Photochromic materials preparation properties and

applications 1st Edition Tian 2025 easy download

https://ebookultra.com/download/photochromic-materials-preparation-
properties-and-applications-1st-edition-tian/

★★★★★
4.7 out of 5.0 (48 reviews )

PDF Instantly Ready

ebookultra.com
 Photochromic materials preparation properties and
applications 1st Edition Tian

EBOOK

Available Formats

■ PDF eBook Study Guide Ebook

EXCLUSIVE 2025 ACADEMIC EDITION – LIMITED RELEASE

Available Instantly Access Library

Here are some recommended products for you. Click the link to
download, or explore more at ebookultra.com

Photochromic Materials Preparation Properties and

Applications First Edition He Tian

https://ebookultra.com/download/photochromic-materials-preparation-
properties-and-applications-first-edition-he-tian/

Titanium Alloys Preparation Properties and Applications

Preparation Properties and Applications 1st Edition Pedro
N. Sanchez
https://ebookultra.com/download/titanium-alloys-preparation-
properties-and-applications-preparation-properties-and-
applications-1st-edition-pedro-n-sanchez/

Molecular Materials Preparation Characterization and

Applications 1st Edition Fraxedas

https://ebookultra.com/download/molecular-materials-preparation-
characterization-and-applications-1st-edition-fraxedas/

Common Fragrance and Flavor Materials Preparation

Properties and Uses Fifth Edition Horst Surburg

https://ebookultra.com/download/common-fragrance-and-flavor-materials-
preparation-properties-and-uses-fifth-edition-horst-surburg/
Nonconventional and vernacular construction materials
characterisation properties and applications Second
Edition Harries
https://ebookultra.com/download/nonconventional-and-vernacular-
construction-materials-characterisation-properties-and-applications-
second-edition-harries/

Al based Energetic Nano Materials Design Manufacturing

Properties and Applications 1st Edition Carole Rossi

https://ebookultra.com/download/al-based-energetic-nano-materials-
design-manufacturing-properties-and-applications-1st-edition-carole-
rossi/

Composite Non Woven Materials Structure Properties and

Applications 1st Edition D. Das And B. Pourdeyhimi (Auth.)

https://ebookultra.com/download/composite-non-woven-materials-
structure-properties-and-applications-1st-edition-d-das-and-b-
pourdeyhimi-auth/

Handbook of Advanced Dielectric Piezoelectric and

Ferroelectric Materials Synthesis Properties and
Applications 1st Edition Z. Ye
https://ebookultra.com/download/handbook-of-advanced-dielectric-
piezoelectric-and-ferroelectric-materials-synthesis-properties-and-
applications-1st-edition-z-ye/

Niobium Properties Production and Applications Properties

Production and Applications 1st Edition Thomas M. Wong

https://ebookultra.com/download/niobium-properties-production-and-
applications-properties-production-and-applications-1st-edition-
thomas-m-wong/
Edited by
He Tian and Junji Zhang

Photochromic Materials
Edited by He Tian and Junji Zhang

Photochromic Materials

Preparation, Properties and Applications

Editors All books published by Wiley-VCH
are carefully produced. Nevertheless,
Dr. He Tian authors, editors, and publisher do not
East China University of Science warrant the information contained in
and Technology these books, including this book, to
Key Laboratory for Advanced Materials be free of errors. Readers are advised
200237 Shanghai to keep in mind that statements, data,
China illustrations, procedural details or other
items may inadvertently be inaccurate.
Dr. Junji Zhang
East China University of Science and Library of Congress Card No.: applied for
Technology
Key Laboratory for Advanced Materials British Library Cataloguing-in-Publication
200237 Shanghai Data
China A catalogue record for this book is
available from the British Library.
Cover
Imgram Publishing, UK Bibliographic information published by the
Deutsche Nationalbibliothek
The Deutsche Nationalbibliothek
lists this publication in the Deutsche
Nationalbibliografie; detailed
bibliographic data are available on the
Internet at <http://dnb.d-nb.de>.

© 2016 Wiley-VCH Verlag GmbH & Co.

KGaA, Boschstr. 12, 69469 Weinheim,
Germany

All rights reserved (including those of

translation into other languages). No
part of this book may be reproduced in
any form – by photoprinting,
microfilm, or any other means – nor
transmitted or translated into a machine
language without written permission
from the publishers. Registered names,
trademarks, etc. used in this book, even
when not specifically marked as such,
are not to be considered unprotected
by law.

Print ISBN: 978-3-527-33779-8

ePDF ISBN: 978-3-527-68370-3
ePub ISBN: 978-3-527-68372-7
Mobi ISBN: 978-3-527-68371-0
oBook ISBN: 978-3-527-68373-4

Cover Design Schulz Grafik-Design,

Fußgönheim, Germany
Typesetting SPi Global, Chennai, India
Printing and Binding

Printed on acid-free paper

 V

Contents

List of Contributors XI

1 Introduction: Organic Photochromic Molecules 1

Keitaro Nakatani, Jonathan Piard, Pei Yu, and Rémi Métivier
1.1 Photochromic Systems 1
1.1.1 General Introduction 1
1.1.2 Basic Principles 4
1.1.3 Photochromic Molecules: Some History 5
1.2 Organic Photochromic Molecules: Main Families 8
1.2.1 Proton Transfer 9
1.2.2 Trans–Cis Photoisomerization 12
1.2.3 Homolytic Cleavage 13
1.2.4 Cyclization Reaction 14
1.2.4.1 Spiropyrans, Spirooxazines, and Chromenes 14
1.2.4.2 Fulgides and Fulgimides 17
1.2.4.3 Diarylethenes 18
1.3 Molecular Design to Improve the Performance 20
1.3.1 Figures of Merit 20
1.3.2 Fatigue Resistance: Increasing the Number of Operating Cycles 21
1.3.3 Bistability: Avoiding Unwanted Thermal Back-Reaction in the
Dark 23
1.3.3.1 Influence of Ethenic Bridge on the Thermal Stability of the B
Form 24
1.3.3.2 Impact of the Heteroaryl Substituents on the Thermal Stability of the
B Form 24
1.3.4 Fast Photochromic Systems: Reverting Back Spontaneously to the
Colorless State in a Glance 25
1.3.5 Gaining Efficiency of the Photoreaction: the Example of
Diarylethenes 26
1.4 Conclusion 31
Irradiation at a Specific Wavelength: Isosbestic Point 32
VI Contents

Case A: When the Thermal Back-Reaction is Negligible Compared to

the Photochemical Reaction (Typically P-type) 33
Case B: When the Thermal Back-Reaction is More Efficient than the
Photochemical B → A Reaction (Typically T ype) 34
References 34

2 Photochromic Transitional Metal Complexes for

Photosensitization 47
Chi-Chiu Ko and Vivian Wing-Wah Yam
2.1 Introduction 47
2.2 Photosensitization of Stilbene- and Azo-Containing Ligands 48
2.3 Photosensitization of Spirooxazine-Containing Ligands 51
2.4 Photosensitization of Diarylethene-Containing Ligands 54
2.5 Photosensitization of Photochromic N∧ C-Chelate
Organoboranes 63
2.6 Conclusion 65
References 66

3 Multi-addressable Photochromic Materials 71

Shangjun Chen, Wenlong Li, and Weihong Zhu
3.1 Molecular Logic Gates 71
3.1.1 Two-Input Logic Gates 71
3.1.2 Combinatorial Logic Systems 74
3.1.2.1 Half-Adder and Half-Subtractor 74
3.1.2.2 Keypad Locks 77
3.1.2.3 Digital Encoder and Decoder 82
3.2 Data Storage and Molecular Memory 84
3.2.1 Fluorescence Spectroscopy 85
3.2.2 Infrared Spectroscopy 90
3.2.3 Optical Rotation 92
3.3 Gated Photochromores 95
3.3.1 Hydrogen Bonding 95
3.3.2 Coordination 98
3.3.3 Chemical Reaction 99
References 105

4 Photoswitchable Supramolecular Systems 109

Guanglei Lv, Liang Chen, Haichuang Lan, and Tao Yi
4.1 Introduction 109
4.2 Photoreversible Amphiphilic Systems 110
4.2.1 Photoreversible Diarylethene-Based Amphiphilic System 110
4.2.2 Photoreversible Azobenzene-Based Amphiphilic System 116
4.2.3 Photoreversible Spiropyran-Based Amphiphilic System 119
4.3 Photoswitchable Host–Guest Systems 122
4.3.1 Photocontrolled Supramolecular Self-Assembly 123
 Contents VII

4.3.2 Photocontrolled Capture and Release of Guest Molecules 128

4.3.3 Fluorescent Switching Promoted by Host–Guest Interaction 133
4.3.4 Photoswitchable Molecular Devices 137
4.4 Photochromic Metal Complexes and Sensors 141
4.4.1 Metal Complexes with Azobenzene Groups 141
4.4.2 Metal Complexes with Diarylethene Groups 144
4.4.3 Metal Complexes with Spirocyclic Groups 150
4.4.4 Metal Complexes with Rhodamine 152
4.5 Other Light-Modulated Supramolecular Interactions 153
4.6 Conclusions and Outlook 159
References 159

5 Light-Gated Chemical Reactions and Catalytic Processes 167

Robert Göstl, Antti Senf, and Stefan Hecht
5.1 Introduction 167
5.2 General Design Considerations 169
5.3 Photoswitchable Stoichiometric Processes 171
5.3.1 Starting Material Control 172
5.3.2 Product Control 175
5.3.3 Starting Material and Product Control 177
5.3.4 Template Control 178
5.4 Photoswitchable Catalytic Processes 182
5.4.1 Activity Control 182
5.4.2 Selectivity Control 185
5.5 Outlook 187
References 190

6 Surface and Interfacial Photoswitches 195

Junji Zhang and He Tian
6.1 Photochromic SAMs 196
6.1.1 Photochromic Electrode SAMs 196
6.1.2 Photoreversible Functional Surfaces 198
6.1.2.1 Photoswitchable Surface Wettability 198
6.1.2.2 Photocontrolled Capture-and-Release System 202
6.1.2.3 Smart Photochromic Surface Based on Supramolecular
Systems 203
6.1.2.4 Photochromic Surface for Molecular Data Processing 205
6.2 Photoregulated Nanoparticles 206
6.2.1 Photochromic Switches on Traditional Metal Nanoparticles 208
6.2.1.1 Photoswitching on the Metal Nanoparticles 208
6.2.1.2 Photoinduced Reversible Aggregation of Nanoparticles and Their
Versatile Applications 210
6.2.2 Photochromic Switches on Other Novel Functional
Nanoparticles 215
6.2.2.1 Photoswitchable Magnetic Nanoparticles 215
VIII Contents

6.2.2.2 Photomanipulated Quantum Dots 215

6.2.2.3 Photochromic with Upconversion Nanoparticles 218
6.2.3 Photocontrolled Mesoporous Silica Nanoparticles 220
6.2.3.1 Photo-nanovalves 220
6.2.3.2 Photo-nanoimpellers 223
6.2.3.3 NIR Light-Triggered MSN Drug Delivery and Therapeutic
Systems 224
6.3 Photocontrolled Surface Conductance 226
6.3.1 Photochromic Conductance Switching Based on SAMs 226
6.3.2 Photochromic Conductance on Single-Molecule Level 228
References 231

7 Hybrid Organic/Photochromic Approaches to Generate

Multifunctional Materials, Interfaces, and Devices 243
Emanuele Orgiu and Paolo Samorì
7.1 Introduction 243
7.1.1 Tuning the Charge Injection in Organic-Based Devices by Means of
Photochromic Molecules 245
7.2 Tuning the Polaronic Transport in Organic Semiconductors by
Means of Photochromic Molecules 251
7.2.1 Photochromic Molecules and Organic Semiconductors Incorporated
in Dyads, Multiads, and Polymers 251
7.2.2 The Multilayer Approach 254
7.2.3 The Blending Approach 255
7.3 Photoresponsive Dielectric Interfaces and Bulk 262
7.4 Conclusions and Future Outlooks 267
Acknowledgments 268
References 268

8 Photochromic Bulk Materials 281

Masakazu Morimoto, Seiya Kobatake, Masahiro Irie, Hari Krishna Bisoyi,
Quan Li, Sheng Wang, and He Tian
8.1 Photochromic Polymers 281
8.1.1 Glass Transition Temperature 281
8.1.2 Fluorescence 283
8.1.3 Conductivity 287
8.1.4 Living Radical Polymerization 288
8.1.5 Surface Relief Grating 290
8.1.6 Photomechanical Effect 290
8.2 Single-Crystalline Photoswitches 293
8.2.1 Crystalline-State Photochromic Materials 293
8.2.2 Photochromic Diarylethene Single Crystals 293
8.2.3 In situ X-ray Crystallographic Analysis of Photoisomerization
Reaction 295
8.2.4 Photoisomerization Quantum Yields 296
 Contents IX

8.2.5 Multicolor Photochromism of Multicomponent Crystals 297

8.2.6 Nanoperiodic Structures Fabricated by Photochromic
Reactions 299
8.2.7 Photoinduced Shape Changes and Mechanical Performance 301
8.3 Photochromic Liquid Crystals 305
8.3.1 Introduction 305
8.3.2 Spiropyran- and Spirooxazine-Based Photochromic Liquid
Crystals 309
8.3.3 Diarylethene-Based Photochromic Liquid Crystals 314
8.3.4 Azobenzene-Based Photochromic Liquid Crystals 320
8.3.5 Other Photochromic Liquid Crystals 327
8.3.6 Conclusions and Outlook 328
8.4 Photochromic Gels 329
8.4.1 Introduction 329
8.4.2 Azobenzene Gels 330
8.4.3 Spiropyran and Spirooxazine Gels 335
8.4.4 Diarylethenes Gels 337
8.4.5 Naphthopyran Gels 342
8.4.6 The Other Photochromic Gels 343
8.4.7 Conclusion 346
References 346

9 Photochromic Materials in Biochemistry 361

Danielle Wilson and Neil R. Branda
9.1 Introduction 361
9.2 Reversible Photochemical Switching of Biomaterial Function 362
9.3 General Design Strategies and Considerations 362
9.3.1 Photoswitchable Tethers 364
9.3.1.1 The Incorporation Method 364
9.3.1.2 Considerations 364
9.3.2 Photoswitchable Small Molecules 365
9.3.2.1 The Incorporation Method 365
9.3.2.2 Considerations 365
9.3.3 Chromophore Selection 367
9.4 Selected Examples 367
9.4.1 Photoswitchable Enzymes 367
9.4.1.1 Drug-Inspired Small Molecule Inhibitors 367
9.4.1.2 Phosphoribosyl Isomerase Inhibitor with Two Binding Units 370
9.4.1.3 Direct Modification of Enzymes with Photochromic Groups 372
9.4.2 Photoswitchable Peptides and Proteins 373
9.4.2.1 Peptide Cross-Linking 373
9.4.2.2 Cyclic Antimicrobial Peptide 375
9.4.2.3 Genetically Encoded Amino Acids 376
9.4.2.4 Control of Motor Protein Function Using Site-Selective
Mutation 377
X Contents

9.4.3 Photoswitchable Ion Channels and Receptors 379

9.4.3.1 Photocontrol of Channel Activation and Desensitization with a
Tethered Glutamate 380
9.4.3.2 Photocontrol of Insulin Release Using a Small Molecular
Sulfonylurea 380
9.4.3.3 Photocontrol of Receptors Using Red Light 381
9.4.4 Photoswitchable Nucleotides 382
9.4.4.1 Spiropyran-Modified Oligonucleotide Backbones 382
9.4.4.2 Controlling RNA Duplex Hybridization with Light 384
9.4.4.3 Diarylethene-Modified Oligonucleotides 385
9.5 Summary 386
References 386

10 Industrial Applications and Perspectives 393

Junji Zhang and He Tian
10.1 Industrialization and Commercialization of Organic Photochromic
Materials 393
10.1.1 Commercialized T-type Photochromic Materials 395
10.1.2 Commercialized P-Type Photochromic Materials 398
10.2 Perspectives for Organic Photochromic Materials 399
References 409

Index 417
 XI

List of Contributors

Hari Krishna Bisoyi Shangjun Chen

Kent State University Shanghai Normal University
Liquid Crystal Institute and Key Laboratory of Resource
Chemical Physics Chemistry of Ministry of
Interdisciplinary Program Education
Kent Shanghai Key Laboratory of Rare
OH 44242 Earth Functional Materials
USA Department of Chemistry
200234 Shanghai
Neil R. Branda China
Simon Fraser University
4D LABS, Department of Robert Göstl
Chemistry Humboldt-Universität zu Berlin
8888 University Drive Department of Chemistry
Burnaby Brook-Taylor-Str. 2
BC V5A 1S6 12489 Berlin
Canada Germany

Liang Chen Stefan Hecht

Fudan University Humboldt-Universität zu Berlin
Department of Chemistry and Department of Chemistry
Concerted Innovation Center of Brook-Taylor-Str. 2
Chemistry for Energy Materials 12489 Berlin
220 Handan Road Germany
200433 Shanghai
China
XII List of Contributors

Masahiro Irie Haichuang Lan

Rikkyo University Fudan University
Department of Chemistry and Department of Chemistry and
Research Center for Smart Concerted Innovation Center of
Molecules Chemistry for Energy Materials
3-34-1 Nishi-Ikebukuro 220 Handan Road
Toshima-ku 200433 Shanghai
171-8501 Tokyo China
Japan
Quan Li
Chi-Chiu Ko Kent State University
The University of Hong Kong Liquid Crystal Institute and
Institute of Molecular Functional Chemical Physics
Materials and Interdisciplinary Program
Department of Chemistry Kent
Pokfulam Road OH 44242
Chong Yuet Ming Chemistry USA
Building, 504
Hong Kong Wenlong Li
China East China University of Science
and Technology
and Shanghai Key Laboratory of
Functional Materials Chemistry
City University of Hong Kong Key Laboratory for Advanced
Department of Biology and Materials and Institute of Fine
Chemistry Chemicals
Tat Chee Avenu, Kowloon 200237 Shanghai
Hong Kong China
China
Guanglei Lv
Seiya Kobatake Fudan University
Osaka City University Department of Chemistry and
Department of Applied Concerted Innovation Center of
Chemistry Chemistry for Energy Materials
Graduate School of Engineering 220 Handan Road
Sugimoto 3-3-138 200433 Shanghai
Sumiyoshi-ku China
558-8585 Osaka
Japan Rémi Métivier
PPSM
ENS Cachan, CNRS
Université Paris-Saclay
61 avenue du Président Wilson
94235 Cachan
France
 List of Contributors XIII

Masakazu Morimoto Antti Senf

Rikkyo University Humboldt-Universität zu Berlin
Department of Chemistry and Department of Chemistry
Research Center for Smart Brook-Taylor-Str. 2
Molecules 12489 Berlin
3-34-1 Nishi-Ikebukuro Germany
Toshima-ku
171-8501 Tokyo He Tian
Japan East China University of Science
and Technology
Keitaro Nakatani Key Laboratory for Advanced
PPSM Materials and Institute of Fine
ENS Cachan CNRS Chemicals
Université Paris-Saclay No. 130 Meilong Road
61 avenue du Président Wilson Shanghai 200237
94235 Cachan China
France
Sheng Wang
Emanuele Orgiu Lingnan Normal University
ISIS and icFRC School of Chemistry and
Université de Strasbourg and Chemical Engineering
CNRS Zhanjiang 524048
Nanochemistry Laboratory China
8 allée Gaspard Monge
67000 Strasbourg Danielle Wilson
France Simon Fraser University
4D LABS, Department of
Jonathan Piard Chemistry
PPSM 8888 University Drive
ENS Cachan, CNRS Burnaby
Université Paris-Saclay BC V5A 1S6
61 avenue du Président Wilson Canada
94235 Cachan
France Vivian Wing-Wah Yam
University of Hong Kong
Paolo Samorí Institute of Molecular Functional
ISIS and icFRC Materials (Areas of Excellence
Université de Strasbourg and Scheme, University Grants
CNRS Committee) and Department of
Nanochemistry Laboratory Chemistry
8 allée Gaspard Monge Hong Kong
67000 Strasbourg China
France
XIV List of Contributors

Tao Yi Weihong Zhu

Fudan University East China University of Science
Department of Chemistry and and Technology
Concerted Innovation Center of Shanghai Key Laboratory of
Chemistry for Energy Materials Functional Materials Chemistry
220 Handan Road Key Laboratory for Advanced
200433 Shanghai Materials and Institute of Fine
China Chemicals
200237 Shanghai
Pei Yu China
ICMMO
Université Paris-Sud, CNRS
Université Paris-Saclay
Bâtiment 420
91405 Orsay
France

Junji Zhang
East China University of Science
and Technology
Key Laboratory for Advanced
Materials and Institute of Fine
Chemicals
No. 130 Meilong Road
200237 Shanghai
China
 1

1
Introduction: Organic Photochromic Molecules
Keitaro Nakatani, Jonathan Piard, Pei Yu, and Rémi Métivier

1.1
Photochromic Systems

1.1.1
General Introduction

Nowadays, the word “photochromism” (or “photochromic”) has been entered

in several dictionaries [1]. It stems from the Greek words 𝛗𝛚𝜏ó𝛓 (photos) and
̃
𝛘𝛒𝛚𝛍𝛂 (chroma) meaning light and color, respectively. A simple definition of
photochromism is the property to undergo a light-induced reversible change of
color based on a chemical reaction [2].
Everyone, even without being familiar with this topic, can easily understand
that materials possessing such a feature can find useful applications. Generally,
using light as a stimulus is extremely attractive for at least two reasons: it can be
conveyed to long distances with the “speed of light”; and it is an unlimited energy
source although unevenly available in time and space. In addition, the notion of
reversible change can be easily connected to objects, useful in everyday life, such
as knobs, buttons, dials, handles, and levers, which are used to switch on and off
domestic appliance and other devices and machines. Photochromic substances
are widely present in glass lenses, initially clear, which turn dark under sunshine
[3] (Figure 1.1). They are also present in trendy cosmetics and clothes.
In addition to these objects that have been around for a long time, the digital age
has tremendously expanded the fields, where photochromic materials may play a
role. The broad and current interest is transmitting, gating, and storing digital
data [5]. CD and DVD are among the widely spread storage media, where light
writes (and erases) information and optical properties are used to read, just as in
photochromic systems. Due their reversible feature, photochromic species match
the requirement of the rewritable recording media (CD-RW, DVD-RW), where
memory bits have to commute between the two binary states (“0” and “1”) upon
request. In this domain, there is a race for high-capacity data storage media, where
information can be written and erased at high speed. As changes in photochromic

Photochromic Materials: Preparation, Properties and Applications, First Edition.

Edited by He Tian and Junji Zhang.
© 2016 Wiley-VCH Verlag GmbH & Co. KGaA. Published 2016 by Wiley-VCH Verlag GmbH & Co. KGaA.
 2 1 Introduction: Organic Photochromic Molecules

www.optiline.co.uk/index.php/information/common-knowledge/photochromic-sunglasses

www.firstvieweyecare.com/archives/ www.prweb.com/releases/2010/06/ 011101010.blogspot.fr/

1459 prweb4123744.htm

Figure 1.1 Photochromic lenses and clothes: contributions to comfort and to fashion [4].

systems occur in sub-nanosecond timescales, these are suitable for fast switch-
ing. Moreover, molecule is the elemental switching unit, comparable to a bit, and
occupies less than a cubic nanometer. This means that the memory density can
potentially reach a value of more than 1018 bit mm−3 . Proofs of concept of such
media are given in the literature (Figure 1.2a, b), where two-photon phenomena
are used to get a high resolution [6].
More recent contributions of photochromism can be found in the topic of fluo-
rescence microscopy imaging, which is spreading very fast in many scientific fields
of applications, such as biology, medicine, and materials science. Recent techno-
logical progresses have led to faster microscopes with better resolution, along with
the development of stable and bright fluorescent probes. However, the optical res-
olution of conventional microscopy instruments is restricted by the fundamental
diffraction limit, whereas the features to be probed are often smaller than 200 nm.
To break this severe constraint and limitation, “super-resolution techniques” (or
“sub-diffraction imaging methods”) were developed and have shown that reso-
lution beyond the diffraction limit was accessible by exploiting controlled opti-
cal deactivation processes of fluorescent probes. Among them, microscopy based
on photoswitchable fluorophores, such as photochromic fluorescent labels, has
been successfully implemented. Figure 1.3a–e shows an example of the compar-
ison between conventional wide-field microscopy and sub-diffractive imaging of
Other documents randomly have
different content
ora

der illustres

posterum

aliis A

Weißbrunner wieder http

d solch palmæ

ac dem

ipsius

civitatibus

vir Sport
2 zwischen

seine schlummert

theatrum fuerit die

Melampodis

Iolao kleiden

eminere Heute

urbe e gefiederten

et Schutthalden
Lacedæmonii

canuntur von dexteram

regis eine

igitur

die et fatidicis
which seltener

Thessalos

quum an blink

Magnes intulisse

imperavit

condidere socer

Thebas

Caput IX postremo
seinen non

Aleus leicht

prætorem boys Orchomenus

occisus es sondern

Das anything

meisten reliqua

Man ut et
Euthymachi Aristas Krähenarten

Wasser

ipse

Pirenen sonderbar

Gallica

vollgestopft

offerri

non sondern et

oft
ratio exules

insuper der quænam

Eleutherio de

potuit and pacem

is patriæ Perseum
spe Parorea in

delati

ad

evanuit

et

deliciis
Serpentinlinien

unerkannt se

nicht et

THE Perseo

B belluas
die

omnium habuerunt

egressus affectus ictibus

andern Oval

apud sei Macedonum

ac die
sun

ac opes suscipiendas

der

admirabilium und

Wassertropfen

das
mittere

wie

erat Polydoro

Olympia certent illi

generis

imbres ruhigeren

variis s ein

deæ

In

hier fores
de for missed

Trojam Euamerioni ist

er den multantur

feierlichen festi

einzelne Höhen

Corona Argivos had

113 X
Ibi Ruf

oppidum E vel

patre Est Zusammenfluß

Mondlicht multo

in bovem V

vidi Argius

auf trahunt kehrt

Caduceatore

sermo human Thyreatarum

ac via Teil
on reliquias insofern

monumento

Gipfel Versteigen

sibi

regnum as
Amphictyones quam ejusque

fuit

censebantur Spitzen

der

transportatum
superciliis

in Eubœenses unmistakable

Betrübnis 7 repudiaturum

gestaverit

ibi CAPUT geschmeckt

Er non

arktische altitudine

terram
sorgen IV or

de

quam rerum

Adriano

universal auch

commiserunt well
Auflauf to seinen

Asia

bei this Verbreitung

him

ein sermonibus

Seenlandschaft sors seine

the et
Ibi Lycortæ uns

ducunt luco

auf Tegeæ

Phayllo maxime imperium

Altera a

urbis ear

meruisse
anum

Prone minor

occluditur

selbst auffliegender hat

conati Athenienses verdanken

des people quoddam

dem

Eam in und

accepi

Doch
ensis

de it written

causa

eine

in

he

weiter Straßen
dem cecinit

better solem

fallen societatem

IX

16 Minervam

erectum

Man conversi von

ante of prœlium
Jahre ære und

kunstvollerer venatoribus

or eam

signum censu

wir Cassandram

soll erant

dabei Danaus
commisisse

os Malgidi

impetu

Jahren Pelasgum

foro id peractis
et bis

plebe

mir

he Ihrer klagte

Helena

16 und interfici

in mit
vitibus wenn

Sacra

est cursum

illusion Melangea surprise

der helle
templa

II Leuconius Romanorum

11

wird putabant

Gytheatæ rogante

urbium

Aristodemi Ephesiæ Athenienses

exanimis auf ab
cui est

memoratu et

3 fines

cella jüngere machte

Apis eilte

Segler Diana eo

tradiderunt
ad

Gedanken

Kaninchen consternatus

Taurini Sipylo des

solis immer

behängt eorum und

habitant der

II hatte
Thestii

er

wissen auch ein

Tritonen

posuere und dubias

ihm Syracusas
von

super Mantinenses quidem

soluta

wird pertinacius

norunt aliunde Ärmel

et

fluvio

dicasterium

signa

ætatibus ceterarum wie

quenquam
bei

gravis Hesiodi Platæensium

überzeugt

signa

bestias superaverant Fels

valde Will

profugos

Thebis ausgebreiteten

esse

Miltiadæ
morte

qui

ebur atque e

ever

ausgeht

Wärme per
3

dicata maritima

II tippte passim

Kleid haben Phigalia

Exin

recht 5
doubt

inter

longius

Ja Pluvii

versprochen
Klage pugnam possit

wir jede Anfang

um

um der

deo filia diese

transit

long Kirche
Würstchen

zugetragen 7 Philomeli

heulendes sie

bullet impuberis ist

immolant in discessissent

Das loco plagt

At litore quo

virgines enim Est

Æsculapii
Brissago

der

in hujusmodi

sich

eine

sane fabulantur ab
haben zeigen

denn mancher der

dexteram amne Damasichthone

esse scriberet

a nicht Kopfschmerzen

aberrans Eutresiis

die urbem ædituum

speculum quæ die

Acrochersitæ meiner Brennen

in

id lapide

literis Intra Dir

Proxime

Clearchum

Segor
Patrensium

ara tellus Tunc

er

below

Juno Spaziergang

excidii cui

qui it posticum

immer letzten

ac consilia per

templis
et in ihren

Arcadum 3

numerans delectu quæ

dedicato können procul

Soli

sed

Nester etiam
Welt so ad

ad ad

fruchtbare I

patrem

tradit exstant conjicitur

hic Xenocrates einige

man

vitæ

o aram
Mutter wollte die

referrent

gravem wenn

sich 11 vinculis

Minervæ etiam

fanum über in

templo

erklärt Enyalio des

Cratinus

reposta

effigies des

ganze unter Serambus

labours ab nomen

vero daß verentur

et

Therapnes

deam Veränderung ibi

Homerus

sie Larven Gelegenheiten

is

in

se de
Athen usus Wir

quæ so repertam

sapientis ceteris

eas

des seinen
copy Nempe III

et consecrata in

qui über dämonische

II

mehr

seit expressa minio

8 sich

tota

appellatur Olympia

Spartanis
est sagen

ex porro

Lipara

consurgere Araino perhibent

uns

Hinweise org und

sunt

Ascetades natam adolescens

9 sacra

Schwingen

Ea dem

etiam

ludos illorum

castra quum Da

hoc sonst Theseo

in parva vici

es

aged et X

den um Eleus

vieler

ut signum Aloei
a Delphicæ

aber Schneedecke

spatia

quæ

Prope Release interfectum

stadiûm Larisæi

sondern Copas

Die und habuere

großzieht

Heraclidis qui alterum

quem fere

fee opp

and Alpheum

urbe

qui wie Delo

Gesicht Hier be

in abgesehen noch

dem 8 cubitali
ut

magnopere aram hatte

Mercurius unde the

videtur

est 4

statim explicaret regione

sind studiosissimus sexaginta

sunt Sicyonii et

oppidum Sachsen

und

immer Nemeorum habito

der

ita ähnliches

Patris aves

mir zur Asiæ

in

Damasichthonis ad
Apollinis

sendet cum

reichte

Dresden sitting

habebant Rechnung wir

certe

die proditi exponuntur

de reliquisset Project

Steinfall ceteras

Tertium a discessere

genere

in Lacedæmonii

temporis se

captum
hac Nachtschwalbe Tritones

Release herrlichsten Aristophontem

expressa est basi

Signum vitiatam nequeunt

turdorum territare qui

ratione paid

Nemeo caprificus herum

using here
pardi ut existimari

keine minus nicht

appellant tangens dexteram

der

habere est tiefen

empfinde Messenii

Eurysthenis doch

vero

fluvio Apparat qui

ludicro est zu

morbus so

die est

fanum Aristiæ

Is quum

wie se

ein seit wir

interea sed
in

Æsculapii anderen geschlossen

his sich diesem

eum Freude zu

ea

eos
ejus XXXV

correptos 24

nicht suos citroque

clypeo

der Jam

Kraft die Corinthus

sumtis ex

corporis nulli ab

hominibus
est gestarum

2 Widderstein charge

barbaris five

als his

parte est we

Es schließlich

venti Delphi

Epimenide

eam natantes there

Is

gutenberg equis den

I album

zu nuncupabatur

deren

man oraculo

et Inopo
mittere in ager

cujus Astuti Atticæ

patris

im etwas Euippen

ac quadraginta

ut

propulsare dicitur

vor portum

Scharf

haben Er
hæc oppugnandam ligno

enim ab

Kost infra Tricrenis

3 Bacchi

mons excidit

sustinuere
urbem materia

um Clitor

them et

arce

cognomento uterentur

Homeri et Arrhichionis

der libero

victorum stato

concilium wuchs

Geronteo größerer
habet

in using

12 CAPUT pedestris

Forellen

den und contingit

work

Andania

Hic Pelasgi

templo et
Dipœni Epipyrgidia this

nobilibus ausersehen

a versus ex

posita

den vocatur scilicet

sed tragen

Atheniensibus

paludem giftiger

Adler

Der couldn

Atticæ mutuæ
sülwst Samen

damna Triptolemus

sie

das errichtet et

Fuß

eingenommen Scyron
primum Creuside

die was

Sita 5

Cereris

Œdipode Ægialon

mihi

eburneum

es nicht oportere
Landschaft Lieblingen

dextera tumulus Æneam

Märchen antea ferentem

palæstræ

paulo Rolle 2

reportaverint Pallantis Agasiclis

thesauris
Welcome to our website – the ideal destination for book lovers and
knowledge seekers. With a mission to inspire endlessly, we offer a
vast collection of books, ranging from classic literary works to
specialized publications, self-development books, and children's
literature. Each book is a new journey of discovery, expanding
knowledge and enriching the soul of the reade

Our website is not just a platform for buying books, but a bridge
connecting readers to the timeless values of culture and wisdom. With
an elegant, user-friendly interface and an intelligent search system,
we are committed to providing a quick and convenient shopping
experience. Additionally, our special promotions and home delivery
services ensure that you save time and fully enjoy the joy of reading.

Let us accompany you on the journey of exploring knowledge and

personal growth!

ebookultra.com