MATERIAL SAFETY DATA SHEET (MSDS)

European

STSM N.200I Revision 32n in compliance with directives (EC) N. 1907/2006 and (EC) N. 1272/2008
Publication date: April 16, 1998 Last revision date: 15.4.16

1. IDENTIFICATION OF PRODUCTS AND THE PRODUCER

1.1.IDENTIFICATION OF PRODUCTS

Insulfrax

Alkali earth fibre (Lane AES)

The above-mentioned product contains silico-alkaline lanes (AES lanes)
Index number: 650-016-00-2 Annex VI
CAS Number: 436083-99-7
Registration number: 01-2119457644-32-0002

1.2 USE OF THE PRODUCT

It can be used in applications for thermal insulation, thermal screens, for heat containment,
for seals and expansion joints in industrial furnaces, blast furnaces, ovens, boilers, and other process equipment
it is also used in the aerospace, automotive, and appliance sectors, protection systems
fire prevention and extinguishers. (For more information, please refer to the relevant technical data sheet).

1.3 IDENTIFICATION OF THE PRODUCER/SUPPLIER

UNITED KINGDOM Unifrax Limited

Mill Lane, Rainford
St Helens, Merseyside
WA11 8LP
Tel: + 44 (0) 1744 88 7600
+ 44 (0) 1744 9916

FRANCE Unifrax France

17, Antoine Durafour Street
42420 Lorette, France
Tel: + 33 (0) 4-77737000
+ 33 (0) 4-77733991

Germany
Unifrax GmbH
Kleinreinsdorf 62
07989 Teichwolframsdorf
Tel: +49 (0) 366 24 40020
Fax: + 49 (0) 366 24 40099

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Czech Republic
Unifrax Ltd.
Russian 311, Pozorka
417 03
Dubi 3, Czech Republic
Tel: + 42 (0) 417 800 356
+ 42 (0) 417 539 838

Commercial Contacts

SPAIN Unifrax Spain ITALY Unifrax Italia Srl

Cristobal Bordiu 20 Via Volonterio 19
Madrid 28003 Saronno (Va) 21047
Spain Italy
+34 91 395 2279 Tel: +39 02 967 01 808
+34 91 395 2124 Fax: + 39 02 962 5721

Numbers to contact in case of emergency

Occupational hygiene and CARE: Tel: + 44 (0) 1744 887603. Fax: + 44 (0) 1744 886173
[email protected]
English
Opening hours: only available during office hours

2. IDENTIFICATION OF HAZARDS

CLASSIFICATION OF SUBSTANCE / MIXTURE

Not applicable

LABELING ELEMENTS
Not applicable

OTHER HAZARDS NOT INCLUDED IN THE CLASSIFICATION

The INSULFRAX fibers can cause slight mechanical irritation to the skin, eyes, and upper respiratory tract.
respiratory. Such effects are usually temporary.
Pre-existing respiratory and skin diseases such as dermatitis, asthma, or lung conditions can worsen with
the exhibition

3. COMPOSITION / INFORMATION ON INGREDIENTS

COMPONENTS CAS NUMBER % Index number

Alkaline fiber 436 083 99 7 100 650-016-00-2

alkaline earth (AES wool)

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COMPOSITION
INSULFRAX is an alkaline earth silicate fiber containing (AES)* containing (SiO2) 60-70% and a (CaO +
MgO) of 30–40%.

Definition of CAS: alkaline earth silicate (AES) consisting of silica (50-82% by weight), calcium oxides and
magnesium (18-43% by weight), aluminum oxides, titanium and zirconium (less than 6% by weight), and traces of oxides.

None of the components is radioactive according to the terms of the European Directive Euratom 96/29.

DESCRIPTION
The productsINSULFRAX is available in the form of: flakes, mats, papers, felts, sheets, shaped parts, modules.
cements, coatings, mixtures, and mastics. Depending on the shape of the product, there may be others present.
ingredients (see table that follows).

4. FIRST AID MEASURES

SKIN
The manipulation of this material may cause a slight temporary mechanical irritation to the skin. If
if this occurs, rinse the affected parts thoroughly with water and wash them gently. Do not scrub or
scratch the irritated skin.

EYES
In case of direct contact with the eyes, rinse thoroughly with water, keep available a
eye wash. Do not rub your eyes.
Nose and throat

If these are irritated, move to an open area free of dust, drink water, and blow your nose abundantly.
nose. If symptoms persist, contact your doctor.

5. FIRE MEASURES

Non-combustible products. The packaging can be combustible.

Use suitable fire extinguishers for combustible packaging.

6. MEASURES IN CASE OF ACCIDENTAL ESCAPE

Where abnormal high concentrations of dust occur, provide workers with appropriate protective equipment.
as described in section 8.

Restore normalcy as soon as possible.

Prevent the dispersion of further dust by moistening materials, for example.
Collect the large pieces and use a vacuum cleaner with a high-efficiency particulate air (HEPA) filter.
If using a broom, make sure the area has been pre-wet.

Do not use compressed air for cleaning.

Do not allow wind gusts.
Do not throw the product into the sewage.

For waste disposal, consult section 13

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 7. HANDLING AND STORAGE

MANIPULATION / METHODS TO REDUCE DUST EMISSIONS DURING HANDLING

MANIPULATION
Manipulation can be the cause of dust production.
Adopt work methodologies that allow to limit manipulations. Whenever possible, the
manipulations must be carried out under controlled conditions (e.g.: use suction systems).
In general, dust dispersion can be easily reduced in environments with a good level of cleanliness.
STORAGE
Keep the product in its original packaging in a dry environment until use.
Always use closed containers with visible labels.
Avoid damaging the containers.
Avoid dust emissions during unpacking.
Empty containers that may contain residues must be cleaned before disposal or recycling.

8. EXPOSURE CONTROL / PERSONAL PROTECTION

Industrial hygiene standards and exposure limits vary between countries and local jurisdictions. Check the level of
exposure of your facility and comply with local regulations. If there are no hygiene standards related
For all dust or other applicable standards, a qualified industrial hygienist can assist you with a specific
evaluation of the workplace suggesting recommendations for respiratory protection. Below
Examples of exposure limits for applied mineral lanes are reported (in January 2010) in different countries:

NATION EXPOSURE LIMIT* SOURCE

Germany 1.25 mg/m3 TRGS 900

France 1.0 f/ml Circular DRT No 95-4 of 12.01.95

U.K. 2.0 f/ml and 5 mg/m3 HSE - EH40–Workplace Exposure Limit

Weighted average concentration of breathable fibers measured over 8 hours of analysis with membrane filter or of the
total respirable dust with the traditional gravimetric method.

TECHNICAL CONTROLS
Review the application methodologies of the fibers considering the potential dispersion of powders.

It is possible to contain the sources of dust and provide for their extraction.
Use vacuum cleaners that collect dust at the source. For example, suction tables, equipment for the
manipulation and equipment for emission control.
Keep the workplace clean. Use a vacuum cleaner with a HEPA filter, avoid using compressed air and
scope.

PERSONAL PROTECTIVE EQUIPMENT

SKIN PROTECTION
Wear gloves and clothing that do not cling to the neck and wrists. Work clothing should be cleaned before
remove them (use vacuum cleaners and compressed air) in order to remove the excess fibers.

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EYE PROTECTION
If necessary, wear masks or glasses with side shields.
PROTECTION OF THE RESPIRATORY TRACTS
For dust concentrations below the limits, RPE masks are not required, but FFP2 masks are.
they can be used on a voluntary basis.
For short-duration work, when concentrations are below ten times the limit, use FFP2 masks.
In case of high concentrations or when the concentration is unknown, seek advice from the company and/or the
supplier.

EMPLOYEE INFORMATION AND TRAINING

Workers must be trained in good work practices and informed about current regulations.

ENVIRONMENTAL CONTROLS AT EXHIBITIONS

Refer to local, national or European standards for release into air, water, and soil.
For waste, refer to section 13.

9. PHYSICAL-CHEMICAL PROPERTIES

COEFFICIENT OF No
ASPECT White fiber
DISTRIBUTION applicable
boiling point Not applicable ODORE None
POINT Melting point
Not applicable 1300° C
INFLAMMABILITY OF FIBERS
No
AUTOIGNITION None FLAMMABILITY
applicable
Oxidizing properties None EXPLOSIVE PROPERTIES None
No
Relative density 50-240 kg/m3 Vapor Pressure
applicable
No
SOLUBILITY Less than 1 mg/l pH
applicable
1.9 - 6 µm
GEOMETRIC MEAN DIAMETER
THOUGHTFUL REGARDING LENGTH
OF FIBERS CONTAINED IN THE PRODUCT

10. STABILITY AND REACTIVITY

CONDITIONS TO AVOID: NOT APPLICABLE MATERIALS TO AVOID: NOT APPLICABLE

DECOMPOSITION PRODUCTS
After prolonged use at temperatures exceeding 900 °C, in these amorphous materials, on the glass matrix,
Various crystallization phases can form, including the crystallization of silica.
For further information refer to section 16.

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 11. TOXICOLOGICAL INFORMATION

IRRITATING PROPERTIES
Tested, according to approved methods (Directive 67/548/EC, appendix V, method B4), these fibers yield results
negatives. All synthetic mineral fibers, like some natural fibers, can cause slight irritation
which causes itching or, rarely in more sensitive individuals, a slight redness. Unlike other reactions of
irritation is not a result of an allergy or chemical damage to the skin, but is caused by effects
mechanics.

DATA RELATING TO ANIMAL EXPERIMENTS

These fibers have been studied to allow for a rapid clearance of lung tissues and their low
Biopersistence has been confirmed in many tests using the EU ECB/TM/27(rev.7) protocol and the German method.
specified in the TEGS 905 of 1999. If inhaled, even at high doses, they do not accumulate at any level capable of
produce serious biological effects. No effects different from those found in tests were observed in half-life tests.
of inert powders. In sub-chronic tests, conducted at the highest possible concentrations, at worst, a
light and transient inflammation. Fibers with the same ability to penetrate lung tissues do not produce
tumors when injected into the peritoneal cavities of mice.

12. ECOLOGICAL INFORMATION

These products are inert materials that remain stable over time.
No harmful effects caused by these products are reported on the environment.

13. DISCHARGE

AES fibers are to be considered as special waste, which can be disposed of in a controlled landfill. Do
reference to the European list (Decision No. 2000/532/EC and its amendments) to identify its number
appropriate and ensure that national and/or regional regulations are compliant.
It is important to consider that during use there may be some contaminations, consult some
experts.
This waste, unless it is wet, is dusty and should therefore be placed in sealed and labeled containers.
In some authorized landfills, these waste materials are treated in such a way that immediate intervention prevents the
diffusion of powders in case of strong wind. Check that national and/or regional regulations are in place.
compliance.
.
14. TRANSPORT

Not classified as hazardous materials by international transport regulations (ADR, RID, IATA, IMDG)
See Section 16 "Definitions".

Ensure that the powders are not dispersed by the wind during transport.

15. REGULATIONS

DEFINITION OF FIBER TYPE UNDER DIRECTIVE 67/548/EEC

According to Directive 67/548/EEC, the fiber contained in this product is a mineral wool belonging to the
group of "glass synthetic fibers (silicates) with random orientation with alkaline earth oxide content
(Na2O +K2O+CaO+MgO+BaO) greater than 18% by weight.

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Based on the criteria listed in note Q of Directive 67/548/EEC, the fibers contained in the products mentioned in the title
they are exempt from classification as carcinogens because of the biopersistance, measured according to the methods
specified in the German and European Union regulations (protocol EU ECB/TM/27 rev.7), in the textiles
pulmonary is low.

The 31st adaptation of the Technical Progress of Directive 67/548/EEC of January 15, 2009, has removed the
classification of skin irritant for artificial glass wool (silicates).

2. DEFINITION OF FIBER TYPE IN ACCORDANCE WITH REGULATION (EC) NO. 1272/2008 WHICH
AMENDS AND REVOKES DIRECTIVES 67/548/EEC AND 1999/45/EC, AND AMENDS REGULATION (EC)
N. 1907/2006.

This regulation aims to incorporate the GHS criteria into the EU community law.
At point 1.1.3.1. (Note Q) of Annex VI of Regulation (EC) 1272/2008, the classification as carcinogen 2.
there is no need to be applied based on short-term biopersistence evidence through installation
intratracheal that shows a half-life of less than 40 days for fibers longer than 20µm.

In accordance with the 1st adaptation of the Technical Progress of the regulation (EC) No. 1272/2008 of August 10, 2009, it is
the irritating classification for glass fibers (silicates) has been removed.

Therefore, the fibers contained in this product are unclassified and do not require labeling.
sensitivity of the CLP regulation.

PROTECTION OF OPERATORS

It must be in accordance with the numerous European Directives and their amendments and the changes introduced by the
Member States:
a) Council Directive 89/391/EEC of June 12, 1989 "on the introduction of measures to encourage improvements
in the health and safety of workers in the workplace" (OJEC, Official Journal of the European Community, L
183 of June 29, 1989, p.1.
b) Council Directive 98/24/EC of April 7, 1998 'on the protection of workers from risks related to the use of chemical agents at work'
of chemical agents in the workplace” (OJEC L 131 of May 5, 1998, p.11).

OTHER POSSIBLE REGULATIONS

Each Member State has the authority to implement European Directives into its national regulations by
period normally set by the directive. Each Member State may impose stricter regulations. Please
to always refer to national regulations.

The above applies to sales in the European Community

PROTECTION OF OPERATORS
It must be in accordance with the European Directives and the amendments introduced by the Member States:

Directive 89/391/EEC of June 12, 1989 'on the introduction of measures to encourage improvements in health and
worker safety in the workplace" (OJEC, Official Journal of the European Community, L 183 of the 29
June 1989, p.1.

Directive 98/24/EC of April 7, 1997 "on the protection of workers from risks related to the use of chemical agents"
"at the workplace" (OJEC L 131 of May 5, 1998, p. 11).

Each Member State can amend the European Directives in its national regulations within the period
normally established by the directive. Each Member State may impose more restrictive regulations. Comply
however to national regulations.

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 16. OTHER INFORMATION

USEFUL REFERENCES (the cited directives must be considered in their amended versions)

Directive 89/391/EEC of June 12, 1989 'on the introduction of measures to improve the health and safety of workers'
workers at the workplace" (OJEC - Official Journal of the European Community - L 183 of June 29
1989, p. 1).
Directive 67/548/EEC concerning "amendments and adjustments to the technological progress of the approximation of
laws, regulations, and administrative provisions related to classification, packaging, and labeling of
"dangerous substances" (OJEC L196 of August 16, 1967, p.1 and its amendments and adaptations to progress
technological).
Directive 97/69/EC of December 5, 1997 'adaptation for the 23rd time to technological progress of the Council
Directive 67/548/EEC (OJEC L 343 of 13/12/97 pg.19).
Directive 98/24/EC of April 7, 1997 "on the protection of workers from risks related to the use of chemical agents"
"at the workplace" (OJEC L 131 of May 5, 1998, p. 11).
TRGS 521: Fiber Dust - Germany
Circular March 15, 2000, n.4–Italy

DEFINITIONS
ADR - Road Transport, Directive 94/55/EC
IMDG - Regulations concerning maritime transport
RID - Transport by railway, directive 96/49/EC
ICAO/IATA - Regulations regarding air transport

Precautionary measures to be taken after use and before removal

In almost all applications, products in high-temperature insulation materials (HTIW) are used as materials.
insulators that help maintain the temperature at 900°C or higher in an enclosed space. As produced, the fibers
Isofrax is a glassy material that, when exposed continuously to high temperatures (above 900 C) they could
dehydration. The occurrence and measurement of the formation of the crystalline phase depend on the duration and the
exposure temperature, from the chemical composition of the fiber and/or from the presence of flux agents. Since
only a thin layer of the insulating hot surface is exposed to the high temperature, the dust
air generated during removal operations do not contain detectable levels of crystalline silica (CS).

In applications where the material is tempered with a heat bath, the duration of exposure to heat is
normally brief and does not result in significant devitrification that allows for the accumulation of crystalline silica
(CS). For example, this is the case of the waste from the casting mold.

The toxicological assessment of the effect of the presence of CS in artificially heated HTIW material has not
increased toxicity in vitro and in vivo. The results of different combinations of factors such as increased fragility
fibers or microcrystals encapsulated in the glass structure of the fiber and therefore not biologically available
they can explain the lack of toxic effects.
The IARC assessment as provided in Monograph 68 is not relevant since the CS is not available.
biologically in HTIW after use.

After using the product and during mechanical disturbance operations, such as demolition, one
they can generate high concentrations of fibers and other powders. Therefore, ECFIA recommends:
That control measures be adopted to reduce dust emissions; and
That all directly involved personnel wear a mask to minimize exposure and comply with the
local regulatory limitations.

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CARE PROGRAM

The European Ceramic Fibres Industry Association (ECFIA) has undertaken an intensive hygiene program.
industrial support for users of RCF products.

The main objectives are:

monitor the concentration of dust both at producers and users
document the production and use of RCF products from an industrial hygiene perspective in order to establish
appropriate recommendations to reduce exposure to dust.

If you want to participate in the CARE program, contact the ECFIA or your supplier.

NOTE
The directives and the resulting regulations described in this safety data sheet are applicable only in
countries of the European Community (EU) and not in non-EU countries..

Websites
European Industry Association representative HTIW (ECFIA): 3, Rue du Colonel Moll, 75017 Paris
+33 (0)6 31 48 74 26
www.ecfia.eu

Review summary
Section 1 addition of identified uses, change of emergency contact number, addition of identifiers of
product
Section 2 formatted in accordance with Regulation (EC) No. 1907/2006
Section 3 addition of classification pursuant to (EC) No. 1272/2008
Section 15 in accordance with the directives (EC) No. 1907/2006 and (EC) No. 1272/2008
Section 16 the addition of products
Section 1 address changed
Additives table name – the addition of products, fyrewrap, Insulfrax Mouldable LSM

Note
The information contained in this document is considered accurate as of the date of drafting.
this Safety Data Sheet. Employers can use this sheet as a supplement to others
information gathered by them in their commitment to ensuring the health and safety of their employees and the use
appropriate for the product. This summary of the relevant data reflects a professional judgment; the employees
they should note that less relevant information has not been included in this document. Therefore,
Due to the summary nature of this document, Unifrax I LLC makes no warranties (express or
implicit), nor does it assume any responsibility or make any statement regarding the completeness of
these informations or their suitability for the purposes envisaged by the user.

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 INSULFRAX Products

Substances according to REACH (EC) No 1907/2006:

Lubricated Ribbon
Insulfrax S, Insulfrax LT

Mixtures
Cements, Mastic and Coatings
Insulfrax Mouldable LSM

Articles according to REACH (EC) No 1907/2006:

Mattresses
Insulfrax S, FyreWrap, Insulfrax LT, FyreWrap LT, Insulfrax WR,
FyreWrap LT, Insulfrax LTWR
Mattresses
Insulfrax/FyreWrap SF(2), SFR(2), SG(2), Insulfrax/FyreWrap LTF(2), LTFR(2), LTFE
LTG(2), FyreWrap Elite 1.5, FyreWrap Cable Insulation
Mattresses
Insulfrax Katiss
Modules
Insulfrax Anchor-Loc, Bonded
Cards and Felt
Insulfrax Paper, Insulfrax Felt, Insulfrax FT Paper,FyreWrapIG Tape
Plates and Shaped Products
Rigiform shapes: Insulfrax 110, Insulfrax 110HD
Flexiform shapes: Insulfrax 110
Plates and Shaped Parts
Insulfrax Board 110LD, AV1100
Plates and Shaped Products
Silplate 1212S, 1108S
Sheets and Shapes
Alusol
Plates and Profiles
Insulfrax Board 110ZK, Boiler parts 110CM, Boiler Parts 110WT, Insulfrax Block 80
Insulfrax Block 110, Insulfrax KT Board, Insulfrax MD Board
Special Products
Insulfrax Moist Pak HD
Fabrics
Insulfrax Ropes, Braids, Cloth, Tape & Bourel

The Mixtures and the Articles may contain both organic and inorganic binders, all of which have been
evaluated based on supplier information, and which are considered as non-
dangerous according to regulationsCLP/(EC) 1272/2008

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