Sri Chaitanya IIT Academy., India.

AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec: Sr.Super60 & All PTA-02 Date: 06-05-2021
Time: 02.30Pm to 05.30Pm 2019_P2 Max.Marks:180

KEY SHEET

PHYSICS

1 ABD 2 BC 3 ABD 4 AB 5 ABCD 6 AC

7 BD 8 BCD 9 4 10 6 11 3 12 6
13 4 14 9 15 B 16 C 17 B 18 C

CHEMISTRY

19 ABD 20 ABC 21 BC 22 ABC 23 BC 24 AB

25 CD 26 ACD 27 12 28 6 29 4 30 4
31 8 32 2 33 B 34 B 35 B 36 C

MATHEMATICS

37 CD 38 AB 39 AB 40 BD 41 AB 42 BCD
43 AD 44 ABC 45 4 46 7 47 6 48 0
49 1 50 1 51 C 52 B 53 A 54 D
Sri Chaitanya IIT Academy 06-05-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_PTA-02_Key & Sol’s
SOLUTIONS
PHYSICS
4 0 ab
1. A) C 
ba
1 Q2 Q2  b  a 
B) U    
2 C 8 0  ab 
a
C) When inner sphere is earthed, Qa     Qb
b
Q2
D) U System  self energy of the system =
8 0 a
2. RA  24, RB  16
24
Initial current through the bulbs I   0.6 A
40
12 12
After switch is closed I A   0.5 A & I B   0.75 A
24 16
Since P  I 2 R
Hence brightness of bulbs A decrease and that of B increases
3. Potential difference to be measured across external setup is
1
A) V , when S1 is closed
3
B) 1 V, when S2 is closed
1
C) V , when both are closed
3
Potential difference across potentiometer wire is 2V.

 E   x
4. J   E  0 J 1  
  l
Let charge density  
 Adx
dEA 
0
dE 
 0 0 J 0
dx l
 
2
R 2  R  5  5 3
2
5.

 
2
R 2  R 2  R  5  5 3
2

R 2  R 2 25  10R  75
R = 10 m

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Sri Chaitanya IIT Academy 06-05-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_PTA-02_Key & Sol’s

1
sin   ,   300 ,   90    600
2
mv RqB 10 106 10
Rv   2m / s
qB m 5 105
6. The magnetic field B due to current is tangential to the curved parts AB and CD of
the loop. Hence every current element dl of parts AB and CD is parallel or antiparallel
to B. The magnetic force on AB or CD is zero since in the expression dF
= BIdl sin . The magnetic force on straight parts AD and BC is not zero. The
magnetic force on AD is directed towards the reader which is equal and opposite to
the force on BC which is directed away from the reader. These equal and opposite
forces cancel each other. Therefore, the net force on the loop ABCD is zero. Since
these equal and opposite forces do not act at the same point, they will exert a net
torque on the loop which will rotate it in the clockwise sense when viewed from O.
7. Conceptual
8. When we fill the cavity with same current density, then magnetic field at
0 I
P  B1   Direction is into the plane
2 2 R
 J  R2 I
 0 J
4 2 R  R2
 JR
B1  0     1
4
Take cavity portion alone.

P
R 3R
2R  
2 2

0 I   R2
B2    0  J
2 3R / 2 3 R 4

 0 JR        2
12
Dir. into the plane
0 JR  1 
 B  B1  B2  1
4  3 

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Sri Chaitanya IIT Academy 06-05-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_PTA-02_Key & Sol’s
0 JR
B Tesla .
6
9. Initial charge in each capacitor = 8 c & energy stored in the capacitor of 2  F  16 J ,
energy stored in capacitor of 4  F  8 J .After switch is shifted to position 2 charge on
capacitor 4  F is constant, where as charge in capacitor or 2  F is 4  C . Final energy
stored in 2  F is 4J
By conservation of energy in left loop
U i  U f  Wb  Q
 16  4  4  2  Q
 Q  4J
Q
10. P.D across B   2 volt & Battery emf  8V
C
 The capacitor ‘A’ acts as short circuit at t = 0
 Hence current at t=0, is
8 2
I  6A
1
11 . t  RC
12. VV  Voltmeter reading initially
VA  Voltage across ammeter initially
Hence VV  VA  8  (1)
VV
Finally  3VA  8  (2)
3
From (1) & (2) VV  6V

13. Let mean radius of the tore is R

N N
Then number of turns in a small section is  Rd  d
R 
 d2 N
So du  I   d
4 
The two components are du cos  and du sin 

 Id 2 N Id 2 N 1 4
u   du sin  d  2   
0
4 2 2 8

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Sri Chaitanya IIT Academy 06-05-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_PTA-02_Key & Sol’s
1 1 B2
14. Energy density of E-field =  0 E 2 and energy density of B – field =
2 2 0
Q. No. 15 & 16 :
Use biotsavart’s law
Q. No. 17 & 18 :
 dq 
Charging rate means current   I . So, if charging rate is maximum, then current
 dt 
is also maximum. Hence, A  p, s. Charge on the capacitor is maximum in steady
state. In steady state current becomes zero. Hence B  r . Power supplied by the
battery is maximum initially because current is maximum initially. At this time,
charge on the capacitor is zero. Hence, C  r .
Difference in the power supplied by battery and power consumed in R is
EI  I 2R  EI  IIR   EI  IE  0 hence D  r

CHEMISTRY

19. c is Na 3 AlF6 

20. Silica will provide acidic lining
21.
NH 3
NH 3
H3N NO 2
CO H3N H 2O
HCl / H 2O CO
 
H3N
NO 2 H3N H 2O
NO 2
Cl
fac only one isomer
NH 3
NH 3
H3N NO 2
CO H3N H 2O
HCl / H2O CO
  
or
O2 N
NO 2 Cl Cl
NH 3
NH 3
mesodiomer 2 isomers
NH 3
H3N Cl
CO

Cl H 2O
NH 3
trans
22. Compound C is having chiral centre
23. Conceptual
24. We know G  G  2.303RT log10 Q
At equilibrium G  0 and Q  K

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Sri Chaitanya IIT Academy 06-05-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_PTA-02_Key & Sol’s
 0  G  2.303RT log10 K
G  2.303RT log10 K  1
H   T S   2.303RT log10 K
H  S 
   2.303RT log10 K   2
RT R
25. Conceptual
26. Conceptual
27. Facial – 6; Meridional – 6

a a a
b b b
e/d f/d f/e

d/e d/f c e/f c

c e d
f
28.
a
c e

d f
b
3 + 3 = 6 optical active isomers
29.
OH

H Br

F F H H
CCC CC
OH , H H Cl Cl
, ,
30. Formation of a stable carbo cation indicates precipitate formation
Cl Cl
Cl

Cl
Cl

Cl
Aq. AgNO3
     4 AgCl ppt
excess

O
CH2
Cl
31. SO 2Cl 2 g 
 SO 2 g   Cl2 g 

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Sri Chaitanya IIT Academy 06-05-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_PTA-02_Key & Sol’s
1 atm x atm 2 atm
x 2
Kp   10
1
x  5atm
ng
32. K p  K c  RT 
ng
0.0105  0.45  0.082  523 
ng
0.0233   0.082  523
ng
0.0233   42.886 
log 0.0233  ng log 42.886
1.632  ng 1.6323
ng  1
3   2  n   1
2n  4
n2

Q. No. 33 & 34 :
I – PQS; II – PQRSU; III – ST; IV – RS
Q. No. 35 & 36 :
A – PS; B – P; C – R; D – Q

MATHEMATICS
37. Conceptual
38. Required No = Coeff of x 15 in (1 + x + x2 + … + x15)3
3
 1 15 
 4k = coeff of x 15 in  1  x 1  x  
 
 4k = co-eff of x15 in (1 – x)–3
(any power of x, which is 15 or greater than 15 is neglected)
 4k  17C15  136
 k = 34
(B) is true and (C) is false as power of x > 15 & < 15 respective.
in (D) Reqd. no = 22C20.
39. (A)
 mn  ! is the number of ways of splitting a set of mn persons into a group of n
m
m!  n!
persons each
(B) m = n in (a)
(C) False, take n = 1, r = 2
(D) False take m = 1, n = 2
40. M, A, T  2
H, E, I, C, S  1

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Sri Chaitanya IIT Academy 06-05-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_PTA-02_Key & Sol’s

Type Combination Permution

8 8
All different C4 P4 = 1680
3
2 same C1  7 C 2 3 4!
C1  7C 2   756
2 different 2!
3
2 same C2 3 4!
C2   18
2 same 2!2!
Total 2454

41.  (1  x  x 2 ) n  a 0  a1 x  a 2 x 2  ......  a 2 n x 2 n
Putting x  i(i  1)
Then, we get
(1  i  i 2 ) n  (a 0  a 2  a 4  a 6  ...)  i(a 1  a 3  a 5  a 7  ...)
 i n  (a 0  a 2  a 4  a 6  ...)  i(a 1  a 3  a 5  a 7  ...)
If n is odd, then Re(in) = 0
 a0 – a2 + a4 – a6 + …. = 0
If n is even, then Im(in) = 0
 a1 – a3 + a5 – a7 + …. = 0
n 1
42. a 
k
C
k 1
1  t  Z1  tZ 2
43. as w  , lies on the line segment joining Z, an Z2
1  t   t
44. Conceptual
n 4
45. (1  x 2 ) 2 (1  x ) n   aK x K
K 0
n
a1  nC1 , 2  C2  a2
n
C3  2. n C1  a3
But a1 , a2 , a3 are in AP
( n  2)(n  3)( n  4)  0  n  2,3, 4
Maximum value of n is 4
40
46.  581    5.580    5. 52    5  26  1  
40

5  40 40 39 38
C0  26   40 C1  26   40 C 2  26   ....  40 C39  26   1   
 526  1  , where   N  5  26  5  
 581   is divisible by 2
 5    26    21
47. Conceptual
2007
48. Series   (1)r (5r  3) 2007
Cr  0  K  0
r 0

3 i a i
49.
2

a i
a  3  2i    3  2 i 1 

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Sri Chaitanya IIT Academy 06-05-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_PTA-02_Key & Sol’s

a
 
3  2 i 1

1
32i 2 3
50. Conceptual
Q. No. 51 & 52 :
P  E1   P  E2   P  E3   P  E4   1/4
P  S/E1   1/6, P  S /E2   1/8, P  S/E3   1/10 and P  S/E4   1/12
Now use Bayes’ rule.
Q. No. 53 & 54 :
1) 2 | x | 4 | y | 4 | x | 2 | y | 2
x  2y  2  0

2
A max  2; A min 
5
2) Z lies on  x  3   y  4  22
2 2

2yi y
B 
i2x x

M  12  59; m  12  59
3) x 2  y 2  2x  4y  4  0
1, 2r  1  4  4  3
M = 8, m = 2
4) M = 6, m = 4

Sec: Sr.Super60 & All Page 9