Wrong Answered Questions

5 A cyclic process ABCD is shown in the P-V diagram. Which of the following curves represent the same process?

A
✓

C You marked
✘

14 For a particular ideal gas, which of the following graphs represents the variation of mean squared velocity of the gas molecules with
temperature?

A
✓

C You marked
✘
 D

24 One mole of a monoatomic ideal gas occupies two chambers of a cylinder partitioned by means of a movable and frictionless piston. The
walls of the cylinder as well as the piston are thermal insulators. Initially equal amounts of gas fill both the chambers at . The left
chamber is slowly heated by an electric heater. The gas in the left chamber expands, pushing the piston to the right. The gas on the right

chamber is compressed until the pressure becomes . The final volume of left chamber is then the value of x is____

YOUR ANSWER 1

CORRECT ANSWER 15

47
The total number of sigma and Pie bonds in 4 – Ethyl – 2, 6 – dimethyldec – 4 – ene

YOUR ANSWER 37

CORRECT ANSWER 42

49
A straight chain hydrocarbon has the molecular formula, The hybridization for the carbon atoms from one end of the chain to the other
are respectively, The lowest position of the double bond according to IUPAC name of the compound is

YOUR ANSWER 2

CORRECT ANSWER 3

61 The domain of the function is

B You marked
✘
C
✓
D

65 If then the domain of is

 A You marked
✘

D
✓

Not Visited Questions

2 Consider the shown diagram where the two chambers separated by piston-spring arrangement contain equal amounts of certain ideal gas.
Initially when the temperatures of the gas in both the chambers are kept at 300 K the compression in the spring is 1m. The temperature of the
left and right chambers are now raised to 400k and 500k respectively. If the pistons are free to slide, the compression in the spring is about

A 1.3m
✓
B 1.5m

C 1.1m

D 1.0m

3 The heat (Q) supplied to a solid, which is otherwise thermally isolated from its surroundings, is plotted as a function of its absolute
temperature . It is found that they are related by the equation. (a, b are constants) The heat capacity of the solid is given by

D
✓
6 When a block of iron floats in mercury at a fraction of its volume is submerged, while at the temperature a fraction is seen
to be submerged. If the coefficient of volume expansion of iron is and that of mercury is then the ratio can be expressed as
 A
✓

7 Two elastic rods are joined between fixed supports as shown in figure. Condition for no change in the lengths of individual rods with the
increase of temperature. ( =linear expansion coefficient, )

D
✓
8 The maximum attainable temperature of ideal gas in the process where and are +ve constants is

A
✓

D
9 Let V denote the root mean square speed of the molecules in an ideal diatomic gas at absolute temperature T. The mass of a molecule is 'm'.
Neglecting vibrational energy terms, which is false?

A A molecule can have a speed greater than

B Vis proportional to

C The average rotational kinetic energy of a molecule is

✓
D The average kinetic energy of a molecule is

11 A cylinder contains and , of equal volume. They are separated by massless freely moving piston as shown. If the gas is adiabatically
compressed by moving the piston so that volume of He becomes half. Finally:

A pressure in chamber will be equal to 4 times pressure in chamber

B pressure in chamber will be less than pressure in chamber

C volume of chamber will be equal to volume of chamber

D volume of chamber will be ✓

13 A cubical box of side 1 m contains helium gas (atomic weight 4) at a pressure of . During an observation time of 1sec, an atom
travelling with the root mean square speed parallel to one of its edges of the cube, was found to make 500 collisions with a particular wall,
without any collision with other atoms. Taking and .
The temperature of the gas is

A 160 K
✓
B 210K

C 280K

D 320 K

15 One mole of a mono-atomic gas is supplied heat in such a way that its molar specific heat during the heating process is 2R, here R is the
universal gas constant. If due to heating, volume of the gas is doubled, by what factor does its temperature change?
 A 1/4

B 1/2

C 2

D 4
✓
16 An ideal mono-atomic gas is trapped in a cylinder closed at its right end. The cylinder is divided into two parts by a fixed heat-conducting
partition and a piston that is to the left of the fixed partition. The piston and walls of the cylinder cannot conduct heat. Masses of the gas in
the left and right parts are and .A force F applied on the piston is slowly increased, starting form some initial value. What is the molar
specific heat of the gas in the left part during this process?

D
✓
18 The P – V diagram of 2gm of helium gas for a certain process is shown in the figure, then the heat given to the gas during the process
is____

B
✓
C

D
20 A gas is found to be obeyed the law constant. The initial temperature and volume are . If the gas expands to a volume , then
the final temperature becomes

A
✓
B

21
0.014 kg of nitrogen is enclosed in a vessel at a temperature of . Heat (in kJ) has to be transferred to the gas to double the r.m.s. velocity
of its molecules is closer to-

SKIPPED

CORRECT ANSWER 9

22 An ideal gas is kept in a long cylindrical vessel fitted with a frictionless piston of cross-sectional area and weight 1 kg. The vessel itself
is kept in a big chamber containing air at atmospheric pressure 100 k Pa. The length of the gas column is 20 cm. If the chamber is now
completely evacuated by an exhaust pump, will be the length of the gas column. Assume the temperature remain constant

throughout the process. Then the value of is____

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CORRECT ANSWER 2

23 A thermodynamic system is taken from an initial state with internal energy to the final state of along two different paths
and , as schematically shown in the figure. The work done by the system along the paths and bf are
and respectively. The heat supplied to the system along the path and bf are and respectively. If the

internal energy of the system in the state b is and , The ratio is

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CORRECT ANSWER 2

25
The molecules of a given mass of a gas have rms. velocity of at and pressure. When the temperature and pressure of
the gas are respectively 400 K and , the rms. velocity of its molecule becomes . Find the value of .
 SKIPPED

CORRECT ANSWER 2

32 Which of the following statement is not correct:-

A Cyclobutane is a planar compound

B Trans cyclohexadecene is relatively more stable than its cis form

C Cis form of 1,3,5-trimethylcyclohexane is relatively more stable than its trans form

D Cis 1,2-dichloroethene is relatively more stable than its trans form.

33 Arrange in the correct order of stability (decreasing order) for the following molecules:

A (I) > (II) > (III) > (IV)

B (IV) > (III) > (II) (I)

C (III) > (I) (II) > (IV)

✓
D (I) > (II) (III) > (IV)

36 In the following the most stable conformation of n-butane is

B
 C
✓

37 The correct statement regarding the comparison of staggered and eclipsed conformation of ethane, is:-

A The staggered conformation of ethane is less stable than eclipsed conformation, because staggered conformation has torsional strain

B The eclipsed conformation of ethane is more stable than staggered conformation, because eclipsed conformation has no torsional strain

The eclipsed conformation of ethane is more stable than staggered conformation even though the eclipsed conformation has torsional
C
strain

D
The staggered conformation of ethane is more stable than eclipsed conformation, because Staggered
conformation has no torsional strain. ✓
38 The number of and H atoms in the following compound is respectively,

A 5,4
✓
B 5,5

C 6,5

D 6,6

41 In Dumas' method for estimation of nitrogen, 0.5 gram of an organic compound gave 60 mL of nitrogen collected at 300 K temperature and
715 mm Hg pressure. The percentage composition of nitrogen in the compound (Aqueous tension at 300 K = 15 mmHg) is

A 1.257

B 20.87

C 18.67
 D 12.57
✓
42 Three organic compounds A, B and C were allowed to run in thin layer chromatography using hexane and gave the
following result (see figure). The value of the most polar compound is the value of is_____

A 50

B 25
✓
C 75

D 12.57

48 In how many of the following molecules, Gauche form is more stable,

(Ethylene Glycol, 2-fluoro-Ethanol, 2- Amino- Ethanol, Glycerol, 3-bromo propane)

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CORRECT ANSWER 4

53
If and then the graph of is

A A circle

B A straight line
✓
C A parabola

D Ellipse

54
Let such that then

A
 B

C
✓
D

55
Let and be defined as and Then, is

A one – one but not onto

B neither one – one nor onto

✓
C onto but not one – one

D both one – one and onto

56
The value of

B
✓

57 If then the range of the function in is (where [. ] denotes the greatest integer function)

B
✓

D
58
The sum of the real values that the function cannot take is

A 2

B –3

C
✓

59
For each let be the greatest integer less than or equal to . then is equal to

A 0

B 1

C sin 1

D – sin 1
✓
60
Let the term be then the value of

A 0

B
✓

D 1

62
If is a onto function, then set of values of ‘a’ is:

A
✓

C
 D Null set

63

A
✓

64 If then the range of is

B
✓
C

66 Number of solutions of the equation is

(where and is greatest integer function)-

A 0
✓
B 1

C 2

D Infinite

67
is-

A 0
 B 4

C 2
✓
D does not exist

68
Let be defined where is onto function. If and are minimum and maximum value of p respectively,

then is equal to

A 1.5
✓
B 1.7

C 2.3

D 3.3

69

A 1

B 0

D
✓
70

Let be a function such that and then the value of is

A 0.5

B 0.6
✓
C 0.7

D 0.8
71

If where [.] denotes the G.I.F and {t} represents the functional part of t then is equal to ….

SKIPPED

CORRECT ANSWER 1

72

If and then the value of expression is_____

SKIPPED

CORRECT ANSWER 1

73

If then is equal to

SKIPPED

CORRECT ANSWER 5

74
If then the value of is:
[Note: [k] and {k} denote greatest integer and fractional part functions of k respectively]

SKIPPED

CORRECT ANSWER 73