weak skin sensitiser, while a human patch test showed no sensitization
in human volunteers.
Genetic toxicity:
The Barium analog was found to be non-mutagenic in the Ames bacterial reverse mutation assay and the mouse lymphoma test
(MLA). The substance was did not cause chromosomal aberrations in human peripheral lymphocytes.
Reproductive toxicity:
DNNSA (di C8-C10, branched, C9 rich, alkylnaphthalene sulphonic acid) is the major structural component of Calcium bis( di
c8-c10, branched, c9 rich, alkylnaphthalene sulphonate). The OECD 422 repeat dose and reproduction/development study with
DNNSA provides reliable read-across for developmental endpoints for Calcium bis( di c8-c10, branched, c9 rich,
alkylnaphthalene sulphonate).
A second OECD 422 study conducted with another analog, Barium bis( di c8-c10, branched, c9 rich, alkylnaphthalene
sulphonate), showed no effects on development at the highest dose in the study of 150 mg/kg/day. Together these studies show
that Calcium bis( di c8-c10, branched, c9 rich, alkylnaphthalene sulphonate) is not a developmental toxin.
*REACh Dossier
Linear alkyl benzene sulfonates are derived from strong corrosive acids. Animal testing has shown they can cause skin
reactions, eye irritation, sluggishness, passage of frequent watery stools, weakness and may lead to death. They may also react
with surfaces of the mouth and intestines, depending on the concentration exposed to. There is no evidence of harm to the
unborn baby or tendency to cause cancer.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity
Serious Eye
STOT - Single Exposure
Damage/Irritation
Respiratory or Skin
STOT - Repeated Exposure
sensitisation
Mutagenicity Aspiration Hazard
Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification

Other information
Not Available

SECTION 12 Ecological information

Toxicity

Endpoint Test Duration (hr) Species Value Source

GulfSea Gear Oil 320 Not Not Not
Not Available Not Available
Available Available Available

Endpoint Test Duration (hr) Species Value Source

calcium bis(di-C8- EC50 48h Crustacea >=0.18mg/l 2
10,branched,C9-
rich)alkylnaphthalenesulfonate EC50 72h Algae or other aquatic plants ~0.16mg/l 2
EC50(ECx) 72h Algae or other aquatic plants ~0.16mg/l 2

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 4. US EPA,
Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI
(Japan) - Bioconcentration Data 8. Vendor Data

DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air
No Data available for all ingredients No Data available for all ingredients

Continued...
Chemwatch: 5612-46 Page 8 of 9 Issue Date: 27/06/2023
Part Number: GulfSea Gear Oil 68, 100, 150, 220, 320, 460, 680 Print Date: 07/05/2025
Version No: 3.1

Bioaccumulative potential
Ingredient Bioaccumulation
No Data available for all ingredients

Mobility in soil
Ingredient Mobility
No Data available for all ingredients

Other adverse effects

No evidence of ozone depleting properties were found in the current literature.

SECTION 13 Disposal considerations

Waste treatment methods

Containers may still present a chemical hazard/ danger when empty.
Return to supplier for reuse/ recycling if possible.
Otherwise:
If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to store the
same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.
Where possible retain label warnings and SDS and observe all notices pertaining to the product.
Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in
their area. In some areas, certain wastes must be tracked.
A Hierarchy of Controls seems to be common - the user should investigate:
Reduction
Reuse
Recycling
Product / Packaging disposal Disposal (if all else fails)
This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. If it has been
contaminated, it may be possible to reclaim the product by filtration, distillation or some other means. Shelf life considerations should also be
applied in making decisions of this type. Note that properties of a material may change in use, and recycling or reuse may not always be
appropriate.
DO NOT allow wash water from cleaning or process equipment to enter drains.
It may be necessary to collect all wash water for treatment before disposal.
In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
Where in doubt contact the responsible authority.
Recycle wherever possible or consult manufacturer for recycling options.
Consult State Land Waste Authority for disposal.
Bury or incinerate residue at an approved site.
Recycle containers if possible, or dispose of in an authorised landfill.

SECTION 14 Transport information

Labels Required

Marine Pollutant NO

Land transport (UN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

14.7. Maritime transport in bulk according to IMO instruments

14.7.1. Transport in bulk according to Annex II of MARPOL and the IBC code
Not Applicable

14.7.2. Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
Product name Group
calcium bis(di-C8-
10,branched,C9- Not Available
rich)alkylnaphthalenesulfonate

14.7.3. Transport in bulk in accordance with the IGC Code

Product name Ship Type
calcium bis(di-C8-
10,branched,C9- Not Available
rich)alkylnaphthalenesulfonate

SECTION 15 Regulatory information

Safety, health and environmental regulations / legislation specific for the substance or mixture

calcium bis(di-C8-10,branched,C9-rich)alkylnaphthalenesulfonate is found on the following regulatory lists

Not Applicable

Additional Regulatory Information

Continued...
Chemwatch: 5612-46 Page 9 of 9 Issue Date: 27/06/2023
Part Number: GulfSea Gear Oil 68, 100, 150, 220, 320, 460, 680 Print Date: 07/05/2025
Version No: 3.1

Not Applicable

National Inventory Status

National Inventory Status
Australia - AIIC / Australia Non-
Yes
Industrial Use
Canada - DSL Yes
Canada - NDSL No (calcium bis(di-C8-10,branched,C9-rich)alkylnaphthalenesulfonate)
China - IECSC Yes
Europe - EINEC / ELINCS /
Yes
NLP
Japan - ENCS Yes
Korea - KECI Yes
New Zealand - NZIoC Yes
Philippines - PICCS Yes
USA - TSCA All chemical substances in this product have been designated as TSCA Inventory ‘Active'
Taiwan - TCSI Yes
Mexico - INSQ No (calcium bis(di-C8-10,branched,C9-rich)alkylnaphthalenesulfonate)
Vietnam - NCI Yes
Russia - FBEPH Yes
Yes = All CAS declared ingredients are on the inventory
Legend:
No = One or more of the CAS listed ingredients are not on the inventory. These ingredients may be exempt or will require registration.

SECTION 16 Other information

Revision Date 27/06/2023

Initial Date 26/06/2023

Other information

Ingredients with multiple cas numbers

Name CAS No
calcium bis(di-C8-
10,branched,C9- 1474044-79-5, 57855-77-3, 86329-66-0
rich)alkylnaphthalenesulfonate

Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the
workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be
considered.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication and may be subject to modification
from time to time. It is the user's responsibility to verify that this Safety Data Sheet is current prior to use or application. The information given is designed only as a guidance for
safe handling, use, application, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates
only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

end of SDS