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07-09-2025 SR - Super60 Sterling BT Jee-Adv (2021-p1) Rpta-05 Q. Paper

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18 views22 pages

07-09-2025 SR - Super60 Sterling BT Jee-Adv (2021-p1) Rpta-05 Q. Paper

Uploaded by

lkishi.shalu
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© © All Rights Reserved
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Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI


A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_STERLING BT RPTA-05 Date: 07-09-2025
Time: 09:00AM to 12:00PM JEE-ADV(2021-P1) Max. Marks: 180

07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Syllabus
PHYSICS : Gravitation: Law of gravitation, Gravitational potential and field, Acceleration due
to gravity, Kepler’s law, Motion of planets and satellites in circular orbits, Escape
velocity, Geostationary orbits (Important for ADVANCED)
Electrostatics: Coulomb’s law, Electric field and potential, Electrical potential
energy of a system of point charges and of electrical dipoles in a uniform
electrostatic field, Electric field lines.
CHEMISTRY : Aldehydes & Ketones: Preparation of aldehydes and ketones from acid chlorides
and nitriles, aldehydes from esters, benzaldehyde from toluene and benzene,
conversion of alcohols into aldehydes and ketones Reactions: oxidation, reduction,
oxime and hydrazone formation, Aldol condensation and Family aldol reactions, .
Cannizzaroreaction, haloform reaction and nucleophilic addition reactions with
RMgX, NaHSO3, HCN, water, alcohol, RSH, amine and derivatives
MATHEMATICS : Definite Integration

Name of the Student: ___________________ H.T. NO:


Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P

JEE-ADVANCE-2021-P1-Model
Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve
No.of Total
Section Question Type Mark Mark
Qs marks

Sec – I(Q.N : 1 – 4) Questions with Single Correct Choice! +3 -1 4 12


Paragraph Questions with Numerical
Sec – II(Q.N : 5 – 10) +2 0 6 12
Value Answer Type
Questions with Multiple Correct Choice
Sec – III(Q.N : 11 – 16) +4 -2 6 24
with partial mark
Questions with Non-negative Integer
Sec – IV(Q.N : 17 – 19) +4 0 3 12
Value Type
Total 19 60

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 20 – 23) Questions with Single Correct Choice +3 -1 4 12
Paragraph Questions with Numerical
Sec – II(Q.N : 24 – 29) +2 0 6 12
Value Answer Type
Questions with Multiple Correct Choice
Sec – III(Q.N : 30 – 35) +4 -2 6 24
with partial mark
Questions with Non-negative Integer
Sec – IV(Q.N : 36– 38) +4 0 3 12
Value Type
Total 19 60

MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 39 – 42) Questions with Single Correct Choice +3 -1 4 12
Paragraph Questions with Numerical
Sec – II(Q.N : 43 – 48) +2 0 6 12
Value Answer Type
Questions with Multiple Correct Choice
Sec – III(Q.N : 49 – 54) +4 -2 6 24
with partial mark
Questions with Non-negative Integer
Sec – IV(Q.N : 55 – 57) +4 0 3 12
Value Type
Total 19 60

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Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P
PHYSICS Max Marks: 60
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 4 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases. Section 1 (Max Marks: 12)
 Section 1 contains Four questions
 Each Question has Four Options and Only One of these four will be the correct answer.
 For each question, choose the option corresponding to the correct answer
 The Marking scheme to evaluate Answer to each question will be :
 Full Marks: +3 (If the answer is correct)
 Zero Marks: 0 (If the question is unanswered)
 Negative Marks: -1 (In all other cases)
1. An asteroid of mass m (<<M) was fast approaching the earth of mass ‘M’, Scientists
fires a racket which hit the asteroid at a distance 5R from the centre of the earth, where
R is radius of earth. Immediately after the hit the asteroids velocity V0 was making a
angle of θ=300 with the line joining the center of the earth the asteroid. The asteroid just
grazed past the surface of the earth. Find its speed when it grazes the earth.

32GM 16GM 64GM 40GM


A) B) C) D)
105R 21R 105 R 21 R
2. If the law of gravitation be such that the force of attraction between two particles vary
inversely as the (5/2)th power of their separation , then the graph of orbital velocity V0
plotted against the distance r of a satellite from the earth’s centre on a loge-loge scale is
as shown. The modulus of slope of the line will be

3 4 5 2
A) B) C) D)
4 3 2 5
SEC: Sr.Super60_STERLING BT Space for rough work Page 3
Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P
3. A non- conducting ring of mass m and radius R is charged as shown in figure and
placed on a rough horizontal non conducting plane. The charge per unit length on the

charged quadrants of ring is  . At time t=0 , a uniform ,electric field E=Ei is switched
on and the ring starts rolling without sliding. Determine the magnitude and direction of
friction force acting on the ring when it starts rolling

A)  RE0 along negative x-axis B)  RE0 along positive x-axis


C) 2 RE0 along negative x-axis D) 2 RE0 along positive x-axis
4. Four point charges, each of charge +q, are rigidly fixed at the four corners of a square
planner soap film of side ‘a’. The surface tension of the soap film is  . If the system of
charges and planar film are in equilibrium, then side of square is given as
1/N
 q2 
a=k   , Find the values of k and N.
 σ 
1/3 1/3
 1  1   1  1 
A)   1  ,3 B)   1  ,3
 8 0  2 2    4 0  2 2  
1/3 1/3
 1  1   1  1  1
C)   1  ,3 D)   1   ,
 4 0  2   4 0  2 2   3
SECTION-II
(PARAGRAPH WITH NUMERICAL VALUE TYPE)
 This section contains THREE (03) questions stems.
 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the on-screen
virtual numeric keypad.
 If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks: +2 If ONLY the correct numerical value is entered at the designated place;
 Zero Marks:0 in all other cases

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Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P
Question Stem for Question Nos. 5 and 6
Question Stem
R
From a uniform sphere of radius ‘R’ a spherical cavity of radius is removed from the
2
edge as shown. The mass of the sphere after removing cavity is M0. Consider points
A,B,C,D. Assume potential at infinity is zero. ‘C’ is the centre of the cavity and AB = R

x GM 0
5. The gravitational field at A is then x  y  _____
y R2
x GM 0
6. The gravitational potential at B is  then x  y  _____
y R
Question Stem for Question Nos. 7 and 8
Question Stem
An artificial satellite is moving in a circular orbit around the earth with a speed equal to

half the magnitude of escape velocity from the earth. g  10m / s 2 ,Re  6400km 
7. The height of the satellite above the earth’s surface is ______ 105 m
8. If the satellite is stopped suddenly in its orbit and allowed to fall freely onto the earth,
the speed with which it hits the surface of the earth is _____ km/sec
Question Stem for Question Nos. 9 and 10
Question Stem
An electric dipole is placed at a distance x form center O on the axis of a charged ring of
radius R and charge Q uniformly distribution over it.

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Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P

 
 2 2 
aqQ R  2x
9. The net force acting on the dipole is   then   ______
2 0  2

R x 2 
  
aqQx
10. The work done in rotating the dipole through 1800 is . Then  =____
 

 0 R 2  x 2

SECTION-III
(ONE OR MORE CORRECT ANSWER TYPE)
 This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks: +4 If only (all) the correct option(s) is (are) chosen;
 Partial Marks: +3 If all the four options are correct but ONLY three options are chosen,
 Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct:
 Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
 Zero Marks: 0 If unanswered;
 Negative Marks: -2 In all other cases.
 For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to the correct answer, then
Choosing ONLY (A), (B) and (D) will get +4 marks;
Choosing ONLY (A), will get +1 mark;
Choosing ONLY (B), will get +1 mark;
Choosing ONLY (D), will get +1 mark;
Choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
Choosing any other option(s) will get -2 marks.
11. A pair of stars rotate about its common centre of mass. One of the stars has a mass M
and the other has mass m such M=2m. The distance between the centres of the stars is d
(d being large compared to the size of either star)

4π 2 3
A) The period of rotation of the stars about their common centre of mass is d
3Gm

2π 2 3
B) The period of rotation of the stars about their common centre of mass is d
Gm
C) The ratio of the angular momentum of the two stars about their common centre of
mass  L m /LM  is 2
D) The ratio of the angular momentum of the two stars about their common centre of
mass  L m /L M  is 1
SEC: Sr.Super60_STERLING BT Space for rough work Page 6
Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P
12. A planet of mass M, has two natural satellites with masses m1 and m2. The radii of their
circular orbits are R1 and R2 respectively. Ignore the gravitational force between the
satellites. Define v1, L1, K1 and T1 to be respectively, the orbital speed, angular
momentum, kinetic energy and time period of revolution of satellite 1: and v2,L2, K2 and
T2 to be the corresponding quantities of satellite 2. Given m1/m2=2 and R1/R2=1/4,
v1 L1 K1 T1 1
A) 2 B) 1 C) 8 D) 
v2 L2 K2 T2 8
13. A planet of mass M moves along an ellipse around the sun, so that its maximum and
minimum distances from the sun are r1 and r2 respectively. Then

V1

M
m r1 S r2

V2

A) V1r1 =V2 r2
B) Total energy of plant is always a constant
2GM  r1r2 
C) Angular momentum of plant is m
 r1+r2 
D) V2 r1 =V1r2
14. The following figure shown a block of mass m suspended from a fixed point means of a
vertical spring. The block is oscillating simple harmonically and carries a charge q.
There also exists a uniform electric field in the space. Consider four different cases. The
electric field is zero, in case -1, E=mg/q downward in case-2, E=mg/q upward in case-3
and E=2mg/q downward in case-4. The speed at mean position of block is same in all
cases. Select which of the following statements is/are correct:

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Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P

A) Time periods of oscillation are equal in case-1, and case-3


B) Amplitudes of displacement are same in case-2 and case-3
C) The maximum elongation (increment in length from natural length) is maximum in
case-4
D) Time periods of oscillation are equal in case-2 and case-4
15. A Charge q is revolving around another charge q as shown in a conical pendulum. The
motion is in a horizontal plane. Which of the following statements is/are correct about
this situation.

A) Tension in the string is greater than the weight of the ball


B) The tension in the string is greater than the electrostatic repulsive force.
C) If the charge is removed, the speed of the ball has to be increased to maintain the
angle.
D) If the charge is removed, the speed of ball has to be decreased to maintain the angle.

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Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P
16. Eight-point charges each of magnitude q are located on the corners of a cube of edge a.
 1 
Then.  K  
 4 0 

kq 2  2 1 
A) Force on each corner charge is  + N
a2  2 2 3 3 

8kq 2
B) Force on a charge placed at centre of cube is N
2
 3 
 a
 2 

27/2  kq 
C) Electric field at centre of top face is  
33/2  a 2 
D) Electric field at centre of top face is directed along area vector of the face.
SECTION-IV
(INTEGER ANSWER TYPE)
 This section contains THREE (03) question.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer the using the mouse and the on-screen virtual numeric keypad in the
place designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks : +4 If ONLY the correct integer is entered;
 Zero Marks : 0 In all other cases.
17. For a certain hypothetical planet revolving around a star, the total energy is given as

GMm
E , where M is the mass of the star, ‘m’ is the mass of the planet, l is a certain
40l

distance and it is given that M>>m. The distance between the planet and the centre of the

star at the perigee position is 4 l . The velocity of the planet at perigee is Vp and that at

Vp
the apogee is Va and the ratio =___
Va

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Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P
18. A uniform sphere has a mass ‘M’ and radius ‘R’. The pressure caused by gravitational

R 9GM 2
compression at a depth from surface is then x=____
2 32 R x

19. A solid non-conducting sphere of radius R is charged with a uniform volume charge
density  . Inside the sphere a cavity of radius r is made as shown in figure. The distance
between the centre of the sphere and the cavity is a. An electron e is kept inside the cavity
and angle  =450 as shown. If at t=0 this electron is released from point P. The time it will

s 2mr 0
take to touch the sphere on inner wall of cavity again is . Then s is ____
e a

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Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P
CHEMISTRY Max. Marks: 60
SECTION-I
(SINGLE CORRECT ANSWER TYPE)
 This section contains Four (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks : +3 If ONLY the correct option is chosen;
 Zero Marks : 0 If the none of the options is chosen (i.e. the question is unanswered);
 Negative Marks : -1 In all other cases.
20.

O O
Re agent O O O
O I
Me Me
Me O
 A Me
 B
Reagent
 II 
Reagent Reagent
O O  III 
Me  IV  O O O O O

Me Me Me
H OH
E  D C 
Reagent
V 
O
Me
Me
F
The different reagents are given as

X  OH
OH
V  H 3O

U  NH 2  NH 2 W  PCC ,

y =NaOH Z  LAH / H 3O  , ether

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Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P
Select the correct order in sequence in order to get the final product (F)
Reagenty I II III IV V
A) X U Z W U ,Y
B) X U Z V U ,Y
C) X Z W U ,Y V
D) X Z W U V

21. Choose the major product of the following reaction


O O
CH 3


i) Li AlD4
ii) H O+

3

O H H O D
A) O D B) C) D D)
H H D

22. An organic compound A (C6 H12O) neither decolourise bromine water nor changes the
colour of acidic dichromate solution A on heating with H2SO4 produces an alkene which
on oxidative ozonolysis gives B(C6H10O3) which gives an yellow precipitate with
NaOH/I2 the most probable structure of A is

A) OMe B) OH

OH OH
C)
D)

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Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P
23. The product of the below reaction is
o
C conc H 3O 
O C O product
OH 
H
O

A) O B) OH
CH  CHO
O O

C) OH D) O
COOH
CH-COOH CH
O OH
SECTION-II
(PARAGRAPH WITH NUMERICAL VALUE TYPE)
 This section contains THREE (03) questions stems.
 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the on-screen
virtual numeric keypad.
 If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
 Zero Marks : 0 In all other cases.
Question Stem for Question Nos. 24 and 25
Question Stem
One of the well known rearrangement is the formation of N-Substituted amides by
rearrangement of aldoximes or ketoximes this is known as Beckmann rearrangement It
is catalyzed by various acidic reagents the mechanism of this reaction is given as
 +
R
O H2
R
C=N H C=N   H O
OH 
 H 2O
O H 2   R1-C =N-R 2  R1 -C=N-R

R 1
1 R 1
 2  3
 4
OH OH

R  C  NH  R  R1  C  N  R
SEC: Sr.Super60_STERLING BT Space for rough work Page 13
Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P
24. Rate – determing step in Beckmann rearrangement is
CH 3
OH
C=N
25.
H
 product  p  ;the molecular weight of product  p  is x.Then 2
x

Question Stem for Question Nos. 26 and 27


Question Stem
An organic compound ‘p’ with molecular formula C8 H8O forms an organic red ppt with

2,4-DNP, gives yellow ppt on heating with I2 in presence of NaOH It neither reduce

Tollen’s or Fehling reagent nor does it decolonize Br2 water or Bayer’s regent on drastic

oxidation with chromic acid  H 2CrO4  it gives an acid (Q) having molecular formula

C7H6O2

26. Total number of  bonds in compound ‘P’ is

dil.OH
3 CH MgBr 1mole 
27. P 
 S 
 T No. of stereo isomers in the final product T is
H3O 
Δ +

Question Stem for Question Nos. 28 and 29


Question Stem
Mechanism of Cannizzaro’s reaction of Benzaldehyde is

O O O O

 Ph slow Ph - C - OH + Ph - CH2 -O


-
Ph C
OH
 Ph C H + C

H O-H H

Ph - CO
2 +Ph - CH2 - OH

28. Order of the above reaction is

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Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P
29. Identify compounds that give Cannizaro reaction
CHO
O O O O
E)
CH 3
A) H H B) H D C) H 3C D) H3C CH 3

O
H3C O
O O
CHO J) H C
F) G) CHO 3
H) I)
CHO CH 3

O
O CH 3 CH 3
H CH 3
K) CH 3 M)
L)
H 3C
H 3C CH 3 N)
O O

SECTION-III
(ONE OR MORE CORRECT ANSWER TYPE)
 This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks: +4 If only (all) the correct option(s) is (are) chosen;
 Partial Marks: +3 If all the four options are correct but ONLY three options are chosen,
 Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct:
 Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
 Zero Marks: 0 If unanswered;
 Negative Marks: -2 In all other cases.
 For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to the correct answer, then
Choosing ONLY (A), (B) and (D) will get +4 marks;
Choosing ONLY (A), will get +1 mark;
Choosing ONLY (B), will get +1 mark;
Choosing ONLY (D), will get +1 mark;
Choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
Choosing any other option(s) will get -2 marks.
30. Which of the following is correct for the final product of the given sequence of reaction
MgBr
CH 2 -OH
HIO4 i 
P1 i)
PCC
P2 
 ii  CH 3 MgBr  P3 (Final product)
CH2 -OH ii) H 2 O
 iii  H 2 O

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Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P
A) Compound P3 on oxidation with (CrO3+H2SO4) gives a compound which gives
2,4-DNP test
B) Compound P3 on reaction with I2+NaOH gives yellow ppt
C) Compound P3 on reaction with ceric ammonium nitrate gives red colorations
D) Compound P3 on reaction with MnO2 gives carboxylic acid
31.
+  CH3CO 2 O   4
 C product  c  is/are
H -Pd BaSo
CH3 COONa

A 
SOCl2
 B 
2
Quinoline

O CHO
O

O
C)
B) C-O-C-CH3 D) CHO
A) O
O O CHO O O

O
i O dil .HO 
  
3  A  products
 ii  Me2 S Δ
32
In the above sequence the final products of the reaction is / are
O
O O CHO
A) CHO
B) D)
C)
CHO CHO
O

33 Benzene 
Et-C-Cl
AlCl
 P1 
3
NH 2  NH 2 / O H

cl2 / h
 P2   P3 ;Reagent R is
aq. NaOH
R
P4

A) MnO2/  B) P.C.C C) Br2  H 2O D) LAH

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Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P

34. O 
dil.H 2SO 4
 P1 +P2

P1 & P2 Products are distinguished by


A) Tollen’s reagent B) Iodoform test C) 2, 4  DNP test D) 1% alkaline KMnO4
35. When 1-phenyl propyne reacts with H2O/Hg SO4/ H2SO4. The major product is
propiophenone this is because
A) Alkyl groups are weak electron donors due to inductive effect
B) Carbonyl groups are electron with drawing groups due to resonance
C) Phenyl groups can stabilize positive charge by resonance
D) The reaction is controlled by steric factors
SECTION-IV
(INTEGER ANSWER TYPE)
 This section contains THREE (03) question.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer the using the mouse and the on-screen virtual numeric keypad in the
place designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks : +4 If ONLY the correct integer is entered;
 Zero Marks : 0 In all other cases.

H
Reaction -1 
1) AC2 O, Aco Na,Δ
2) H o + ,Δ
A
3

36
OH
Reaction-2 Ph-CH=CH-CH-CH 3 
1) NaOI
2) H 
  B
Degree of unsaturation present in compound  A  B  is
37. What is the molecular weight of a compound that undergoes an aldol self condensation
reaction and whose dehydrated product has a molecular weight of 70
38. How many products are possible when ethanal and phenyl ethanal mixture is treated with
dil. NaOH about 00 C. (including stereo isomers)

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Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P
MATHEMATICS Max. Marks: 60
SECTION-I
(SINGLE CORRECT ANSWER TYPE)
 This section contains Four (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks : +3 If ONLY the correct option is chosen;
 Zero Marks : 0 If the none of the options is chosen (i.e. the question is unanswered);
 Negative Marks : -1 In all other cases.
102
 1 1 1 
39.   x-1 x-2 ....... x-100 ×  x-1 +  x-2  +...+ x-100  dx =________
0  
A) 101!-100! B) 100!-99! C) 102!-101! D)101!+100!

sin 2 x -1 cos 2 x
40. If y= 1 
sin tdt + 1 cos -1 tdt , where 0  x  π/2, is the equation of a

8 8
straight line parallel to the x-axis , its equation is
π -3π 3 
A) y = B) y = C) y= D) y=
16 16 16 4

dx
 _____(. is G.I .F )
3
41. 1
x   x  1  2 x  x 
2 2

π π 3π 5π
A) B) C) D)
4 2 4 4
42. Let f(x) be a non-negative continuous function defined on R such that
 1 1500 9000
f  x  +f  x+  =3 and the value of  f  x  dx  then  
 2 0 
A) 2 B) 1 C) 3 4) 4
SECTION-II
(PARAGRAPH WITH NUMERICAL VALUE TYPE)
 This section contains THREE (03) questions stems.
 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the on-screen
virtual numeric keypad.
 If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks: +2 If ONLY the correct numerical value is entered at the designated place;
 Zero Marks: 0 In all other cases.

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Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P
Question Stem for Question Nos. 43 and 44
Question Stem
a 1  2 2
-1 x -x+1 x -x+1

Let f  a  = -1 cot 
 +  dx and
a  x 2  3-2x 
 2x-3x
 2 
lna  x -3x+2 -  x+1 x+2  + x+1 + x-1 
g a   1  dx
ln  x+1 + x-1 
a 
 
2 3  
Where a   0,  -  ,  . If f  200   g  50    ln  ( ,   I )
3 2 2 3
43.  =_____ (if  is prime)
44.   _____ (if  is odd prime )
Question Stem for Question Nos. 45 and 46
Question Stem
100

  cot 
x    tan 1 x  dx . is G.I .F   p  q.cot q then
1
If
0

45. P  _____

q5
46.  _____
10
Question Stem for Question Nos. 47 and 48
Question Stem
  3    3 
Let gi :  ,   R, i  1, 2 and f :  ,   R be functions such that
8 8  8 8 
g1  x   1 , g 2  x   4 x   , f  x   sin x
2

3
8
  3 
x   ,  and Si 
8 8   f  x  gi  x  dx (i=1,2)

8
48S1
47. The value of  ____

32S 2
48. The value of =____
2

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Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P
SECTION-III
(ONE OR MORE CORRECT ANSWER TYPE)
 This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
 Partial Marks : +3 If all the four options are correct but ONLY three options are chosen,
 Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which are correct:
 Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
 Zero Marks : 0 If unanswered;
 Negative Marks: -2 In all other cases.
 For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to the correct answer, then
Choosing ONLY (A), (B) and (D) will get +4 marks;
Choosing ONLY (A), will get +1 mark;
Choosing ONLY (B), will get +1 mark;
Choosing ONLY (D), will get +1 mark;
Choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
Choosing any other option(s) will get -2 marks.
x2 y 2
49. Let e be the eccentricity of a hyperbola   1 , and f  e  be the eccentricity of
a2 b2

 x2 y 2 3 fff.....f  e 
conjugate hyperbola 2  2  1, then
a b 1 n times
de is equal to

A) 2, if n is even B) 4, if n is even C) 2 2 if n is odd D) 4 2, if n is odd


 
50. Let f  x   7 tan 8 x  7 tan 6 x  3tan 4 x  3tan 2 x for all x    ,  then the correct
 2 2

expression (s) is (are)


 /4 1  /4
A)  xf  x  dx  B)  f  x  dx  0
o 12 o

 /4 1  /4
C)  xf  x  dx  D)  f  x  dx  1
o 6 o

51. If f  2  x   f  2  x  and f  4  x   f  4  x  and f  x  is a function of which


2
50
 f  x  dx  5, then  f  x dx is equal to
0
0

51 52
 f  x dx  f  x dx
46
A) 125 B)  f  x dx C) D)
4 1 2

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Sri Chaitanya IIT Academy 07-09-2025_Sr.Super60_STERLING BT_Jee-Adv(2021-P1)_RPTA-05_Q.P

sin 2 nx
52. If un  2

0 sin 2 x
dx then which of the following is (are) true

 n 
A) u1  B) un  C) un  un 1  D) u1, u2 , u3..... are in A.P
2 2 2
 x  dx, I
53. Let I1  
104
0
x 
10
2 0 x x
2
   dx where  x  is fractional part of x , then which

of the following is/are correct.


A) I1  I 2 B) I1  I 2 C) I1  4 I 2 D) I1  100
 sin nx
54 If I n   dx, n  0,1,2,..... , then which of the following is/are true?

 1   x .sin x

10 10
A) I n  I n  2 B)  I 2 m 1  10 C)  I 2m  0 D) I n  I n 1
m 1 m 1
SECTION-IV
(INTEGER ANSWER TYPE)
 This section contains THREE (03) question.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer the using the mouse and the on-screen virtual numeric keypad in the
place designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks : +4 If ONLY the correct integer is entered;
 Zero Marks : 0 In all other cases.
1
3 
2  4 
3 3x 1
55. If f  x   x  x then the value of  f  x  dx 
 is
2 4 1 
 
4 
1  x , x 1
56. If f  x    , and g  x   f  x  1  f  x  1
 0, x 1

5
then the value of 3 g  x  dx is
2
1  x3  x 2  2 x  dx equal to
3
57. The value of 0  
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SEC: Sr.Super60_STERLING BT Space for rough work Page 22

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