JEE-Chemistry

. P
nRT 2x0.0821x 300
5
9.85 atm ALLIN
(11) 1f the gas behaves like a real gas, we apply van der Waal's equation L.e.
an
PV - nb) =nRT
or P
nRT an?
2x0.0821lx 300 4.17 x(2 =9.33 atm
V-nb V² 5-2x0.037 (5
BEGINNER'S BOX-6
Real Gases
1. The compressibility factor of real gas is usually greater than one (2 > 1) at high temperature and high
This is because pressure.
(A)the constant a is negligible while b is not (B) the constant b is negligible while a is not
(C) both a and b are negligible (D) both aand b are no negligible

2, What is not true about the vander waal constant 'b' among the statements given below?
L It is called excuded volume II. It accounts for the interparticle forces
III. ts units are mol dm V. Its value depends on molecular size
(A) I, II (B) II, IV (C) II, II (D) I, IV
3. Among the four statements given below for real gases, which are incorect :
(A)The molecules causes attractive interactions. (B) They show deviation from ideal gas laws.
(C) The molecules are almost volume less points. (D) The molecules have negligible mass.
4. Consider an ideal gas contained in a vessel. If the intermolecular interaction suddenly begins to act, which of
the following will happen:
(A)the observed pressure decreases (B) the observed pressure increases
(C) the observed pressure remains same (D) none of these
5. Areal gas obeying Vander Waals equation will resemble ideal gas, if the:
(A) constants a &b are small (B) a is large & b is small
(C) a is small & b is large (D) constant a & b are large
6 Calculate the compressibility factor for CO,, if one mole of it occupies 0.4 litre at 300 Kand 40 atm. Comment
on the result :
(A)0.40, CO, is more compressible than ideal gas (B)0.65, CO, is more compressible than ideal gas
(C) 0.55, CO, is more compressible than ideal gas (D) 0.62, CO, is more compressible than ideal gas
7. Calculate the radius of He atoms if its Vander Waal's constant 'b' is 24 ml mo-1 ;
(Note ml = cubic centimetre)
(A) 1.355 ¢ (B) 1.314 ¢ (C) 1.255¢ (D) 0.355 Å
Q.8 & Q.9: True &False
8. The behaviour of a real gas approach ideal gas at high temperature & low pressure.
9. Real gases deviate from ideal behaviour because their molecules cause attractive interaction on one another.
10.0 LIQUEFACTION OF GASES ANDCRITICAL POINTS
sLAL
The phenomenon of converting a gas into liquid is known as liquefaction. The liquefaction of a gas takes
place when the intermolecular forces of attraction become so high that exist in the liquid. A gas can 0e
liquefied by:
(a) Increasing pressure: An increase in pressure results in an increase in attraction amongmolecules.
(b) Decreasing temperature: A decrease in temperature results in a decrease in kinetic energy
molecules.

78
ALLENO

Gaseous state
Andrews Isotherms
s JAL
The essential conditions for liquefaction
dy of P-V-T relationship for CO,.The of gases were discovered by Andrews (1869) as a result of his
types of isotherms are shown in figure.

Presure 48°C
35.5°C
-31.1°C
Vapour 'Gas

+ liquld 21.5°C
D E
13.1°C
BA
Volume
Fig: Isotherms for carbon dioxide
showing critical region
Observations from figure
(a) At low temperatures: For the curve ABCF. as the pressure
increases, volume of the curve decreases
(curve A to B).
At point B, at constant pressure, liquefaction commences and the volume
is converted to liquid with higher density). decreases rapidly (because gas
At point C, liquefaction is complete. The line CF represents the variation of V
The steepness of the line CF indicates that the liguid cannot be easily with P of the liquid state.
compressed.
gaseous state, BC represent liquid and vapour in equilibrium. CF represents liquid Thus AB, represernt
The pressure corresponding to the line BC is there vapour pressure of state.
the liquid.
(b) At higher temperatures: Similar type of curve as in case (a) is obtained but the
width of the horizontal
portion is reduced. The pressure corresponding to this portion is higher than at lower
(c) At high temperatures: (like 48°C), the isotherms are like thOse of ideal gas. temperatures.
(d) At temperature (31.1°C): The horizontal portion is reduced to a point.
The isotherm at T, is called critical isotherm.
dP
At point 0, =0.
dV
The point O is called the point of inflection.
Critical temperature (T) : The maximum temperature at which gas can be liquefied by the
application
of pressure alone i.e. the temperature above which a liquid cannot exit is called the
critical temperatureT.
8a
T=
27Rb
Critical pressure (P).The minimum pressure required to liquefy the gas at the temperature T is
called
the critical pressure Pc:

P8
Critical volume (V):The volume occupied by one mole of the gas at critical
temperature, T,and critical
presure, P is called the critical volume (Vc) of the gas.
Ve=3b
) Therefore the value of critical compressibility factor in terms of vander wall's constants is given by
a a
x 3b
zPV 27b 9b 9b
8b 8Ra 8a
Rx
27Rb 27Rb 27b
2 a27b =0.375
9b 8a
79
 JEE-Chemistry

(#) f we compart the value of=0.375,

RT with the experimental values, it has been foiund ALLIP
agreement is very poor.
Critical constants of gases
Gas Pc (atm) 'm,c (cmmol-l) T (K)
He 2.26 57.9 5.2
Ne 26.9 41.7 44.4
12.8 65.5 33.3
O2 50.1 78.2 154.8
Ng 33.5 90.1 126.2
72.8 94.0 304.2
H,0 218.0 55.6 647.3
NH, 111.5 72.5 405.0
CH¡ 45.6 98.7 190.6

Virial Equation Of State For 1 Mole Of Gas

PV 1 1
=1+ B +C
+ ... (B, C, D... are temp. dependent constant)
RT

B= second virial coefficient =b-.

RT
C= third virial coefficient = b2 gas dependent

Boyle's temperature
The temperature at which a real gas behaves like an ideal gas over
an appreciable range of pressure is
known as Boyle's temperature (TR). It means that at this temperature, the value of PV remains constant
for an appreciable range of pressure, i.e. Boyle's Law is obeyed. Mathematically we
may express the Boyle
temperature or Boyle point as the temperature where O(PV) =0 when P > 0.
OP
Soto use ideal gas equation for real gas, we will use some correction factor for volume
as well as for presSure.
Tp = Rb
Illustrations
B
Illustration 23. One way of writing the equation of state for real gases is PV =RT|1++.. where Bis a
constant. Derive an approximate expression for B in terms of van der Waal's constants a and
b
Solution. According to van der Waal's equation
RT
P+ V-b] = RT or P= (V-b) y2
Multiply by V, then
RTV a
PV=
(V-b) V

or PV =RT V-b VRT PV =

VRT

b
. PV =RT|1+..VET

80
 Gaseous state
A L L E N O

.:. B= b
RT

Jlustration 24. The critical temperature and pressure of CO, gas are 304.2 Kand 72.9 atm respectively. What is
the radius of CO, molecule assuming it to behave as vander Waal's gas ?
Solution.
T =304.2KP = 72.9 atm
8a
27Rb Pe 276
8a
27Rb 8a 276? 8b
Pc 27Rb R
27b2
1 0.082× 304.2
or b= =0.04277 lit mo-1
8P 72.9

b= 4NA xa3 r = 42.77 cm

4
= 42.77

3x 42.77x 103
Or r3
16x6.023 x3.14
or r = 0.424 x 10-23 = 4.24 × 10-24
or r = (4.24)13 × 10- cm = 1.62 × 10-8 cm
.. Radius of CO, moiecule = 1.62

11.0 EUDIOMETRY
AL
Eudiometry or gas analysis involves the calculations based on gaseous reactions or the reactions in which at
least two components are gaseous, in which the amounts of gases are represented by their volumes, measured
at the same pressure and temperature. Some basic assumptions related with calculations are:
(i) Gay-Lussac's law of volume combination holds good. According to this law, the volumes of
gaseous reactants reacted and the volumes of gaseous products formed, all measured at the same
temperature and pressure, bear a simple ratio.
N, (g) + 3H, (g)’ 2NH, (g)
1vol. 3 vol. 2vol.
(ii) The volumes of solids or liquids is considered to be negligible in comparison to the
volume of gas. It is due to the fact that the volume occupied by any substance in gaseous state is even
more than thousand times the volume occupied by the same substance in solid or liquid states.
2H, (g) + O, (g)’ 2H,0 ()
2mole 1mole 2 mole
2 vol. 1vol. Ovol.
(ii)
Air is considered as a mixture of oXygen and ritrogen gases only. It is due to the fact that about 99%
volume of air is composed of oxygen and nitrogen gases only.

NIDrogen gas is considered as an non- reactive gas. It is due to the fact that nitrogen gas reacts only at
very high temperature due to its very high thermal stability. Eudiometry is perfomed in an eudiometer
tuoe and the tube cannot withstand very high temperature. This is why, nitrogen gas can not participate
in the reactions occuring in the eudiometer tube.

81
 JEE-Chemistry

(v) Volume of gases is generally measured by passing them through appropriate solvent
them. Some solvents are : yrich aoSuta
Solvent gas (es) absorb
KOH CO, SO, Ch
Ammonical Cu,Cl,, CO
Turpentine oil O3
Alkaline pyrogallol
Water NH¡, HCI
CuS0, /CaC, H,0
Illustrations
Illustration 25. Calculate volume contraction during complete combustion of 30ml of toluene. per
CH, reaction.

(g) + O, (g) ’ CO,g) + H,0)

Solution. C,H,CH, +90, ’7C0, +4H,O()
AV =V,-V,
- 30+ Vo, lakenVo,et -Vco,fomed
= 30+Vorodod-210
= 30 + 270-210 = 90 ml.

Illustration 26. The percentage by volume of CçH, in a mixture of CçH, CH, and COis 51%. When 100 ml of
the mixture is burnt in excess of O,, the volume of CO, produced is
(A) 100 ml (B) 304 ml (C) 267 ml (D) 255 ml
Ans. (B)
Solution. CzH, + CH, +CO excessCO,
51 X 49 -x
POAC on C
5x 51 +x+ 49-X= 1xco,
Vco, = 255 +41 =304

BEGINNER'S BOX-7
Liquification, Critical Phenomena and Eudiometry
1. Agas witha = 0 can be very easily liquefied. (T/E)
2. For three different gases values of vander Waal's constant 'a' and b' are given, What is the correct order ot
liquefaction of gases :
Gases b
1.3 0.090
4.1 0.023
2.,2 0.075
(A) X, > Y, >2, (B) Y, > Z,>X (C) Z, > Y, > X, (D}) X, > Z>Y,
3. The value of vander Waal's constant 'a' for the gases O,, N, NH, and CH, are 1.36, 1.39, 4.17 and 2.203
atm, m², respectively. The gas which can most easily be liquefied is
(A) O, (B) N, (C)NH, (D) CH,

82
 ALLENO Gaseous state

orbs Vander Waal's constant for three different gases are given
Gas b
X 3.0 0.025
10.0 0.030
6.0 0.035
Which is correct ?
(A) Maximum critical temperature - Y (B) Most ideal behaviour - X
(C) Maximum molecular volume-2 (D) Allare correct
Thecritical constant for water are 374°C, 218atm and 0.0566 litre mol!,
Calculate a & b.
(A) a=1.095 litre? atm mol2, b=0.0185 litre mol (B) a=1.92 litre2 atm mol2, b=0.185 litre moti
(C) a= 2.095 litre atm mo2,b=0.0189 litre mo! (D) a=2.95 litre² atm mol,b=0.1185 litre moli

Thecritical temperature of water is higher than that of O, because the H,0

molecule has :
(A) fewer electrons than O, (B) two cOvalent bonds.
(C) V-shape (D) dipole moment.
C;H,OH (g) + O, (g)’Co, (g) + H,O ()
Magnitude of volume change if 30 ml of CeHOH (g) is burnt with excess amount of oxygen, is
(A) 30 ml (B) 60 ml (C) 20 ml (D) 10ml
10 ml of a compound containing N' and 'O' is mixed with 30 ml of H, to produce
H,0 ) and 10 ml of N, (g).
Molecular formula of compound if both reactants reacts completely, is
nl of (A) N,O (B) NO, (C) N,O, (D) N,O5
Amixture of C,H, and CHg occupied a certain volume at 80 mm Hg. The mixture was
completely burnt to
CO, and H,O(0). When the pressure of CO, was found to be 230 mm Hg at the
same temperature and
volume, the fraction of C,H, in mixture is
(A)0.125 (B) 0.5 (C) 0.85 (D) 0.25
0. 20 ml of a mixture of C,H, and CO was exploded with 30 ml of oxygen. The gases after the reaction
had a
volume of 34 ml. On treatment with KOH, 8 ml of oxygen remained. Calculate the commposition of the
mnixture.

r of

3P

83
 JEE-Chemistry

BEGINNER'S B0X-1 ANSWERS ALLL

1. (B) 2.(A) 3.(A)
4.(i) 10cm of Hg (ii) 66 cm of Hg (ii) 86 cm of Hg
5.(i) 10132500 (ii) 76000
(iü) 1033.6
6. (A) (iv) 76000
(v) 100
BEGINNER'S BOX-2
1.96g 2. 262.2 ml 3.327.6 K
6.(a) 0.37L (b) 181.55 4.41.33 5. 1.57 gL-!
(c) 2.27 atm (d) 0.418 L 7.(C)
BEGINNER'S BOX-3
1.0.56 atm 2. 489.23 mm. 260.77 mm
3. Pm = 2.4 atm PN = 0.667 atm
Po, =0.733 atm
4. Po = 0.49 atm Poo = 1.5latm Pcoz =latm
5.(B) 6. (A) 7.(C)
BEGINNER'S BOX-4
1. (C) 2.(A) 3.(A)
6.6.82 7. M = 16 4.(A) 5.(D)

BEGINNER'S BOX-5
1. (D) 2.(B) 3.(B)
7.(A) 4.(B) 5.(B) 6.(B)
8.(B) 9.(A)
BEGINNER'S BOX-6
1.(A) 2.(C) 3.(C,D) 4.(A)
7.(A) 8. (T) 5.(A) 6.(B)
9. (T)
BEGINNER'S BOX-7
1. (F) 2.(B) 3.(C)
7. (B) 4.(D) 5.(C) 6.(D)
8. (C) 9. (A) 10. C,H, =6ml, CO = 14 ml

94
 ALLEN®
JEE-MAINS EXERCISE
Essentially to be Discussed in Class
EXERCISE-1

SINGLE CHOICE CORRECT QUESTIONS

confined gas will be:
In the following arrangement the pressure of the P=?
Pm=76cm of Hg
p=27.2gm/cc 10cm
p=6.8gm/cc 30cm
p=1gm/cc+ |13.6cm
76cm
T15cm

Hg

(B) 25 cm of Hg (C) 35 cm of Hg (D) 45 cm of Hg

(A) 15 cm of Hg
The density of a gas at 27°C and 1 atm is d. Pressure remaining constant at which of the following
2.
temperatures will its density become 0.75 d? Ao
(A) 20 °C (B) 30 °C (C) 400K (D) 300K

3. At 27°C the ratio of rms velocities of ozone to oxygen is :

(A) /3/5 B) 4/3 (C) /2/3 (D) 0.25

4. real gas most closely approaches the behaviour of an /deal gas at :

A
(A) 15 atm and 200 K (B) 1atm and 273 K
(C) 0.5 atm and 500 K (D) 15 atm and 500 K

V
vs T curves at constant P, and P, for an ideal gas are shown in figure. Which is correct?
5.

(A) P, > P (B) P, < P (C) P, = P, (D) all

reaction occured
6 At STP, 2.8 litres of hydrogen sulphide were mixed with 1.6 litres of sulphur dioxide and the
according to the equation :
2H,S (g) + SO, (g)2H,0 (0) + 3S (s)
Which of the followingshows the volume of the gas remaining after the reaction?
(A) 0.2 litres of SO, (g) (B) 0.4 litres of H, (g)
(C) 1.2litres of H,S (g) (D) 1.2 itres of SO, (g)
7. The rates of diffusion of SO,, CO,, POCl, and SO, are in the following order :
(A) PCI, > SO, > SO,> CO, (B) CO, > SO,> PCI,> SO,
(C) SO, > SO, > PCI, > CO, (D) CO, > S0,> SO,> PC,
8 Helium atom istwo times heavier than a hydrogen molecule. At 298 K, the average kinetic energy of a helium
atom is:
(A) two times that of a hydrogen molecules (B) same as that of a hydrogen molecules
(C) four times that of a hydrogen molecules (D) half that of a hydrogen molecules

95
 JEE-Chemistry

9. Which of the following curves does not represent Boyle's law

ALLENP
D
P log P|
(A) (B) (C) (D)
logV 1//

10. Aclosed vessel contains equal number of nitrogen and oxygen molecules at pressure of P
mm. f
fdesl is removed from the system, then the pressure will be: nitrogen
(A) P (B) 2P (C) P/2 (D) P2
11. 11 moles N, and 12 moles of H, mixture reacted in 2O litre vessel at
800K. After equilibrium was reachod
6 mole of H, was present. 3.58 litre of liquid water is injected in equilibrium
ldeal mixture and resultant o2co
mixture suddenly cooled to 300 K. What is the final pressure of gaseous mixture ? Negative
liquid solution. Assume (i) all NH, dissolved in water (i) no change in volume of vapour pressure of
liquid (ii) no reaction f
and H, at 300K:

N, :11 moles T=800K T=300 K;P=?

N,H,
H, :12 moles V=20L NH,aq) solution
Initial condition

(A)18.47 atm (B) 60 atm (C) 22.5 atm (D) 45 atm

12. Which one of the following V, T plots represents the behaviour of one mole of an ideal gas at
one atm?
38.8L 88L
373 K 373 K
22.4 L| 20.4 L
(A) 273 K| (B)
z73 K
T()
30.6L 14.2 L
373 K 373 K
22.4 I 22.4 LI
(C) 273K
(D) 73K
T(K)
13. The corect order of normal boiling points of O.,, N,, NH, and CH, for whom the values of vander waals
constant 'a' are 1.360, 1.390, 4.170 and 2.253 L².atm.mol² respectively, is :
(A) O, < N, < NH, < CH, (B) O, < N, < CH, < NH,
(C) NH, < CH, < N, <O, (D) NH, <CH, < 0, < N,
tdaah

A chemist has synthesized a greenish yellow gaseous compound of chlorine and oxägen
density is 7.71 g/Lat 36°C and 2.88 atm. Then the molecular formula of the compound will beand
:
finds that its
(A)CIO, (B) CIO, (C) CIO (D) CI0,
(15. Two closed vessel A and B of equal volume containingair at pressure P, and temperature T,
are connected
to each other through a narrow open tube. If the temperature of one is now
maintained at T, and other at 2
(where T, > T)then that what wil be the final pressure?
(A) (B) 2P, T, (C) 2P,T, 2P,
2P, T, (D)
T,+T, T, +T,
96
 Gaseous state
ALLEN
:
16. Compressibility factor for H, behaving as real gas is
Pb RTV
(A) 1
(B)1-R0V (C) 1+ RT (D)
(1-a).

17. certain volume of argon gas (Mol Wt. 40) requires 45 s to etfuse through a hole at a certain pressure and
temperature. The same volume of another gas of unknown molecular weight requires 60 s to pass through
the same hole under the same conditions of temperatureand pressure. The molecular weight of the gas is
(A) 53 (B) 35 (C) 71 (D) 120

fraction of the total

18. Equal masses of methane and oxyaen are mixed in an empty container at 25°C. The
pressure exerted by oxygen is : (D) (1/3) (273/298)
(A)1/3 (B) 1/2 (C) 2/3

of 19. On the surface of the earth at 1 atm pressure, a balloon filled with H, gas occupies 500 mL. This volume
balloon
N, 5/6of its maximum capacity. The balloon is left in air. It starts rising. The height above which the
will burst if temperature of the atmosphere remains constant and the pressure decreases 1 mm for every 100
cm rise of height is :
(A)120 m (B) 136.67 m (C) 126.67 m (D)100 m

20. Consider the following statements:Ifthevander Waal's parameters of twogases are given as
a (atm lit mol²) b (lit mol-i)
Gas X: 6.5 0.056
Gas Y:8.0 0.011
then a:V,(X) < V,(Y)
b:P(X) < P()
c:T (X) << T{Y)
Select correct alternate :
(A) a alone (B) a andb (C) a,b and c (D) b and c
 JEE-Chemistry ALLEN
JEE-ADVANCED
Essentially to be
EXERCI8E
EXERCISE -2 Discussed in Clau

cORRECT QUESTIONS
EGION - 1 : MULTIPLE CHOCE
When a fixed amount of gas is expanded at constant temperdtae
(A) the pressure decreases
(B) the kinetic energy of the molecules remains the same
(C) the kinetic energyof the molecules decreases
(D)the number of molecules of the gas decreases
via a tube of negligible volume.
2 A1Lof vessel containing Ar(g) and 2L vessel containing Ne(g) are attached

Ar Ne
2 atm 2atm
1L 2L
300K 400K

Container I Container II
Temperature of both vessels is maintained at 300 Kand 400
Krespectively throughout when tne tap is opened
and gases are allowed to mix completely then -
(A) Final pressure of mixture is 4 atm.
(B) Ratio of total number of moles of gas in container-I to container-II is 2:3.
(C) Pressure of Ar(g) in container-I is 0.8 atm.
(D) Pressure of Nelg) in container-II is 1.2atm.
3. Which of the following are correct statements :
(A) vander waals constant 'a'is a measure of attractive force
(B)vander waals constant 'b' is also called co-volume or excluded volume
(C) 'b' is expressed in L mol
(D) 'a' is expressed in atm L? mo2

4. Which of the following statements are incorrect:

(A) Molar volume of every gas at NTP is 22.4 L.
(B) Under critical states compressibility factor is 1
(C) Allgases will have equal value of average translational KE at a given temperature
3
(D) At absolute zero, KE isR.
2

For a fixed amount of an ideal gas P vs T plot is given as shown. ldentify the incorrect option:

A
Platm) straight line
graph

T(Kelvin)
(A) The change from A to B should be isochoric
(B)Volume first increases reaches maxima and then decreases
(C) PV = nRT is not applicable
(D) None of the statements are corect

98
 ALLENO Gaseous state
According to the kinetic theory of gases.
6. AL the pressure exerted by fixed amount of a gas is
proportional to the mean square speed of the molecules in
a rigid vessel.
IR) the pressure exerted by fixed amount of a gas is proportional
to the rOot mean square speed of the
molecules in a rigid vessel.
IC) the root mean square speed is inversely proportional to the temperature.
Di themean translational kinetic energy of the molecule is directly
proportional to the absolute temperature.
Which of the following is correct for critical termperature?
(A) It is the highest temperature at which liquid and vapour can coexist.
(B) Beyond this temperature, there is no distinction between the two phases
and agas cannot be liquefied by
compression.
(C) At this temperature, the surface tension of the system is zero.
(D) At this temperature, the gas and the liquid phases have different critical
densities.
3. For a gaseous system, the pressure can be increased by
(A) increasing the volume of container but keeping the amount and
(B) increasing the amount of gas at constant temperature and volumetemperature constant
(C) decreasing the volume of container but keeping the amount and
(D) decreasing temperature but keeping amount and volume constanttemperature constant
9. Four gas balloons A, B, C, D of equal volumes containing H, H,0,
with needle and immersed in a tank containing CO,. Which of CO, CO, respectively were pricked
them will shrink after some time.
(A)A (B) B (C) C (D) Both A and D
10. Three gases of densities A(0.82), B(0.25), C(0.51) are enclosed in a vessel
correct statement : (Assume ideal behaviour) of 4L capacity. Pick up the
(A)Gas A will tend to lie at the bottom
(B) The number of atoms of various gases A, B, C
are sarme
(C) The gases wil diffuse to form homogeneous
(D)The average kinetic energyof each gas is same.
mixture.

SECTION -2 : COMPREHENSION BASED QUESTIONS

(SINGLE CHOICE CORRECT QUESTION)
Comprehension-1
The rate of change of pressure (p) of a gas at constant
effusion of gas from a vessel of constant volume is related totemperature
rate
and constant external pressure due to
dp kT dN
of change of number of molecules present by
d V dt
where k=Boltzmann constant, T=temperature, V= volume of
dN vessel &N = No. of molecules and
-pA, where A, = area of
dt (2rmkT2 orifice and m = mass of molecule.
11, Time required for pressure inside vessel to reduce to l/e of its initial value
\1/2
in (In e = 1)
(A)2 m (2rmkT)/2
(B) (C) 2rum V
kT Ao 2m A (D)
A kT A,
12, If the gas inside
the vessel had molecular weight 9 times the gas in previous
doubled and temperature maintained at 4T, time required for pressure to fallexample
to
and area of orifice was
would be (t = answer of previous option) 1/e times of its initial value
(A) 1.33t (B) 4.24t (C) 0.75 t (D) 1.125 t
13. The incorrect statement (s) is/are.
]Pressure will not fall to zero in infinite time.
]Time required for pressure to decrease to half its initial value is independent of
[ ]The relations given above are true for real gases also. initial pressure.
(A) I (B) II (C) II (D) Iand II
99
 JEE-Chemistry

JEE-ADVANGED ALLEN
EXERCISE
FSsentially to be Discussed
EXERCISE-3

in Clae
QUESTIONS
SECTION-1: NUMERICAL ANSWER BASED
3.6 a of an ideal gas was injected into a bulb of internal volume of 8 L at pressure P atm and temp T K. The
1.
bulb was then placed in a themostat maintained at (T + 15)K 0.6 g of the gas was let off to keep the original
is 44
pressure. Find P and
T if mol weight of
volumes maintained at temperatures 300
K and 600 K contain equal
and B of equal mass of H.
Two flasks A total translational kinetic energy of gas in flask Ato that in flask Bis
2.
respectively. The ratio of
and CH,
liquid of density 6.8 amos o.
infinitely long tube contains trapped air along with Hg && another
3. An
horizontally as shown.
24 cm 10 cm(d=6.8 gm/cc)

air PI atm = 75 cm

10 cm
of Hg
the lenath fk
nowplaced vertically with the open end upward at the same temperature then
If the tube is
column is 4x cm. What is X.
sufficient air into
is to remain submerged for 1hr, what pressure must be applied to force
Ifa scuba diver respiration rate
4. breath at standard atmosphericpressure, a
thetank to be used. Assume 0.5 dm' of air per
capacity of 30 dm.
of 38 breaths per minute, and a tank
porosity are filled to apressure of 2 atm, one
with 14 kgN, &
At 20°C two balloons of equal volume and
5. (in min)
pressure of atm in one hour. How long will ie take for H,
other with 1 kg H,. The N, balloon leaks to a 2 Pleaked/t
balloon to leaks to a pressure of
2
-atm.
YH Pleaked Jt
QUESTIONS
SECTION -2: MATRIX- MATCH

6. Match the Column.

Column-II
Column-I
Dalton's law of partial pressures at constant
(A) P,V, = P,V, = P,V, = (p) temperature

at constant pressure (g) Kinetic equation of ideal gases

(B)

(r) 22.4 litre

(C) r oc

(D) P= P, + P, + P, + (s) Isotherm

(E) (V-b)[P+ = RT () Isobar

(F) RN (u) Charles' law

(G) Molar volume (v) Graham's law
1
(H) PV=mnc? (w) Boyle's law
Graph between P and Vat constant temperature (x) Equation for real gases
(J) Graph between V
and T at constant pressure (y) Boltzmann's constant

-E
100
 ALLENO Gaseous state

7. Match the entries in column Iwith entries in Column IIand then pick out coect options.
Column-I Column-II

1
(A) vs P for ideal gas at constant Tandn (p)

(B) V
vs for ideal gas at constant P and n (q)

(C) logP vs log V for ideal gas at constantT and n (r)

1
(D) Vvs 31or ideal gas at constant T andn (s)

8. ColumnI consists of compressibility factor (Z) and column II consists of conditions in which the gas is present.
Match Column Iwith Column II.

Column-I Column-II
(A) Z=1 (p) Any Vander Waal gas at its critical temperature
(B) Z>1 (g) ldeal gas at any pressure and temperature
(C) Z<1 (r) H, gas at normal temperature and high pressure
3
(D) Z= (s) NH,gas at normal temperature and low pressure
(t) Anyreal gas at pressure close to zero and normal temperature

101
 JEE-Chemistry

EXERCISE-4A) PREVIOUS YEARS AIEEEIEE (MAIN)-FUNDAMENTAL

ALLEN
Essentially to be LEVEL
Discussed in Cl
1. For gaseous state, if most probable speed is denoted by C*, average speed and mean square sneod
then for a large number of molecules the ratio of these speeds are: [JEE MAINS-2013)
(1) C*: C:C= 1.225: 1,128: 1 (2) C* : C:C=1.128: 1.225: 1
(3) C*: C :C=1:1.128 : 1.225 (4) C*: :C= 1: 1.225:1.128
2. The initial volume of a gas cylinder is 750.0 mL. If the pressure of gas inside the cylinder changes from 8400
mm Hg to 360.0 mm Hg, the final volume the gas will be [JEE MAINS - ONLINE - 20141
(1) 1.750 L (2) 7.50 L (3)3.60L (4) 4.032 L
3. Which of the following is not an assumption of the kinetic theoryof gases?
IJEE MAINS - ONLINE- 20151
(1)Gas particles have negligible volume.
(2) A gas consists of many identical particles which are in continual motion.
(3) At high pressure, gas particles are difficult to compress.
(4)Collisions of gas particles are perfectly elastic.
4. When does a gas deviate the most from its ideal behaviour ? JEE MAINS - ONLINE - 2015]
(1) At high pressure and low temperature (2) Athigh pressure and high temperature
(3) At low pressure and low temperature (4)At low pressure and high termperature
5. At very high pressure, the compressibility factor of one mole of a gas is given by :
[JEE MAINS - ONLINE- 2016)
pb
(1) 1+ pb (2) 1
(3) 1- pb (4)
RT (VRT) RT RT

6. Two closed bulbs of equal volume (V) containing an ideal gas initially at pressure p, and temperature T, are
connected through a nanowtube of negligible volume as shown in the figure below. The temperature of one
of the bulbs is then raised to T,. The final presure p, is [JEE-MAIN - 2016]
T, T,
P,V
P,V. p,V

T, (3) 2 p T (4) 2p, TT,

(4) T, +T,)
(2) 2p,
(T+T, ) I, +T, T, +T,)

7. Among the following, the incorrect statement is: (JEE MAINS -ONLINE - 2017]
(1)At low pressure, real gases show ideal behaviour
(2) At very large volume, real gases show ideal behaviour
(3) At Boyle's temperature, real gases show ideal behaviour
(4)At very low temperature, real gases show ideal behaviour

8. At 300K. the density of a certain gaseous.molecule at 2 bar is double to that of dinitrogen (N) at 4 bar. The
molar mass of gaseous molecule is: [JEE MAINS - ONLINE - 2017
(1) 28 g mol! (2) 56 g mol-1 (3) 224 g mol-l (4) 112 go mol
9. 0.5 moles of gas Aand x moles of gas Bexert a pressure of 200 Pa in a container of volume 10 m³ at 1000 K.
Given R is the gas constant in JK mol-l, x is : [JEE MAINS- ONLINE- 2019]
2R 2R 4-R 4+R
(1) 4+12 (2) 4-R
(3) (4)
2R 2R

E
102
 ALLENO Gaseous state
The combination of plots which does not represent isothermal expansion of an ideal gas is:
10. [JEE MAINS - ONLINE - 2019]
P PV
P

(A) (B) (C) (D)

1/V, m
V.
(1) (A) and (C) (2) (A) and (D) (3) (B) and (D) (4) (B) and (C)
1 Consider the van der Waals constants, a andb, for the following gases.
(JEE MAINS - ONLINE - 2019]
Gas Ar Ne Kr Xe
al (atrm dm mol) 1.3 0.2 5.1 4.1
b/ (10 dm mo-! 3.2 1.7 1.0 5.0
Which gas is expected to have the highest critical temperature?
(1) Kr (2) Ne (3) Ar (4) Xe

2. At agiven temperature T, gases RTNe, Ar, Xe and Kr are found to deviate from ideal gas behaviour. Theit
equation of state is given as p= at T. [JEE MAINS - ONLINE - 2019]
V-b
Here, b is the van der Waals constant. Which gas will exhibit steepest increase in the plot of Z
(Compression
factor) vs p?
(1)Ne (2) Ar (3) Xe (4)Kr
3.

Presure Presure
Amixture of gases O, H, and CO are taken in a closed vessel containing charcoal. The graph that
the corect behaviour of pressure with time is :
Presure
[JEE MAINS - ONLINE - 2020]
represents
Presure
(1) (2 (3) {4

Time Time Time Time

4. Which one of the following graphs is not correct for ideal gas? [JEE MAINS - 2020 - ONLINE]
d= Density, P= Pressure, T= Temperature
2
d d

T’ T’
() (II)

1/T> P’
(HI) (V)
(1) II (2) III (3) I (4)V
 JEE-Chemistry

15. A mixture of one mole each of H,, He and O, each are enclosed in a cylinder of volume
Vat
ALLEN
the partial pressure of H, is 2 atm, the total pressure of the gases in the cylinder is : temperatuxeT.
JEE MAINS- 2020 -
(1) 14 atm (2) 22 atn (3) 6 atm ONLINE)
(4) 38 atm
16. Arange the following gases in increasing order of van der Waals constant 'a'
A. Ar B.CH, C. H,0 D. CeHs
Choose the correct option from the following : SJEE MAINS -ONLINE - 20231
(1) B, C, D
and A (2) C, D, Band A (3) A, B, Cand D (4) D, C, B and A

104
 ALLEN Gaseous state

EXERCISE - 4(B) PREVIOUSYEARS AIEEEIJEE (MAIN)-ADVANCE LEVEL

Essentlaly to be Discussed in Class
SECTION -1 :SINGLE CHOICE CORRECT QUESTIONS
By how many folds the temperature of agas would increase
1 when the root mean square velocity of the gas
molecules in a container of fixed volume is increased from 5 x 0 cm/s to 10 x J0 cm/s?
(1)Four (2) three [JEE MAINS - ONLINE - 2013]
(3)Two (4) Six
Which one of the following is the wrong assumption of kinetic
2. theory of gases ?
(1) All the molecules move in straight line between [JEE MAINS - ONLINE - 2013]
(2) Molecules are separated by great distances compared collision and with same velocity.
to
(3) Pressure is the result of elastic collision of molecules with their sizes.
(4) Momentum and energy always remain conserved. the container's wall.

3. Vander Waal's equation for a gas is stated as,

[JEE MAINS -ONLINE -2014]
nRT
p=
V-nb

This equation reduces to the perfect gas nRT

equation, p = when,
(1) both temperature and pressure are very low
(2) both temperature and pressure are very high
(3) temperature is sufficiently high and pressure is low
(4)temperature is sufficientBy low and pressure is high.
4. The temperature at which oxygen molecules have the
same root mean square speed as helium atoms have at
300 K is :
(Atomic masses: He = 4 u, O = 16 u) [JEE MAINS - ONLINE - 2014]
(1) 1200 K (2) 600 K (3) 300 K (4) 2400K
5. Sulphur dioxide and oxygen were allowed to diffuse through a porous
partition. 20 dm of SO, diffuses
through the porous partition in 60 seconds. The volume of O, in dm which
diffuses under the similar
condition in 30 seconds will be (atomic mass of sulphur = 32u) [JEE MAINS -
(1) 28.2 ONLINE -2014]
(2) 14.1 (3) 7.09 (4) 10.0
6. If Z is a compressibility factor, van der Waals equation at low pressure can
be written as:
(JEE MAIN - 2014]
RT
(1) 2 =1+ Pb Pb
Pb (2) Z =1 VRT
(3) Z =1 (4) Z =1+
RT RT
7 Initially the root mean square (rms) velocity of N, molecules at certain temperature is u. If this
temperature is
doubled and all the nitrogen molecules dissociate into nitrogen atoms, then the new ms velocity will
be:
[JEE MAINS - ONLINE - 2016]
(1) u/2 (2) 4u (3) 14u (4) 2u
8. An open vessel at 27°C is heated until two fifth of the air (assumed as an ideal gas) in it has escaped from
the
vessel. Assuming that the volume of the vessel rermains constant, the temperature at which the vessel has been
heated is : [JEE MAINS- ONLINE-2019]
(1) 750°C (2) 500°C (3) 750K (4) 500 K
9
The volume of gas A is twice than that of gas B. The compressibility factor of gas A is thrice than that of gas B
at same temperature. The pressures of the gases for equal number of moles are :
[JEE MAINS - ONLINE - 2019]
(1) 2PA 3P (2) PA =3PB (3) PA = 2P (4) 3PA = 2P
105
10. lo>9
JEE-Chemistry

Consider the following table:

Gas a/(k Pa dm
642.32
mol) b/(dm mol-)
0.05196
0.04136
ALLEN
[JEE MAINS - ONLINE - 20191

B 155.21
431.91 0,05196
D 155.21 0.4382
aand b are vandes waals constant. The coect statement about the gases is:
(1)Gas Cwill occupy lesser volume than gas A;gas B will be lesser compressible than gas D
(2)Gas Cwill occupy more volume than gas A; gas B will be lesser compressible than gas D
(3) Gas Cwilloccupy more volume than gas A; gas B will be more compressible than gasD
(4) Gas C willoccupy lesser volume than gas A; gas B wll be more compressible than gas D

Points I, land l in the following plot respectively corespond to (V.n

mp : most probable velocity)

fDu(instvcrbi)uo’n,
11.
[JEE MAINS - ONLINE - 20191

II III
Speed, v ’
(1)Vm of N, (300K); Vmp of H,(300K); V,mp of 0,(400K)
(2) Vm of H, (300K); Vmp of N,(300K); Vmp of O,(400K)
(3) Vmp of 0, (400K);Vmp of N,(300K); Vmp of H,(300K)
(4) Vmp of N, (300K); Vmp of O,(400K);Vmp of Hz(300K)
12. Identify thecorrect labels of A, B and C in the following graph from the options given below:
[JEE MAINS - ONLINE - 2020)
no.
of
molecules

speed
Root mean square speed (V,m); most probable speed (Vmp)i Average speed (V,)
(1) A-Vms i B-VmpiC-V, (2) A-VayiB-VmsiC-Vmn
(3) A-V,mniB-Vms ;C-Va (4) A-Vmm i B-VaiiC-Vms
13. An evacuated gla_s vessel weighs 40.0 g when empty, 135.0 g when filled with a liquid of density 0.95 g mL
and 40.5 gwhen filled with an ideal gas at 0.82 atm at 250 K. The molar mass of thegas in g mol-! is:
(Given :R = 0.082 Latm K mol) [JEE MAINS - ONLINE -2022)
(1)35 (2)50 (3) 75 (4) 125

106
 ALLENO Gaseous state
Eor l mol of gas, the plot of pV vs p is shown below. p is the pressure and V is the volume of the gas.

pV

P
What is the value of compressibility factor at point A? [JEE MAINS - ONLINE - 2023]
(1) 1-RTV (2) 1ýb (3) 1 (4) 1+
RTV
SECTION-2 :NUMERICAL ANSWER BASED QUESTIONS
A Spherical balloon of radius 3 cm containing helium gas has a
1 pressure of 48 x 10 bar. At the same
temperature, the pressure, of a spherical balloon of radius 12 cm containing the same
× 10 bar. amount of gas will
be [JEE MAINS - 2020 - ONLINE]

2 The volume occupied by 4.75 gof acetylene gas at 50 Cand 740 mmHg
the nearest integer)
pressure is L. (Rounded off to
[JEE MAINS - 2021 - ONLINE]
[Given R = 0.0826 L atm K- motl]
3. A car tåre is filled with nitrogen gas at 35 psi at 27°C. It will burst if
in C at which the car tyre will burst is
pressure exceeds 40 psi. The temperature
(Rounded-off to the nearest integer)
[JEE MAINS - 2021 - ONLINE]

4 Acertain gas obeys P(V-b)= RT. The value of xb

is The value of x is
RT
(Integer answer) (Z:compressibility factor) [JEE MAINS- 2021 - ONLINEJ
5. The pressure exerted by a non-reactive gaseous mixture of 6.4 g of methane and 8.8 g of
carbon dioxide in a
10L vessel at 27°C is kPa. [JEE MAINS - 2021 - ONLINEJ
(Round off to the Nearest Integer).
[Assume gases are ideal, R = 8.314 J mo- K-1
Atomic masses :C: 12.0 u, H:1.0 u, O: 16.0 u]

6. A box contains 0.90 g of liquid water in equilibrium with water vapour at

27°C. The equilibrium vapour
pressure of water at 27°C 32.0 Torr. When the volume of the box is increased, somne of the liquid water
evaporates to maintain the equilibrium pressure. If all the liquid water evaporates, then the volume of the box
must be litre. [nearest integer)
(Given: R = 0.082 Latm K mol) [JEE MAINS - 2022 - ONLINE]
(Ignore the volume of the liquid water and assume water vapours behave as an ideal gas.)

72 At 300 K, a sample of 3.0 g of gas A occupies the same volume as 0.2 g of

hydrogen at 200K at the same
pressure. The molar mass of gas A is g mol- (nearest integer) Assume that the behaviour of gases as
ideal. (Given: The molar mass of hydrogen (H) gas is 2.0 g mol) (JEE MAINS - 2022 - ONLINE]
8 A rigid nitrogen tank stored inside a laboratory has a pressure of 30 atm at 06:00 am when the
1
27 °C. At 03:00pm, when the temperature is 45°C, the pressure in the tank will be
temperature is
50 integer] atm. nearest
[JEE MAINS -2022 - ONLINE]
9 100 gof an ideal gas is kept in a cylinder of 416 L volume at 27°C under 1.5 bar pressure. The molar
mass of
1 the gas is gmol-i. (Nearest integer) (Given:R= 0.083 Lbar K-! mo)
[JEE MAINS - 2022 - ONLINE)

-107
 JEE-Chemistry

10. Asealed flask with acapacity of 2 dm

contains 11 gof propane gas. The flask is so
nrOsSITe becomes 2 MPa. The minimum temperature at which the
weak that iit will ALLEN
burst if the
flask will burst is
integer] °C. (Nearest
(Given: R = 8.3 J K mo-l Atomic masses of Cand H are 12u and lu
respectively.) (Assume that propane
behaves as an ideal gas.) [JEE MAINS- 2022 - ONLINE]

11, The pressure of a moist gas at 27°C is 4 atm. The volume of the container is doubled
at the same
The new pressure of the moist gas is ... x10 atm. (Nearest integer) temperature.
(Given : The vapour pressure of water at 27°C is 0.4 atm) JEE MAINS - 2022 - ONLINEI

12. A 10 g mixture of hydrogen and helium is contained in a vessel of

capacity 0.0125 m° at 6 bar and 27°0 The
mass of helium in the mixture is g. (nearest integer) [JEE MAINS - 2022 - ONLINE)
Given: R=8.3 JK'mol (Atomic masses of Hand He are lu and 4u,
respectively)

13. A mixture of hydrogen and oxygen contains 40% hydrogen by

mass when the pressure is 2.2 bar. The partial
pressure of hydrogen is bar. (Nearest Integer) [JEE MAINS -2022 - ONLINEJ

14. For a real gas at 25°C temperature and high pressure (99 bar) the value of
compressibility factor is 2, so the
value of Vander Waal's constant 'b' should be x10 Lmol-1 (Nearest integer)
(Given R= 0.083L bar K-1 mo) [JEE MAINS - 2022- ONLINE]

15. The number of statement's, which are corect with respect to the
compression of carbon dioxide from point (a)
in the Andrews isotherm from the following is
[JEE MAINS -ONLINE - 2023]

Presure d)

Volume
(i)) Carbon dioxide remains as a gas upto point
(b)
(i) Liquid carbon dioxide appears at point
(c)
(ii) Liquid and gaseous carbon dioxide coexist between points (b) and (c)
(iv) As the volume decreases from (b) to (c), the amount of liquid
decreases.

108
 ALLENO Gaseous state

P=2 atn P=4 atm P=3 atm

16. V=2 L V=3L V=4 L
CH,() cO,(e) Nelg)

Three bulbs are filled with CH¡, CO, and Ne as shown in the
picture. The bulbs are connected through pipes
of zero volume. When the stop cocks are opened
and the temperature is kept constant throughout,
the
pressure of the system is found to be atm. (Nearest integer) [JEE MAINS-ONLINE -
2023]
17 At constant temperature a gas is at a pressure
of 940.3 mm Hg. The pressure at which its
volume decreases by
40% is mm Hg. (Nearest Integer)
[JEE MAINS -ONLINE - 2023]

al

e
 JEE-Chemistry

PREVIOUS YEARS I|T-JEEIJEE ALLEW

EXERCISE- 5

Waals equation
Essentially to be (ADVANCED)Claes
Discussed in
gas described by van der
1. A
(A) behaves similar toan ideal gas in the limit of large
molar volumes
ideal gas is in limit of large pressures
(JEE-2008)
(B)behaves similarto an
(C) is by van der Waals
characterised coefficients that are dependent on the identity of
independent of the temperature.
the gas but
are.
(D bas the pressure that is lower than the pressure exerted by the same gas behaving ideally

2. The term that corects for the attractive forces present in a real gas in the vander Waals equation ie :
an? ( C )a n ?
[JEE-2009)
(A) nb (B) (D) -nb

3. At 400K the root mean square (ms) speed of a gas X (molecular weight = 40) is equal to the most nralel,
speed of gas Y at 60 K. The molecular weight of the gas Y is. [JEE-2009]
4. If the value of Avogadro number 6.023x 102% mo and the value of Boltzmann constant is 1.380x10-23 |
K-l then the number of significant digits in the calculated value of the universal gas constant is
(JEE-2014]
Paragraph For Question (Q.5 to 6)
X and Y are two volatile liquids with molar weights of 10g mo' and 40 g mol respectively. Two cotton
plugs, one soaked in Xand the other soaked in Y, are simultaneously placed at the ends of a tube of length I.
=24 cm, as shown in the figure. The tube is filled with an inert gas at 1 atmosphere pressure and a
temperature of 300K. Vapours of X and Y react to form a product which is first observed at distance d cm
from the plug soaked in X. Take X and Y to have equal molecular diameter and assume ideal behaviour for
the inert gas and the two vapours. (JEE-2014]

L=24 cm

Cotton wool Cotton wool

soaked in X soaked in Y
Initial formation of
the product
*5. The value of d in cam (shown in the figure), as estimated from Graham's law, is
(A)8 (B) 12 (C) 16 (D) 20

*6. The experiment value of d is found to be smaller than the estimate obtained using Graham's Baw. This is due to
(A) larger mean free path for X as compared to that of Y.
(B) larger mena free path for Y as compared to that of X.
(C) increased collision frequency of Y with the inert gas as compared to that of X with the inert gas.
(D) increased collision freguencyof X with the inert gas as compared to that of Y with the inert gas.

110
 Gaseous state
ALLBNO

a monoatomic real gas satisfies the equation p(V - b) = RT where b is a constant. The
One mole of potential V(r) and interatomic distancerfor the gas is given by (JEE-2015]
7.
relationship of interatomic

(A)
V(r)|
(B)
V(r)
(C)
V(r)
r
(D)
t
mean speed, The absolute
The diffusion coefficient of an ideal gas is proportional to its mean free path and
"8. tormnerature of an ideal gas is increased 4 times and its pressure is increased 2 times. As a result. the diffusion
coefficient of this gas increases x times. The
value of x is (JEE-2016]

Aclosed tank has two compartments A and B, both filled with oxygen (assumed to be ideal gas). The partition
senarating the two compartments is fixed and is a perfect heat insulator (Figure 1). If the old partition is
«9.
ronlaced by a new partition which can slide and conduct heat but does NOT allow the gas to leak across
(Figure 2), the volume (in m°) of the compartment A after the system attains equilibrium is :
[JEE-2018]

1m, 5 bar, 3 m 1bar, 300 K

400 K B
A

Figure 1

A B

Figure 2
10. Which of thefollowing statement(s) is (are) correct regarding the root mean square speed (U,m)and average
translational kinetic energy (E)of a molecule in a gas at equilibrium? [JEE-2019]
(A) msU. is doubled when its temperature is increased four times
(B) E ata given temperature does not depend on its molecular mass
(C)Ums is inversely proportional to the square root of its molecular mass
(D) E, is doubled when its temperature is increased four times

11. Agas has a compressibility factor of 0.5 and a molar volume of 0.4 dm mol at a temperature of 800 Kand
pressure x atm. If it shows ideal gas behaviour at the same temperature and pressure, the molar volume will be
ydm² mol', The value of X is [JEE-2023]

[Use: Gas constant, R = 8x 102 Latm K-'mol]

-111
 JEE-Chemistr1'
ALLEN
ANSWERS
EXERCISE-1
Que. 1 3 4 5 7 8 10 11 12 13
Ans. B C A A D B D B
Que. 14 15 16 17 18 19 20
Ans. B C A D

EXERCISE-2
MULTIPLE CHOICE CORRECT QUESTIONS
1 (AB) 2 (BCD) 3 (ABCD) 4. (BD) 5. (ABC)
6. (AD) 7. (ABC) 8. (BC) 9. 10.
(ABC) (CD)
COMPREHENSION BASED QUESTIONS
11. (A) 12. (C) 13. (C)

EXERCISE-3
NUMERICAL ANSWER BASED QUESTIONS
1. P= 0.062 atm. T=75 k 2. (4) 3. (5) 4. 3.8 x 10 kPa
5. (16)

MATRIX MATCH QUESTIONS

6. (A) - (w), (B) - (u), (C) - (v), (D) - (p), (E) - (x), (F) - (y), (G) - (r), (H) - (g), () - (s), (J) - (t)
7. (A) - (r), (B)- (s), (C) - (p), (D) - (q)
8. (A) - (gt), (B) - (r), (C) - (ps), (D) - (p)
EXERCISE-4(A)
Que. 1 2 3 4 5 6 7 8 10 11 12 13 14 15
Ans. 3 3 4 4 3 13 4 1 3
Que. 16
Ans.

EXERCISE-4(B)
SECTION -1SINGLE CORRECT CHOICE QUESTIONS
Que. 123 45 6 9 10 11 12 13
Ans. 1 - 1 3 4 2 2 4 4 3 4 4 4
Que. 14
Ans. 1
SECTION -2 NUMERICAL ANSWER BASED QUESTIONS
Que. 1 2 3 4 5 67 8 910 11 12 13
Ans. 750 5 70 1 150 29 45 32 4 1655 22 2
Que. 14 15 16 17
Ans. 25 2 3 1567

EXERCISE-5
1. (ACor ACD) 2. (B) 3. M, = 4. 4. (4) 5. (C)
6. (D) 7. (C) 8. (4) 9. (2.22) 10. (ABC)
11. (100)

112