1

12th JEE Adv (P2)

CTA-01 [13-07-2025]
TIME: 3 Hrs. M. MARKS: 180
[JEE ADVANCED 2024 PAPER-2]
Topics Covered
PHYSICS : Complete Chapters: Electrostatics, Current electricity, Capacitors, Electromagnetism,
Classical Magnetism EMI, AC, EM Waves)
CHEMISTRY : Complete Chapters: Alkyl Halide and Aryl Halide, Alcohol, Phenol & Ether, Aldehyde
and Ketones, CAD, Amines, Liquid Solutions, Electorchemistry, Chemical Kinetics,
Radioactivity, p-block Group-15, p-block Group-16, p-block Group-17, p-block Group-18,
Coordination Chemistry
MATHEMATICS : Complete Chapters:(Matrices, Determinants, Relations & Functions (12th Class),
Inverse trigonometric functions, Limits, Continuity & Differentiability, Method of
differentiation, Application of Derivatives, Indefinite integration), Definite integration
(Basics of Definite Integrals, Definite Integrals as Limit of Sum, Properties of Definite
Integral, Properties of Definite Integral)

SECTION-1 (Maximum Marks: 12)

• This section contains FOUR (04) questions
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer
• For each question, darken the buble corresponding to the correct option(s) in the ORS.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.

SECTION-2 (Maximum Marks: 12)

• This section contains THREE (03) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct
answer(s).
• For each question, darken the buble corresponding to the correct option(s) in the ORS.
• For each question, marks will be awarded in one of the following categories:
Full Marks : +4 If only the bubble(s) corresponding to all the correct options is (are) darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided NO incorrect option is
darkened.
Zero Marks : 0 If unanswered;
Negative Marks : –2 In all other cases.
 2
SECTION-3 (Maximum Marks: 24)
• This section contains SIX (06) questions.
• The answer to each question is a NON-NEGATIVE INTEGER.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual numeric
keypad in the place designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.

SECTION-4 (Maximum Marks: 12)

• This section contains TWO (02) question stems.
• There are TWO (02) questions corresponding to each question stem.
• The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and
the on-screen virtual numeric keypad.
• If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the bubble(s) corresponding to all the correct options is (are) darkened.
Zero Marks : 0 In all other cases.
 3

PHYSICS
SINGLE CORRECT ANSWER TYPE
1. If all resistances are identical to 4.0  and all identical batteries have an emf of 10 V. The value of I1 – I2 is

(A) 2 Amp (B) 3 Amp (C) 4 Amp (D) 5 Amp

dB
2. Time dependent magnetic field is set up in a circular region as shown in figure. is positive. Choose CORRECT
dt
option.

R Q
I)  E.dl is positive; for straight line path QR II)  E.dl is negative; for straight line path PQ
Q P

P Q
III)  E.dl is negative; for curve arc path RQP IV)  E.dl = 0 ; for straight line path PQ
R P

(A) Only I, III and IV are correct

(B) Only I, II and III are correct
(C) Only II, III and IV are correct
(D) None of the above

3. A direct current of 2A and an alternating current having a maximum value of 2A flow through two identical
resistances. The ratio of heat produced in the two resistances in the same time interval will be
(A) 1 : 1 (B) 1 : 2 (C) 2 : 1 (D) 4 : 1

4. In an electromagnetic wave, the amplitude of electric field is 1V/m. The frequency of wave is 5 × 1014 Hz. The
wave is propagating along z-axis. The average energy density of electric field in Joule /m3, will be
(A) 1.1 × 1011 (B) 2.2 × 10–12 (C) 3 × 10–13 (D) 4.4 × 10–14
 4
ONE OR MORE THAN ONE CORRECT ANSWER TYPE
3
5. Two concentric shells A and B have radii R and 2R, charges qA and qB and potential 2V and   V respectively.
2
Now shell B is earthed and let charges on them become qA & qB . Then

qA 1
(A) =
qB 2
qA
(B) =1
qB
3
(C) Potential of A after earthing becomes   V
2
V
(D) Potential difference between A and B ( VA − VB ) after earthing becomes
2

6. A parallel plate air capacitor having separation ‘a’ between the plates is charged to Q and battery is disconnected
from the capacitor. Now the separation between the plates is increased to ‘2a’ slowly by external force. The work
done by external force is numerically equal to:
(A) Electrostatic energy stored in the increased volume of the capacitor
(B) Half of the electrostatic energy stored in the increased volume of the capacitor
(C) Two times the electrostatic energy stored in the increased volume of the capacitor
(D) Electrostatic energy stored in the initial volume of the capacitor

7. A rectangular loop (a  b) carries a current i . A uniform magnetic field B = B0 ˆi exists in space. Then

(A) Magnitude of torque on the loop is iabB0sin

(B) Torque on the loop is in negative y-direction
(C) If allowed to move, the loop will turn so as to increase 
(D) If allowed to move, the loop will turn so as to decrease 
 5
INTEGER TYPE (NON-NEGATIVE)
8. The diagram shown is a modified meter bridge, which is used for measuring two unknown resistances R1 and R2
at the same time. When only the first galvanometer is used, balance point is found at point C. Now the first
galvanometer is removed and the second galvanometer is used, which gives balance point D. Using the details
KR
given in the diagram, the value of R1 + R2 is found to be , then the value of K is ………
3

9. ( )
Potential function V(x, y) of an electrostatic field E = 2axyiˆ + a x 2 − y 2 ˆj (a is a constant) is given by

ay3
V0 + ( −1) ax m y +
n
(n is either ‘0’ or ‘1’) then value of (n + m + p) is
p

10. Analyse the given circuit in the steady state condition. The capacitor has capacitance 4 F Charge on the capacitor
is q0 = 16 C . If the e.m.f. of the battery is 6 k (in SI units) then find the value of k.

11. A conducting rod AB of mass m and length l is supported by conducting massless wires and carrying a steady
current I as shown in the figure. There exist a uniform magnetic field B in the vertically upward direction. The
rod is slightly displaced into the paper such that rod always remains parallel to x-axis and released to perform
−1/ 4
ka   BIl  
2

SHM. If its time period is 2 1 +    find the value of k. (neglect motional emf)
g   mg  
 

B
 6
12. Figure shows a conducting loop made of three identical coplanar squares. Side of each square is 1.2 m.
Perpendicular to the plane of loop in complete space there exists uniform time dependent magnetic field B = 20 t
Tesla, where ‘t’ is in sec. Resistance per unit length of wire of each square is 1/m . Find current in loop in
amperes?

13. A series R-C combination is connected to an AC voltage of angular frequency  = 500 rad s–1. If the impedance
of the R - C circuit is R 1.25 , find the time constant (in millisecond) of the circuit.

NUMERICAL VALUE ANSWER TYPE

Question Stem for Question Nos. 14 and 15:
A coil having a resistance of 50.0Ω and an inductance of 0.5 H is connected to an AC source of 110 V, 50 Hz.
14. The impedance (in ) of the coil is ……

15. The rms current (in A) in the circuit is……

Question Stem for Question Nos. 16 and 17:

A circular loop of radius R is kept in x-y plane with centre at origin. Magnetic field in region is given by
B = B ˆi + 2B ˆj + 3B kˆ . Based on above information, answer the following questions
0 0 0

16. If loop starts rotating with angular velocity  about x–axis. Then value of average induced emf during the time
loop changes its plane from x-y plane to x–z plane for the first time is KB0R2. Then the value of 1/K is……

17. If a current i is flowing in loop when it was in x–y plane and at rest. The direction of current is such that when an
observer situated at positive z-axis looks at loop he finds direction of current clockwise. The value of net torque
 ĵ 
about centre of loop is liR 2 B0  ˆi −  . Then the value of l is …… (Given  = 3.14)
 2
 
 7
CHEMISTRY

SINGLE CORRECT ANSWER TYPE

18. The best sequence of reactions for preparation of the following compound from benzene is

(A) (i) CH3COCl/Anhydrous AlCl3(ii) Oleum (iii) (CH3)2CH–Cl(1 mole)/ Anhydrous AlCl3
(B) (i) (CH3)2CH–Cl(1 mole)/Anhydrous AlCl3(ii) CH3COCl/Anhydrous AlCl3 (iii) Oleum
(C) (i)Oleum(ii) CH3COCl/Anhydrous AlCl3 (iii) (CH3)2CH–Cl(1 mole)/Anhydrous AlCl3
(D) (i) (CH3)2CH–Cl(1 mole)/Anhydrous AlCl3 (ii) Oleum (iii) CH3COCl/Anhydrous AlCl3

99
19. The half-life of Tc is 6.0 hrs . The total residual activity in a patient after receiving an injection containing
99
Tc must not be more than 0.01 μCi, after 36.0 hours. What is the maximum activity (in μCi) that the sample
injected can have?
(A) 0.06 (B) 0.16 (C) 0.32 (D) 0.64

20. Identify the correct order of wavelength of light absorbed for the following complex ions.
3+
Co ( H 2 O ) 
 6 Co(CN)6 3− Co(I)6 3− Co(en)3 3+
I II III IV
(A) III > I > IV > II (B) II > IV > I > III (C) III > I > II > IV (D) I > III > IV > II

21. The element with least electron affinity is

(A) S (B) O (C) Se (D) Te

ONE OR MORE THAN ONE CORRECT ANSWER TYPE

22.


( CH3CH2 )3 O+ CH3CO2− ⎯⎯
→Y + Leaving group ‘Z’
••
Identify the correct statement(s)
(A) X and Z are identical compounds
(B) ‘X’ is formed through SN1 path and ‘Y’ is formed through S N 2 path, majorly.
(C) ‘X’ is an aromatic compound
(D) ‘X’ and ‘Z’ are ether whereas ‘Y’ is ester

23. Two liquids A and B form an ideal solution. The solution has vapor pressure of 700 torr at 80° C. It is distilled
till 2/3rd of the solution is collected as condensate. The composition of the condensate is X 'A = 0.75 and that of
the residue is X ''A = 0.30 . If the vapor pressure of the residual liquid at 80^∘ C is 600 torr, which of the following
is/are true?
(A) The composition of the original liquid was XA = 0.6
(B) The composition of the original liquid was XA = 0.2
2500
(C) PA = torr
3
(D) PB = 500torr
 8
24. Choose correct statement(s):
(A) Ozone oxidizes acidic potassium iodide solution to iodine and is itself reduced to O 2 , undergoing a +2 change
in oxygen oxidation state.
(B) Reaction of Cl2O with water yields an acid whose conjugate base has one Cl − O bond and one O – H bond
per molecule.
(C) Heating rhombic sulphur above 95.5 C forms a more thermodynamically stable allotrope containing S8
puckered rings.
(D) Disproportionation of ClO− in hot alkaline solution gives a chloride and a chlorate; in this reaction, the
oxidation number of chlorine changes by 2 and 4 units respectively.

INTEGER TYPE (NON-NEGATIVE)

25. How many of the following compounds undergo self cannizzaro reaction (or) Internal cannizzaro reaction.

26. Schemes 1 and 2 describe the conversion of P to Q and R to S, respectively. Scheme 3 describe the synthesis of
T from Q and S. The total number of ‘Br’ atoms in molecule of ‘T’ is
Scheme 1:

Scheme 2:

Scheme 3:
 9
27. The vapour pressure of pure X are given by the following equation.
300
Solid X: ln P(mm of Hg ) = 10 −
T
200
Liquid X: ln P(mm of Hg ) = 5 − (All temperature are in K)
T
Calculate the freezing point of X (in K):

+
28. Number of stereo isomers possible for a complex ion are Co ( NH3 )2 ( H 2O )2 Cl Br  is

29. Haemoglobin exists in two predominant forms in our bodies.

One form, known as oxyhaemoglobin, has O2 bound to the metal ion (A) and the other known as
deoxyhaemoglobin, has a water molecule bound instead. Oxyhaemoglobin is a low spin complex that gives arterial
blood its red colour and deoxyhaemoglobin is a high spin complex that gives venous blood its darker colour.
x y
If the electronic configurations of metal ion (A) in oxyhaemoglobin and deoxyhaemoglobin are t 2g eg and t a2g egb
x+y
respectively, then the value of is:
a+b

30. If the number compounds, which can shows the Claisen condensation is X, then 8x/3 is.

NUMERICAL VALUE ANSWER TYPE

Question Stem for Question Nos. 31 and 32:
The Ksp of MI is 1 10−5 M 2 . A cell is constructed, represented as
–
M(s)|MI(s)|I (1M)||Cu2+ (1M)|Cu(s)
RT
[Given that = 0.06 and also E 0cell = 3.7 V , also M is a metal]
F
E cell
31. Determine .
3.7

32. Determine the oxidation potential of metal if E = 0.34 V (nearest integer).

Cu 2+∣ Cu

Question Stem for Question Nos. 33 and 34:

Xenon forms fluorides like XeF6 which, on controlled hydrolysis, yield oxyfluorides such as XeOF4 and XeO2F2. These
compounds exhibit distinct geometries and oxidation states. XeF6 also reacts with silica (SiO2) to form SiF4 and xenon
oxyfluorides. VSEPR theory helps predict the shape and bonding in these species.
33. When 2 moles of XeF6 react with excess SiO2, the number of fluorine atoms bonded to xenon in the final products is

34. In XeO2F2, the sum of σ bonds to xenon and lone pairs on xenon is
 10

MATHEMATICS
SINGLE CORRECT ANSWER TYPE
6
 yi
6  ex 
( )
i =1
35. If sin −1 x i + cos −1 yi = 9 , then  ( )
x n 1 + x2  2x  dx
i =1 6 1+ e 
 xi
i =1

 37 
(A) 0 (B) e6 + e−6 (C) n  (D) e6 − e−6
 12 

x
36. let ‘f’ be a real valued function defined on the interval (–1, 1) such that e− x .f ( x ) = 2 +  t 4 + 1dtx  ( −1,1) and
0

let ‘g’ be the inverse function of ‘f’. Then g(2) = (Derivative of g(x) at x = 2)
1 1
(A) 3 (B) (C) (D) 2
2 3

1+ x
37. Let g ( x ) =  t f  ( t ) dt , where f(x)does not behave like a constant function in any interval (a, b) and the graph
1− x

of y = f (x) is symmetric about the line x = 1. Then

(A) g(x) is increasing x  R (B) g(x) is increasing only if x  1
(C) g(x) is increasing only if f is increasing (D) g(x) is decreasing x  R

38. Let the function f (x) = ax6 + bx5 + cx4 + dx3 + ex2 + fx + g (a  0) touches the line y = g(x) = x + p at x = 1, 2 and 3 and
3
32
h(x) = f(x) – g(x). If  h ( x ) dx = .Then the value of a is equal to ______
1 105
(A) 2 (B) 3 (C) 4 (D) –2

ONE OR MORE THAN ONE CORRECT ANSWER TYPE

n ( n + 1) n + 1 −1
39. (n) = 0 1 n which of the following options is/are correct?
1 −n − 1 1
(A)  ( n ) can be written as a perfect square of a natural number for all “n  I’’
(B)  ( n ) can be written as sum of perfect square of 3 natural numbers for all such “n  N’’
(C) If n  I , then minimum value of Δ(n) = 1
(D) If n  I , then minimum value of Δ(n) = 2

40. Suppose that f : R→ R is a continuous function and f(x). f(f(x)) = 1, for all real x.
Let f(1000) = 999, then which of the following must be true?
1 1
(A) f (500) = (B) f (1000) =
500 1000
x
(C) f ( x ) = has at least 3 solutions (D) f (x) can be a one function
2
 11
41. Which of the following statement(s) is (are) correct?
(A) The value of tan( tan(tan–13) – tan–1(tan3)) equals 0
(B) The range of function f (x) = ln(sgn x) contains exactly one integer, where sgn x denotes signum function of x.
k

 ( cot ( cot −1 2) )
10
(C) The value of equals 2047
k =1

(D) The value of sin–1 (cos1) – cos–1 (sin1) equals 0.

INTEGER TYPE (NON-NEGATIVE)

42. A polynomial function P(x) of degree 5 with leading coefficient one, increases in the interval (–  , 1] and [3, )
P ( 6 )
and decreases in the interval [1, 3]. Given that P(0) = 4 and P(2) = 0, then the value of is,
200

2
43. The value of the definite integral I =  In 2sin x + 1dx = ____________
0

x x x
44. f n ( x ) = sin x + sin + sin +… sin .( n  N ) . If fundamental period of f100(x) is T1 fundamental period of
2 3 n
 T 
f103(x) is T2, then  2  is equal to ____________. ([] denotes G.I.F.)
100T1 

45. If f (x) = 3x 5 − 5x 3 + 1 , then number of distinct real roots of fof (x) = 0 , is

 1 1
46. When    − ,  , then the number of roots of equation 100x3 − 99x +  = 0 in the interval [–1, 1] is ….
 2 2

47. A line drawn from the origin touches the curve y 2 = x 2 − x + 1 in the first quadrant. If the line is inclined
at an acute angle  with the positive x-axis, then [2 tan  ] is equal to
(where [.] is greatest integer function)

NUMERICAL VALUE ANSWER TYPE

Question Stem for Question Nos. 48 and 49:
2
Consider f (x) = kex − x for all real x where k is a real constant.
2
48. The positive value of k for which kex − x = 0 has two solutions only then the value of [5k] is equal to
(where [.] is greatest integer function):

2
49. For k > 0, the set of all values of k for which curve y = | x | and y = ke x has more than two distinct roots, is (a,
b) then the value of [a + b] is equal to (where [.] is greatest integer function):
 12
Question Stem for Question Nos. 50 and 51:
Let f : R → R be a differentiable function such that f(1) = 1, f(2) = 20, f (–4) = –4, f (0) = 0
and f (x + y) = f(x) + f(y) + 3xy (x + y) + bxy + c(x + y) + 4  x, y , where a, b, c are constants.
50. The value of (b + c) is equal to:

51. Number of solutions of the equation f(x) = x3 + 4ex is equal to:

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