PM SHRI KENDRIYA VIDYALAYA MHOW

CLASS: XII WORKSHEET No: 01

CHAPTER: SOLUTION

Q.1 Increasing the temperature of an aqueous solution will cause:

(a) decrease in molality (b) decrease in molarity (c) decrease in mole fraction (d) decrease in % (w/w)

Q.2 The value of Henry’s constant KH is:

(a) greater for gases with higher solubility (b) greater for gases with lower solubility.

(c) constant for all gases. (d) not related to the solubility of gases

Q.3 Which of the following condition is not satisfied by an ideal solution?

(a) ΔHmixing = 0 (b) ΔVmixing = 0 (c) Raoult’s Law is obeyed (d) Formation of an azeotropic mixture

Q.4 If 2 gm of NaOH is present is 200 ml of its solution, its molarity will be_

(a) 0.25 mol L-1 (b) 0.5 mol L-1 (c) 5 mol L-1 (d) 1.0 mol L-1

Q.5 If two liquids A and B form minimum boiling azeotrope at some specific composition then _____.

(a) A–B interactions are stronger than those between A–A or B–B.

(b) vapour pressure of solution increases because a greater number of molecules of liquids A and B can escape from
the solution.

(c) vapour pressure of solution decreases because a smaller number of molecules of only one of the liquids escape
from the solution.

(d) A–B interactions are weaker than those between A–A or B–B

Q.6 Colligative properties depend on:

(a) the nature of the solute (b) the number of solute particles in solution

(c) the physical properties of solute (d) the nature of the solvent

Q.7 The most suitable colligative property to determine molecular weight of biomolecules is:

(a) Lowering of vapour pressure (b) Osmotic pressure

(c) Elevation of boiling point (d) Depression of freezing point

Q.8 Which has highest boiling point:

(a) 1 M Glucose (b) 1 M NaCl (c) 1 M CaCl2 (d) 1 M AlF3

Q.9 A beaker contains a solution of substance ‘A’. Precipitation of substance ‘A’ takes place when small amount of ‘A’
is added to the solution. The solution is _________.

(a) saturated (b) supersaturated (c) unsaturated (d) concentrated

Q.10 The values of Van’t Hoff factors for KCl, NaCl and K2SO4, respectively, are_____.

(a) 2, 2 and 2 (b) 2, 2 and 3 (c) 1, 1 and 2 (d) 1, 1 and 1

Given below are two statements labelled as Assertion (A) and Reason (R) Select the most appropriate answer from
the options given below:

(a) Both A and R are true and R is the correct explanation of A

(b) Both A and R are true but R is not the correct explanation of A
(c) A is true but R is false

(d) A is false but R is true

Q.11 Assertion (A): Azeotropic mixtures are formed only by non-ideal solutions and they may have boiling points
either greater than both the components or less than both the components.

Reason (R): The composition of the vapour phase is same as that of the liquid phase of an azeotropic mixture.

Q.12 Assertion (A): Soda bottles are sealed under high pressure.

Reason (R): High pressure increases the solubility of carbon dioxide gas

Q.13 Assertion(A): Boiling point of 0.1 M KCl solution is higher than 0.1 M Glucose solution.

Reason: Glucose is a non-electrolyte while KCl molecule dissociates in aqueous state.

Q.14 Assertion (A): Human blood cell swell-up when it is placed in a NaCl solution having concentration more than
0.9%.

Reason (R): Osmosis involves movement of solvent molecules from its higher concentration to its lower
concentration.

Answer the questions in short

Q.15 (a) Define Mole fraction: (b) Azeotropes

Q.16 State the law co-relating the pressure & solubility of a gas in a liquid. State an application of this law.

Q.17 What type of deviation is shown by mixture of ethanol and acetone? Give reason.

Q.18 Write two differences between the solutions showing positive & negative deviation from Raoult’s law.

Q.19 Define (a) Abnormal molar mass: (b) van’t Hoff factor

Q.20 Give reasons:

(a) RBC shrink when placed in saline water but swell in distilled water.

(b) 0.1 M KCl has higher boiling point than 0.1 M Glucose.

Q.21 A solution of glycerol (C3H8O3) in water was prepared by dissolving some glycerol in 500 g of water. This
solution has a boiling point of 100.420C. What mass of glycerol was dissolved to make this solution?

(Kb for water = 0.512 K Kg mol -1)

Q.22 A solution containing 15 g urea (molarmass= 60 g mol–1) per liter solution in water has the Same osmotic
pressure (isotonic) as a solution of glucose (molar mass= 180 g mol–l) in water. Calculate the mass of glucose present
in one liter of its solution.

Q.23 Calculate the freezing point of a solution when 20 g of CaCl2 (M=111 g mol -1) was dissolved in 500 g of water,
assuming CaCl2 undergoes complete ionization. (Kf for water = 1.86 K kg mol-1)

Q24 Calculate the boiling points of solution when 2 gm of Na2SO4 (molecular mass 142 gm/mol) was dissolved in 50
gm of water assuming Na2SO4 undergoes complete ionization. (Kb for water = 0.52 K Kg mol-1)

Q.25 A 5% solution (by mass ) of cane sugar in water has freezing point of 271 K. Calculate the freezing point of 5%
solution (by mass ) of glucose in water (Molecular mass: Glucose C6H12O6 : 180 amu; Cane –sugar C12H22O11: 342
amu)

Q26 3.9 g of benzoic acid dissolved in 49 g of benzene shows a depression in freezing point of 1.62K. Calculate the
van’t Hoff factor and predict the nature of solute (associated or dissociated)

(Given molar mass of benzoic acid = 122 g mol -1, Kf for benzene = 4.9 K kg mol -1)