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E2301 12 (2022)

This document outlines the international standard E2301-12 for measuring the daytime colorimetric properties of fluorescent retroreflective sheeting and marking materials used in high visibility traffic control and personal safety applications. It details the test method, apparatus requirements, and procedures for obtaining colorimetric data under daylight conditions, emphasizing the importance of safety and calibration. The standard is developed in accordance with principles established by the World Trade Organization's Technical Barriers to Trade Committee.
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0% found this document useful (0 votes)
9 views6 pages

E2301 12 (2022)

This document outlines the international standard E2301-12 for measuring the daytime colorimetric properties of fluorescent retroreflective sheeting and marking materials used in high visibility traffic control and personal safety applications. It details the test method, apparatus requirements, and procedures for obtaining colorimetric data under daylight conditions, emphasizing the importance of safety and calibration. The standard is developed in accordance with principles established by the World Trade Organization's Technical Barriers to Trade Committee.
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This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles

for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

Designation: E2301 − 12 (Reapproved 2022)

Standard Test Method for


Daytime Colorimetric Properties of Fluorescent
Retroreflective Sheeting and Marking Materials for High
Visibility Traffic Control and Personal Safety Applications
Using 45°:Normal Geometry1
This standard is issued under the fixed designation E2301; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.

1. Scope Color Differences from Instrumentally Measured Color


1.1 This test method describes the instrumental measure- Coordinates
ment of the colorimetric properties (CIE tristimulus values, E179 Guide for Selection of Geometric Conditions for
luminance factors, and chromaticity coordinates) of Measurement of Reflection and Transmission Properties
fluorescent-retroreflective sheeting and marking materials of Materials
when illuminated by daylight. E284 Terminology of Appearance
E308 Practice for Computing the Colors of Objects by Using
1.2 This test method is generally applicable to any sheeting the CIE System
or marking material having combined fluorescent and retrore- E691 Practice for Conducting an Interlaboratory Study to
flective properties used for daytime high visibility traffic Determine the Precision of a Test Method
control and personal safety applications. E1164 Practice for Obtaining Spectrometric Data for Object-
1.3 The values stated in SI units are to be regarded as Color Evaluation
standard. No other units of measurement are included in this E1767 Practice for Specifying the Geometries of Observa-
standard. tion and Measurement to Characterize the Appearance of
1.4 This standard does not purport to address all of the Materials
safety concerns, if any, associated with its use. It is the E2152 Practice for Computing the Colors of Fluorescent
responsibility of the user of this standard to establish appro- Objects from Bispectral Photometric Data
priate safety, health, and environmental practices and deter- E2153 Practice for Obtaining Bispectral Photometric Data
mine the applicability of regulatory limitations prior to use. for Evaluation of Fluorescent Color
1.5 This international standard was developed in accor- 2.2 CIE Document:3
dance with internationally recognized principles on standard- CIE 15:2004 Colorimetry
ization established in the Decision on Principles for the
Development of International Standards, Guides and Recom- 3. Terminology
mendations issued by the World Trade Organization Technical 3.1 Definitions—The definitions contained in Guide E179,
Barriers to Trade (TBT) Committee. Terminology E284, and Practice E1164 are applicable to this
test method.
2. Referenced Documents
4. Summary of Test Method
2.1 ASTM Standards:2
D2244 Practice for Calculation of Color Tolerances and 4.1 This test method provides a procedure for measuring the
colorimetric properties of fluorescent-retroreflective sheeting
and markings under simulated daylight illumination. Colori-
1
metric properties are determined for CIE D65, which approxi-
This test method is under the jurisdiction of ASTM Committee E12 on Color
and Appearance and is the direct responsibility of Subcommittee E12.05 on
mates outdoor illumination at midday, and Daylight 15 000 K,
Fluorescence. which is an alternate D illuminant chosen to represent low
Current edition approved Oct. 1, 2022. Published November 2022. Originally ambient light/dawn/dusk daylight illumination conditions (see
approved in 2003. Last previous edition approved in 2017 as E2301 – 12 (2017). CIE 15:2004).
DOI: 10.1520/E2301-12R22.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at [email protected]. For Annual Book of ASTM
3
Standards volume information, refer to the standard’s Document Summary page on Available from CIE (International Commission on Illumination) at www-
the ASTM website. .cie.co.at or www.techstreet.com.

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E2301 − 12 (2022)
4.2 This test method requires the use of a calibrated bispec- 6.1.4.1 Circumferential instruments are acceptable provided
trometer (two-monochromator spectrometer) with either 45:0 the procedure described in 9.3.1 is followed.
or 0:45 geometry that can measure the specimen’s Donaldson 6.1.4.2 Uniplanar instruments are acceptable provided the
matrix (see Practice E2153). procedure described in 9.3.2 is followed.
4.3 This test method provides for calculation and reporting 6.1.5 The referee aperture sizes shall be 10 degrees for
of separated fluorescence, reflectance and total tristimulus illumination and 10 degrees for viewing. Use of aperture sizes
values (XYZ) and luminance factors (Y, %), and total chroma- deviating from these may affect the measurement results. See
ticity coordinates (x,y) from the Donaldson matrix for the CIE Practice E1767 for fundamentals of specification of apertures.
1931 Standard Colorimetric Observer. NOTE 4—Fluorescent colorimetric properties (for example, Fluores-
cence tristimulus values (XYZ)F) are not significantly influenced by the
5. Significance and Use aperture sizes. Reflectance colorimetric properties (for example, Reflec-
tance tristimulus values (XYZ)R) may be greatly affected by aperture sizes.
5.1 This test method provides procedures for obtaining Consequently total colorimetric properties (for example, Total tristimulus
tristimulus values, luminance factors and chromaticity coordi- values (XYZ)T) may be greatly affected.
nates of fluorescent-retroreflective materials by bispectral colo- 6.1.6 The illumination monochromator shall illuminate the
rimetry using a 45:0 or 0:45 optical measuring system. specimen over the wavelength range from 300 nm to 780 nm at
5.2 The CIE 1931 (2°) standard observer is used to calculate intervals of 10 nm or less.
the colorimetric properties of fluorescent-retroreflective sheet- 6.1.7 The viewing monochromator shall detect the speci-
ing and markings used in daytime high visibility traffic control men radiance over the wavelength range from 380 nm to
and personal safety applications because in practice these 780 nm at intervals of 10 nm or less.
materials are primarily viewed from a distance where they 6.1.8 The minimum illuminated sample area shall be
subtend less than 4° of the visual field. 100 mm2 with no dimension less than 5 mm.
5.3 This test method is applicable to object-color specimens 6.2 Calibration Standards, as outlined in Practice E2153,
of any gloss level. supplied by the instrument manufacturer or obtained
5.4 Due to the retroreflective properties of these materials separately, with calibration values no older than 24 months.
the colorimetric data may not be suitable for use in computer 6.3 Verification Standards—Verification of the precision and
colorant formulation. bias of the entire system, including calculation of tristimulus
5.5 This test method is suitable for quality control testing of values, shall be conducted on an annual basis using non-
fluorescent-retroreflective sheeting and marking materials. retroreflective/non-fluorescent, fluorescent/non-retroreflective
NOTE 1—Separation of the fluorescence and reflectance components and fluorescent retroreflective color standards with calibration
from the total colorimetric properties provides useful and meaningful values traceable to an accredited National Standards Labora-
information to evaluate independently the luminescent and diffuse reflec- tory. The calibration values for the verification panels shall be
tive efficiency and consistency of these materials. no older than 36 months.
5.6 This test method is the referee method for determining NOTE 5—Stable fluorescent/non-retroreflective and fluorescent retrore-
the conformance of fluorescent-retroreflective sheeting and flective color artifact standards are not widely available as Standard
Reference Materials (SRMs). However, measurement services are avail-
marking materials to standard daytime colorimetric specifica-
able from Independent Testing Laboratories and National Standards
tions. Laboratories to calibrate artifacts for use as Verification Standards.

6. Apparatus 7. Test Specimen


6.1 Bispectrometer, with either 45:0 or 0:45 (illumination- 7.1 Specimen Preparations:
:viewing) geometry. 7.1.1 Samples shall be tested mounted on the substrate that
6.1.1 The tolerance on the inclination of the 45-degree axis will be utilized for the intended application. Apply the sample
shall be 2 degrees (45 6 2 degrees). to the substrate in accordance with the recommendations of the
6.1.2 The tolerance on the 0-degree axis shall be 2 degrees material’s manufacturer.
from the normal (0 6 2 degrees). 7.1.2 If the sample is not supplied with its intended
NOTE 2—For maximum reproducibility smaller tolerances on the axis substrate, or if the intended substrate is not defined, then the
angles are recommended. sample shall be mounted or backed by a black panel, such as a
6.1.3 For the 45:0 condition, the illumination geometry may black tile. The black panel shall have a luminance factor (Y) of
be annular, circumferential or uniplanar and the viewing shall less than 4 %.
be normal to the specimen. For the 0:45 condition, the NOTE 6—The measurement results will depend upon the spectral
illumination shall be normal to the specimen and the viewing reflectance properties of the material behind the specimen as well as the
geometry may be annular, circumferential or uniplanar. specimen thickness.
6.1.4 The referee geometry shall be annular 45:0. 7.1.3 Specimens should be uniform in physical properties
over the area measured.
NOTE 3—Reciprocity between 45:0 and 0:45 geometry for commercial
instruments may not be observed in practice for retroreflective materials 7.1.4 Number of Test Specimens—Measurements shall be
because of the variation in axis angles and aperture sizes of instruments. made on a minimum of 3 test specimens.

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7.1.5 Specimens that have been subjected to additional After washing, rinse thoroughly with clean water, and blot dry
testing, such as outdoor or machine exposure testing, shall be with a soft clean cloth. After washing and drying, condition the
tested on the substrate used for these additional tests. panels at room temperature for at least 2 h prior to conducting
7.2 Test Conditions—Unless otherwise specified, condition any property measurements.
all test specimens at a temperature of 23 °C 6 2 °C and 50 % 9.3 Position the test specimen at the measurement port of
6 5 % relative humidity for 24 h prior to testing. the instrument.
7.3 Sampling—Unless otherwise specified test samples shall 9.3.1 If the measurement geometry is circumferential, then
be selected according to the following sampling plan. the testing laboratory must verify that the apertures in the ring
7.3.1 Sheeting for Traffıc Control Applications—Test are sufficiently close for the measurement to approximate
samples shall be cut from 1 m2 of sheeting. The test samples measurement with annular geometry. This may depend on the
shall be cut from the lower left corner, center and upper right optical construction of the specimen, and must be determined
corner of the sheeting as shown in Fig. 1. This insures test by the testing laboratory. Otherwise treat the instrument as a
samples reflect crossweb and downweb variability of the uniplanar geometry (see 9.3.2).
sheeting. 9.3.2 If the measurement geometry is uniplanar, then a
7.3.1.1 For materials manufactured in widths less than 1 m sequence of measurements shall be made on the same speci-
the size of the sample shall be such that the width times the men area at incremental rotations, and the measurement values
length shall equal 1 m2 (that is, length × width = 1 m2). An shall be averaged over all the rotations. The number of
example is shown in Fig. 1B. rotations must be sufficient to assure good approximation to an
7.3.2 Marking Materials for Personal Safety Applications— annular measurement. The number depends on the optical
Test samples shall be cut from a 2 m length by sample width of construction of the specimen and must be determined by the
material as shown in Fig. 2. Test samples shall be cut from the testing laboratory. The averaging over rotations shall be
beginning, middle and end of the 2 m long length of test applied to the values in the Donaldson matrix.
material. This insures test samples reflect variability of the 9.4 Obtain the illuminant independent Donaldson matrix for
marking material. each test specimen at illumination and viewing sampling
7.3.3 Materials Subjected to Outdoor Exposure—Sampling intervals of no greater than 10 nm (see Practice E2153 and the
of materials subjected to outdoor exposure shall conform to instrument manufacturer’s instructions).
these sampling requirements to the extent practical based on
the number and size of the exposed test specimen. 10. Calculation
10.1 Tristimulus Values:
8. Calibration and Verification 10.1.1 Tristimulus Values for CIE D65—Calculate the indi-
8.1 Calibrate the bispectrometer in accordance with Practice vidual Total tristimulus values (XYZ)T, Reflectance tristimulus
E2153, or values (XYZ)R and Fluorescence tristimulus values (XYZ )F for
each test specimen from the respective Donaldson matrix for
8.2 Verify the accuracy of the instrumental data by measure-
the CIE 1931 Standard Observer and CIE D65 (see Practice
ment of a series of calibrated verification standards.
E2152).
9. Procedure 10.1.1.1 Calculate the averages and standard deviations for
the individual tristimulus values (X, Y, and Z) for each
9.1 Handle the specimen carefully; avoid touching the area component (Total, Reflectance, and Fluorescence) for CIE D65
to be measured. for each set of test specimens:
9.2 Clean the specimen prior to measurement as necessary, Total tristimulus values: XT-average = (Σ XT)/n; YT-average
for example when measuring specimens that have been sub- = (Σ YT)/n; ZT-average = (Σ ZT)/n);
jected to outdoor or machine exposure testing. Reflectance tristimulus values: XR-average = (Σ XR)/n;
9.2.1 Washing Panels—Gently wash the panels using a soft YR-average = (Σ YR)/n; ZR-average = (Σ ZR)/n);
cloth or sponge and clean water or a dilute solution (1 % by Fluorescence tristimulus values: XF-average = (Σ XF)/n;
weight in water, maximum concentration) of a mild detergent. YF-average = (Σ YF)/n; ZF-average = (Σ ZF)/n

FIG. 1 Test Samples

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E2301 − 12 (2022)

FIG. 2 Test Sample

10.1.2 Tristimulus Values for Daylight 15 000 K—Calculate 10.2.3 Other Colorimetric Quantities—When other colori-
the individual Total tristimulus values (XYZ)T, Reflectance metric properties or values, such as CIELAB, are specified,
tristimulus values (XYZ)R and Fluorescence tristimulus values these shall be calculated from tristimulus values in accordance
(XYZ)F for each test specimen from the respective Donaldson with Practices E308 or E2152 as applicable.
matrix for the CIE 1931 Standard Observer and Daylight 10.3 Other Quantities:
15 000 K (see Practice E2152). 10.3.1 Other quantities derived from the Donaldson matrix,
10.1.2.1 The spectral power distribution for Daylight such as the Stokes Shift.
15 000 K shall be calculated in accordance with the procedure 10.3.2 Tristimulus values and Colorimetric quantities for
described in CIE 15:2004 for other D Illuminants (tabulated other alternate illuminants.
values at 10 nm intervals for CIE D65 and Daylight 15 000 K
are provided in Annex A1). 11. Report
10.1.2.2 Calculate the averages and standard deviations for 11.1 Specimen description including the following:
the individual tristimulus values (X, Y, and Z) for each 11.1.1 Sample Identification including any commercial des-
component (Total, Reflectance, and Fluorescence) for Daylight ignation (for example, trade-name and product number) and
15 000 K for each set of test specimens. manufacturer lot number.
10.2 Colorimetric Quantities: 11.1.2 Description of the exposure conditions and total
10.2.1 CIE 1931 Total Chromaticity Coordinates (x,y) for exposure duration for any test specimens that have undergone
CIE D65—Calculate the average Total CIE 1931 Chromaticity outdoor or machine exposure testing.
Coordinates (x,y)T-average from the average Total tristimulus 11.2 Date of Measurement.
values (XYZ)T-average for CIE D65 in accordance with estab-
lished procedures (see Practice E308). 11.3 Instrument Description:
10.2.2 CIE 1931 Total Chromaticity Coordinates (x,y) for 11.3.1 Make and Model number of Bispectrometer.
Daylight 15 000 K—Calculate the average Total CIE 1931 11.3.2 Instrument geometry (annular, circumferential or
Chromaticity Coordinates (x,y)T-average from the average uniplanar).
Total tristimulus values (XYZ)T-average for Daylight 15 000 K 11.4 Calibration and Verification Information:
in accordance with established procedures (see Practice E308). 11.4.1 Date of most recent instrument calibration.

TABLE 1 CIE 1931 Tristimulus Values for CIE D65


XF YF ZF XR YR ZR
Fluorescent Yellow Green ASTM Type IX
Average 25.4 47.6 2.2 32.2 35.8 1.1
σ 1.6 2.5 0.4 1.6 1.9 0.2
SR 95 % CI ±4.5 ±7.4 ±1.2 ±4.7 ±5.3 ±0.6
CV % R 18 % 16 % -- 15 % 15 % --
Fluorescent Yellow ASTM Type IX
Average 44.4 45.3 0.5 26.2 20.8 0.4
σ 1.9 2.0 0.5 1.2 1.1 0.1
SR 95 % CI ±5.5 ±5.8 ±1.5 ±3.4 ±3.0 ±0.4
CV % R 12% 13 % -- 13 % 15 % --
Fluorescent Orange ASTM Type VII
Average 37.0 23.0 0.0 26.5 14.4 0.6
σ 1.9 1.3 0.4 5.1 2.9 0.1
SR 95 % CI ±5.5 ±3.8 ±1.3 ±14.8 ±8.3 ±0.3
CV % R 15 % 16 % -- 56 % 58 % --
Fluorescent Red ASTM Type IX
Average 29.3 14.9 0.0 11.2 5.1 2.4
σ 1.0 0.6 0.4 0.8 0.4 0.3
SR 95 % CI ±3.0 ±1.8 ±1.1 ±2.3 ±1.2 ±0.8
CV % R 10 % 12 % -- 21 % 23 % --
White Non-fluorescent/ Non-retroreflective
Average 0.0 0.1 -0.2 76.8 81.4 88.1
σ 0.66 0.64 0.53 1.00 1.01 1.28
SR 95 % CI ±1.9 ±1.8 ±1.5 ±2.9 ±2.9 ±3.7
CV% R -- -- -- 4% 4% 4%

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TABLE 2 Round Robin Results 4 colored fluorescent retroreflective sheeting specimens (red,
Mean Color Difference
Critical T2 orange, yellow and yellow green) and one white non-
(95 % CI) = fluorescent/non-retroreflective marking film mounted on black
from the Mean (MCDM)
12.7
anodized aluminum panels were measured twice on each of 7
CIEDE2000 CIELAB DE* Maximum T2
different bispectrometers. The first measurement was made
Yellow Green 0.9 2.7 5.5
Yellow 1.4 6.5 9.3 immediately after calibration of the instrument; the second
Orange 1.8 6.0 7.9 measurement was made the next day after system verification
Red 1.2 2.8 5.6 only.
White Non-fluor/Non-retro 0.6 0.6 5.6
12.2 Reflectance and Fluorescence tristimulus values,
(XYZ)R and (XYZ)F respectively, were calculated from each
11.4.2 Calibration date of instrument calibration standards. Donaldson matrix for the CIE 1931 Standard Observer and CIE
11.4.3 Calibration date of verification standards. D65. These tristimulus values were then used to calculate the
Total CIE 1931 Chromaticity coordinates (x,y)T for each
11.5 Measurement Results: measurement.
11.5.1 Donaldson matrix.
12.3 Table 1 summarizes the results of the round robin. The
11.5.2 Average Total tristimulus values (XYZ)T, Reflectance
between laboratory (XYZ)R and (XYZ)F averages, standard
tristimulus values (XYZ)R and Fluorescence tristimulus values
deviations (σ), 95 % Confidence Intervals for reproducibility
(XYZ)F calculated for CIE D65.
(SR 95 % CI), and Coefficients of Variation (CV % R) were
11.5.3 Average Total CIE 1931 Chromaticity coordinates
calculated in accordance with Practice E691.
(x,y)T-average calculated for CIE.
11.5.4 Average Total tristimulus values (XYZ)T, Reflectance 12.4 Table 2 summarizes the results of the round robin
tristimulus values (XYZ)R and Fluorescence tristimulus values relative to measurement of CIE 1931 total color coordinates
(XYZ )F calculated for Daylight 15 000 K. (x,y)T and total luminance factor (YT). Repeatability and
11.5.5 Average Total CIE 1931 Chromaticity coordinates reproducibility are expressed as Mean Color Differences from
(x,y)T-average calculated for Daylight 15 000 K. the Mean (MCDM) in terms of CIELAB DE* and CIEDE2000
11.5.6 Other colorimetric quantities derived from the Total (see Practice D2244), and in terms of Hotelling’s T-squared
tristimulus values (XYZ)T, Reflectance tristimulus values statistic derived through a Multivariate Statistical Analysis of
(XYZ)R or Fluorescence tristimulus values (XYZ)F calculated the individual (x,y,Y)T values.
for either CIE D65 or Daylight 15 000 K as required.
11.5.7 Other quantities as required.
12. Precision and Bias
F GF G F G
XF
YF
ZF
1
XR
YR
ZR
5
XT
YT
ZT

12.1 Data for the precision and bias of this test method is 13. Keywords
based on the results of an international round robin using the 13.1 bispectral; color; fluorescence; personal safety; retrore-
same make and model of annular 45:0 bispectrometer. A set of flective; traffic control

ANNEX

(Mandatory Information)

A1. RELATIVE SPECTRAL POWER DISTRIBUTIONS

A1.1 Relative spectral power distributions for CIE D65 and CIE 15:2004 for calculating the relative spectral power distri-
Daylight 15 000 K computed by the procedures described in butions of alternate D illuminants. See Table A1.1.

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TABLE A1.1 Relative Spectral Power Distributions for CIE D65
and Daylight 15 000 K
Daylight Daylight
Wavelength CIE D65 Wavelength CIE D65
15 000 K 15 000 K
300 0.03 0.08 560 100.00 100.00
310 3.29 16.27 570 96.33 92.88
320 20.24 77.21 580 95.79 88.32
330 37.05 145.16 590 88.69 83.26
340 39.95 143.92 600 90.01 80.65
350 44.91 149.80 610 89.60 78.15
360 46.64 141.40 620 87.70 73.77
370 52.09 158.07 630 83.29 67.79
380 49.98 142.97 640 83.70 67.00
390 54.65 137.24 650 80.03 64.55
400 82.75 181.87 660 80.21 63.39
410 91.49 198.08 670 82.28 62.35
420 93.43 194.21 680 78.28 59.79
430 86.68 171.08 690 69.72 52.51
440 104.86 186.55 700 71.61 53.05
450 117.01 196.45 710 74.35 55.31
460 117.81 189.74 720 61.60 45.98
470 114.86 176.16 730 69.89 52.71
480 115.92 168.89 740 75.09 57.03
490 108.81 153.07 750 63.59 48.51
500 109.35 144.96 760 46.42 34.98
510 107.80 136.72 770 66.81 50.30
520 104.79 123.18 780 63.38 47.97
530 107.69 120.54 790 64.30 48.68
540 104.41 113.50 800 59.45 45.15
550 104.05 108.06

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