TEST CODE : 121007

IIT-JEE
Batch – Excel (April) | Minor Test-07

Time: 3 Hours Test Date: 31st August 2025 Maximum Marks: 300

Name of the Candidate: ____________________________________________________Roll No.______________

Centre of Examination (in Capitals):_______________________________________________________________

Candidate’s Signature:____________________________Invigilator’s Signature:___________________________

READ THE INSTRUCTIONS CAREFULLY

1. The candidates should not write their Roll Number anywhere else (except in the specified
space) on the Test Booklet/Answer Sheet.
2. This Test Booklet consists of 75 questions.
3. This question paper is divided into three parts PART A - MATHEMATICS, PART B - PHYSICS
and PART C - CHEMISTRY having 25 questions each and every PART has two sections.
(i) Section-I contains 20 multiple choice questions with only one correct option. Marking
scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
(ii) Section-II contains 5 questions with INTEGERAL VALUE.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other
cases.
4. No candidate is allowed to carry any textual material, printed or written, bits of papers,
mobile phone any electronic device etc., except the Identity Card inside the examination
hall/room.
5. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
6. On completion of the test, the candidate must hand over the Answer Sheet to the
invigilator on duty in the Room/Hall. However, the candidate is allowed to take away this
Test Booklet with them.
 TEST CODE : 121007

TEST SYLLABUS

Batch – Excel (April) | Minor Test-07

31st August 2025

Mathematics : Indefinite Integral

Physics : Geometrical Optics - 1 ( Reflection & Refraction through

Plane Surface, TIR, Prism)

Chemistry : Alkyl and Aryl Halide & Optical isomerism

Useful Data Chemistry:

Gas Constant R = 8.314 JK −1 mol−1
= 0.0821Lit atm K−1 mol−1
= 1.987  2 Cal K−1 mol−1
Avogadro's Number Na = 6.023  1023
Planck's Constant h o
= 6.25  10−27 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
1 amu = 1.66  10−27 kg
1 eV = 1.6  10−19 J

Atomic No:
H = 1, D = 1, Li = 3, Na = 11, K = 19, Rb = 37, Cs = 55, F = 9, Ca = 20, He = 2, O = 8, Au = 79.

Atomic Masses:
He = 4, Mg = 24, C = 12, O = 16, N = 14, P = 31, Br = 80, Cu = 63.5, Fe = 56, Mn = 55, Pb = 207,
Au = 197, Ag = 108, F = 19, H = 2, Cl = 35.5, Sn = 118.6

Useful Data Physics:

Acceleration due to gravity g = 10 m / s2

IIT-JEE | Excel Batch | Minor Test-07_April 2

 TEST CODE : 121007

PART-A: MATHEMATICS
SECTION-A
sin8 x − cos8 x
 1 − 2 sin2 x cos2 x dx
1. is equal to
1
(A) sin 2x + C
2

1
(B) − sin 2x + C
2

1
(C) − sin x + C
2

(D) − sin2 x + C

Ans. (B)

sin8 x − cos8 x
Sol.  1 − 2 sin2 x cos2 x dx

(sin
2
)(
x − cos2 x sin4 x + cos4 x )
=  2 2
1 − 2 sin x cos x

1
=  − cos 2xdx = − 2 sin2x + C

x  2 tan x   
2. e  + cot2  x +   dx is equal to
 1 + tan x  4 
 
(A) ex tan  − x  + c
 4 

 
(B) ex tan  x −  + c
 4 

 3 
(C) ex tan  − x + c
 4 

(D) None of these

Ans. (B)

2 tan x  
Sol. + cot2  x + 
1 + tan x  4 

IIT-JEE | Excel Batch | Minor Test-07_April 3

 TEST CODE : 121007

  
+ cot2  + x + − 
2 1 2

 
+ cot2  + x − 
 2 4 

 
+ tan2  x − 
 4 

 
+ sec2  x −  − 1
 4 

2 tan x  
+ 1 + sec2  x − 
1 + tan  4 

2 tan x − 1 − tan x  
+ sec2  x − 
1 + tan x  4 

tan x − 1  
+ sec2  x − 
tan x + 1  4 

 
 tan  x − 
 4 

dx 1
3. If  x 4 − x2 = + log f ( x ) + C then f(x) is given by
x

x +1
(A)
x −1

x −1
(B)
x +1

1/2
 x − 1
(C)  
 x + 1

2
 x − 1
(D)  
 x + 1

Ans. (C)

1 1 1 1  1 1 
Sol. = =  − 
x −x4 2
x 2
( x − 1) ( x + 1) 2 x2  x − 1 x + 1

1 1 1 1  1 1 1  
=  − − 2 − 2 − −  
2  x − 1 x x x  x x + 1  
IIT-JEE | Excel Batch | Minor Test-07_April 4
 TEST CODE : 121007

1 1 2 1 
=  − 2 − 
2 x − 1 x x + 1

dx 1 1
 x 4 − x2 = log x − 1 − log x + 1 +  + C
2 x

1/2
1 x −1
= + log +C
x x +1

xex
4. If  dx = f ( x ) 1 + ex − 2 log g ( x ) + C , then
x
1+ e

1 + ex + 1
(A) g ( x ) =
1 + ex − 1

1 + ex − 1
(B) g ( x ) =
1 + ex + 1

(C) f(x) = x – 1

(D) f(x) = 3(x – 2)

Ans. (B)

Sol. Putting 1 + ex = t2 . The given integral reduces to

 (
2 log t2 − 1 dt )


( 

) 
= 2  t log t2 − 1 − 2  1 +
2
1  
dt 
t − 1 


( 
) 1
= 2  t log t2 − 1 − 2  t + log
  2
t − 1 
 + C
t + 1 

1 + ex − 1
= 2x 1 + ex − 4 1 + ex − 2 log +C
1 + ex + 1

1 + ex − 1
So, f(x) = 2(x − 2), g(x) =
1 + ex + 1

x + sin x x
5. If  1 + cos x dx = f ( x ) tan 2 + C
(A) f(x) = x2

(B) f(x) = x

(C) f(x) = 1 + cos x

IIT-JEE | Excel Batch | Minor Test-07_April 5

 TEST CODE : 121007

(D) None of these

Ans. (B)

x + sin x 1 2 x sin x
Sol.  1 + cos x dx = 2  x sec 2
dx + 
1 + cos x
dx

1 x x x x
= 2x tan − 2 tan  +  tan dx = x tan + C
2 2 2 2 2

x
33 x
6. 3 33 3x dx is equal to
x
x3
(A) +C
(log 3)
3

3x
(log 3)
3
(B) 33 +C

3x
33
(C) +C
(log 3)
3

(D) None of these

Ans. (C)

3x 3x x dt
Sol. Put 33 = t  (log 3)3 33  33  3x =
dx

dt t
So given integral is equal to  = +C
(log 3) (log 3)
3 3

7. The value of e
sec x
(
sec3 x sin2 x + cos x + sin x + sin x cos x dx is )
(A) esec x ( sec x + tan x ) + C

(
(B) esec x sec2 x + sec x tan x + C )
(
(C) esec x sec2 x + tan x + C )
(D) None of these

Ans. (A)

Sol. The given integral is equal to

e
sec x
sec x(sec x tan x + tan2 x + sec x + tan x)dx

IIT-JEE | Excel Batch | Minor Test-07_April 6

 TEST CODE : 121007

e
sec x
= sec x tan x(sec x + tan x) + esec x (sec2 x + sec x tan x)dx

d
 dx (e
sec x
= (sec x + tan x))dx = esec x (sec x + tan x) + C

x3 − 1
8.  4x3 − x is equal to

1 3 9
(A) x + log x − log 2x − 1 − log 2x + 1 + C
4 16 16

1 5 7
(B) x − log x − log 2x − 1 − log 2x + 1 + C
4 16 16

1 7 9
(C) x − log x − log 2x − 1 + log 2x + 1 + C
4 16 16

1 7 9
(D) x + log x − log 2x − 1 − log 2x + 1 + C
4 16 16

Ans. (D)

1
x −1
x3 − 1 1 4 1 1 7 1 9 1
Sol. = + = + − −
3
4x − x 4 x (2x − 1) (2x + 1) 4 x 8 2x − 1 8 2x + 1

x3 − 1 1 7 9
 4x3 − 1 dx = 4
+ log x −
16
log 2x − 1 −
16
log 2x + 1 + C

sin x 2 1
9. If  cos 9/2
x
dx =
3
tana/ 4 x + tanb/ 4 x + C then (a + b) is
7
(A) 20

(B) 25

(C) 30

(D) 40

Ans. (A)

sin1/ 2 x dx
Sol. Let I =  cos 9/2
x
dx =  sin
−1/ 2
x cos9 / 2 x

1 9
Here m + n = − = −4 (negative even integer).
2 2

Divide numerator and denominator by cos4x.

IIT-JEE | Excel Batch | Minor Test-07_April 7

 TEST CODE : 121007

I=  tan x sec4 xdx =  ( )

tan x 1 + tan2 x sec2 xdx =  t (1 + t ) dt (Using tan x = t)
2

2 3/2 2 7 /2 2 2
= t + t + c = tan3/2 x + tan7 /2 x + c
3 7 3 7

x
Evaluate :  ( x − 3) x +1
dx
10.
 3 x +1 − 2 
2  x + 1 + log +c
(a)   4 x + 1 + 2 
 3 x +1 − 2 
2  x + 1 − log +c
(b) 
 4 x + 1 + 2 
 3 x +1 + 2 
2  x + 1 − log +c
(c) 
 4 x + 1 − 2 
(d) None of these
Ans. (a)
x
Sol. I = 
( x − 3) x + 1
x +1 = t2
dx = 2tdt

I= 2
(
t 2 − 1 2tdt )
(
t −1 − 3 t )
t2 −1
= 2 dt
t2 − 4

 3 
I = 2  1 + 2 dt
 t − 4 
 1 t−2 
= 2 t + 3 log +c
 2.2 t + 2 
 3 x +1 − 2 
= 2  x + 1 + log +c
 4 x + 1 + 2 

1 x 
11. If  1 + sin x dx = tan  2 + a  + c, then

(a) a = − , C R
4

(b) a = , C R
4
5
(c) a = , C R
4

(d) a = , C R
3

IIT-JEE | Excel Batch | Minor Test-07_April 8

 TEST CODE : 121007

Ans. (a)
1
Sol. I= dx
1 + sin x
1
= dx
 
1 + cos  − x 
2 
dx
=
  x
2 cos 2  − 
 4 2
1   x
=
2  sec 2  −  dx
 4 2
  x
tan  − 
1  4 2
= +c
2 1
−
2
  x
I = − t an  −  + c
 4 2
 x 
I = tan  −  + c
 2 4

a = − , c R
4


sin x
12. The integral cot xe cos x dx equals :
tan xe sin x
(a) +C
cos x
(b) 2e sin x + C
1
(c) − e sin x + C
2
cot xe sin x
(d) +C
2 cos x
Ans. (b)
Sol. I =  cotx  e sin x
cos xdx
cos x
= e sin x
cos xdx
sin x
e sin x
=  cos xdx
sin x
e sin x
=t
1
e sin x
 cos xdx = dt
2 sin x
I =  2dt
=2t+c
= 2e sin x
+c

IIT-JEE | Excel Batch | Minor Test-07_April 9

 TEST CODE : 121007

cos3 x + cos5 x
13.  sin 2 x + sin 4 x dx
(a) sin x – 6 tan-1 (sin x) + c
(b) sin x – 2 sin-1 x + c
(c) sin x – 2 (sin x)-1 – 6 tan-1 (sin x) + c
(d) sin x – 2 (sin x)-1 + 5 tan-1 (sin x) + c
Ans. (c)

I=
(1 − t )( 2 − t ) dt ;f ( x ) = ( y − 1)( y − 2)
2 2

Sol. sin x = t ;
t (1 + t )2 2  y (1 + y)
2 (1 − 2y )
= 1+ ; y = t2
y ( y + 1)
1 1 
= 1+ 6  − 
 3y y + 1
 2 6 
I =  1 + 2 − dt
 t 1 + t 2 
sin x − 2(s in x) −1 − 6 tan −1 (sin x) + c

( 2x + 3) dx 1
14.  x ( x + 1)( x + 2)( x + 3) + 1 = C − f ( x ) where f(x) is of the form ax2 + bx + c then

(a + b +c) equals
(a) 4
(b) 5
(c) 6
(d) None
Ans. (b)
2x + 3
Sol.  (x 2
)(
+ 3x x 2 + 3x + 2 + 1
dx
)
Put x + 3x = t 2

 ( 2x + 3) dx = dt
dt dt 1 1
 t ( t + 2) + 1 =  ( t + 1)2 = C − t + 1 = C − x 2 + 3x + 1
 a = 1, b = 3,c = 1
a+b+c = 5

(x 2
)
− 1 dx
= n f ( x ) + C, then f(x) is :
15. If   x 2 + 1
( x + 3x + 1 tan 
4 2

 x 
) −1

 1
(a) n  x + 
 x
 1
(b) tan −1  x + 
 x

IIT-JEE | Excel Batch | Minor Test-07_April 10

 TEST CODE : 121007

 1
(c) cot −1  x + 
 x
  1
(d) n  tan −1  x +  
  x
Ans. (d)
1
1−
x2
Sol.  1  −1  1
dx;
 x + 2 + 3 tan  x + 
2

x x
 1
1 − 2  dx  1
x 
  1 2  dx = n  tan −1  x +  
  x
−1  1
  x +  + 1 tan  x + 
 x  x

dx
16. The value of x+ x +1
2
is equal to

3  2x + 1
(a) tan −1  +C
2  3 
2  2x + 1
(b) tan −1  +C
3  3 
1  2x + 1
(c) tan −1  +C
3  3 
2  2x − 1
(d) tan −1  +C
3  3 
Ans. (b)
dx
Sol. I=
x + x +1
2

dx
= 2 2
 1  1
x + x +   −   +1
2
 2  2
dx
= 2
 1 1
 x +  − + 1
2 4
dx
= 2
 1 3
 x +  +
2 4
dx
= 2
1  3 
2

 x +  +  
2  2 

IIT-JEE | Excel Batch | Minor Test-07_April 11

 TEST CODE : 121007

 1
 x +
=
2
tan −1  2 +c

3  3 
 2 
2  2x + 1
= tan −1  +c
3  3 

dx
17. The integral  8 6 is equal to :
( x + 4)  ( x − 3)
7 7

(where C is a constant of integration)

−13
1  x − 3 7
(a) −   +C
13  x + 4 
−1
 x − 3 7
(b) −  +C
 x + 4 
3
1  x − 3 7
(c)   +C
2  x + 4
1
 x − 3 7
(d)  +C
 x + 4 
Ans. (d)
x −3 2
Sol. =t
x+4
( x + 4) 1 − ( x − 3) 1 dx = 2t dt
( x + 4) 2
x+4−x+3
dx = 2t dt
( x + 4) 2
7
dx = 2t dt
( x + 4) 2
1 2t
I=  ( x + 4) 
2
8 6
dt
7
( x + 4) ( x − 3)
7 7

=
( x + 4) 2− 7  2t dt
6
( x − 3) 7 7
6

=
( x + 4) 7  2t dt
6
( x − 3) 7 7
6
2  x + 4 7
=   t dt
7  x − 3
6
2  17
=   2  t dt
7 t 

IIT-JEE | Excel Batch | Minor Test-07_April 12

 TEST CODE : 121007

2 −127 +1
7
= t dt

2 −5
=  t 7 dt
7
2
2 t7
= +c
7 2
7
1
 x − 3 7
= +c
 x + 4 

dx 1  xq 
18. Let  x 2008 + x p n  1 + x r  + C , where p, q, r  N and need not be distinct, then the
=

value of (p + q + r) equals :
(a) 6024
(b) 6022
(c) 6021
(d) 6020
Ans. (c)
dx x 2007 + 1 − x 2007
Sol. I= = dx
(
x x 2007 + 1 ) (
x x 2007 + 1 )
1 x 2006 
=  − dx
 x 1 + x 2007 
1 n x 2007 − n 1 + x 2007 ( )
nx−
2007
n 1+ x (
2007
= ) 2007
1  x 2007

= n 2007 
+C
2007  1 + x 
p + q + r = 6021
19.  sin x  cos x  cos 2x  cos 4x  cos8x  cos16x equals :
sin16x
(a) +c
1024
cos 32x
(b) − +c
1024
cos 32x
(c) +c
1096
cos 32x
(d) − +c
1096
Ans. (b)
Sol. I =  sin x  cos x  cos 2x  cos 4x  cos8x  cos16x  dx
sin 25 x
=  sin x  dx
25 sin x
1
32 
= sin 32xdx

IIT-JEE | Excel Batch | Minor Test-07_April 13

 TEST CODE : 121007

1  cos 32x 
= −  +c
32  32 
cos 32x
=− +c
1024

(
n x + 1+ x2 ) dx equals
20.  x 1+ x2
(a) (
1+ x2 n x + 1+ x2 − x + c )
(b)
x
2
(
 n2 x + 1+ x2 −
x
1+ x2
+c )
x
(
(c)  n 2 x + 1 + x 2 +
2
x
1+ x2
+c )
(d) (
1+ x2 n x + 1+ x2 + x + c )
Ans. (a)
Sol. Use IBP taking In x + 1 + x 2 ( ) as the first function
x
and as the second function
1+ x2

SECTION-B
xdx  x − 2
21. If  2
x − 4x + 8
(
= k log x2 − 4x + 8 + tan−1 
 2 
)
 + C , then the value of 2k is:

Ans. (1)

xdx u+2
Sol. Put x − 2 = u to get I = x 2
− 4x + 8
= u 2
+4
du

=
1

2u
2 u2 + 4
du + 2
2
du
u +4
1
2 
u 1
( ) x − 2
= log u2 + 4 + tan−1   + C = log x 2 − 4x + 8 + tan−1 
2
  2  2 
+C ( )

k 1 − cos x
22.  1 + sec xdx is equal to tan−1 + C then k is:
101 cos x
Ans. (202)

sec2 x − 1 tan x
Sol. I =  1 + sec xdx =  sec x − 1
dx =  sec x − 1
dx

2tdt 
[Put sec x − 1 = t2  sec x tan xdx = 2tdt  tan xdx = 
t2 + 1

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1  2t 
 t  t
−1 −1
I=  dt = 2 tan (t) + C = 2 tan ( sec x − 1) + C
2
+ 1

23. If f ( x ) = 
(5x + 4x ) dx
4 5

and f ( 0) = 0 , then the vlaue of 30f (1) is:

( x + x + 1)
2
5

Ans. (10)

Sol. Let I = 
(5x + 4x ) dx 4 5

( x + x + 1)
2
5

 5 4
 6 + 5  dx
Dividing above and below by x10, we get I = 
x x 
2
 1 1
 1 + + 
 x 4 x5 

1 1  4 5   4 5 
Putting 1 + 4
+ = t,  −
5 5
−
6 
dx = dt or 
5
+  dx = −dt , we get
x x  x x  x x6 

dt 1 1 x5 1
I=− t 2
=
t
+c =
 1 1
+c=
5
x + x +1
+ c = f(x)f(0) = 0  c = 0  f(1) =
( )3
1 + 4 + 5 
 x x 

2x + 1 xn
24. If  3
dx = 1
+ c then n is_______
(x 2
+ 4x + 1 ) 2
(x 2
+ 4x + 1 ) 2

Ans. (1)
2x + 1 2x + 1
Sol.  3
dx =  3
dx
(x 2
+ 4x + 1 ) 2  4 1 2
x 3 1 + + 2 
 x x 
2x −2 + x −3
= 3
dx
 4 1 2
1 + + 2 
x x
1 4
Now put 2 + + 1 = t 2
x x

ex ex + q
25.  e2x + 6ex + 5
If dx = p log
ex + r
+ c , then find the value of 16p + r – q

Ans. (8)
ex ex
Sol. I =  2x dx =  ex 2 + 6ex + 5 dx
e + 6ex + 5 ( )
Let e x = t or ex dx = dt

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dt
I = 
t + 6t + 5
2

1
= dt
( t + 3)2 − 22
1 t +3− 2 1 ex + 1
= log + c = log x +c
22 t + 3+ 2 4 e +5

PART-B: PHYSICS
SECTION-A
26. A light ray is reflected by a mirror. If unit vectors along the incident and normal direction are
1 ˆ 1 ˆ 1 ˆ
Iˆ = i− j+ k and Nˆ = iˆ then unit vector, R̂ along reflected direction is
3 3 3

1
(A) ( 2iˆ + 2 ˆj − 3kˆ)
7
−1 ˆ −1 ˆ −1 ˆ
(B) i− j− k
3 3 3
1 ˆ 1 ˆ 1 ˆ
(C) − i− j+ k
3 3 3
1 ˆ 1 ˆ 1 ˆ
(D) i+ j+ k
3 3 3
Ans. (C)

Sol.

27. The light rays from an object have been reflected towards an observer from a standard flat mirror.
The image observed by the observer is:
A. Real
B. Erect
C. Smaller in size than the object
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D. Laterally inverted
Choose the most appropriate answer from the options given below:
(A) B and D only
(B) A and D only
(C) A,C and D only
(D) B and C only
Ans. (A)

Sol.

28. An object is placed symmetrically between two plane mirrors, inclined at an angle of 72°, then the
total number of images observed is
(A) 5
(B) 4
(C) 2
(D) Infinite
Ans. (B)

Sol.

29. The frequency of a light ray is 6×1014 Hz. Its frequency when it propagates in a medium of refractive
index 1.5 will be
(A) 1.67 10 Hz
14

(B) 9.10 10 Hz

14

(C) 6 10 Hz
14

(D) 4 10 Hz
14

Ans. (C)
Sol. When a ray of light passes from one medium to another, then its fequency does not change, but its
speed and wavelength change.

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Hence. its frequency in a medium of refractive index 1.5 is 6 10 Hz .

14

Note: Intensity of light also changes, because a part of it is reflected.

30. If r1,r2 are the angle of refraction at first face and second face of a prism, then the angle of the
prism is
(A) r1 − r2
r1 − r2
(B)
2
r1 + r2
(C)
2
(D) r1 + r2
Ans. (D)
Sol. Conceptual

31. A ray is incident on the boundary separating glass and water. The refractive index for glass is 3/2
refractive index for water is 4/3 critical angle at glass-water boundary is

−1 3
(A) sin  
4
−1 2
(B) sin  
3
−1 8
(C) sin  
9
−1 1
(D) sin  
9
Ans. (C)

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Sol.

32. A ray of light passes through four transparent media with refractive indices 1 , 2 , 3 and  4 as

shown in the figure. The surfaces of all media are parallel. If the emergent ray CD is parallel to the
incident ray AB, we must have

(A) 1 = 2

(B) 2 = 3

(C) 3 =  4

(D)  4 = 1

Ans. (D)

Sol. Applying Snell’s law at A,

1 sin i 
2 = = 2 …(i)
sin r1 1

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Applying Snell’s law at B,

2 sinr1 3
3 = = …(ii)
sinr2 2

Again applying Snell’s law at C,

3 sin r2 4
4 = = …(iii)
sin i 3

Multiplying eq. (i), (ii) and (iii)

2 3 4 sini sinr1 sinr2

  =  
1 2 3 sin 1 sinr2 sini

4
 = 1  1 =  4
1

If the emergent ray is parallel to incident ray after travelling a number of parallel interfaces then
the refractive index of the first and the last medium is always same. Here incident ray is medium-1
OA || CD emergent ray in medium-4

 1 =  4

33. Statement I : Light going from air to water can not undergo total internal reflection.
Statement II : Total internal reflection takes place only when light goes from a denser to a rarer
medium.
(A) Statement I and Statement II are true and Statement II is the correct explanation of Statement
I.
(B) Statement I and Statement II are true but the Statement II is not the correct explanation of
Statement I.
(C) Statement I is true but Statement II is false.
(D) Statement I and Statement II are false.
Ans. (A)
Sol. Statement I and Statement II are true and Statement II is the correct explanation of Statement I.

34. The expected graphical representation of the variation of the angle of deviation(δ) with the angle of
incidence(i) in a prism is:

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(A)

(B)

(C)

(D)
Ans. (B)

Sol.

35. An object is placed at a distance of 12 cm in front of a plane mirror. A virtual and erect image

is formed by the mirror. Now the mirror is moved by 4 cm towards the stationary object. The

distance by which the position of the image would be shifted will be

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(A) 4 cm towards the mirror

(B) 8 cm towards the mirror
(C) 8 cm away from the mirror
(D) 2 cm towards the mirror
Ans. (C)

Sol.

36. Two plane mirrors are inclined to each other as shown. A ray of light is incident at an angle of 30°

on one of them. The ray after reflection falls on second mirror and finally retraces its path. Then

calculate the value of θ.

(A) 60o

(B) 45o

(C) 30o

(D) 4

Ans. (C)
Sol. The path of the light ray is as shown in the figure.

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37. Which of the following is incorrect?

(A) The frequency of light from a given source remains the same in all media.
(B) The frequency of light from a given source is lower in a medium with lower optical density.
(C) The speed of light is lower in a medium with higher optical density.
(D) The frequency of light does not change as it gets reflected.
Ans. (A)
Sol. • Frequency of light depends on the nature of the R source. It does not depend on the nature of
the medium. So, the frequency of a given light remains the same in all media.
• Speed of light is lower in an optically denser medium.

38. An object of mass m is moving with velocity u towards a plane mirror kept on a stand as shown in
the figure. The mass of the mirror and stand system is m. A head-on elastic collision takes place
between the object and the mirror stand, the velocity of image before and after the collision is

(A) u, 2u

(B) −u, − 2u

(C) −u, 2u

(D) u, − 2u

Ans. (C)

Sol. Before collision

Vimage = 2Vmirror − Vobject = −u

After collision

Vimage = 2Vmirror − Vobject = 2u

39. A ray of light is incident at the glass water interface at an angle i and it emerges finally parallel to
the surface of water. Then the value of  g would be

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4
(A)   sin i
3

1
(B)
sin i

4
(C)
3

(D) 1

Ans. (B)

Sol. From Snell’s law, g sini = air sin90

1
 g =
sin i

40. A point source of light B is placed at a distance L in front of the centre of a mirror of width d hung
vertically on a wall. A man walks in front of the mirror at a distance 2L from it as shown. The
greatest distance over which he can see the image of the light source in the mirror is

(a) d/2
(b) d
(c) 2d
(d) 3d
Ans. (d)
Sol.

41. An observer can see through a pin-hole, the top end of a thin rod of height h, placed as shown in
the figure. The beaker height is 3h and its radius h. When the beaker is filled with a liquid up to a
height 2h, he can see the lower end of the rod. Then the refractive index of the liquid is

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5
(A)
2
5
(B)
2

3
(C)
2
3
(D)
2
Ans. (B)

Sol. For the image of point P of the rod. PQ to be seen by the observer, it should be formed at point Q.

In QNS, NS = QS = 2h

 NQS = 45

 r = 45

Now, in QMA ,

MQA = 45

 MA = QA = h

1 sinr sin 45

2 = =
sini sini

In PMB ,

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 TEST CODE : 121007

PM2 = 4h2 + h2 = 5h2

h 1
 sin i = = …(ii)
5h 5

sin 45 5
From eq. (i) and (ii) 12  = =
sin i 2

42. A plane mirror is placed at the bottom of a tank containing a liquid of refractive index , P is a small

object at a height h above the plane mirror. An observer O, vertically above P, outside the liquid,

observers P and its image in the mirror. The apparent distance between object and its image will be

(a) 2h
2h
(b)

2h
(c)
 −1
 1
(d) h  
 
Ans. (b)

Sol. x is distance of object from surface.

x
Apparent depth of object from surface =

x + 2h
Apparent depth of image from surface =

2h
Distance between the apparent depths of objects and image =


43. Light travels through a glass plate of thickness t and having refractive index

. If c be the velocity of light in vacuum, the time taken by the light to travel this thickness of glass

is

t
(a)
c
(b) t  c

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t
(c)
c
tc
(d)

Ans. (C)
velocity of light in vacuum c c
Sol.  = = ' or c' =
velocity of light in glass plate c 
dis tan ce t t
time taken = = =
velocity ( c /  ) c

44. A ray of light strikes a glass plate at an angle of 60 O with the vertical. If the reflected and refracted
rays are perpendicular to each other, the refractive index of glass is

3
(a)
2
3
(b)
2
1
(c)
2
(d) 3
Ans. (d)
Sol.  = tan i = tan 60o = 3

45. The light ray is incident at angle of 60o on a prism of angle 45o. When the light ray falls on the other
surface at 90o, the refractive index of the material of prism  and the angle of deviation
 are given by

3
(a) = ,  = 30o
2
(b)  = 1.5,  = 15o
3
(c) = ,  = 30o
2
3
(d) = ,  = 15o
2
Ans. (d)
Sol. r1 = 45o

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sin i sin 60o 3

 = = =
sin r1 sin 45o 2

 = i + e − A = 60o + 0 − 45o
  = 15o
SECTION-B
46. A ray of light is incident normally on the face AB of an isosceles prism ABC with AB = AC
and A = 30O, placed in air. After entering the prism, the ray strikes the face AC directly.
The minimum refractive index of the prism so that the ray suffers total internal reflection
at the face AC is_____________.
Ans. 2
Sol. At face AB, both the angle of incidence and the angle of refraction are zero. Therefore, we
can observe from geometry that the angle of incidence at the face AC is 30O.
 1 
So, for total internal reflection, sin 300     prism  2
 prism 

47. An object moves with 5m/s towards right while the mirror moves with 1 m/s towards the left as
shown in Fig. Find the magnitude of velocity (in ms-1) of image.

Ans. (7)
Sol. x1 = ( 2x 2 − x1 )

V1 = 2Vmirror − Vobject
= −2  1 − 5
= -7m / sec

48. A prism of angle A = 1° has a refractive index µ = 1.5. A good estimate for the minimum angle of
N
deviation (in degrees) is close to . Value of N is ______.
10
Ans. (5)

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Sol.

49. A ray of light suffers minimum deviation when incident on a prism having angle of the prism equal to
60o. The refractive index of the prism material is √2. The angle of incidence (in degrees) is _____.
Ans. (45O)

Sol.

50. Two vertical parallel mirrors A and B are separated by 10 cm. A point object O is placed at a
distance of 2 cm from mirror A. The distance of the second nearest image behind mirror A from the
mirror A is ....... cm.

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Ans. (18)

Sol.

PART-C: CHEMISTRY
SECTION-A
51. The catalysts used in the preparation of an alkyl chloride by the action of dry HCl on an alcohol is
(A) Anhydrous AlCl3
(B) FeCl3
(C) Anhydrous ZnCl2
(D) Cu
Ans. (C)
Sol. Primary and secondary alkyl chlorides are prepared from the respective alcohols by using HCl
gas and anhydrous ZnCl2 (Groove’s process).
Note : Tertiary alcohols are very reactive and hence they react readily with conc. HCl even in the
absence of ZnCl2.

52. Identify the set of reagents/ reaction conditions ‘X’ and ‘Y’ in the following set of transformations –
CH3–CH–CH3
|
X Y
CH3 – CH2 –CH2Br ⎯⎯→ Product ⎯⎯→ Br
(A) X = dilute aqueous NaOH, 20ºC; Y = HBr / acetic acid, 20ºC
(B) X = concentrated alcoholic NaOH, 80ºC; Y = HBr / acetic acid, 20ºC
(C) X = dilute aqueous NaOH, 20ºC; Y = Br2/ CHCl3, 0ºC
(D) X = concentrated alcoholic NaOH, 80ºC; Y = Br2/CHCl3, 0ºC
Ans. (B)

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Sol. The dehydrohalogenation of 1-bromo propane with alco. NaOH or KOH gives propene which on
again hydrohalogenation with HBr gives 2-bromopropane due to addition of Markonikoves rule for
addition.
o
CH3CH2CH2Br ⎯⎯⎯⎯⎯⎯ 80 C
→ CH3CH = CH2 ⎯⎯⎯
⎯ HBr
→ CH3CHBrCH3
alc. NaOH/KOH .
53. In the following process, product A is

(A) Fluorobenzene
(B) Benzene
(C) 1,4-difluorobenzene
(D) 1,3-difluorobenzene
Ans. (A)

Sol.

54. The reaction of chlorobenzene with Cl2 in presence of Anhydrous FeCl3 gives
(A) m-dichlorobenzene
(B) O– and P–dichlorobenzene
(C) Benzene hexachloride
(D) Only O-dichlorobenzene.
Ans. B.
Sol. Cl group is ortho and para directing group

55. Which one of the following compounds is inactive towards SN1 reaction?

(A)

(B)

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(C)

(D)

Ans. (C)
Sol. Rate of SN1 reaction depends on stability of carbocation.

Hence, compound of option (c) is inactive towards SN1 reaction. However, in other options,
carbocations are stabilised by +R - effect and hyperconjugation.

56. For the SN2 reaction

RX + Nu → RNu + X– (X = halogen, Nu = nucleophile)
Rate of reaction is maximum when R is
(A) Methyl
(B) Ethyl
(C) Isoprophyl
(D) tert-Butyl
Ans. A.
Sol.

In SN2 reaction Nu will attack from backside to carbon-leaving group bond. Therefore, there
should be least steric hinderance at carbon-leaving group bond.

57. The decreasing order of reactivity towards dehydrohalogenation (E 1) reaction of the following
compounds is
a.

b.

c.

d.

(A) b>a>d>c
(B) b>d>a>c

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(C) d>b>c>a
(D) b>d>c>a
Ans. C.
Sol. E1 reaction proceeds via carbocation formation, therefore greater the stability of carbocation
faster is the reaction. Carbocation formed by d, (2°, resonance stabilised and the

product is diene) is most stable followed by b, (1° and the product formed is diene).

Further among c and a, the carbocation formed by c is more stable (2°) than a,

(1°).
Thus, the reactivity towards dehydrohalogenation follows the order :
d>b>c>a

58. Which of the following compounds will show faster aryl nucleophilic substitution?

(A)

(B)

(C)

(D)

Ans. A.

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Sol.

In these reactions carbanion is generated as an intermediate which is stabilized by highly electron

withdrawing group. F is highly electron withdrawing among halogen. Therefore it will give more
fast aryl nucleophilic substitution.

59. How many of the following reactions, lead to the formation of diastereomers?

Which of the following is correct

(A) 2
(B) 3
(C) 4
(D) 5
Ans. (C)

Sol.

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60. Consider the reaction:

CH3 CH2 CH2 Br + NaCN ⎯→ CH3 CH2 CH2 CN + NaBr
The reaction will be the fastest in
(A) Ethanol
(B) Methanol
(C) N, N-dimethyl formamide (DMF)
(D) Water
Ans. C.
Sol. The given reaction is SN2 reaction and SN2 reaction is favored by polar aprotic solvent like DMF,
DMSO, Acetone, etc. Except DMF in the above option all are polar protic solvent. So, option C is
correct.

61. Alkyl iodides are often prepared by the reaction of alkyl chlorides/bromides with NaI in dry Acetone.
This reaction is known as
(A) Corey-House reaction
(B) Swarts reaction
(C) Finkelstein reaction
(D) Sandmeyer’s reaction.
Ans. C.
Sol.

62. Which of the following is the major product in the following reaction?

(A)

(B)

(C)

(D)
Ans. (C)

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Sol.

63.

Consider the above chemical reaction. The total number of stereoisomers possible for Product "P"
is _________
(A) 5
(B) 3
(C) 2
(D) 7
Ans. (C)

Sol.
ENT denote enantiomer of product.
The total number of products possible=2

64.
What are N and M ?
(A) 6,6
(B) 6,4
(C) 4,4
(D) 3,3
Ans. (B)

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Sol.

65. The number of structural and configurational isomers of a bromo compound, C5H9Br formed by the
addition HBr of to 2-pentyne respectively are
(A) 1 and 2
(B) 2 and 4
(C) 4 and 2
(D) 2 and 1
Ans. (B)

Sol.

66.
Product P is

(A)

(B)

(C)

(D)

Ans. (C)
Sol.

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67. Which of the following is correct order of ease of leaving group?

− − −
(A) C6H5SO3  CH3COO  C6H5O
− − −
(B) CH3COO  C6H5SO3  C6H5O
− − −
(C) C6H5O  CH3COO  C6H5SO3
− − −
(D) CH3COO  C6H5O  C6H5SO3
Ans. (A)

Sol.
Stability of negative charge increases, leaving ability increases.

68. Match List I and List II

List I List II

a. i. Wurtz reaction

b. ii. Sandmeyer reaction

c. iii. Fittig reaction

d. iv. Gatterman reaction

Choose the correct answer from the options given below

(A) a–III, b–I, c–IV, d–II
(B) a–II, b–I, c–IV, d–III
(C) a–II, b–IV, c–I, d–III
(D) a–III, b–IV, c–I, d–II
Ans. C.
Sol. Benzene diazonium chloride undergo Sandmeyer reaction in presence of Cu2Cl2 while in presence
of Cu/HCl it undergo Gatterman reaction to gave chlorobenzene along with N 2 gas while in Wurtz
reaction ethyl chloride reacts with sodium in presence of dry ether to give n-butane and the
reaction of chlorobenzene in presence of dry ether to give biphenyl is fittig reaction.
So correct match is a–II, b–IV, c–I, d–III.

69. Which of the following statement is correct about alkyl/aryl halides?

(A) Alkyl halides are less reactive than aryl halides towards nucleophilic substitution reactions.
(B) Alkyl halides are more reactive than aryl halides towards nucleophilic substitution reactions.
(C) The presence of an electron−withdrawing substituent at ortho and/or para position decreases
the reactivity of nucleophilic substitution of chlorine in the substituted chlorobenzene.
(D) The replacement of chlorine in chlorobenzene by strong bases proceeds by S N1 mechanism.

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Ans. (B)
sp2
Sol. i. The low reactivity of aryl halides is due to the resonance effect and hybrid state of carbon
to which halogen atom is attached.
ii. In aryl halides, one of the lone pairs of electrons on the halogen atom is in conjugation with  -
electrons of the ring. Due to resonance, the C - X bond acquires partial double bond character.
Thus, the C - X bond in aryl halides is stronger and shorter than alkyl halides. Hence, it is difficult
to break C-X bond in aryl halides.
iii. Further, the phenyl cation produced due to the self-ionization of aryl halide will not be
SN 1
stabilised by resonance. This rules out the possibility of mechanism. Also, the backside attack
S 2
of nucleophiles is blocked by the aromatic ring. This rules out the possibility of N mechanism.
As a result, nucleophilic substitution reaction involving cleavage of C - X bond in haloarenes
proceeds with difficulty.
iv. Therefore, aryl halides are less reactive than alkyl halides towards nucleophilic substitution
reactions.

CH3
70. Major product (P) in the following reaction is: ⎯D
⎯ – Cl
⎯→ (P)

CH3
H
Cl

(A) H

CH3
D
Cl
(B) H

D
H
CH3

(C) Cl

D
Cl
CH3

(D) H

Ans. (B)

Sol.
SECTION-B
71. How many of following statement are correct
(a) The Dipole moment of p-Dichlorobenzene is O
(b) CCl4 is used as fire Extinguisher
(c) The B.P. order iodobenzene > Chlorobenzene >Fluorobenzene

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(d) The B.P. of Haloarenes are generally more than that of Haloalkanes
Ans. 3
Sol. The B.P. of Haloarenes are generally less than that of Haloalkanes

72. How many of the following substrates are more reactive than ethyl bromide for SN 2 reaction

Ans. 4.
Sol. For SN2 reaction
1. CH3 – Br > 1° > 2° > 3° (rate of SN2 reaction)
2. allyl bromide will give more fast SN2 than ethyl bromide
3. If electron with drawing group is present at carbon – leaving group bond then it increases
SN2 rate.
Substrates (I), (II), (V), (VI) are more reactive than ethyl bromide for SN2 reaction.

73. How many different monochlorinated products are formed when n-butane is chlorinated in
presence of sunlight
Ans. (3)
Sol.

74. The total number of optical active compounds in Product P are

Ans. (4)
Sol. In this product there are two chiral carbons hence there will be 22 = 4 optically active
compounds.

75. 2-Chlorobutane + Cl2 → C4H8Cl2 (isomers)

Total number of optically active isomers obtained in the above reaction if all stereoisomers of 2-
chlorobutene are reacted with Cl2?
Ans. 6

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Sol.

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