Mass and Heat Transfer Analysis of Mass Contactors and Heat Exchangers 1st Edition T. W. Fraser Russell PDF Version
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P1: KAE
CUFX282-pre CUFX282/Russell 978 0 521 88670 3 March 7, 2008 11:4
This book allows instructors to teach a course on heat and mass transfer that will equip
students with the pragmatic, applied skills required by the modern chemical industry. This
new approach is a combined presentation of heat and mass transfer, maintaining mathe-
matical rigor while keeping mathematical analysis to a minimum. This allows students to
develop a strong conceptual understanding and teaches them how to become proficient
in engineering analysis of mass contactors and heat exchangers and the transport theory
used as a basis for determining how the critical coefficients depend on physical properties
and fluid motions.
Students will first study the engineering analysis and design of equipment important
in experiments and for the processing of material at the commercial scale. The second
part of the book presents the fundamentals of transport phenomena relevant to these
applications. A complete teaching package includes a comprehensive instructor’s guide,
exercises, design case studies, and project assignments.
Norman J. Wagner is the Alvin B. and Julia O. Stiles Professor and Chair of the Depart-
ment of Chemical Engineering at the University of Delaware. His international teaching
and research experience includes a Senior Fulbright Scholar Fellowship in Konstanz, Ger-
many, and a sabbatical as a Guest Professor at ETH, Zurich, as well as at “La Sapienza,”
Rome, Italy.
i
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CUFX282-pre CUFX282/Russell 978 0 521 88670 3 March 7, 2008 11:4
ii
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Series Editor:
Arvind Varma, Purdue University
Editorial Board:
Alexis T. Bell, University of California, Berkeley
Edward Cussler, University of Minnesota
Mark E. Davis, California Institute of Technology
L. Gary Leal, University of California, Santa Barbara
Massimo Morbidelli, ETH, Zurich
Athanassios Z. Panagiotopoulos, Princeton University
Stanley I. Sandler, University of Delaware
Michael L. Schuler, Cornell University
iii
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iv
P1: KAE
CUFX282-pre CUFX282/Russell 978 0 521 88670 3 March 7, 2008 11:4
T. W. FRASER RUSSELL
University of Delaware
NORMAN J. WAGNER
University of Delaware
v
CAMBRIDGE UNIVERSITY PRESS
Cambridge, New York, Melbourne, Madrid, Cape Town, Singapore, São Paulo
Cambridge University Press has no responsibility for the persistence or accuracy of urls
for external or third-party internet websites referred to in this publication, and does not
guarantee that any content on such websites is, or will remain, accurate or appropriate.
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CUFX282-pre CUFX282/Russell 978 0 521 88670 3 March 7, 2008 11:4
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viii
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Contents
PART I
1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
References 19
ix
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x Contents
Contents xi
PART II
5 Conduction and Diffusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 187
5.1 Rate of Thermal Conduction 187
5.1.1 Experimental Determination of Thermal Conductivity k and
Verification of Fourier’s Constitutive Equation 187
5.1.2 Definition of the Biot Number for Heat Transfer 195
5.1.3 Definition of the Nusselt Number 199
5.2 Rate of Molecular Diffusion 201
5.2.1 Experimental Determination of Binary Diffusivities DAB and
Verification of Fick’s Constitutive Equation 201
5.2.2 Definition of the Biot Number for Mass Transfer 206
5.2.3 Definition of the Sherwood Number 208
5.3 Geometric Effects on Steady Heat Conduction and Diffusion in
Solids and Quiescent Fluids 209
5.3.1 One-Dimensional Heat Conduction in Nonplanar Geometries 209
5.3.2 One-Dimensional Diffusion in a Conical Geometry 211
5.4 Conduction and Diffusion Through Composite Layered Materials
in Series 212
5.4.1 Overall Heat Transfer Coefficient for Composite Walls:
Resistance Formulation 212
5.4.2 Overall Heat Transfer Coefficient for a Tubular Exchanger 217
5.4.3 Overall Mass Transfer Coefficient for Diffusion Through a
Composite Wall 220
5.5 Molecular Conduction and Diffusion with Generation 222
5.5.1 Radial Heat Conduction with Generation 222
5.5.2 Diffusion with Chemical Reaction 224
5.6 Diffusion-Induced Convection: The Arnold Cell 225
5.7 Basics of Membrane Diffusion: The Sorption–Diffusion Model 230
5.8 Transient Conduction and Diffusion 231
5.8.1 Short-Time Penetration Solution 233
5.8.2 Small Biot Numbers—Lumped Analysis 235
Nomenclature 236
Important Dimensionless Groups 238
References 239
Problems 240
xii Contents
Preface
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