과 목 : G eneral Chem istry

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 14 .
4

00 m 50
M CcOv]=5
. 80 mlz
0 = 16 .

0
.

= 0. 00-

= Hocg t
Hcg ) t cov (g ) ) cocg
)
I θ-
16 o -
l6 0 00
. OOO

x x tx tx
C
-

E f x 16 x x
o - O .
-

CHho ] Cco )
Kc
2
- x
= =
4
CH . 3 ( col xx
co - 1 - b

x
-
= 2 →
o 1b -

x x =

C > = o . onM . [ con ] = oo 5 u , CH 20] = 01 M , CC =

14 58
.

the reacfioniS . if raised

ca)
endotherhic S .
femperatove ,

Sastem ulichamge from leff fo right to remove heat .

cb ) Zf d (g)2
implied, Sustem
i ulichamge fom right to left

to vemove
dacg )

If Pas (g) removed, sustem

CC ) is
ulichamge Ifromlefftoright
tt male move pas (g )

(d ) If isincheased, Sastm well < mangefronm right to left

Nnessuve
fo decrease presswre
ce) If catalest is added .
fhe rate of reacfron increases
14 62
.

KP = CCov)

incoeaselc ull from leffto

ac) If volume is , sustem change

fhevefove decaease Voluner

right t
8 increae Presswle ,

C) If Cao is added , thee is no

alrge Change of Volcne .
So theve

is no change in neactioni

CC ) . Removvy Caco3 do not

chonge Volone S
.theve [s no
changee
cd , If coz is added .
Kp ull be increased . So sastem ull

shiff toleftt

ce ) reactiow
IF Oaot isadded, the

CO 2 (g) + NooH ( aq) → (Oallcon (af )

uli
happen S .fle
presswve ofCozis decreased, eventually

Sustem shiff to rigut to supply Corcg ) .

Cf ) If Ha solutrou isadded )

Caco 3 (s) t tCo

g) tto ( l
2lt cack. laq) )
caq)
s
2

uli be happened . f. hedue Pwduced COzcg ) ,

Sastem shiff

toleff .

endothermic So incueased
cg) This reactcon Is ( f
femperatwve ,

Sustem shiff fom leff to right .

14 72
.

=( . 60 ) =

Kp= PA 0 0

PB . 60 p-(
-

PA + PB =
1 5
. atm > PB= 1 .5 -
PA

( 1. -PA 5

ICp =
-
)
AtPA -1 . 5 =0

PA
2

By fhe
Solvrng quadvaticebuatcon ( ,

PA = 0 . 69 atm ,
PB = o & latum .

14 84 ,

N2 +← H ,
I 0 .
862 0 . 373

x 3x 12x
C
-

U &62 x U 323 3x 2X
E
-

-
- .

'

( RoH)) 104
4 31 ×
Kp
- =

PHl73
= .

XPN .

2
( 2x ) 4
. 31 × 10
-

= (
( 0 m73 3× 3 0. 862- ) - x

Bgapproximatron :

0 . 373 -3 x ≈ 07 0862 -x ≈ 0 .
802

=
x2
4 4
. 31 × 104
0 n 3y 0 . 862-

A= 2 .20 xlo 3 alm

 x 20 x (0 3 )
-

Puz = 0 862 -
=
o .

860 atm

)
PHz =
on7 n -

nx ( 202× 10 m = 0
. 3 bbatm

Ror =
2x ( 220x 10 -
)
= 4
- 40 xl 0 3 atm
-

15 6
-

acid thethingthatbase uth (H + )

conjugate is proton
( a ) Hs ( b )H 2 co3 LC ) HCO ; (d) Hspo 4 Ce ) 2 po←

( f ) HPO 42 SO4 M 7 HSo

-

( H Li ) HS 65
-

(
g) 4

15 .
20

+
- g ] 520
IPH
=
ca)
10
=

-
520
6 3 X 10 6
CHx ] 10
-

= = .

- gcHt) =
16 00
C ∞) pH =
10 .

1
- 0 × 101600 M
=

14
CC ) Kw= CHtJcoH ] = -o × 1-
1

. 0× 4=
- 2 .. 0 ,
-
=

37 × 009
H]

15 26 .

[ d] =
io
mallfug
x
364
z -
= 0 . 762 M
-
60nlon

01 (
- 10 g cHty -l
0 gcHa - g (0262 ) =

.
.

PH
= )
=
1
=