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Physics and Chemistry
of Classical Materials
Applied Research and Concepts

Editor
Ewa Kłodzińska, PhD
PHYSICS AND CHEMISTRY OF
CLASSICAL MATERIALS
Applied Research and Concepts
PHYSICS AND CHEMISTRY OF
CLASSICAL MATERIALS
Applied Research and Concepts

Edited by
Ewa Kłodzińska, PhD

A. K. Haghi, PhD, and Gennady E. Zaikov, DSc

Reviewers and Advisory Board Members

Apple Academic Press

TORONTO NEW JERSEY
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ABOUT THE EDITOR

Ewa Kłodzińska, PhD

Ewa Kłodzińska, PhD, is working at the Institute for Engineering of Polymer Ma-
terials and Dyes in Torun, Poland, and investigates surface characteristics of bio-
degradable polymer material on the basis of zeta potential measurements. She
performed research on determination and identification of microorganisms using
the electromigration techniques for the purposes of medical diagnosis for 10 years.
She he has written several original articles, monographs, and chapters in books for
graduate students and scientists and has made valuable contributions to the theory
and practice of electromigration techniques, chromatography, sample preparation,
and application of separation science in pharmaceutical and medical analysis. Dr.
Ewa Kłodzińska is a member of editorial boards of ISRN Analytical Chemistry and
the International Journal of Chemoinformatics and Chemical Engineering (IJCCE).
She earned her PhD degree from Nicolaus Copernicus University, Faculty of Chem-
istry in Torun, Poland.
REVIEWERS AND ADVISORY BOARD
MEMBERS

A. K. Haghi, PhD
A. K. Haghi, PhD, holds a BSc in urban and environmental engineering from Uni-
versity of North Carolina (USA); a MSc in mechanical engineering from North
Carolina A&T State University (USA); a DEA in applied mechanics, acoustics and
materials from Université de Technologie de Compiègne (France); and a PhD in
engineering sciences from Université de Franche-Comté (France). He is the author
and editor of 65 books as well as 1000 published papers in various journals and con-
ference proceedings. Dr. Haghi has received several grants, consulted for a number
of major corporations, and is a frequent speaker to national and international audi-
ences. Since 1983, he served as a professor at several universities. He is currently
Editor-in-Chief of the International Journal of Chemoinformatics and Chemical
Engineering and Polymers Research Journal and on the editorial boards of many
international journals. He is a member of the Canadian Research and Development
Center of Sciences and Cultures (CRDCSC), Montreal, Quebec, Canada.

Gennady E. Zaikov, DSc

Gennady E. Zaikov, DSc, is Head of the Polymer Division at the N. M. Emanuel
Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russia,
and Professor at Moscow State Academy of Fine Chemical Technology, Russia,
as well as Professor at Kazan National Research Technological University, Kazan,
Russia. He is also a prolific author, researcher, and lecturer. He has received several
awards for his work, including the Russian Federation Scholarship for Outstanding
Scientists. He has been a member of many professional organizations and on the
editorial boards of many international science journals.
CONTENTS

List of Contributors.......................................................................................xiii
List of Abbreviations.................................................................................... xvii
List of Symbols.............................................................................................. xix
Preface.......................................................................................................... xxi
1. A Lecture Note on Quantum-Chemical Calculation of Molecule of
1-[2-(О-Acetylmethyl)-3-О-Acetyl-2-Ethyl]-Methyldichlorinephosphite
(I) and Components of Its Synthesis..............................................................1
V. A. Babkin, V. U. Dmitriev, G. A. Savin, E. S. Titova, and G. E. Zaikov

2. Quantum-Chemical Lecture Note on the Mechanism of Synthesis of

1-[2-(О-Acetylmethyl)-3-О-Acetyl-2-Ethyl]-
Methyldichlorinephosphite.............................................................................9
V. A. Babkin, V. U. Dmitriev, G. A. Savin, E. S. Titova, and G. E. Zaikov

3. A Lecture Note on the Effect of Antioxidant Compounds on Oxidative

Stress in Unicellular Aquatic Organisms.....................................................21
O. V. Karpukhina, K. Z. Gumargalieva, and A. N. Inozemtsev

4. On the Diffusion of Ammonium Salts in Aqueous Solutions.....................27

Luís M. P. Veríssimo, Abílio J. F. N. Sobral, Ana C. F. Ribeiro, Carmen Teijeiro,
and M. A. Esteso

5. A Lecture Note on Influence of Electric Current on the Oxidation

Process of Conductive Polymer Compositions............................................41
E. O. Sazonova, and I. A. Kirsh

6. A Technical note on Quantum and Wave Characteristics of

Spatial-Energy Interactions..........................................................................51
G. А. Korablev, and G. Е. Zaikov

7. A Technical Note on Nanocomposites Poly (Vinyl Chloride)/

Organoclay Flame-Resistance.......................................................................63
I. V. Dolbin, G. V. Kozlov, G. E. Zaikov, and A. K. Mikitaev

8. A Short Note on Reinforcement Mechanism of Polymer

Nano composites.............................................................................................73
G. V. Kozlov, K. S. Dibirova, G. M. Magomedov, and G. E. Zaikov
x Contents

9. A Research Note on Reinforcement Degree of Semicrystalline

Polymers as Natural Hybrid Nanocomposites............................................81
G. M. Magomedov, K. S. Dibirova, G. V. Kozlov, and G. E. Zaikov

10. Kinetic Modeling of Polystyrene Controlled Radical

Polymerization................................................................................................91
Nikolai V. Ulitin, Aleksey V. Oparkin, Rustam Ya. Deberdeev, Evgenii B. Shirokih,
and Gennady E. Zaikov

11. A Research Note on Semi empirical and DFT Modeling of the

IR Spectra of Benzoyl Peroxide Derivatives.............................................. 117
N. А. Тurovskij, Yu. V. Berestneva, E. V. Raksha, E. N. Pasternak, I. A. Opeida,
and G. Е. Zaikov

12. Polyelectrolyte Ensym-Bearing Microdiagnosticum: A New Step

in Clinical-Biochemistry Analysis...............................................................127
Sergey A. Tikhonenko, Alexei V. Dubrovsky, Ekaterina A. Saburova,
and Lyudmila I. Shabarchina

13. A Research Note on Transport Properties of Films of Сhitosan

Amikacin.......................................................................................................139
A. S. Shurshina, E. I. Kulish, and S. V. Kolesov

14. Crystalline Phase Morphology in Polymer/Organoclay

Nanocomposites............................................................................................153
K. S. Dibirova, G. V. Kozlov, G. M. Magomedov, and G. E. Zaikov

15. Achievements in Design and Synthesis of Hydrogel-Based Supports.....161

D. Horák, and H. Hlídková

16. Structural Changes in Synthetic Minerals................................................181

A. M. Ignatova, and M. N. Ignatov

17. A Research Note on Ozonation as a Method of Unsaturated Rubber

Modification for Improving Its Adhesion Properties................................193
V. F. Kablov, N. A. Keibal, S. N. Bondarenko, D. A. Provotorova, and G. E. Zaikov

18. A Research Note on the Intumescent Fire and Heat Retardant

Coatings Based on Perchlorovinyl Resin for Fiberglass Plastics.............201
V. F. Kablov, N. A. Keibal, S. N. Bondarenko, M. S. Lobanova, and A. N. Garashchenko

19. A Lecture Note on Influence of Hidrophylic Filler on Fire Resistance

of Epoxy Composites...................................................................................213
V. F. Kablov, A. A. Zhivaev, N. A. Keibal, T. V. Krekaleva, and A. G. Stepanova
Contents xi

20. Polyelectrolyte Microsensors as a New Tool for Metabolites’

Detection.......................................................................................................219
Kazakova L. I., Sukhorukov G. B., and Shabarchina L. I.

21. Simulation in Classical Nanomaterials: New Development and

Achievements................................................................................................235
Shima Maghsoodlou and Arezoo Afzali

.
LIST OF CONTRIBUTORS

Arezoo Afzali
University of Guilan, Rasht, Iran

Korablev Grigory Andreevich

Doctor of Chemical Science, Professor, Head of the Laboratory of Basic Research and Educational Cen-
ter, Udmurt Scientific Center, Ural Division, Russian Academy of Science; Head of the Department
of Physics at Izhevsk State Agricultural Academy. 426052, Izhevsk, 30 let Pobedy St., 98-14, Tel.: +7
(3412) 591946; E-mail: [email protected], [email protected]
V. A. Babkin
Volgograd State Architect-Build University Sebrykov Departament, 403300 Michurin Street 21, Mi-
chailovka, Volgograd region, Russia, E-mail: [email protected]
Yu. V. Berestneva
Donetsk National University, 24 Universitetskaya Street, 83 055 Donetsk, Ukraine, E-mail: chembio@
sky.chph.ras.ru

S. N. Bondarenko
Volzhsky Polytechnical Institute (branch) Volgograd State Technical University 42a Engelsa Street, Vol-
zhsky, Volgograd Region, 404121, Russian Federation, E-mail: [email protected]; www.volpi.ru

Rustam Ya Deberdeev
Kazan National Research Technological University, 68 Karl Marx Street, 420015 Kazan, Republic of
Tatarstan, Russian Federation, Fax: +7 (843) 231-41-56; E-mail: [email protected]
K. S. Dibirova
Dagestan State Pedagogical University, Makhachkala 367003, Yaragskii st., 57, Russian Federation

V. U. Dmitriev
Volgograd State Architect-Build University Sebrykov Departament, 403300 Michurin Street 21, Mi-
chailovka, Volgograd region, Russia, E-mail: [email protected]

I. V. Dolbin
Kh.M. Berbekov Kabardino-Balkarian State University, KBR, Nal’chik 360004, Chernyshevskii st., 173,
Russian Federation
Alexei V. Dubrovsky
Institute of Theoretical and Experimental Biophysics RAS, Institutskaya Street 3, 142290 Pushchino,
Moscow region, Russia

M. A. Esteso
U.D. Química Física, Universidad de Alcalá. 28871 Alcalá de Henares (Madrid), Spain, E-mail: miguel.
[email protected], [email protected].

A. N. Garashchenko
Volzhsky Polytechnical Institute (branch) Volgograd State Technical University 42a Engelsa Street, Vol-
zhsky, Volgograd Region, 404121, Russian Federation, E-mail: [email protected]; www.volpi.ru
xiv List of Contributors

K. Z. Gumargalieva
N. N. Semenov Institute of Chemical Physics, RAS, 4 Kosygin Street

H. Hlídková
Institute of Macromolecular Chemistry Academy of Sciences of the Czech Republic, v.v.i. Heyrovský Sq.
2, 162 06 Prague 6, Czech Republic
D. Horák
Institute of Macromolecular Chemistry Academy of Sciences of the Czech Republic, v.v.i. Heyrovský Sq.
2, 162 06 Prague 6, Czech Republic, E-mail: [email protected]

M. N. Ignatov
Mechanical Engineering Faculty, National Research Perm Technical University, Perm, Russia, E-mail:
[email protected]

A. M. Ignatova
Mechanical Engineering Faculty, National Research Perm Technical University, Perm, Russia, E-mail:
[email protected]

A. N. Inozemtsev
M. V. Lomonosov MSU, Biological Faculty, Leninskie Gory, 119991 Moscow, Russia, E-mail: olga-
[email protected].
V. F. Kablov
Volzhsky Polytechnical Institute (branch) Volgograd State Technical University 42a Engelsa Street, Vol-
zhsky, Volgograd Region, 404121, Russian Federation, E-mail: [email protected]; www.volpi.ru
O. V. Karpukhina
N. N. Semenov Institute of Chemical Physics, RAS, 4 Kosygin Street

L. I. Kazakova
Institute of Theoretical and Experimental Biophysics Russian Academy of Science, 142290 Pushchino,
Moscow region 142290, Russia
N. A. Keibal
Volzhsky Polytechnical Institute (branch) Volgograd State Technical University 42a Engelsa Street, Vol-
zhsky, Volgograd Region, 404121, Russian Federation, E-mail: [email protected]; www.volpi.ru
I. A. Kirsh
Moscow National University of Food Production, Moscow, Russia, E-mail: [email protected]

S. V. Kolesov
Bashkir State University, Russia, Republic of Bashkortostan Ufa-450074, ul Zaki Validi, 32, Tel:+7 (347)
229 96 14, E-mail: [email protected], The Institute of Organic Chemistry of the Ufa Scientific
Centre the Russian Academy of Science, October Prospect 71, 450054 Ufa, Russia

G. V. Kozlov
N. M. Emanuel Institute of Biochemical Physics of Russian Academy of Sciences, Moscow 119334, Ko-
sygin st., 4, Russian Federation / Dagestan State Pedagogical University, Makhachkala 367003, Yarag-
skii st., 57, Russian Federation, Kh.M. Berbekov Kabardino-Balkarian State University, KBR, Nal’chik
360004, Chernyshevskii st., 173, Russian Federation

T. V. Krekaleva
Volzhsky Polytechnical Institute (branch) Volgograd State Technical University 42a Engelsa Street, Vol-
zhsky, Volgograd Region, 404121, Russian Federation, E-mail: [email protected]; www.volpi.ru
List of Contributors xv

E. I. Kulish
Bashkir State University, Russia, Republic of Bashkortostan Ufa 450074, ul Zaki Validi, 32, Tel.: +7
(347) 229 96 14; E-mail: [email protected], The Institute of Organic Chemistry of the Ufa Scien-
tific Centre the Russian Academy of Science, October Prospect 71, 450054 Ufa, Russia

M. S. Lobanova
Volzhsky Polytechnical Institute (branch) Volgograd State Technical University 42a Engelsa Street, Vol-
zhsky, Volgograd Region, 404121, Russian Federation, E-mail: [email protected]; www.volpi.ru
Shima Maghsoodlou
University of Guilan, Rasht, Iran

G. M. Magomedov
Dagestan State Pedagogical University, Makhachkala 367003, Yaragskii st., 57, Russian Federation.

A. K. Mikitaev
Kh. M. Berbekov Kabardino-Balkarian State University, KBR, Nal’chik 360004, Chernyshevskii st.,
173, Russian Federation

V. Ulitin Nikolai
Kazan National Research Technological University, 68 Karl Marx Street, 420015 Kazan, Republic of
Tatarstan, Russian Federation, Fax: +7 (843) 231-41-56; E-mail: [email protected]
Alexey V. Oparkin
Kazan National Research Technological University, 68 Karl Marx Street, 420015 Kazan, Republic of
Tatarstan, Russian Federation, Fax: +7 (843) 231-41-56; E-mail: [email protected]
I. A. Opeida
L. M. Litvinenko Institute of Physical Organic and Coal Chemistry National Academy of Sciences of
Ukraine. 70 R. Luxemburg Street, 83 114, Donetsk, Ukraine

E. N. Pasternak
Donetsk National University, 24 Universitetskaya Street, 83 055 Donetsk, Ukraine

D. A. Provotorova
Volzhsky Polytechnical Institute, branch of Federal State Budgetary Educational Institution of Higher
Professional Education “Volgograd State Technical University” 42a Engels Str., 404121, Volzhsky, Vol-
gograd Region, Russia, E-mail: [email protected]; www.volpi.ru

E. V. Raksha
Donetsk National University, 24 Universitetskaya Street, 83 055 Donetsk, Ukraine

Ana C. F. Ribeiro
Department of Chemistry, University of Coimbra, 3004-535 Coimbra, Portugal, Tel: +351-239-854460;
Fax: +351-239-827703, E-mail: [email protected].

Ekaterina A. Saburova
Institute of Theoretical and Experimental Biophysics RAS, Institutskaya Street 3, 142290 Pushchino,
Moscow region, Russia

G. A. Savin
Volgograd State Pedagogical University, 40013, Lenin Street, 27, Volgograd, Russia E-mail: gasavin@
mail.ru

E. O. Sazonova
Moscow National University of Food Production, Moscow, Russia, post-graduate student E-mail: kaf.
[email protected]
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