07-09-2025 SR - Super60 Sterling BT Jee-Adv (2021-p1) Rpta-05 Q. Paper
07-09-2025 SR - Super60 Sterling BT Jee-Adv (2021-p1) Rpta-05 Q. Paper
07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Syllabus
PHYSICS : Gravitation: Law of gravitation, Gravitational potential and field, Acceleration due
to gravity, Kepler’s law, Motion of planets and satellites in circular orbits, Escape
velocity, Geostationary orbits (Important for ADVANCED)
Electrostatics: Coulomb’s law, Electric field and potential, Electrical potential
energy of a system of point charges and of electrical dipoles in a uniform
electrostatic field, Electric field lines.
CHEMISTRY : Aldehydes & Ketones: Preparation of aldehydes and ketones from acid chlorides
and nitriles, aldehydes from esters, benzaldehyde from toluene and benzene,
conversion of alcohols into aldehydes and ketones Reactions: oxidation, reduction,
oxime and hydrazone formation, Aldol condensation and Family aldol reactions, .
Cannizzaroreaction, haloform reaction and nucleophilic addition reactions with
RMgX, NaHSO3, HCN, water, alcohol, RSH, amine and derivatives
MATHEMATICS : Definite Integration
JEE-ADVANCE-2021-P1-Model
Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve
No.of Total
Section Question Type Mark Mark
Qs marks
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 20 – 23) Questions with Single Correct Choice +3 -1 4 12
Paragraph Questions with Numerical
Sec – II(Q.N : 24 – 29) +2 0 6 12
Value Answer Type
Questions with Multiple Correct Choice
Sec – III(Q.N : 30 – 35) +4 -2 6 24
with partial mark
Questions with Non-negative Integer
Sec – IV(Q.N : 36– 38) +4 0 3 12
Value Type
Total 19 60
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 39 – 42) Questions with Single Correct Choice +3 -1 4 12
Paragraph Questions with Numerical
Sec – II(Q.N : 43 – 48) +2 0 6 12
Value Answer Type
Questions with Multiple Correct Choice
Sec – III(Q.N : 49 – 54) +4 -2 6 24
with partial mark
Questions with Non-negative Integer
Sec – IV(Q.N : 55 – 57) +4 0 3 12
Value Type
Total 19 60
3 4 5 2
A) B) C) D)
4 3 2 5
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3. A non- conducting ring of mass m and radius R is charged as shown in figure and
placed on a rough horizontal non conducting plane. The charge per unit length on the
charged quadrants of ring is . At time t=0 , a uniform ,electric field E=Ei is switched
on and the ring starts rolling without sliding. Determine the magnitude and direction of
friction force acting on the ring when it starts rolling
x GM 0
5. The gravitational field at A is then x y _____
y R2
x GM 0
6. The gravitational potential at B is then x y _____
y R
Question Stem for Question Nos. 7 and 8
Question Stem
An artificial satellite is moving in a circular orbit around the earth with a speed equal to
half the magnitude of escape velocity from the earth. g 10m / s 2 ,Re 6400km
7. The height of the satellite above the earth’s surface is ______ 105 m
8. If the satellite is stopped suddenly in its orbit and allowed to fall freely onto the earth,
the speed with which it hits the surface of the earth is _____ km/sec
Question Stem for Question Nos. 9 and 10
Question Stem
An electric dipole is placed at a distance x form center O on the axis of a charged ring of
radius R and charge Q uniformly distribution over it.
2 2
aqQ R 2x
9. The net force acting on the dipole is then ______
2 0 2
R x 2
aqQx
10. The work done in rotating the dipole through 1800 is . Then =____
0 R 2 x 2
SECTION-III
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains SIX (06) questions.
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct answer(s).
For each question, choose the option(s) corresponding to (all) the correct answer(s).
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen,
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct:
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If unanswered;
Negative Marks: -2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to the correct answer, then
Choosing ONLY (A), (B) and (D) will get +4 marks;
Choosing ONLY (A), will get +1 mark;
Choosing ONLY (B), will get +1 mark;
Choosing ONLY (D), will get +1 mark;
Choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
Choosing any other option(s) will get -2 marks.
11. A pair of stars rotate about its common centre of mass. One of the stars has a mass M
and the other has mass m such M=2m. The distance between the centres of the stars is d
(d being large compared to the size of either star)
4π 2 3
A) The period of rotation of the stars about their common centre of mass is d
3Gm
2π 2 3
B) The period of rotation of the stars about their common centre of mass is d
Gm
C) The ratio of the angular momentum of the two stars about their common centre of
mass L m /LM is 2
D) The ratio of the angular momentum of the two stars about their common centre of
mass L m /L M is 1
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12. A planet of mass M, has two natural satellites with masses m1 and m2. The radii of their
circular orbits are R1 and R2 respectively. Ignore the gravitational force between the
satellites. Define v1, L1, K1 and T1 to be respectively, the orbital speed, angular
momentum, kinetic energy and time period of revolution of satellite 1: and v2,L2, K2 and
T2 to be the corresponding quantities of satellite 2. Given m1/m2=2 and R1/R2=1/4,
v1 L1 K1 T1 1
A) 2 B) 1 C) 8 D)
v2 L2 K2 T2 8
13. A planet of mass M moves along an ellipse around the sun, so that its maximum and
minimum distances from the sun are r1 and r2 respectively. Then
V1
M
m r1 S r2
V2
A) V1r1 =V2 r2
B) Total energy of plant is always a constant
2GM r1r2
C) Angular momentum of plant is m
r1+r2
D) V2 r1 =V1r2
14. The following figure shown a block of mass m suspended from a fixed point means of a
vertical spring. The block is oscillating simple harmonically and carries a charge q.
There also exists a uniform electric field in the space. Consider four different cases. The
electric field is zero, in case -1, E=mg/q downward in case-2, E=mg/q upward in case-3
and E=2mg/q downward in case-4. The speed at mean position of block is same in all
cases. Select which of the following statements is/are correct:
kq 2 2 1
A) Force on each corner charge is + N
a2 2 2 3 3
8kq 2
B) Force on a charge placed at centre of cube is N
2
3
a
2
27/2 kq
C) Electric field at centre of top face is
33/2 a 2
D) Electric field at centre of top face is directed along area vector of the face.
SECTION-IV
(INTEGER ANSWER TYPE)
This section contains THREE (03) question.
The answer to each question is a NON-NEGATIVE INTEGER.
For each question, enter the correct integer corresponding to the answer the using the mouse and the on-screen virtual numeric keypad in the
place designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.
17. For a certain hypothetical planet revolving around a star, the total energy is given as
GMm
E , where M is the mass of the star, ‘m’ is the mass of the planet, l is a certain
40l
distance and it is given that M>>m. The distance between the planet and the centre of the
star at the perigee position is 4 l . The velocity of the planet at perigee is Vp and that at
Vp
the apogee is Va and the ratio =___
Va
R 9GM 2
compression at a depth from surface is then x=____
2 32 R x
19. A solid non-conducting sphere of radius R is charged with a uniform volume charge
density . Inside the sphere a cavity of radius r is made as shown in figure. The distance
between the centre of the sphere and the cavity is a. An electron e is kept inside the cavity
and angle =450 as shown. If at t=0 this electron is released from point P. The time it will
s 2mr 0
take to touch the sphere on inner wall of cavity again is . Then s is ____
e a
O O
Re agent O O O
O I
Me Me
Me O
A Me
B
Reagent
II
Reagent Reagent
O O III
Me IV O O O O O
Me Me Me
H OH
E D C
Reagent
V
O
Me
Me
F
The different reagents are given as
X OH
OH
V H 3O
U NH 2 NH 2 W PCC ,
i) Li AlD4
ii) H O+
3
O H H O D
A) O D B) C) D D)
H H D
22. An organic compound A (C6 H12O) neither decolourise bromine water nor changes the
colour of acidic dichromate solution A on heating with H2SO4 produces an alkene which
on oxidative ozonolysis gives B(C6H10O3) which gives an yellow precipitate with
NaOH/I2 the most probable structure of A is
A) OMe B) OH
OH OH
C)
D)
A) O B) OH
CH CHO
O O
C) OH D) O
COOH
CH-COOH CH
O OH
SECTION-II
(PARAGRAPH WITH NUMERICAL VALUE TYPE)
This section contains THREE (03) questions stems.
There are TWO (02) questions corresponding to each question stem.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the on-screen
virtual numeric keypad.
If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.
Question Stem for Question Nos. 24 and 25
Question Stem
One of the well known rearrangement is the formation of N-Substituted amides by
rearrangement of aldoximes or ketoximes this is known as Beckmann rearrangement It
is catalyzed by various acidic reagents the mechanism of this reaction is given as
+
R
O H2
R
C=N H C=N H O
OH
H 2O
O H 2 R1-C =N-R 2 R1 -C=N-R
R 1
1 R 1
2 3
4
OH OH
R C NH R R1 C N R
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Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P
24. Rate – determing step in Beckmann rearrangement is
CH 3
OH
C=N
25.
H
product p ;the molecular weight of product p is x.Then 2
x
2,4-DNP, gives yellow ppt on heating with I2 in presence of NaOH It neither reduce
Tollen’s or Fehling reagent nor does it decolonize Br2 water or Bayer’s regent on drastic
oxidation with chromic acid H 2CrO4 it gives an acid (Q) having molecular formula
C7H6O2
dil.OH
3 CH MgBr 1mole
27. P
S
T No. of stereo isomers in the final product T is
H3O
Δ +
O O O O
H O-H H
Ph - CO
2 +Ph - CH2 - OH
O
H3C O
O O
CHO J) H C
F) G) CHO 3
H) I)
CHO CH 3
O
O CH 3 CH 3
H CH 3
K) CH 3 M)
L)
H 3C
H 3C CH 3 N)
O O
SECTION-III
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains SIX (06) questions.
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct answer(s).
For each question, choose the option(s) corresponding to (all) the correct answer(s).
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen,
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct:
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If unanswered;
Negative Marks: -2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to the correct answer, then
Choosing ONLY (A), (B) and (D) will get +4 marks;
Choosing ONLY (A), will get +1 mark;
Choosing ONLY (B), will get +1 mark;
Choosing ONLY (D), will get +1 mark;
Choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
Choosing any other option(s) will get -2 marks.
30. Which of the following is correct for the final product of the given sequence of reaction
MgBr
CH 2 -OH
HIO4 i
P1 i)
PCC
P2
ii CH 3 MgBr P3 (Final product)
CH2 -OH ii) H 2 O
iii H 2 O
O CHO
O
O
C)
B) C-O-C-CH3 D) CHO
A) O
O O CHO O O
O
i O dil .HO
3 A products
ii Me2 S Δ
32
In the above sequence the final products of the reaction is / are
O
O O CHO
A) CHO
B) D)
C)
CHO CHO
O
33 Benzene
Et-C-Cl
AlCl
P1
3
NH 2 NH 2 / O H
cl2 / h
P2 P3 ;Reagent R is
aq. NaOH
R
P4
34. O
dil.H 2SO 4
P1 +P2
H
Reaction -1
1) AC2 O, Aco Na,Δ
2) H o + ,Δ
A
3
36
OH
Reaction-2 Ph-CH=CH-CH-CH 3
1) NaOI
2) H
B
Degree of unsaturation present in compound A B is
37. What is the molecular weight of a compound that undergoes an aldol self condensation
reaction and whose dehydrated product has a molecular weight of 70
38. How many products are possible when ethanal and phenyl ethanal mixture is treated with
dil. NaOH about 00 C. (including stereo isomers)
sin 2 x -1 cos 2 x
40. If y= 1
sin tdt + 1 cos -1 tdt , where 0 x π/2, is the equation of a
8 8
straight line parallel to the x-axis , its equation is
π -3π 3
A) y = B) y = C) y= D) y=
16 16 16 4
dx
_____(. is G.I .F )
3
41. 1
x x 1 2 x x
2 2
π π 3π 5π
A) B) C) D)
4 2 4 4
42. Let f(x) be a non-negative continuous function defined on R such that
1 1500 9000
f x +f x+ =3 and the value of f x dx then
2 0
A) 2 B) 1 C) 3 4) 4
SECTION-II
(PARAGRAPH WITH NUMERICAL VALUE TYPE)
This section contains THREE (03) questions stems.
There are TWO (02) questions corresponding to each question stem.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the on-screen
virtual numeric keypad.
If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks: 0 In all other cases.
cot
x tan 1 x dx . is G.I .F p q.cot q then
1
If
0
45. P _____
q5
46. _____
10
Question Stem for Question Nos. 47 and 48
Question Stem
3 3
Let gi : , R, i 1, 2 and f : , R be functions such that
8 8 8 8
g1 x 1 , g 2 x 4 x , f x sin x
2
3
8
3
x , and Si
8 8 f x gi x dx (i=1,2)
8
48S1
47. The value of ____
32S 2
48. The value of =____
2
x2 y 2 3 fff.....f e
conjugate hyperbola 2 2 1, then
a b 1 n times
de is equal to
/4 1 /4
C) xf x dx D) f x dx 1
o 6 o
51 52
f x dx f x dx
46
A) 125 B) f x dx C) D)
4 1 2
n
A) u1 B) un C) un un 1 D) u1, u2 , u3..... are in A.P
2 2 2
x dx, I
53. Let I1
104
0
x
10
2 0 x x
2
dx where x is fractional part of x , then which
5
then the value of 3 g x dx is
2
1 x3 x 2 2 x dx equal to
3
57. The value of 0
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Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P