Clariant SDS Nipaguard PE 9010 USA English
Clariant SDS Nipaguard PE 9010 USA English
SECTION 1. IDENTIFICATION
GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Acute toxicity (Oral) : Category 4
Other hazards
None known.
Components
Chemical name CAS-No. Concentration (% w/w)
2-Phenoxyethanol 122-99-6 >= 70 - < 90
3-(2-Ethylhexyloxy)propane-1,2-diol 70445-33-9 >= 5 - < 10
Actual concentration is withheld as a trade secret
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.
Consult a physician.
Further information : In the event of fire and/or explosion do not breathe fumes.
Do not allow run-off from fire fighting to enter drains or water
courses.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Environmental precautions : The product should not be allowed to enter drains, water
courses or the soil.
Advice on protection against : Observe the general rules of industrial fire protection
fire and explosion
Advice on safe handling : Handle in accordance with good industrial hygiene and safety
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practice.
For personal protection see section 8.
Avoid contact with skin, eyes and clothing.
Use only with adequate ventilation.
Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
Keep away from heat, sparks and open flames. Store in
proper container and keep container closed when not in use.
Conditions for safe storage : Keep container tightly closed in a cool, well-ventilated place.
Protect from moisture.
Keep only in the original container.
Hand protection
Remarks : Chemical resistant gloves (butyl rubber, nitrile rubber,
polyvinyl alcohol). However, please note that PVA degrades
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in water.
Skin and body protection : Wear protective clothing, including long sleeves and gloves,
to prevent skin contact.
Hygiene measures : Wash hands before breaks and at the end of workday.
Use protective skin cream before handling the product.
Take off immediately all contaminated clothing and wash it
before reuse.
Appearance : Liquid
Colour : colourless
pale yellow
Odour : characteristic
pH : 6 - 8 (68 °F / 20 °C)
Concentration: 1 %
Solubility(ies)
Water solubility : 24 g/l soluble (68 °F / 20 °C)
Viscosity
Viscosity, dynamic : 40 mPa.s (68 °F / 20 °C)
Method: Brookfield
By analogy with a product of similar composition
Components:
2-Phenoxyethanol:
Acute oral toxicity : Acute toxicity estimate: 1,394 mg/kg
Assessment: The component/mixture is moderately toxic after
single ingestion.
Acute inhalation toxicity : LC50 (Rat, male and female): > 1000 mg/m³
Exposure time: 14 d
Test atmosphere: dust/mist
Method: OECD Test Guideline 412
GLP: yes
Assessment: The substance or mixture has no acute
inhalation toxicity
Acute dermal toxicity : LD50 (Rabbit, male and female): > 2,214 mg/kg
Method: Other
GLP: no
Assessment: The substance or mixture has no acute dermal
toxicity
3-(2-Ethylhexyloxy)propane-1,2-diol:
Acute inhalation toxicity : LC50 (Rat, male and female): 2.83 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: OECD Test Guideline 403
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Skin corrosion/irritation
Not classified due to lack of data.
Product:
Remarks : no data available
Components:
2-Phenoxyethanol:
Species : Rabbit
Exposure time : 4h
Method : OECD Test Guideline 404
Result : No skin irritation
GLP : no
Components:
2-Phenoxyethanol:
Result : Irritating to eyes.
3-(2-Ethylhexyloxy)propane-1,2-diol:
Result : Risk of serious damage to eyes.
Components:
2-Phenoxyethanol:
Test Type : Maximisation Test
Exposure routes : Skin contact
Species : Guinea pig
Method : OECD Test Guideline 406
Result : Not a skin sensitizer.
GLP : yes
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Components:
2-Phenoxyethanol:
Genotoxicity in vitro : Test Type: Ames test
Test system: Salmonella typhimurium
Concentration: 20 - 5000 µg/plate
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
GLP: yes
Germ cell mutagenicity - : In vitro tests did not show mutagenic effects, In vivo tests did
Assessment not show mutagenic effects
Carcinogenicity
Not classified due to lack of data.
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Product:
Carcinogenicity - : No information available.
Assessment
Components:
2-Phenoxyethanol:
Carcinogenicity - : No information available.
Assessment
IARC No component of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
OSHA No component of this product present at levels greater than or equal to 0.1% is
on OSHA’s list of regulated carcinogens.
NTP No component of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.
Reproductive toxicity
Not classified due to lack of data.
Product:
Reproductive toxicity - : No information available.
Assessment No information available.
Components:
2-Phenoxyethanol:
Effects on fertility : Test Type: Two-generation study
Species: Mouse, male and female
Strain: CD1
Application Route: oral (feed)
Dose: 0,25 - 1,25 - 2,5 % in diet
General Toxicity - Parent: NOAEL: 1,875 mg/kg body weight
General Toxicity F1: NOAEL: 375 mg/kg body weight
General Toxicity F2: NOAEL: 375 mg/kg body weight
Method: Other
GLP: yes
Product:
Remarks : no data available
Components:
2-Phenoxyethanol:
Assessment : The substance or mixture is not classified as specific target
organ toxicant, repeated exposure.
Components:
2-Phenoxyethanol:
Species : Rat, male and female
NOAEL : 369 mg/kg
Application Route : oral (gavage)
Exposure time : 13 w
Number of exposures : daily
Dose : 1250-2500-5000-10000-20000mg/l
Control Group : yes
Method : OECD Test Guideline 408
GLP : yes
Aspiration toxicity
Not classified due to lack of data.
Product:
no data available
Components:
2-Phenoxyethanol:
No aspiration toxicity classification
Ecotoxicity
Product:
Toxicity to fish : Remarks: no data available
Toxicity to algae/aquatic :
plants Remarks: no data available
Components:
2-Phenoxyethanol:
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 344 mg/l
End point: mortality
Exposure time: 96 h
Test Type: flow-through test
Analytical monitoring: yes
Method: Other
GLP: no data available
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 500 mg/l
aquatic invertebrates End point: Immobilization
Exposure time: 48 h
Test Type: static test
Analytical monitoring: no
Method: OECD Test Guideline 202
GLP: no
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Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 9.43 mg/l
aquatic invertebrates End point: Reproduction rate
(Chronic toxicity) Exposure time: 21 d
Test Type: semi-static test
Analytical monitoring: yes
Method: OECD Test Guideline 211
GLP: yes
EC50: 37 mg/kg
Exposure time: 19 d
Species: Brassica napus
Analytical monitoring: no
Method: OECD Guide-line 208
GLP: yes
3-(2-Ethylhexyloxy)propane-1,2-diol:
Ecotoxicology Assessment
Chronic aquatic toxicity : Harmful to aquatic life with long lasting effects.
Components:
2-Phenoxyethanol:
Biodegradability : aerobic
Inoculum: activated sludge
Concentration: 30 mg/l
Biochemical Oxygen Demand (BOD)
Result: Readily biodegradable.
Biodegradation: 90 %
Exposure time: 28 d
Method: OECD Test Guideline 301F
GLP: yes
aerobic
Inoculum: activated sludge
Concentration: 20 mg DOC/l
Dissolved organic carbon (DOC)
Result: Readily biodegradable.
Biodegradation: > 90 %
Exposure time: 15 d
Method: OECD Test Guideline 301A
GLP: yes
removability
Bioaccumulative potential
Product:
Bioaccumulation : Remarks: no data available
Components:
2-Phenoxyethanol:
Bioaccumulation : Species: Other
Bioconcentration factor (BCF): 0.35
Method: calculated
GLP: no
Mobility in soil
Product:
Distribution among : Remarks: no data available
environmental compartments
Components:
2-Phenoxyethanol:
Distribution among : adsorption
environmental compartments Medium: water - soil
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Components:
2-Phenoxyethanol:
Environmental fate and : no data available
pathways
Results of PBT and vPvB : Substance is not persistent, bioaccumulative, and toxic (PBT).
assessment
Additional ecological : The product should not be allowed to enter drains, water
information courses or the soil.
Disposal methods
RCRA - Resource : This product, if discarded as sold, is not a Federal RCRA
Conservation and Recovery hazardous waste.
Authorization Act
Waste Code : NONE
Waste from residues : Dispose of this product in accordance with all applicable local,
state and federal regulations.
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 112 (40 CFR
61):
2-Phenoxyethanol 122-99-6 >= 70 - < 90 %
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for
Accidental Release Prevention (40 CFR 68.130, Subpart F).
The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI
Intermediate or Final VOC's (40 CFR 60.489):
2-Phenoxyethanol 122-99-6 >= 70 - < 90 %
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act,
Section 311, Table 116.4A.
This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act,
Section 311, Table 117.3.
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section
307
This product does not contain any priority pollutants related to the U.S. Clean Water Act
The components of this product are reported in the following inventories:
TSCA : This product is not listed on the TSCA Inventory. It is to be
used as a cosmetic ingredient only. Any other use will subject
the user to penalties under the Toxic Substances Control Act
and the regulations issued thereunder.
Further information
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NFPA 704:
Flammability
1
Health Instability
3 0
Special hazard
AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response,
Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN -
Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL -
Domestic Substances List (Canada); ECx - Concentration associated with x% response; EHS -
Extremely Hazardous Substance; ELx - Loading rate associated with x% response; EmS -
Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx -
Concentration associated with x% growth rate response; ERG - Emergency Response Guide;
GHS - Globally Harmonized System; GLP - Good Laboratory Practice; HMIS - Hazardous
Materials Identification System; IARC - International Agency for Research on Cancer; IATA -
International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory
concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing
Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50
- Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test
population (Median Lethal Dose); MARPOL - International Convention for the Prevention of
Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise
Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals;
OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical
Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS
- Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure
Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation
(EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-
Accelerating Decomposition Temperature; SARA - Superfund Amendments and Reauthorization
Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TECI - Thailand
Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United
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This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Clariant makes no warranties, express
or implied, as to the information’s accuracy, adequacy, sufficiency or freedom from defect and
assumes no liability in connection with any use of this information. Any user of this product is
responsible for determining the suitability of Clariant's products for its particular application. NO
EXPRESS OR IMPLIED WARRANTY IS MADE OF THE MERCHANTABILITY, SUITABILITY,
FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE OF ANY PRODUCT OR
SERVICE. Nothing included in this information waives any of Clariant’s General Terms and
Conditions of Sale, which control unless it agrees otherwise in writing. Any existing
intellectual/industrial property rights must be observed. Due to possible changes in our products
and applicable national and international regulations and laws, the status of our products could
change. Material Safety Data Sheets providing safety precautions, that should be observed when
handling or storing Clariant products, are available upon request and are provided in compliance
with applicable law. You should obtain and review the applicable Material Safety Data Sheet
information before handling any of these products. For additional information, please contact
Clariant.
US / EN