NEeEa erm NARAYANA IT ACADEMY a G@).NARAYANA IT - JEE ACADEMY - INDIA Lee Ra STRY ASSIGNMENT PT-4_SYLLABUS 1. Which of the following compound can form Grignard reagent on reaction with Mg/dry ether? A) Py CH,—CH—CH,—cl B) YS Br Br ° er Fr Db) ° 4 2. = CH Mer ° 10 sH OW The value of ‘x’ is . 3. Choose the CORRECT reaction(s) among the following is (are)NEeEa erm 2. Ph-CHO H A) CH;MgBr(1.0 equivalent) 2. NH,CV/H,O Ho” MgBr 1, CH\COCH, —_— 2. NHg B) c) 1. Mg/dry ether 3. NH,CV/H,0 NARA on Cro N # (Major) HQ cy Ho ) (Major) HC, OH ‘cHs (Major) ° ° CHMgBr wa) = we A CH; ‘CH; D) (Major)NESE e ree NARA) 4. The major product (P) formed in the following reaction is: 1. CH MgBr (Excess) —___—_> ((P) 2. ag. NH,CI © oS, 9 oH on Wwe " A) B) on on oH An ° © D) (CH,),CMgCl on reaction with D,0 produces A) (CH,),CD B) (CH,), 0D ©) (CD,),cD D) (CD,), CH How many moles of Grignard reagent will be required by one mole of given compound? sH 9 (OH, .C—OE8t O O c—cl a) C1 ch, How many isomers of C,/1,,0 reacts with CH,MgBr to evolve CH, gas? (Excluding stereoisomer) Choose the halogen which is most reactive towards SN' reaction in the given compounds (A, B, C and D)NEeEa erm Bra) br A) () B) ® Br) oC %@ oH D) Pra) A) A= BrigsB—I,y3C—BryysD- Brgy 3C-Bi,);D- Br.) (0) B — [iy 3C — Bry; D— Bray D) A- BR, ;B—1,4);C— Bri):D — Bry (a B) A-Bry B14 ©) A-Br, 9. Arrange the below mentioned bromine atoms in decreasing order of their reactivity towards hydrolysis through Sw1 path r ar Eee Br(2) om SS Br(1) A)2>1>4>3 B)2>1>3>4 C)2>4>3>1 D)4>2>1>3 10. Which among the following has the most tendency to follow the $1 mechanism. (X isa halogenNESE e ree D) x xX wee A) ‘os x no ° ‘CH 1. ci ' a} wal ms eet ep Ee xe DMF Nos sPh sph sr “Ph : - F ©) D) A) B) NOz NO2 1 NO, 12. The major product of the given reaction is Cihy—cHy—on a BaeNESE e ree f~ a 13. Find out total number of reactions those proceed with retent ° D) aq KOH, ) — pr Br Ph SOCh ) p—_+— z ) 0: OH Pyridine CHs KOH vp 4 KsH HB VID DIGEOHLT | CH, VU) Pr SnO CH; HOH » —_> Pro & Br CH; soc, my wi | ——$— Pr OH Hs V Nal Vs Cl “Keetone Ph a) 14, because 4 Generally, Alkyl chlorides in pure form are prepared by the action of SOC on alcohols A) alkyl chlorides are immiscible with SOCh B) In this reaction alkyl halide is formed along with gases SO, and HCI, the two gaseous products are escapable, hence the reaction gives pure alkyl halides C) alcohol and SOC\ are soluble in water D) the reaction does not occurs via intermediate formation of an alkyl! chlorosulphite CH;—cH,—Br asNESE e ree 13. 16. 17. Which among the following compound will undergo fastest SN? reaction Br Br ‘Br A) B) ° py LJ Given below are two statements: one is labeled as Assertion (A) and the other is labeled as Reason (R). Assertion (A): Sy2 reaction of C,/,CH.,Br occurs more readily than the S,2 reaction of CH,CH,Br Reason (R): The partially bonded hybridized p-orbital that develops in the trigonal bipyramidal transition state is stabilized by conjugation with the phenyl ring In the light of the above statements, choose the most appropriate answer form the options given below: A) (A) is not correct but (R) is correct B) (A) Is correct but (R) is not correct C) Both (A) and (R) are correct and (R) is the correct explanation of (A) D) Both (A) and (R) are correct but (R) is not the correct explanation of (A) Given below are two statements: Statement ~ I: High concentration of strong nucleophilic reagent with secondary alkyl halides which do not have bulky substituents will follow Sx2 mechanism. Statement — II: A secondary alkyl halide when treated with a large excess of ethanol follows Sx] mechanism, In the light of the above statements, choose the most appropriate from the questions given below: A) Statement | is true but Statement Il is false. B) Statement I is false but Statement I is true. C) Both statement I and Statement II are false. D) Both statement I and Statement II are true.NA HT ACADEM NEeEa erm NARS 18. Find out the major product formed from the following reaction. [Me:~CH,] H(2equiv) NMe, ~ NMe, _-NMe; ( A) | B) Nase? NMe, NMe, oN = o & my Me, 19. Among the following which is most reactive towards Sx2 reaction? A)CH,-Cl —_B) H,C=CH-CI_ C)CeHs-Cl (D) CH,-F 20. Mark out the CORRECT nucleophilicity order in DMF: A) CH, > OH” > NH; > F> Ir B) CH; > OH > NH; >I > F- ©) > F > OH” > NH; >CH; D) CH, > NH; > OH >F >I 21. (¥)<*2—ca,cH, -Cl—*“> (X) , here (X) and (Y) respectively are: isin is A) CH,CH,CN and CH,CH,NC B) CH,CH,CN and CH,CH,CN C) CH,CH,NC and CH,CHCN D) CH,CH,NC and CH,CH,NC qa CH; Ho +NaQH ————> Major product "A" 22, Consider the above chemical reaction. product “A’ A) oH B) ‘OH istNESE e ree 23. 24. 25. 26. 27. OH CH Ow" Cc) D) Which of the following statement is FALSE. A) During SN' reaction, the nucleophile plays no kinetic role in the rate of reaction. B) During SN* reaction, if the substrate is optically pure with (R)- configuration, then the product obtained is always an optically pure product with (S) ~ configuration, C) SN? reaction takes place in single step and no intermediate is formed. D) The boiling points of isomeric alkyl halides decreases with increase in branching. Observe the below given order i) NHs>CHsCOO" ii) NOx >OH- iii) Cr > SH iv) CN > OH Select the correct one A)i) B)i) &iv) ©)i), iil) Riv) —_D) i), i), iii) & iv) Which of the following compound will undergo 5x? most rapidly with KI in acetone A) CCL B) (CH,),CCI () Ph-CH, -Cl py Ph-CO-CH, ~Cl Given below are half-cell reaction A? +20" — A; E* =-0.56V AP 4 > AP; B= 41 ABV The E° for 34° A+24% will be A) -2.04V, reaction will not occur B) 2.04’, reaction will occur C) -0.92 V , reaction will not occur D) 0.92 V, reaction will occur Higher alkynes can be prepared from lower alkynes by using sodamide, followed by nucleophilic substitution reaction with alkyl halide DEtCI(Ieq) wea cH ace Stticen 2)CH, coon ~ * (Alone) = cH Mate, 4 | CHEIGed) vy cangas) X&Y areNESE e ree A) functional isomers B) ring chain isomers C) positional isomers D) tautomers 28. Given below are two statements: One is labeled as Assertion (A) and the other is labeled as Reason (R). Assertion (A): CH, = CHCl is an example of vinyl halide Reason (R): Vinyl halides are the compounds in which the halogen atom is attached to sp hybridized carbon atom In the light of the two above statements, choose the most appropriate answer from the options given below: A) (A) is true but (R) is false B) Both (A) and (R) are true but (R) is not the correct explanation of (A) C) (A) is false but (R) is true D) Both (A) and (R) are true and (R) is the correct explanation of (A) 29. Which of the following alkyl halide forms the maximum number of hydrocarbons as products upon reaction with ale. KOH? CH,CH,CHCH, A) CH,CH,CH,CH,Cl B) | C) CICH,CH,CH,CH,CI 30. Identify the set of reagents/reaction-conditions *X’ and *Y’ in the following set of transformation: CH, ~ CH, ~ CH, Br Product—>CH, — CH=CH, Br A) X = dilute aqueous NaOH, 20°C; Y = Bro/CCls, 20°C. B) X = cone. alcoholic NaOH, 80°C; Y = HBr/CHsCOOH C) X = dilute aqueous NaOH, 20°C; Y = Br2/CHCh, 20°C D) X = cone. alcoholic NaOH, 80°C; Y = Brx/CHClsNEeEa erm 31. nomenclature for the following compound is HH CHg H Br HgC A) 2-Bromo-3-methyl But-3-ene B) 3-Bromo-2-methyl-But-I-ene C) 3-Bromo-2,3-dimethyl propene __D) 1-Bromo-1,2-dimethyl prop-2-ene 32. The rate of solvolysis (hydrolysis) of I-III follows Ho PT Pa He. 7 Hac, wo dy (i A)IL> >I B)M>1> UL Cu>m>1 — D)IM>>1 33. The correct order for the given property for following compounds is SUCATIONAL INSTITUTIONS, 2 B) Bond enthalpy ; ©#sCI> CHy# > CH,Br > CH A) Boiling Point ©) Dipole moment; (HsF > CH:Cl> CH,Br> CHL 1 8 we PRCA TI TNT we D) Density: 34, 4+SOCI, > B+SO,+HCI 1 A+Na>C+5H, B+C>(C,H,),0+ NaCl The compound [A] in the above sequential reaction is A) GH.CI B) CHf,0H c) OMe pD) C00NESE e ree 35. 36. ar 38, How are good yields of alkyl iodides (R ~ I) obtained? A) By heating alcohols with sodium or potassium iodide in 95 % orthophosphoric acid B) By shaking alcohols with concentrated HCI at room temperature C) By using phosphorus tribromide and triiodide as reagents D) By reacting alcohols with bromine and iodine at low temperatures. The number of possible enantiomeric pairs that can be produced during mono chlorination of 2-methyl butane is The major product [QJ of the following reaction is Hs6. Br f PhSNa aa [Q] Major NOs Hac. SPh Me se Me. Br Hic. er F F Ph | F A) Nop B) Noe ©) NOp D) SPH The compound which will have the lowest rate (or) not participated towards nucleophilic aromatic substitution on treatment with OH” isNESE e ree NARAYANA 40. ¢ a Noe a cr NOs A) NO B) NO» Oo D) NO2 Consider the following 5» 4" reaction on. ci + KCN ———> [Product] (excess) f The CORRECT statement(s) is /are A) Cl will be substituted first as it is a better leaving group. B) F will be substituted first because nitro group from para position facilitate this. C) After substitution of one halogen, substitution of the second halogen becomes more difficult. D) First chorine and then fluorine would be substituted subsequently. Given below are two statements Statement-I: Melting point of 1,2-dichlorobenzene is more than 1,4 ~ dichlorobenzene Statement-II: Dipole moment of 1,2-dichlorobenzene is more than 1,4-dichlorobenzene In the light of the above statements, choose the most appropriate answer from the options given below: A) Both Statement — I and Statement ~ II are correct B) Both Statement — I and Statement — II are incorrect C) Statement — I is correct but Statement — II is incorrect D) Statement ~ 1 is incorrect but Statement ~ II is correct