Class XI
Atomic structure
WORKSHEET 2
1.The number of unpaired electrons in Ni (atomic number = 28) are
(a)0
(b) 2
(c)4
(d) 8
2.With respect to atomic spectrum, each line in the Lyman Series is due to electrons
returning
(a)From a particular higher energy level to n = 3
(b) From a particular higher energy level to n = 2
(c)From a particular higher energy level to n = 1
(d) From a particular higher energy level to n = 4
3.The orbital nearest to the nucleus is
(a)4f
(b) 5d
(c)4s
(d) 7p
4.Which of the following set of quantum numbers
is not possible?
(a) n = 3, l = 0, m = 0
(b) n = 3, l = 1, m = -1
(c) n = 2, l = 0, m = -1
(d) n = 2, l = 1, m = 0
5.The electronic configuration of Cu2+ ion is
(a)[Ar] 3d8 4s1
(b) [Ar] 3d9 4s0
(c)[Ar] 3d7 4s2
(d) [Ar] 3d8 4s0
6. According to Bohr’s theory, the angular momentum of an electron in 5th orbit is
(b) 10 h/ 𝜋
(a) 1.0 h/𝜋
(c) 2.5 h/ 𝜋
(d) 25 h/ 𝜋
7.How many electrons can fit in the
orbital for which n = 3 and l = 1?
(a)2
(b) 6
(c)10
(d) 14
8. The measurement of the electron position is associated with an
uncertainty in momentum which is equal to 1× 10-18 g cm s-1. The
uncertainty in velocity of electron is (mass of electron is 9 × 10-28 g)
is
(a) 1 × 109 cm s-1
(b) 1 × 106 cm s-1
(c) 1 × 105 cm s-1
(d) 1 × 1011 cm s-1
9. The number of unpaired electrons in 1s22s22p3
(a)2
(b) 0
(c)3
(d) 1
10. Maximum number of electrons in a subshell can be
(a)4l + 2
(b) 4l – 2
(c) 2n2
(d) 2l + 1
11. The ground state electronic configuration of Fe3+ ion is
(a) [Ar] 3d34s2
(b) [Ar] 3d6 4s2
(c) [Ar] 3d5
(d) [Ar] 3d6
12. The total possible values for magnetic quantum number for the value of l = 3 is
(a) 3
(b) 1
(c) 5
(d) 7
13. The electrons present in K-shell of the atom will differ in
(a) Principal quantum number
(b) Azimuthal quantum number
(c) Magnetic quantum number
(d) Spin quantum number
14. Different lines in Lyman series of hydrogen spectrum lie in
(a) Ultraviolet
(b) Infrared
(c) Visible
(d) Far Infrared
15. There is no difference between a 2p and a 3p orbital regarding
(a) Shape
(b) Size
(c) Energy
(d) Value of n
16. For which of the following species, Bohr’s theory is not applicable?
3+
(a) Be
2+
(b) Li
2+
(c) He
(d) H
17. The number of unpaired electrons in an atom of atomic number 24 (in ground
state) is
(a) 3
(b) 4
(c) 5
(d) 6
18. The outer electronic configuration of 3s23p5 is possessed by
(a) O
(b) Cl
(c) Br
(d) Ar
19. Which of the following electron transition in a hydrogen atom will require the
largest amount of energy?
(a) From n = 1 to n = 2
(b) From n = 2 to n = 3
(c) From n = ∞ to n = 1
(d) From n = 3 to n = 5
20. Photon of which light has maximum energy
(a) Red
(b) Blue
(c) Violet
(d) Green
21. The MRI (magnetic resonance imaging) body scanners used in hospitals
operates with 400 MHz radio frequency energy. The wavelength of this radio
frequency is
(a) 0.75 m
(b) 0.75 cm
(c) 1.5 m
(d) 2 cm
22. For a f-orbital, the
values of m are
(a) -2,-1, 0, +1, +2
(b) -1, 0, +1
(c) -3, -2, -1, 0, +1, +2, +3
(d) 0, +1, +2, +3
2 2
23. In case
x y of d - orbital
(a) Probability of finding the electron along x-axis is zero.
(b) Probability of finding the electron along y-axis is zero.
(c) Probability of finding the electron is maximum along x and y-axis.
(d) Probability of finding the electron is zero in x-y plane.
1. Which of the following conclusions could not be derived from Rutherford’s α -
particle scattering experiment?
(i) Most of the space in the atom is empty.
(ii) The radius of the atom is about 10–10 m while that of nucleus is 10–15 m.
(iii)Electrons move in a circular path of fixed energy called orbits.
(iv)Electrons and the nucleus are held together by electrostatic forces of attraction.
2. Which of the following statement is not correct about the characteristics of cathode
rays?
(i) They start from the cathode and move towards the anode.
(ii) They travel in straight line in the absence of an external electrical or magnetic field.
(iii) Characteristics of cathode rays do not depend upon the material of electrodes
in cathode ray tube.
(iv) Characteristics of cathode rays depend upon the nature of gas present in the
cathode ray tube.
3. Which of the following statements about the electron is incorrect?
(i) It is a negatively charged particle.
(ii) The mass of electron is equal to the mass of neutron.
(iii)It is a basic constituent of all atoms.
(iv) It is a constituent of cathode rays.
4. Which of the following properties of atom could be explained correctly by
Thomson Model of atom?
(i) Overall neutrality of atom.
(ii) Spectra of hydrogen atom.
(iii)Position of electrons, protons and neutrons in atom.
(iv)Stability of atom.
5. Two atoms are said to be isobars if.
(i) they have same atomic number but different mass number.
(ii) they have same number of electrons but different number of neutrons.
(iii)they have same number of neutrons but different number of electrons.
(iv) sum of the number of protons and neutrons is same but the number of protons
is different.
6. Which of the following is responsible to rule out the existence of definite paths or
trajectories of electrons?
(i) Pauli’s exclusion principle.
(ii) Heisenberg’s uncertainty principle.
(iii)Hund’s rule of maximum multiplicity.
(iv)Aufbau principle.
7. Chlorine exists in two isotopic forms, Cl-37 and Cl-35 but its atomic mass is 35.5.
This indicates the ratio of Cl-37 and Cl-35 is approximately
(i) 1:2
(ii) 1:1
(iii)1:3
(iv) 3:1
8. If travelling at same speeds, which of the following matter waves have the
shortest wavelength?
(i) Electron
(ii) Alpha particle (He2+)
(iii)Neutron
(iv)Proton
Multiple Choice Questions (Type-II)
In the following questions two or more options may be correct.
9. Identify the pairs which are not of
isotopes?
10. Whi
ch of the following will not show deflection from the path on passing through an
electric
field?
Proton, cathode rays, electron, neutron.
11. Matching Type Questions
1. Match the following
2. Match the following
Assertion and Reason Type Questions
In the following questions a statement of Assertion (A) followed by a statement of
Reason (R) is given. Choose the correct option out of the choices given below each
question.
1. Assertion (A) : All isotopes of a given element show the same type
of chemical behaviour.
Reason (R) : The chemical properties of an atom are controlled by the number of
electrons in the atom.
(i) Both A and R are true and R is the correct explanation of A.
(ii) Both A and R are true but R is not the correct explanation of A.
(iii) A is true but R is false.
(iv) Both A and R are false.
2. Assertion (A) : Black body is an ideal body that emits and absorbs radiations
of all frequencies.
Reason (R) : The frequency of radiation emitted by a body goes from a lower
frequency to higher frequency with an increase in temperature.
(i) Both A and R are true and R is the correct explanation of A.
(ii) Both A and R are true but R is not the explanation of A.
(iii) A is true and R is false.
(iv) Both A and R are false.
