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DK6044_half 9/16/05 3:31 PM Page 1
FOUNDING EDITOR
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                                         Department of Electrical Engineering
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                                      A CRC title, part of the Taylor & Francis imprint, a member of the
                                      Taylor & Francis Group, the academic division of T&F Informa plc.
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        This book contains information obtained from authentic and highly regarded sources. Reprinted material is quoted with
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                 537.5’32 – dc22                                                                               2005044020
range though excellent reviews (reference 10 of Chapter 3) are available that cover fewer
energy values. To facilitate comparison, most of the curves of cross sections as a function
of energy have been redrawn and grid lines have been retained for finding the approximate
value in rapid mode. This method of providing cross section data, in addition to the tabular
form, has been adopted throughout the volume.
    Analytical representation of cross sections as a function of energy is required for the
purposes of modeling, energy distribution computations, and simulation studies. Many
such equations have been provided, though more work needs to be done to represent
momentum transfer cross sections as a function of energy. As far as the author is aware there
has been only a single equation available for argon (reference 107 of Chapter 3) and the
rapid variation of cross section as a function of energy due to the Ramsauer–Townsend
effect and the rather broader variation at higher energies due to shape resonance render
the problem difficult.
    Cross sections in the very low energy range are also represented analytically by the
modified effective range theory (MERT). Each gas is discussed in the light of this theory
and appropriate information is given. Again, it is thought, this is the first time that such
a compilation has been made available in a single volume and the author expresses the
opinion that this powerful technique has not been used adequately for molecular gases.
Significant experimental investigations of low-energy inelastic collision cross sections in
several gases have now become available (reference 41 of Chapter 4).
    Chapter 4 continues with the presentation of cross sections of diatomic gases. The
gases considered are carbon monoxide (CO), hydrogen (H2), nitrogen (N2), oxygen (O2), and
nitric oxide (NO). CO and NO are polar and electron attaching. O2 is electron attaching
without possessing a permanent dipole moment. The remaining gases (H2 and N2) are
both nonpolar and nonelectron attaching. The long-range dipole interaction between the
electron and molecule in polar gases presents difficulties for complete theoretical under-
standing and experimental measurements are the main source, unlike the case with rare
gases (Chapter 3) where theory can supplement experiment. The influence played by
dipolar moment and electron attachment is highlighted and a broad interpretation of shape
resonance as applicable to the gases considered is provided. The interaction potential is an
integral part of the theory and a brief description of the potentials is included in Chapter 1.
The similarities and differences in the cross section–energy behavior of isoelectronic
molecules are dealt with.
    The presentation of scattering cross section data is continued in Chapter 5, with attention
focusing upon a variety of complex molecules. Polyatomic molecules such as SF6 and CO2
are nonpolar but electron attaching. On the other hand, there are a number of gases which
are both attaching and polar. Extensive discussion is not presented for a few gases that
have been analyzed thoroughly in recent years (reference 174 in Chapter 5). These gases
include SF6, CCl2F2, CF4, and selected fluorocarbons. Gases of environmental concern such
as NO2, N2O, SO2, and O3 are also considered, though in some cases the data appear in
a later chapter. Chapter 5 concludes with a discussion of how the ionization cross section
can be understood by using the most common parameters of a gas neutral: the ratio of the
maximum of the ionization cross section to the ionization cross section at a given energy.
Another attractive formulation is due to Hudson (reference 302 of Chapter 5) and involves
the polarization of the molecule and its ionization potential. Considerable scope exists
for original research in exploring this idea with necessary modifications to accommodate the
specifics of a molecule under investigation.
    While scattering cross sections are measured by using beam techniques, the focus
now shifts to electron swarms. At the turn of the twentieth century the discovery of the
electron and the advent of quantum mechanics gave birth to two schools of investigators.
One school, led by Ramsauer and colleagues, adopted beam techniques; the other school,
                                                                                         Preface
led by Townsend, adopted the swarm technique in which the electrons move through
the gaseous medium under the influence of an applied external field. From the results of these
investigations the details of electron–neutral interactions were deciphered. The method of
measuring the drift velocity by employing grids (reference 6 of Chapter 6) and the availabil-
ity of the oscilloscope facilitated the measurement of drift velocity of electrons. Development
of the theory of diffusion by Huxley (reference 9 of Chapter 6) and the measurement of
the diffusion coefficient by the use of the concentric and insulated collector led the method
of approach. The experimental discovery of the lateral diffusion coefficient (reference 92
of Chapter 6) was followed by advancement of the theory to explain the observed results
(references 93 and 94 of Chapter 6).
     Chapter 6 summarizes the data on drift and diffusion of electrons in several gases
as a function of reduced electric field E/N (E ¼ electric field, N ¼ gas number density). Early
measurements of these parameters at low values of E/N (reference 118 of Chapter 6) have
been extended to larger E/N values in various laboratories and a compilation of these is
presented. Analytical expressions for a wide range of E/N are given, with an analysis of
the range of applicability and the limits of accuracy. It is appropriate to comment that the
best fitting equation given for the purpose of simulation etc. does not imply that there
is theoretical background for that form of equation.
    Swarm parameters have been measured as an end in themselves, and also to obtain
low-energy momentum transfer cross sections where experimental difficulties render the
measurements less accurate. The method of unfolding the swarm parameters to obtain the
low-energy momentum transfer cross sections was pioneered in the early 1960s (reference 156
of Chapter 6) and extended to many gases. The results of these investigations have been
blended into the data presented in Chapter 6.
    Chapter 7 continues the presentation of these data to more complex molecules. Hydro-
carbon gases, nitrogen compounds, and plasma industrial gases have been considered over
a wide range of E/N.
     Chapter 8 deals with the ionization process and presents the first ionization coefficient
in nonattaching gases. Both the steady state method and time-resolved current methods
have been employed and the data cover a wide range of E/N. At higher values of E/N the
drift velocity and diffusion coefficients are subject to ionization effects and results obtained
by simulation or theoretical computation are not excluded, though attention has been drawn
to situations where experimental confirmation is desirable.
    Chapter 9 extends the presentation of ionization coefficients to electron-attaching
gases. Electron attachment is a process that depletes electrons from the ionization region.
It may be a two-body process (electron and molecule) or a three-body process (electron
and two molecules). Dissociative attachment involves the dissociation of the molecule and
the attachment of the electron to one of the fragments. Dissociative attachment cross section
is dominant at relatively low energies while at higher energies ion pair formation is
more frequently encountered. The change of the familiar Townsend’s semiempirical relation
due to attachment is explained by several examples. The chapter provides attachment
cross sections for several gases in addition to ionization and attachment coefficients. A point
to note is that collision cross sections have been provided for some gases for which these
data were not given earlier.
    Chapter 10 shifts the focus to high-voltage phenomena in gaseous electronics, though in
a compact form necessitated by limitation of space. For our present purpose high voltage
is defined as that above 200 kV with no restriction on electrode geometry, gap length,
or polarity of the voltage. This definition is, of course, purely arbitrary to serve the purpose
of limiting the topics for inclusion. Only large air gaps of relevance to high-voltage power
transmission and sulfurhexafluoride at elevated gas pressures have been considered. As
an introduction to the chapter, methods of generating high voltages in the laboratory are
Preface
described, though measurement aspects have had to be deleted. Standard volumes (reference
2 of Chapter 10) deal exhaustively with these methods. Switching impulse breakdown of
large air gaps and volt–time characteristics of compressed gases have been briefly considered.
     Chapter 11 concerns ionization and breakdown in crossed electric and magnetic fields.
This area of research is still only moderately explored, relatively to the volume of literature
available on other areas of gaseous electronics. The potential industrial uses of this type
of discharge are at least as promising as those of other areas of research and the author
is aware of just a single review paper (reference 2 of Chapter 11), published in 1980. The
chapter begins by describing the motion of charge carriers in crossed fields in vacuum and
extends the discussion to phenomena in the presence of gaseous neutrals. The effective
reduced electric field concept is described, as is the influence of a crossed magnetic field on
the ionization coefficients. Quantitative data on Townsend’s first ionization coefficient
in gases as a function of reduced electric and magnetic fields have been compiled for the
first time, to the extent available. The effects of a crossed magnetic field on breakdown,
time lags, and corona formation in nonuniform fields are described. Results obtained
by computational methods are commented upon, with brief comments on the research to be
completed.
     The final chapter deals with high-frequency breakdown, included for completeness
in view of the needs of beginners and students. RF discharges have assumed an important
role in view of the explosive electronic industry, and discharge phenomena are described.
A software package available (reference 11 of Chapter 12) has, in the author’s opinion, served
well to elucidate the complexities of this type of discharge and to provide visual images of
the influence of various parameters on the discharge phenomena. Both microwave break-
down and laser breakdown are dealt with, largely for the sake of completeness.
     The present volume is the culmination of forty-seven years of the author’s interac-
tion with the study of gaseous electronics, beginning with his first entry to the Department
of High Voltage Engineering at the Indian Institute of Science in 1958 as a graduate student.
The topics chosen to be included have a personal bias, of course, though he has personally
studied and researched in all the topics chosen, some with greater intensity than others. It
is realized that topics such as ion mobilities, photo-ionization cross sections, and recent
advances in lightning research have not been included due to limitations of space.
REFERENCES
  1. Massey, H. S. W. and E. H. S. Burhop, Electronic and Ionic Impact Phenomena, Oxford
     University Press, Oxford, 1952.
  2. McDaniel, E. W., Collision Phenomena in Ionized Gases, John Wiley & Sons, New York, 1964.
  3. Loeb, L. B., Basic Processes of Gaseous Electronics, University of California Press, Berkeley,
     1965.
  4. MacDonald, A. D., Microwave Breakdown in Gases, John Wiley & Sons, New York, 1966.
  5. Hasted, J. B., Physics of Atomic Collisions, Elsevier, New York, 1972.
  6. Meek, J. M. and J. D. Craggs, Electrical Breakdown of Gases, John Wiley & Sons, New York,
     1978.
  7. Roth, J., Industrial Plasma Engineering, vol 1., Principles, Institute of Physics Publishing,
     Bristol, 1995.
About the Author
Gorur Govinda Raju was born in 1937. He obtained the B.Eng. degree in electrical engineer-
ing from the University of Bangalore, India, and the Ph.D. degree from the University of
Liverpool, United Kingdom. He then worked in research laboratories of Associated
Electrical Industries, United Kingdom. He joined the Department of High Voltage
Engineering, Indian Institute of Science, Bangalore, and became its head from 1975 to
1980. He has held the Leverhulme Fellowship and Commonwealth Fellowship at the
University of Sheffield, United Kingdom. He joined the University of Windsor, Ontario,
Canada, in 1980 and became the Head of the Department of Electrical and Computer
Engineering during 1989–1997 and 2000–2002. He is currently an Emeritus Professor at the
University of Windsor. He has published over 130 research papers and two previous books.
He is a Registered Professional Engineer and Fellow of the Institute of Engineers, India.
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