SYLLABUS:- Full Modern Physics Except Semiconductor, Full Organic, Full Calculus

PHYSICS
1. When the speed of electrons increase, then the value of its specific char
(a) increases (b) decreases (c) remains unchanged (d) increases up to some velocity and then
begins to decrease
2.Photoelectric emmision occurs only when the incident light has more than a certain minimum
(a) power (b) wavelength (c) intensity (d) frequency
3.The kinetic energy of emitted electron is 𝑬 when the light incident on the metal has wavelength 𝝀.
To double the kinetic energy, the incident light must have wavelength :
𝐡𝐜 𝐡𝐜𝝀 𝐡𝝀 𝐡𝐜𝝀
(a) 𝐄𝝀−𝐡𝐜 (b) 𝐄𝝀+𝐡𝐜 (c) 𝐄𝝀+𝐡𝐜 (d) 𝐄𝝀−𝐡𝐜

4. . Light of a particular frequency 𝒗 is incident on a metal surface. When the intensity of incident
radiation is increased, the photoelectric current
(a) decreases (B)increases (c) remains unchanged (d) sometimes increases and sometimes decreases
5. The Electromagnetic theory of failed to explain
(a)photoelectric effect (b)polarization (c) diffraction (d) interference
6. In a photoelectric experiment, anode potential (v) is plotted against plate current (I)
(a) A and B will have different intensities while B and C will have different frequencies
(b) 𝐁 and 𝐂 will have different intensities while 𝐀 aîd𝐂 will have different frequencies
(c) 𝐀 and 𝐁 will have different intensities while 𝐀 and 𝐂𝟐−𝟓 will have equal frequencies
(d) A and B will have equal intensities while B and C will have different frequencies
7. Light of wavelength 𝝀𝑨 and 𝝀𝑩 falls on two identical metal plates 𝑨 and 𝑩 respectively. The maximum
kinetic energy of photoelectrons is 𝑲𝑨 and 𝑲𝑩 respectively, then which one of the following relations is
true (𝝀𝐀 = 𝟐𝝀𝐁 )
𝐊𝐁
(a) 𝐊 𝐀 < (b) 𝟐𝐊 𝐀 = 𝐊 𝐁 (c) 𝐊 𝐀 > 𝟐𝐊 𝟐𝐁 (d) 𝐊 𝐀 > 𝟐𝐊 𝐁
𝐊 𝟐𝐁

8. Einstein's photoelectric equation states that 𝐡𝝂 = 𝐖𝟎 + 𝐄𝐤 . In this equatin, 𝐄𝐤 refers to the

(a) kinetic energy of all the emitted electrons (b) mean kinetic energy of the emitted electrons
(c) maximum kinetic energy of the emitted electrons(d) minimum kinetic energy of the emitted electrons
9. A free particle with initial kinetic energy 𝑬, de-Broglie wavelength 𝝀, enters a region wherein it has a
potential energy 𝑽, what is the new de-Broglie wavelength?
(a) 𝝀(𝟏 + 𝑬/𝑽) (c) 𝝀(𝟏 + 𝑽/𝑬)𝟎.𝟓 (b) 𝝀(𝟏 − 𝑽/𝑬) (d) 𝝀/(𝟏 − 𝑽/𝑬)𝟎.𝟓
10. An electron of mass 𝒎 and charge e initially at rest gets accelerated by a constant electric field 𝐄. The
rate of change of de-Broglie wavelength of this electron at time 𝒕 ignoring relativistic effects i
−𝐡 −𝐞𝐡𝐭 −𝐦𝐡 −𝒉
(a) 𝐞𝐄𝐭 (b) (c) 𝐞𝐄𝐭𝟐 (d)
𝐄 𝐞𝐄

11. A particles of mass 𝒎 is projected from ground with velocity 𝒖 making angle 𝜽 with the vertical. The
de Broglie wavelength of the particle at the highest point is
(a) ∞ (b) 𝐡/𝐦𝐮𝐬𝐢𝐧⁡ 𝜽 (c) 𝐡/𝐦𝐮𝐜𝐨𝐬⁡ 𝜽 (d) 𝐡/𝐦𝐮
12.A particle is dropped from a height 𝑯. The de-Broglie wavelength of the particle as a function of
height is proportional to (a) H (b) 𝐇 𝟏/𝟐 (c) 𝐇 𝟎 (a) 𝐇 −𝟏/𝟐

13.The nuclear radius of 𝟖 𝐎𝟏𝟔 is 𝟑 × 𝟏𝟎−𝟏𝟓 𝐦. If an atomic mass unit is 𝟏. 𝟔𝟕 × 𝟏𝟎−𝟐𝟕 𝐤𝐠, then the
nuclear density is approximately
(a) 𝟐. 𝟑𝟓 × 𝟏𝟎𝟏𝟕 𝐠𝐜𝐦−𝟑 (b) 𝟐. 𝟑𝟓 × 𝟏𝟎𝟏𝟕 𝐤𝐠𝐦−𝟑 (c) 𝟐. 𝟑𝟓 × 𝟏𝟎𝟏𝟕 𝐠𝐦−𝟑 (d) 𝟐. 𝟑𝟓 × 𝟏𝟎𝟏𝟕 𝐤𝐠𝐦𝐦−𝟑
𝟗
14. The radius of germanium (𝐆𝐞) nuclide is measured to be twice the radius of 𝟒 𝐁𝐞. The number of
nucleons in Ge are (a) -74 (b) 75 (c) 72 (d) 73
15. The mass of an atomic nucleus is less than the sum of the masses of its constituents. This mass defect
is converted into
(a) heat energy (b) light energy (c) electrical energy (d) energy which binds nucleons together
16. Radioactivity is
(a) irreversible process (b) self disintegration process (c) spontaneous (d) all of the above
17.The mass number of 𝐇𝐞 is 4 and that for sulphur is 32 . The radius of sulphur nuclei is larger than that

of helium by (a) √𝟖 (b) 4 (c) 2 (d) 8

18. A nucleus of mass number 189 splits into two nuclei having mass number 125 and 64 . The ratio of
radius of two daughter nuclei respectively is:
(a) 𝟒: 𝟓 (b) 𝟓: 𝟒 (c) 𝟐𝟓: 𝟏𝟔 (d) 𝟏: 𝟏
19. . Which of the following is not a mode of a radioactive decay?
(a) Positron emission (b) Electron capture (c) Fusion (d) Alpha decay

20. If 𝟏𝐦𝐠 of 𝐔 𝟐𝟑𝟓 is completely annihilated, the energy liberated is

(a) 𝟗 × 𝟏𝟎𝟏𝟎 𝐉 (c) 𝟗 × 𝟏𝟎𝟏𝟖 𝐉 (b) 𝟗 × 𝟏𝟎𝟏𝟗 𝐉 (d) 𝟗 × 𝟏𝟎𝟏𝟕

21. The ratio of volumes of nuclei (assumed to be in spherical shape) with respective mass numbers 8
and 64 is
𝟐𝟕 𝟏𝟐𝟓
22. If radius of the 𝟏𝟑 𝐀𝐥 nucleus is estimated to be 3.6 fermi then the radius of 𝟓𝟐 𝐓𝐞 nucleus be
nearly
23. A heavy nucleus having mass number 200 gets disintegrated into two small fragments of mass
number 80 and 120 . If binding energy per nucleon for parent atom is 6.5 MeV and for daughter nuclei is
𝟕𝐌𝐞𝐕 and 𝟖𝐌𝐞𝐕 respectively, then the energy released in the decay is 𝐗 × 𝟏𝟏𝟎𝐌𝐞𝐕. Find X .
24. In Rutherford's 𝜶-particle scattering experiment, what will be correct angle for 𝜶 scattering for an
impact parameter = 𝟎 ?
25. The third line of Balmer series of an ion equivalnet to hydrogen atom has wavelength of 𝟏𝟎𝟖. 𝟓𝐧𝐦.
The ground state energy of an electron of this ion will be
 33333333333333).+3/9:8?
CHEMESTRY
1. Which property of carbon is responsible for number of carbon compounds?
(a) Catenation (b) Isomerism (c) Tetravalency (d) All of these
2. The most stable carbanion among the following is
(a) (b)

(c) (d)

3. Which of the following does not represent formation of reactive intermediate correctly?
(i) (ii)

(iii) (iv)

(a) (ii) only (b) (ii) and (iii) (c) (ii) and (iv) (d) (iii) and (iv)
4. With respect to benzyl carbocation and benzyl carbanion, the correct statement is:
(a) C6 H5 C+ H2 ion is more stable that C +H3 ion and C6 H5 C2−ion is also more stable than C − H3 ion
(b) C6 H5 C +H2 ion is less stable than C +H3 ion and C6 H5 CH2−ion is more stable than C − H3 ion
(c) C6 H5 C+ H2 ion is more stable than C + H3 ion and C6 H5 C −H2 ion is less stable than CH3−ion
(d) C6 H5 C +H2 ion is less stable than C +H3 ion and C6 H5 C− H2 ion is also less stable than C − H3 ion.
5. But-2-ene exhibits cis,trans-isomerism due to
(a) rotation around C3 − C4 sigma bond (b) restricted rotation around C = C bond
(c) rotation around C1 − C2 bond (d) rotation around C2 − C3 double bond
Reagent
6. R − CH2 − CCl2 − R → R − C ≡ C − R
The reagent is
(a) Na (b) HCl in H2 O (c) KOH in C2 H5 OH (d) Zn in alcohol.
7. In which case CO2 is not produced as a by product?
(d) Both in (a) and (c )

8. During the nitration of benzene. In the process of generation of nitronium ion sulphuric acid behaves as
a/an______and nitric acid behave as a/an_________
(a) base, acid (b) acid, base (c) strong acid, weak acid (d) weak acid, strong acid
9. The mechanism of 𝑆𝑁 1 reaction is given as:
Y⊖
R − X ⟶ R⊕ X ⊖ ⟶ R⊕ ∥ X ⊖ ⟶ R − Y + X ⊖
Ion pair Solvent
Separated ion
pair
A student writes general characteristics based on the given mechanism as :
(1) The reaction is favoured by weak nucleophiles.
(2) 𝑅 ⊕ . would be easily formed if the substituents are bulky.
(3) The reaction is accompanied by racemization.
(4) The reaction is favoured by non-polar solvents.
Which observations are correct?
(a) (1) and (2) (b) (1) and (3) (c) (1), (2) and (3) (d) (2) and (4)
10. 2-Bromopentane is heated with potassium ethoxide in ethanol. The major product obtained is
(a) 2-ethoxypentane (b) pentene-1 (c) trans-2-pentene (d) cis-pentene-2
11. Consider the following bromides:

The correct order of SN 1 reactivity is

(a) B > 𝐶 > 𝐴 (b) B > 𝐴 > 𝐶 (c) C > 𝐵 > 𝐴 (d) A > B > 𝐶
12. Which one of the following compounds has the most acidic nature?
(a) (b)

(C) (d)

13. The major product formed in the following reaction is :

(a) (b)

(C) (d)

14. In the commercial manufacture of ethyl alcohol from starchy substances by fermentation method. Which
enzymes stepwise complete the fermentation reaction
(a) Diastase, maltase and zymase (b) Maltase, zymase and invertase
(c) Diastase, zymase and lactase (d) Diastase, invertase and zymase
15. The products formed in the following reaction, 𝐀 and 𝐁 are

(a) (b)

(C) (d)

16. Which will have maximum enol content?

(a) (b)

(C) (d)

17. In Friedel-Crafts alkylation of aniline, one gets :

(a) alkylated product with ortho and para substitution. (b) secondary amine after acidic treatment.
(c) an amide product. (d) positively charged nitrogen at benzene ring.
18. For the below given cyclic hemiacetal (X), the correct pyranose structure is :

(a) (b)

(C) (d)

19. Invert sugar is

(a) chemically inactive form of sugar (b) equimolecular mixture of glucose and fructose
(c) mixture of glucose and sucrose (d) a variety of cane sugar
20. Select the false statement about the cyclic glucose.
(a) If the OH group is added to CHO group it will form cyclic hemiacetal structure
(b) Glucose form Six-membered ring in which-OH is at C-5 position
(c) Melting point of 𝛼-glucose is 423K and of 𝛽-glucose is 419K
(d)

21

.
22. 12.0 g of benzoic acid (C₇H₆O₂, M = 122 g·mol⁻¹) is reacted with excess methanol to give methyl benzoate (M
=.136 g·mol⁻¹). After workup you obtain 9.6 g methyl benzoate. Calculate % yield
23. Determine degrees of unsaturation for C₈H₁₀O.
24. Combustion of 0.500 g of an organic compound gave 1.467 g CO₂ and 0.600 g H₂O. Determine empirical formula
(assume only C and H present).Then what is the molecular formula of getting this empirical formula.
25. 1, 2-Diethylbenzene on ozonolysis gives how many different products?
 MATHEMATICS
1. ∫𝑥51 tan−1 𝑥 + cot−1 𝑥 𝑑𝑥

𝑥 52 𝑥 52
(a) tan−1 𝑥 + cot −1 𝑥 + 𝑐 (b) tan−1 𝑥 − cot −1 𝑥 + 𝑐
52 52
𝜋x 52 𝜋 x 52 𝜋
(c) +2+c (d) +2+c
104 52
𝑑𝑦 2𝑥 −𝑦 2𝑦 −1
2. If 𝑑𝑥 + 2𝑥 −1 = 0, 𝑥, 𝑦 > 0, 𝑦(1) = 1, then 𝑦(2) is equal to :
(a) 2 + log 2 3 (b) 2 + log 3 2 (c) 2 − log 3 3 (d) 2 − log 2 3
1−sin 3 𝑥 𝜋
,𝑥 <
3cos 2 𝑥 2
𝜋 𝜋
3 .Let 𝑓(𝑥) = 𝑝, 𝑥 = 2
If f(x) is continuous at x = 2 , (p, q) =
𝑞(1−sin 𝑥) 𝜋
,𝑥 >
(𝜋−2𝑥)2 2
1 1
(a) (1,4) (b) ,2 (c) ,4 (d) None of these
2 2
𝑥(cos 𝑥−sin 𝑥) 𝑔(𝑥) 𝑒 𝑥 +1−𝑥𝑒 𝑥 𝑥𝑔 (𝑥)
4. Let 𝑔: (0, ∞) → 𝑅 be a differentiable function such that ∫ + 𝑑𝑥 = + 𝑐,
𝑒 𝑥 +1 𝑒 𝑥 +1 2 𝑒 𝑥 +1
for all 𝑥 > 0, where 𝑐 is an arbitrary constant. Then
𝜋 𝜋
(a) 𝑔 is decreasing in 0, 4 (b) 𝑔′ is increasing in 0, 4
𝜋 𝜋
(c) 𝑔 + 𝑔′ is increasing in 0, 2 (d) ' 𝑔 − 𝑔′ is increasing in 0, 2
𝑑𝑦
5. If 𝑦 = 𝑦 𝑥 is the solution of the differential equation 1 + 𝑒 2𝑥 + 2 1 + 𝑦 2 𝑒 𝑥 = 0 and 𝑦(0) = 0,
𝑑𝑥
2
then 6 𝑦 ′ (0) + 𝑦 log 𝑒 3 is equal to:
(a) 2 (b) -2 (c) -4 (d) -1
8
6. If the ordinate 𝑥 = 𝑎 divides the area bounded by 𝑥-axis, part of the curve 𝑦 = 1 + 𝑥 2 and the ordinates
𝑥 = 2, 𝑥 = 4 into two equal parts, then 𝑎 is equal to
(a) 2 (b) 2 2 (c) 3 2 (d) None of these
d𝑦
7 .If 𝑦(𝑥) is the solution of the differential equation (𝑥 + 2) d𝑥 = 𝑥 2 + 4𝑥 − 9, 𝑥 ≠ −2 and y(0) = 0, then
y(−4) is equal to :
(a) 0 . (b) 2 (c) 1 (d) -1
cos (2𝜋𝑥 )−𝑥 2𝑛 sin (𝑥−1)
8. The function 𝑓: R → R defined by 𝑓(𝑥) = lim𝑛→∞ is continuous for all 𝑥 iS
1+𝑥 2𝑛 +1 −𝑥 2𝑛
(a) R − {−1} (b) R − {−1,1} (c) R − {1} (d) R − {0}
1
9. ∫ (𝑥−1)3 (𝑥+2)5 1/4 𝑑𝑥 is equal to
4 𝑥−1 1/4 4 𝑥+2 1/4 1 𝑥−1 1/4 1 𝑥+2 1/4
(a) 3 +𝐶 (b) 3 +𝐶 (c) 3 +𝐶 (d) 3 +𝐶
𝑥+2 𝑥−1 𝑥+2 𝑥−1
2𝑒 2𝑥 −6𝑒 −𝑥 +9
10. The slope of the tangent to a curve 𝐶: 𝑦 = 𝑦(𝑥) at any point (𝑥, 𝑦) on it is . If 𝐶 passes
2+9𝑒 −2𝑥
1 𝜋 1
through the points 0, 2 + 2 and 𝛼, 2 𝑒 2𝛼 , then 𝑒 𝛼 is equal to:
2
3+ 2 3 3+ 2 1 2+1 2+1
(a) 3− (b) (c) (d)
2 2 3− 2 2 2−1 2−1
2x 𝑑𝑦
11. Let the solution curve 𝑦 = 𝑦(𝑥) of the differential equation 1 + e + 𝑦 = 1 pass through the
𝑑𝑥
𝜋
point 0, . Then, lim𝑒 𝑥 𝑦(𝑥) is equal to:
2
𝜋 3𝜋 𝜋 3𝜋
(a) 4 (b) 4 (c) 2 (d) 2
12. If 𝑦 = 3cos(log𝑥) + 4sin(log𝑥), then
(a) 𝑥𝑦2 + 𝑦1 + 𝑦 = 0 (b) 𝑥𝑦2 + 𝑦1 − 𝑦 = 0
(c) 𝑥 2 𝑦2 + 𝑥𝑦1 + 𝑦 = 0 (d) None of these
3 5 4 6 8
13. If ∫ sin 𝑥 cos 𝑥𝑑𝑥 = 𝐴sin 𝑥 + 𝐵sin 𝑥 + 𝐶sin 𝑥 + 𝐷. Then
 1 1 1 1 1 1
(a) A = 4 , B = − 3 , C = 8 , D ∈ R (b) A = 8 , B = 4 , C = 3 , D ∈ R
1 1
(c) A = 0, B = − 6 , C = 8 , D ∈ R (d) None of these
14. Let 𝑓(𝑥) be a continuous function such that the area bounded by the curve 𝑦 = 𝑓(𝑥), 𝑥-axis and the
𝑎2 𝑎 𝜋 𝜋
lines 𝑥 = 0 and 𝑥 = 𝑎 is + 2 sin𝑎 + 2 cos𝑎, then 𝑓 =
2 2
1 1
(a) 1 (b) 2 (c) 3 (d) None of these
1
15. If 𝑦 = 𝑦(𝑥) is the solution curve of the differential equation 𝑥 2 𝑑𝑦 + 𝑦 − 𝑥 𝑑𝑥 = 0; 𝑥 > 0 and
1
𝑦(1) = 1, then 𝑦 is equal to:
2
3 1 1
(a) 2 − (b) 3 + (c) 3 + e (d) 3 − e
e e
2𝑥 1−x 2
16. The derivative of sin−1 1+𝑥 2 with respect to cos −1 1+x 2 is equal to :
(a) 1 (b) -1 (c) 2 (d) None of these
2
17. 𝑓(𝑥) = 4log 𝑒 (𝑥 − 1) − 2𝑥 + 4𝑥 + 5, 𝑥 > 1, which one of the following is NOT correct?
(a) 𝑓 is increasing in (1,2) and decreasing in (2, ∞) (b) 𝑓(𝑥) = −1 has exactly two solutions
′ ′′
(c) 𝑓 (𝑒) − 𝑓 (2) < 0 (d) 𝑓(𝑥) = 0 has a root in the interval (𝑒, 𝑒 + 1)
1 𝑛+5 𝑥 2 −1
18. ∫ 𝑥 + 𝑥 𝑑𝑥 is equal to :
𝑥2
1 𝑛 +6 𝑛+6
𝑥+ 𝑥 2 +1 𝑥 𝑛+6
𝑥
(a) +𝑐 (b) (𝑛 + 6) + 𝑐 (c) (𝑛 + 6) + 𝑐 (d) None of these
𝑛 +6 𝑥2 𝑥 2 +1
𝑑𝑦 1
19. Let 𝑦 = 𝑦(𝑥) be a solution of the differential equation, 1 − 𝑥 2 𝑑𝑥 + 1 − 𝑦 2 = 0, |𝑥| < 1. If 𝑦 =
2
3 −1
, then 𝑦 is equal to:
2 2
3 1 1 3
(a) (b) − (c) (d) −
2 2 2 2
𝜋 𝑒 cos 𝑥 sin 𝑥
20. The value of ∫0 1+cos 2 𝑥 𝑒 cos 𝑥 +𝑒 −cos 𝑥 𝑑𝑥 is equal to
𝜋2 𝜋2 𝜋 𝜋
(a) 4 (b) 2 (c) 4 (d) 2
21 .For the curve C: 𝑥 2 + 𝑦 2 − 3 + 𝑥 2 − 𝑦 2 − 1 5
= 0, the value of 3𝑦 ′ − 𝑦 3 𝑦 ′′ , at the point
(𝛼, 𝛼), 𝛼 < 0, on C, is equal to
22. Let 𝑓: ℝ → ℝ be a function defined as
𝜋[𝑥]
𝑓(𝑥) = 𝑎sin + [2 − 𝑥], 𝑎 ∈ ℝ, where [𝑡] is the greatest integer less than or equal to 𝑡. If
2
4
lim𝑥→−1 𝑓(𝑥) exists, then the value of ∫0 𝑓(𝑥)𝑑𝑥 = -X. Then X = ?

23. Let 𝑓(𝑎) = 𝑔(𝑎) = 𝑘 and their nth derivatives 𝑓 𝑛 (𝑎), 𝑔𝑛 (𝑎) exist and are not equal for some 𝑛.
Further if
𝑓(𝑎)𝑔(𝑥)−𝑓(𝑎)−𝑔(𝑎)𝑓(𝑥)+𝑓(𝑎)
lim = 4, then the value of 𝑘 is
𝑥→𝑎 𝑔(𝑥)−𝑓(𝑥)
0
24. Let 𝑓(𝑥) = max{|𝑥 + 1|, |𝑥 + 2|, … , |𝑥 + 5|}. Then ∫−6 𝑓(𝑥)𝑑𝑥 is equal to
𝑥2 𝑦2
25. If the curves 𝑎 2 + 12 = 1 and 𝑦 3 = 8𝑥 intersect at right angles, then the value of 𝑎2 is equal to