Sub : Chemistry, Chapter -1: Solution, Class –XII, Worksheet -1

S.N. Question ANS

1 Which of the following units is useful in relating concentration of solution with its vapour pressure?
(a)mole fraction (b) parts per million (c) mass percentage (d) molality
2 On dissolving sugar in water at room temperature solution feels cool to touch. Under which of the
following cases dissolution of sugar will be most rapid?
(a) Sugar crystals in cold water. (b) Sugar crystals in hot water.
(c) Powdered sugar in cold water. (d) Powdered sugar in hot water.
3 At equilibrium the rate of dissolution of a solid solute in a volatile liquid solvent is .
(a) less than the rate of crystallization (b) greater than the rate of crystallisation
(c) equal to the rate of crystallization (d) zero
4 A beaker contains a solution of substance ‘A’. Precipitation of substance ‘A’ takes place when small
amount of ‘A’ is added to the solution. The solution is .
(a) saturated (b) supersaturated (c) unsaturated (d) concentrated
5 Maximum amount of a solid solute that can be dissolved in a specified amount of a given liquid
solvent does not depend upon .
(a) Temperature (b) Nature of solute (c) Pressure (d) Nature of solvent
6 Low concentration of oxygen in the blood and tissues of people living at high altitude is due to .
(a) low temp (b) low atm. pressure (c) high atm. pressure (d) both low temp & high atm. pressure
7 Considering the formation, breaking and strength of hydrogen bond, predict which of the following
mixtures will show a positive deviation from Raoult’s law?
(a) Methanol and acetone. (b) Chloroform and acetone. (c) Nitric acid and water. (d) Phenol and
aniline.
8 Colligative properties depend on .
(a) the nature of the solute particles dissolved in solution. (b)the number of solvent particles in solution.
(c) the physical properties of the solute particles dissolved in solution. (d) the nature of solvent particles.
9 Which of the following aqueous solutions should have the highest boiling point?
(a) 1.0 M NaOH (b) 1.0 M Na2SO4 (c) 1.0 M NH4NO3 (d) 1.0 M KNO3
10 The unit of Ebullioscopic constant is .
(a) K kg mol–1 (b) mol kg K–1 (c) kg mol–1 K (d) K mol kg–1
11 In comparison to a 0.01 M solution of glucose, the depression in freezing point of a 0.01 M MgCl2
solution is :
(a) the same (b) about twice (c) about three times (d) about six times
12 An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because .
(a) it gains water due to osmosis. (b) it loses water due to reverse osmosis.
(c) it gains water due to reverse osmosis. (d) it loses water due to osmosis.
13 At a given temperature, osmotic pressure of a concentrated solution of a substance .
(a) is higher than that at a dilute solution. (b) is lower than that of a dilute solution.
(c) is same as that of a dilute solution. (d) cannot be compared with osmotic pressure of dilute solution.
14 Which of the following is an example of a solid solution ?
(a) Sea water (b) Sugar solution (c) Smoke (d) 22 carat gold

15 The values of Van’t Hoff factors for KCl, NaCl and K2SO4, respectively, are .
(a) 2, 2 and 2 (b) 2, 2 and 3 (c) 1, 1 and 2 (d) 1, 1 and 1
16 Which of the following statements is false?
(a)Units of atmospheric pressure and osmotic pressure are the same.
(b)In reverse osmosis, solvent molecules move through a semipermeable membrane from a region
of lower concentration of solute to a region of higher concentration.
(c)The value of molal depression constant depends on nature of solvent.
(d)Relative lowering of vapour pressure, is a dimensionless quantity.
17 Value of Henry’s constant KH .
(a) increases with increase in temperature. (b) decreases with increase in temperature.
(c) remains constant. (d) first increases then decreases.
18 The value of Henry’s constant KH is .
(a) greater for gases with higher solubility. (b) greater for gases with lower solubility.
(c) constant for all gases. (d) not related to the solubility of gases.

19 KH value for Ar(g), CO2(g), HCHO (g) and CH4(g) are 40.39, 1.67, 1.83×10–5 and 0.413
respectively. Arrange these gases in the order of their increasing solubility.
(a) HCHO < CH4 < CO2< Ar (b) HCHO < CO2 < CH4 < Ar
 (c) Ar < CO2 < CH4 < HCHO (d) Ar < CH4 < CO2 < HCHO

20 We have three aqueous solutions of NaCl labelled as ‘A’, ‘B’ and ‘C’ with concentrations 0.1M,
0.01M and 0.001M, respectively. The value of van’t Hoff factor for these solutions will be in the
order.
(a) A< B< C (b) A> B> C (c) A= B= C (d) A< B> C
21 On the basis of information given below mark the correct option. Information:
(i) In bromoethane and chloroethane mixture intermolecular interactions of A–A and B–B type are
nearly same as A–B type interactions.
(ii)In ethanol and acetone mixture A–A or B–B type intermolecular interactions are stronger than A–B
type
(iii)In chloroform and acetone mixture A–A or B–B type intermolecular interactions are weaker than A–
B type
(a)Solution (B) and (C) will follow Raoult’s law. (b) Solution (A) will follow Raoult’s law.
(c) Solution (B) show -ve deviation from Raoult’s law. (d) Solution (C) show +ve deviation from
Raoult’s law.
22 Two beakers of capacity 500 mL were taken. One of these beakers, labelled as “A”, was filled
with 400 mL water whereas the beaker labelled “B” was filled with 400 mL of 2 M solution of
NaCl. At the same temperature both the beakers were placed in closed containers of same
material and same capacity as shown in Fig. 2.2.
At a given temperature, which of the following statement is correct about the vapour pressure of pure
water and that of NaCl solution.
(a)vapour pressure in container (A) is more than that in container (B).
(b)vapour pressure in container (A) is less than that in container (B).
(c)vapour pressure is equal in both the containers.
(d)vapour pressure in container (B) is twice the vapour pressure in container (A).
23 If two liquids A and B form minimum boiling azeotrope at some specific composition then .
(a)A–B interactions are stronger than those between A–A or B–B.
(b)vapour pressure of solution increases because more number of molecules of liquids A and B can
escape from the solution
(c)vapour pressure of solution decreases because less number of molecules of only one of the liquids
escape from the solution.
(d)A–B interactions are weaker than those between A–A or B–B.
24 24. 4L of 0.02 M aqueous solution of NaCl was diluted by adding one litre of water. The molality of the
resultant solution is:
(a) 0.004 (b) 0.008 (c) 0.012 (d) 0.016
25 On the basis of information given below mark the correct option.
Information : On adding acetone to methanol some of the hydrogen bonds between methanol molecules
break.
(a)At specific composition methanol-acetone mixture will form minimum boiling azeotrope and will
show +ve deviation
(b)At specific composition methanol-acetone mixture forms maximum boiling azeotrope and will show
+ve deviation
(c)At specific composition methanol-acetone mixture will form minimum boiling azeotrope and will
show -ve deviation
(d)At specific composition methanol-acetone mixture will form maximum boiling azeotrope and will
show -ve deviation
Direction (Question nos.26-30): Each of the following questions consists of two statements, one Is
Assertion (A) and the other is reason (R). Select the correct answers to these questions from the Codes
a,b,c, and d as given below.
(a) Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
(b)Both Assertion and Reason are true but Reason is not the correct explanation of Assertion.
(c)Assertion is true but Reason is false.
(d)Assertion is false but reason is true.

26 Assertion : Molarity of a solution in liquid state changes with temperature.

Reason : The volume of a solution changes with change in temperature.
27 Assertion : When methyl alcohol is added to water, boiling point of water increases.
Reason : When a volatile solute is added to a volatile solvent elevation in boiling point is observed.
28 Assertion : When NaCl is added to water a depression in freezing point is observed.
Reason : The lowering of vapour pressure of a solution causes depression in the freezing point.
29 Assertion : When a solution is separated from the pure solvent by a semipermeable membrane, the
solvent molecules pass through it from pure solvent side to the solution side.
Reason : Diffusion of solvent occurs from a region of high concentration ssolution to a region of low
concentration solution.
30 Assertion : osmosis is colligative property.
Reason : Reverse osmosis is used for desalination of water.