SAFETY DATA SHEET

Tankguard DW Comp B
Section 1. Identification
GHS product identifier : Tankguard DW Comp B
Product code : 9441
Product description : Hardener.
Other means of : Not available.
identification
Product type : Liquid.

Supplier's details : Jotun Paints, Inc.

9203 Highway 23
Belle Chasse, LA 70037
Telephone: (800) 229-3538 or
+1 504-394-3538
[email protected]

Emergency telephone : 1-800-424-9300

number (with hours of (Staffed 24/7)
operation)
1,2 9441 ^(ValidationDate) 1

Approved

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : SKIN CORROSION - Category 1B
substance or mixture SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1

GHS label elements

Hazard pictograms :

Signal word : Danger.

Hazard statements : Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Precautionary statements
Prevention : Wear protective gloves. Wear eye or face protection. Wear protective clothing. Wash
hands thoroughly after handling. Contaminated work clothing must not be allowed out
of the workplace.
Response : IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Immediately call a POISON CENTER or physician. IF SWALLOWED: Immediately call
a POISON CENTER or physician. Rinse mouth. Do NOT induce vomiting. IF ON
SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or
shower. Wash contaminated clothing before reuse. Immediately call a POISON
CENTER or physician. IF ON SKIN: Wash with plenty of soap and water. Wash
contaminated clothing before reuse. If skin irritation or rash occurs: Get medical
attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON
CENTER or physician.
Storage : Store locked up.

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Section 2. Hazards identification

Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Other means of : Not available.
identification

CAS number/other identifiers

CAS number : Not applicable.
Product code : 9441
Ingredient name % CAS number
Carbomonocyclic alkylated mixtures of poly-aza-alkanes, hydrogenated ≥90 1173092-74-4
Poly[oxy(methyl-1,2-ethanediyl)], α-(2-aminomethylethyl)-ω-(2- ≤10 9046-10-0
aminomethylethoxy)-
2,4,6-tris(dimethylaminomethyl)phenol ≤3 90-72-2
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush
eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and
remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns
must be treated promptly by a physician.
Inhalation : Get medical attention immediately. Call a poison center or physician. Remove victim to
fresh air and keep at rest in a position comfortable for breathing. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained
breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest
occurs, provide artificial respiration or oxygen by trained personnel. It may be
dangerous to the person providing aid to give mouth-to-mouth resuscitation. If
unconscious, place in recovery position and get medical attention immediately. Maintain
an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of
inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under medical surveillance for 48 hours.
Skin contact : Get medical attention immediately. Call a poison center or physician. Wash with plenty
of soap and water. Remove contaminated clothing and shoes. Wash contaminated
clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for
at least 10 minutes. Chemical burns must be treated promptly by a physician. In the
event of any complaints or symptoms, avoid further exposure. Wash clothing before
reuse. Clean shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do
so by medical personnel. If vomiting occurs, the head should be kept low so that vomit
does not enter the lungs. Chemical burns must be treated promptly by a physician.
Never give anything by mouth to an unconscious person. If unconscious, place in
recovery position and get medical attention immediately. Maintain an open airway.

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Section 4. First aid measures

Loosen tight clothing such as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes severe burns. May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst.
from the chemical
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

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Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Do not breathe vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Do not get in eyes or on skin or clothing. Do not breathe vapor or
mist. Do not ingest. If during normal use the material presents a respiratory hazard,
use only with adequate ventilation or wear appropriate respirator. Keep in the original
container or an approved alternative made from a compatible material, kept tightly
closed when not in use. Empty containers retain product residue and can be hazardous.
Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected from
including any direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
incompatibilities (see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.

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Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Carbomonocyclic alkylated mixtures of poly-aza-alkanes, hydrogenated None
Poly[oxy(methyl-1,2-ethanediyl)], α-(2-aminomethylethyl)-ω-(2- None
aminomethylethoxy)-
2,4,6-tris(dimethylaminomethyl)phenol None

Appropriate engineering : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
controls local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles and/
or face shield. If inhalation hazards exist, a full-face respirator may be required instead.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
There is no one glove material or combination of materials that will give unlimited
resistance to any individual or combination of chemicals.
The breakthrough time must be greater than the end use time of the product.
The instructions and information provided by the glove manufacturer on use,
storage, maintenance and replacement must be followed.
Gloves should be replaced regularly and if there is any sign of damage to the glove
material.
Always ensure that gloves are free from defects and that they are stored and used
correctly.
The performance or effectiveness of the glove may be reduced by physical/chemical
damage and poor maintenance.
Barrier creams may help to protect the exposed areas of the skin but should not be
applied once exposure has occurred.
Wear suitable gloves tested to EN374.
Recommended, gloves(breakthrough time) > 8 hours: nitrile rubber, neoprene, butyl
rubber

Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.

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Section 8. Exposure controls/personal protection

Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Color : Various
Odor : Characteristic.
Odor threshold : Not available.
pH : Not available.
Melting point : Not available.
Boiling point : Lowest known value: 232°C (449.6°F) (Poly[oxy(methyl-1,2-ethanediyl)], α-(2-
aminomethylethyl)-ω-(2-aminomethylethoxy)-).
Flash point : Closed cup: Not applicable.
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Vapor pressure : Not available.
Vapor density : Not available.
Relative density : 1.05 g/cm³ 8.76 pounds/gallon
Solubility : Insoluble in the following materials: cold water and hot water.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 mm2/s)

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : No specific data.

Incompatible materials : No specific data.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

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Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Poly[oxy(methyl-1,2- LD50 Dermal Rabbit 360 mg/kg -
ethanediyl)], α-(2-
aminomethylethyl)-ω-(2-
aminomethylethoxy)-
LD50 Oral Rat 242 mg/kg -
2,4,6-tris LD50 Oral Rat 1673 mg/kg -
(dimethylaminomethyl)phenol
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Poly[oxy(methyl-1,2- Eyes - Severe irritant Rabbit - 100 -
ethanediyl)], α-(2- milligrams
aminomethylethyl)-ω-(2-
aminomethylethoxy)-
2,4,6-tris Eyes - Severe irritant Rabbit - 24 hours 50 -
(dimethylaminomethyl)phenol Micrograms
Skin - Mild irritant Rat - 0.025 Mililiters -
Skin - Severe irritant Rat - 0.25 Mililiters -
Skin - Severe irritant Rabbit - 24 hours 2 -
milligrams
Sensitization
Not available.
Mutagenicity
Not available.

Carcinogenicity
Not available.

Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.

Information on the likely : Not available.

routes of exposure
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes severe burns. May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

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Section 11. Toxicological information

Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : Once sensitized, a severe allergic reaction may occur when subsequently exposed to
very low levels.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Route ATE value
Oral 6666.7 mg/kg

Section 12. Ecological information

Toxicity
Not available.

Persistence and degradability

Not available.

Bioaccumulative potential

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Section 12. Ecological information

Product/ingredient name LogPow BCF Potential
Poly[oxy(methyl-1,2- 1.34 - low
ethanediyl)], α-(2-
aminomethylethyl)-ω-(2-
aminomethylethoxy)-
2,4,6-tris 0.219 - low
(dimethylaminomethyl)phenol

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.

Section 14. Transport information

DOT TDG Mexico ADR/RID IMDG IATA
Classification Classification Classification
UN number 3066 3066 3066 3066 3066 3066

UN proper Paint related Paint related Paint related Paint related Paint related Paint related
shipping name material material material material material material
Transport 8 8 8 8 8 8
hazard class(es)

Packing group II II II II II II
Environmental No. No. No. No. No. No.
hazards

Additional information
DOT Classification : -
TDG Classification : Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.40-2.42 (Class 8).
Mexico Classification : -
ADR/RID : Tunnel restriction code: (E)
Hazard identification number: 80
IMDG : Emergency schedules (EmS): F-A, S-B
Marine pollutant: No.
IATA : -

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Section 14. Transport information

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.

Transport in bulk according : Not available.

to Annex II of MARPOL and
the IBC Code

Section 15. Regulatory information

U.S. Federal regulations : TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): Not determined.
Clean Air Act Section 112 : Not listed
(b) Hazardous Air
Pollutants (HAPs)
Clean Air Act Section 602 : Not listed
Class I Substances
Clean Air Act Section 602 : Not listed
Class II Substances
DEA List I Chemicals : Not listed
(Precursor Chemicals)
DEA List II Chemicals : Not listed
(Essential Chemicals)
SARA 302/304
Composition/information on ingredients
No products were found.

SARA 304 RQ : Not applicable.

SARA 311/312
Classification : Immediate (acute) health hazard
Composition/information on ingredients
Name % Fire Sudden Reactive Immediate Delayed
hazard release of (acute) (chronic)
pressure health health
hazard hazard
Carbomonocyclic alkylated ≥90 No. No. No. Yes. No.
mixtures of poly-aza-alkanes,
hydrogenated
Poly[oxy(methyl-1,2-ethanediyl)], ≤10 No. No. No. Yes. No.
α-(2-aminomethylethyl)-ω-(2-
aminomethylethoxy)-
2,4,6-tris(dimethylaminomethyl) ≤3 No. No. No. Yes. No.
phenol

State regulations
Massachusetts : None of the components are listed.
New York : None of the components are listed.
New Jersey : None of the components are listed.
Pennsylvania : None of the components are listed.
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol (Annexes A, B, C, E)

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Section 15. Regulatory information

Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
International lists
National inventory
Australia : Not determined.
Canada : Not determined.
China : Not determined.
Europe : Not determined.
Japan : Not determined.

Malaysia : Not determined.

New Zealand : Not determined.
Philippines : Not determined.
Republic of Korea : Not determined.
Taiwan : Not determined.

Section 16. Other information

Procedure used to derive the classification
Classification Justification
Skin Corr. 1B, H314 Calculation method
Eye Dam. 1, H318 Calculation method
Skin Sens. 1, H317 Calculation method
History
Date of printing : 27.02.2019
Date of issue/Date of : 27.02.2019
revision
Date of previous issue : 02.11.2016
Version : 1.03
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader

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Section 16. Other information

The information in this document is given to the best of Jotun's knowledge, based on laboratory testing and
practical experience. Jotun's products are considered as semi-finished goods and as such, products are often
used under conditions beyond Jotun's control. Jotun cannot guarantee anything but the quality of the product
itself. Minor product variations may be implemented in order to comply with local requirements. Jotun reserves
the right to change the given data without further notice.

Users should always consult Jotun for specific guidance on the general suitability of this product for their needs
and specific application practices.

If there is any inconsistency between different language issues of this document, the English (United Kingdom)
version will prevail.

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