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GREEN NANOMATERIALS IN
ENERGY CONVERSION AND
STORAGE APPLICATIONS
GREEN NANOMATERIALS IN
ENERGY CONVERSION AND
STORAGE APPLICATIONS

Edited by
Ishani Chakrabartty, PhD
Khalid Rehman Hakeem, PhD, FRSB
First edition published 2024
Apple Academic Press Inc. CRC Press
1265 Goldenrod Circle, NE, 2385 NW Executive Center Drive,
Palm Bay, FL 32905 USA Suite 320, Boca Raton FL 33431
760 Laurentian Drive, Unit 19, 4 Park Square, Milton Park,
Burlington, ON L7N 0A4, CANADA Abingdon, Oxon, OX14 4RN UK

© 2024 by Apple Academic Press, Inc.

Apple Academic Press exclusively co-publishes with CRC Press, an imprint of Taylor & Francis Group, LLC
Reasonable efforts have been made to publish reliable data and information, but the authors, editors, and publisher cannot
assume responsibility for the validity of all materials or the consequences of their use. The authors, editors, and publishers
have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders
if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged, please write
and let us know so we may rectify in any future reprint.
Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced, transmitted, or utilized
in any form by any electronic, mechanical, or other means, now known or hereafter invented, including photocopying,
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and explanation without intent to infringe.

Library and Archives Canada Cataloguing in Publication

CIP data on file with Canada Library and Archives

Library of Congress Cataloging-in-Publication Data

CIP data on file with US Library of Congress

ISBN: 978-1-77491-388-8 (hbk)

ISBN: 978-1-77491-389-5 (pbk)
ISBN: 978-1-00339-857-8 (ebk)
Dedication

Dedicated to
our parents and siblings
About the Editors

Ishani Chakrabartty, PhD

Assistant Professor, Department of Applied Biology,
School of Biological Sciences, University of Science and Technology,
Meghalaya (USTM), India

Ishani Chakrabartty, PhD, is currently working as Assistant Professor

in the Department of Applied Biology, School of Biological Sciences,
University of Science and Technology, Meghalaya (USTM), India
(accredited “A” grade by NAAC). She completed her PhD at the Dept. of
Biosciences and Bioengineering, IIT Guwahati, in 2019. She has special-
ization in biotechnology, particularly in natural products, microbiology,
and nanotechnology. She has been teaching graduate and postgraduate
students for the past 2.5 years. She has published around seven papers in
international journals (all Scopus and WOS indexed) of repute and more
than three book chapters with national and international publishers such
as Springer, Elsevier, Taylor and Francis, Frontiers, and others. She is a
budding young researcher who cares immensely for science and its associ-
ated implications. At 28, she was appointed as the Head of the Department
in P.A First Grade College, Mangalore University, where she served for
a year (2019–2020). She has a number of national awards to her credit
and holds life memberships in several national organizations, including
BRSI, ECPFO, and the Indian Science Congress. She was awarded Best
Science Story in 2018 by AWSAR-DST, Government of India. Currently,
she collaborates with many scientists all over the world for fruitful knowl-
edge sharing and learning experience. Apart from being a researcher,
Dr. Chakrabartty is also an avid writer on social issues in newspapers,
magazines, and different online forums.

Khalid Rehman Hakeem, PhD, FRSB

Professor, King Abdulaziz University, Jeddah, Saudi Arabia.

Khalid Rehman Hakeem, PhD, FRSB, is presently working as Professor

at King Abdulaziz University, Jeddah, Saudi Arabia. After completing
viii About the Editors

his PhD (Botany; specialization in Plant Ecophysiology and Molecular

Biology) from Jamia Hamdard, New Delhi, India, in 2011, he worked as
an assistant professor at the University of Kashmir, Srinagar, for a short
period. Later, he joined Universiti Putra Malaysia, Selangor, Malaysia,
and worked there as Post-Doctorate Fellow in 2012 and Fellow Researcher
(Associate Prof.) from 2013–2016, respectively. He joined King Abdulaziz
University in August 2016 and was promoted to professorship in 2019.
Dr. Hakeem has more than 12 years of teaching and research expe-
rience in plant ecophysiology, biotechnology and molecular biology,
medicinal plant research, plant-microbe-soil interactions as well as in
environmental studies. He is the recipient of several fellowships at both
national and international levels. He has recently been elected as a Fellow
of the Royal Society of Biology, London. Prof. Hakeem has served as a
Visiting Scientist at Fatih Universiti, Istanbul, Turkey, as well as at Jinan
University, Guangzhou, China. Currently, he is involved with a number
of international research projects with different government organiza-
tions. To date, Dr. Hakeem has authored and edited more than 80 books
with international publishers, including Springer Nature, Academic
Press (Elsevier), CRC Press, etc. He has also to his credit 160 research
publications in peer-reviewed international journals and 65 book chapters
in edited volumes with international publishers. At present, Dr. Hakeem
serves as an editorial board member and reviewer of several high-impact
international scientific journals from Elsevier, Springer Nature, Taylor,
Cambridge and Francis, and John Wiley Publishers.
About the Book

This publication is designed to introduce doctoral and graduate students to

a specialized application of nanomaterials and how “green” nanomaterials
can be designed and utilized in energy conversion and storage devices.
Energy crisis is a matter of serious global concern, and all the major
nations of the world are investing huge capital in the quest for sustainable
energy sources. Fossil fuels are very limited, and their utilization comes
with a number of harmful effects on human health and environment. As
such, designing nanomaterials, particularly biosynthesized nanomaterials,
can serve as a possible solution to this ongoing search.
The book will emphasize on the importance and different modes of
synthesis of nanomaterials, with detailed emphasis on green nanomate-
rials. It will, then, present the picture of energy crisis and how nanomate-
rials can be utilized as energy conversion and storage devices. Details of
the energy efficiency and environmental impact of the utilization of green
nanomaterials as energy conversion devices will be the major focus of
the book, and hence, will be appropriately highlighted. The target audi-
ence for this book includes the industrial and educational units/societies/
authorities/operators/agencies who are engaged in finding solutions or
replacements for the traditional sources of energy as well as M.Phil/Ph.D
scholars and graduate students, junior researchers, and professors teaching
courses on mechanical/electrical/chemical engineering, nanotechnology
and green chemistry, although senior researchers can also use this book as
a handy and compact reference.
This edited book will bring the information available on all the
applications of nanomaterials in the energy sector. Energy crisis is very
real and this book highlights that and makes an attempt to bring it to the
notice of young minds. Different kinds of research are being carried out
for designing energy efficient devices; hence, the book highlights the role
of green nanomaterials in dealing with this challenging problem. This
book also focuses on the different areas of the energy sector where green
nanomaterials are playing a pivotal role. It will give focus toward gaining
knowledge and understanding the concepts of thermal conductivity,
x Green Nanomaterials in Energy Conversion and Storage Applications

energy efficiency, energy consumption, and the new emergence of green

nanomaterials in this important sector.
Furthermore, this book will recognize the innovate measures taken
by different countries to overcome the existing limitations in the energy
sector and the application of green nanomaterials for the sustainable
growth, environment, and a futuristic bio-based economy.
Contents

Contributors....................................................................................................... xiii
Abbreviations .................................................................................................... xvii
Preface ............................................................................................................... xxi

1. An Introduction to Nanomaterials in Energy Applications .................... 1

Kabari Krishna Borah, Yashodhara Goswami, Ishani Chakrabartty, and
Khalid Rehman Hakeem

2. Green Nanomaterials: Importance and Applications............................ 17

Mohd Ishfaq Bhat, Shikhangi Singh, Utpreksha Thapliyal, and Asfaq

3. Global Energy Crisis: Need for Energy Conversion and Storage ........ 45
P. Periasamy and Yugal Kishore Mohanta

4. Energy Conversion and Storage Devices ................................................ 75

Madhusudan B. Kulkarni and N. H. Ayachit

5. MOF-Based Nanomaterials as Electrocatalysts for

Energy Applications.................................................................................. 95
Naseem Ahmad Khan, Tayyaba Najam, and Syed Shoaib Ahmad Shah

6. Cellulose-Based Nanomaterials in Energy Conversion/Storage

Devices...................................................................................................... 119
Adil Majeed Rather, Arif Hassan Dar, Umair Hussain Shah,
Arpita Shome, and Angana Borbora

7. Recent Advances in Nanomaterials for Energy

Conversion and Storage ......................................................................... 145
Ruqiya Bhat and Wakeel Ahmed Dar

8. Thermal Conductivity of Green Nanomaterials: A Special

Reference to Nanofluids.......................................................................... 169
Qudsiya Y. Tamboli, Kranti R. Zakde, Mehboobali Pannipara, and
Yugal Kishore Mohanta
xii Contents

9. Green Nanotechnology for a Sustainable Future................................. 189

Roheela Ahmad, Nasir Bashir Naikoo, and Shafat Ahmad Ahanger

10. Green Nanomaterials for a Sustainable Future Environment............ 215

Anandkumar Naorem, A. Patel, A. Bhaguna, S. Sharma, A. Singh, N. Priya,
P. H. Chanu, R. Patel, P. Singh, M. Jaison, B. Sahu, G. Sahu, and S. K. Udayana

Index ................................................................................................................. 239

Contributors

Shafat Ahmad Ahanger

Division of Plant Pathology, Faculty of Agriculture, Sher-e-Kashmir University of Agricultural
Sciences and Technology, Wadura, Sopore, Jammu and Kashmir, India

Roheela Ahmad
Division of Soil Science, Faculty of Agriculture, Sher-e-Kashmir University of Agricultural Sciences
and Technology, Wadura, Sopore, Jammu and Kashmir, India
Asfaq
Department of Agriculture, Integral University, Lucknow, Uttar Pradesh, India

N. H. Ayachit
School of Advanced Sciences, KLE Technological University, Vidyanagar, Hubballi, Karnataka,
India
A. Bhaguna
Department of Soil Science and Agricultural Chemistry, IAS, Banaras Hindu University, Varanasi,
India
Mohd Ishfaq Bhat
Department of Post Harvest Process and Food Engineering, GBPUAT, Pantnagar, Uttarakhand, India

Ruqiya Bhat
Department of Physics, University of Kashmir, Srinagar, Jammu and Kashmir, India

Kabari Krishna Borah

Department of Applied Biology, School of Biological Sciences, University of Science and
Technology Meghalaya (USTM), Ri-Bhoi, Baridua, Meghalaya, India
Department of Biotechnology, Dolphin PG Institute of Biomedical and Natural Sciences,
HNB Garhwal Central University, Srinagar, Jammu and Kashmir, India

Angana Borbora
Department of Chemistry, Indian Institute of Technology, Guwahati, Assam, India

Ishani Chakrabartty
Department of Applied Biology, School of Biological Sciences, University of Science and
Technology Meghalaya (USTM), Ri-Bhoi, Baridua, Meghalaya, India

P. H. Chanu
Department of Soil Science and Agricultural Chemistry, IAS, Banaras Hindu University, Varanasi,
India

Arif Hassan Dar

Energy Unit, Institute of Nano Science and Technology, Mohali, India

Wakeel Ahmed Dar

International Centre for Clean Water (ICCW), an Initiative of IIT Madras, IIT Madras Research
Park, Taramani, Chennai, India
xiv Contributors

Yashodhara Goswami
Department of Applied Biology, School of Biological Sciences, University of Science and
Technology Meghalaya (USTM), Ri-Bhoi, Baridua, Meghalaya, India

Khalid Rehman Hakeem

Department of Biological Sciences, King Abdulaziz University, Jeddah, Saudi Arabia
Princess Dr Najla Bint Saud Al-Saud Center for Excellence Research in Biotechnology, King
Abdulaziz University, Jeddah, Saudi Arabia

M. Jaison
Institute of Agricultural Sciences, Siksha ‘O’ Anusandhan University, Bhubaneswar, Odisha, India

Naseem Ahmad Khan

Institute of Chemistry, The Islamia University of Bahawalpur, Bahawalpur, Pakistan

Madhusudan B. Kulkarni
School of Electronics and Communication Engineering, KLE Technological University, Vidyanagar,
Hubballi, Karnataka, India
Yugal Kishore Mohanta
Department of Applied Biology, School of Biological Sciences, University of Science and
Technology Meghalaya, Baridua, Ri-Bhoi, Meghalaya, India

Nasir Bashir Naikoo

Division of Soil Science Faculty of Agriculture, Sher-e-Kashmir University of Agricultural Sciences
and Technology, Wadura, Sopore, Jammu and Kashmir, India

Tayyaba Najam
Institute for Advanced Study and Institute of Microscale Optoelectronics, Shenzhen University,
Shenzhen, China

Anandkumar Naorem
ICAR-Central Arid Zone Research Institute, RRS-Bhuj, Gujarat, India

Mehboobali Pannipara
Department of Chemistry, Faculty of Science, King Khalid University, Abha, Saudi Arabia

A. Patel
ICAR-Central Arid Zone Research Institute, RRS-Bhuj, Gujarat, India

R. Patel
Forest Ecology and Climate Change Division, Institute of Forest Biodiversity, Hyderabad,
Telengana, India

P. Periasamy
Department of Physics, Nehru Institute of Engineering and Technology, T.M. Palayam, Coimbatore,
Tamil Nadu, India

N. Priya
Department of Soil Science and Agricultural Chemistry, IAS, Banaras Hindu University, Varanasi,
India

Adil Majeed Rather

Department of Mechanical and Aerospace Engineering, North Carolina State University, Raleigh,
North Carolina, USA

B. Sahu
Institute of Agricultural Sciences, Siksha ‘O’ Anusandhan University, Bhubaneswar, Odisha, India
Contributors xv

G. Sahu
Centurion University of Technology and Management, Bhubaneswar, Odisha, India

Syed Shoaib Ahmad Shah

Institute of Chemistry, The Islamia University of Bahawalpur, Bahawalpur, Pakistan
Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of
Soft Matter Chemistry, School of Chemistry and Materials Science, University of Science and
Technology of China, Hefei, Anhui, China
Umair Hussain Shah
Department of Mechanical Engineering, The Ohio State University, Ohio, USA

S. Sharma
Department of Soil Science and Agricultural Chemistry, IAS, Banaras Hindu University, Varanasi,
India

Arpita Shome
Department of Chemistry, Indian Institute of Technology, Guwahati, Assam, India

A. Singh
Department of Soil Science and Agricultural Chemistry, IAS, Banaras Hindu University, Varanasi,
India

P. Singh
Institute of Agricultural Sciences, Siksha ‘O’ Anusandhan University, Bhubaneswar, Odisha, India

Shikhangi Singh
Department of Post Harvest Process and Food Engineering, GBPUAT, Pantnagar, Uttarakhand, India

Qudsiya Y. Tamboli
Department of Basic and Applied Science, MGM University, Aurangabad, Maharashtra, India

Utpreksha Thapliyal
Department of Biotechnology, National Institute of Technology, Allahabad, India

Kranti R. Zakde
Department of Basic and Applied Science, MGM University, Aurangabad, Maharashtra, India

S. K. Udayana
Dr. Y.S.R. Horticultural University, Venkataramannagudem, Andhra Pradesh, India
Abbreviations

AFM atomic force microscopy

BC black carbon
BET Brunauer–Emmett–Teller
BGA blue-green algae
CA cardanol
CAES compressed air energy storage
CBM carbon-based materials
CBN cellulose-based nanomaterials
CBNF cellulose-based nanofibers
CCIP Climate Change Intergovernmental Panel
CCS carbon capture and storage
CDC carbide-derived carbon
CDU carbon dioxide utilization
CEC cation exchange capacity
CEO clove essential oil
CNTs carbon nanotubes
COD chemical oxygen demand
CSP concentrated solar power
CVD chemical vapor deposition
DLC double-layer capacitors
DLS dynamic light scattering
DOE Department of Energy
DSC differential scanning calorimetry
DSSCs dye-sensitized solar cells
DTA differential thermal analysis
EDLC electric double-layer capacitors
EELS electron energy loss spectroscopy
ESR enhancement of surface Raman
ETP effluent treatment plants
EXAFS extended X-ray absorption fine structure
FMR ferromagnetic resonance
GCC Gulf Cooperation Council
GMC graphitized mesoporous carbon
Discovering Diverse Content Through
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