HALOALKANE & HALOARENES CLASS XII MCQ Hasin Ahmed Dekho seekho jano 9425761832
Q.N. Question Answer
1. The order of reactivity of following alcohols with halogen acids is ___________.
(i) (A) > (B) > (C) (ii) (C) > (B) > (A) (iii) (B) > (A) > (C) (iv) (A) > (C) > (B)
2. Which of the following alcohols will yield the corresponding alkyl chloride on reaction with
concentrated HCl at room temperature?
(i) (ii)
(iii) (iv)
3.
Identify the compound Y in the following reaction.
4. Toluene reacts with a halogen in the presence of iron (III) chloride giving ortho and para halo
compounds. The reaction is _________________________
(i) Electrophilic elimination (ii) Electrophilic substitution (iii) Free radical addition (iv) Nucleophilic
substitution
5. Which of the following is the halogen exchange reaction?
6. Which reagent will you use for the following reaction?
CH3CH2CH2CH3 → CH3CH2CH2CH2Cl + CH3CH2CHClCH3
(i) Cl2/UV light (ii) NaCl + H2SO4
(iii) Cl2 gas in dark (iv) Cl2 gas in the presence of iron in dark
7. Arrange the following compounds in the increasing order of their densities.
(i)(a) < (b) < (c) < (d) (ii) (a) < (c) < (d) < (b) (iii) (d) < (c) < (b) < (a) (iv) (b) < (d) < (c) < (a)
8. Arrange the following compounds in increasing order of their boiling points.
(i) (b) < (a) < (c) (ii) (a) < (b) < (c) (iii) (c) < (a) < (b) (iv) (c) < (b) < (a)
9. In which of the following molecules carbon atom marked with an asterisk (*) is asymmetric?
(i) (a), (b), (c), (d) (ii) (a), (b), (c) (iii) (b), (c), (d) (iv) (a), (c), (d)
10. Which of the following structures
is enantiomeric with the molecule (A)
11. Which of the following is an example of vic-dihalide?
(i) Dichloromethane (ii) 1,2-dichloroethane (iii) Ethylidene chloride (iv) Allyl chloride
12. The position of –Br in the compound in CH3CH==CHC(Br)(CH3)2 can be classified as ____.
(i) Allyl (ii) Aryl (iii) Vinyl (iv) Secondary
13. Chlorobenzene is formed by the reaction of chlorine with benzene in the presence
of AlCl3. Which of the following species attacks the benzene ring in this reaction?
(i) Cl– (ii) Cl+ (iii) AlCl3 (iv) [AlCl4]–
14. 14. Ethylidene chloride is a/an ______________.
(i) vic-dihalide (ii) gem-dihalide (iii) allylic halide (iv) vinylic halide
15. What is ‘A’ in the following reaction?
16. A primary alkyl halide would prefer to undergo _____________.
(i) SN1 reaction (ii) SN2 reaction (iii) α–Elimination (iv) Racemisation
17. Which of the following alkyl halides will undergo SN1 reaction most readily?
(i) (CH3)3C—F (ii) (CH3)3C—Cl (iii) (CH3)3C—Br (iv) (CH3)3C—I
18. Which is the correct increasing order of boiling points of the following compounds?
1-Iodobutane, 1-Bromobutane, 1-Chlorobutane, Butane
(i) Butane < 1-Chlorobutane < 1-Bromobutane < 1-Iodobutane
(ii) 1-Iodobutane < 1-Bromobutane < 1-Chlorobutane < Butane
(iii) Butane < 1-Iodobutane < 1-Bromobutane < 1-Chlorobutane
(iv) Butane < 1-Chlorobutane < 1-Iodobutane < 1-BromobutaneSolution
19. What should be the correct IUPAC name for diethylbromomethane?
(i) 1-Bromo-1,1-diethylmethane (ii) 3-Bromopentane
(iii) 1-Bromo-1-ethylpropane (iv) 1-Bromopentane
20. The reaction of toluene with chlorine in the presence of iron and the absence of light yields _______.
21. Chloromethane on treatment with an excess of ammonia yields mainly
22. Molecules whose mirror image is non-superimposable over them are known as chiral. Which of the
following molecules is chiral?
(i) 2-Bromobutane (ii) 1-Bromobutane (iii) 2-Bromopropane (iv) 2-Bromopropan-2-ol
23 Reaction of C6H5CH2Br with aqueous sodium hydroxide follows ____________.
(i) SN1 mechanism (ii) SN2 mechanism (iv) Saytzeff rule
(iv) Any of the above two depending upon the temperature of the reaction
ANSWERS – MCQ 1 2 3 4 5 6 7 8 9 10
HALOALKANE & HALOARENES II iv i ii i i i iii ii i
11 12 13 14 15 16 17 18 19 20 21 22 23 24 25
ii i ii ii iii ii iv ii d iii i i
By- HASIN AHMED Dekho seekho jano 9425761832 KV Bairagarh Bhopal
