Che 23 Adv
Che 23 Adv
JEE‐ADVANCE‐2021‐P1‐Model
Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 4) Questions with Single Correct Choice +3 -1 4 12
Paragraph Questions with Numerical
Sec – II(Q.N : 5 – 10) +2 0 6 12
Value Answer Type
Questions with Multiple Correct Choice
Sec – III(Q.N : 11 – 16) +4 -2 6 24
with partial mark
Questions with Non-negative Integer
Sec – IV(Q.N : 17 – 19) +4 0 3 12
Value Type
Total 19 60
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 20 – 23) Questions with Single Correct Choice +3 -1 4 12
Paragraph Questions with Numerical
Sec – II(Q.N : 24 – 29) +2 0 6 12
Value Answer Type
Questions with Multiple Correct
Sec – III(Q.N : 30 – 35) +4 -2 6 24
Choice with partial mark
Questions with Non-negative Integer
Sec – IV(Q.N : 36– 38) +4 0 3 12
Value Type
Total 19 60
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 39 – 42) Questions with Single Correct Choice +3 -1 4 12
Paragraph Questions with Numerical
Sec – II(Q.N : 43 – 48) +2 0 6 12
Value Answer Type
Questions with Multiple Correct
Sec – III(Q.N : 49 – 54) +4 -2 6 24
Choice with partial mark
Questions with Non-negative Integer
Sec – IV(Q.N : 55 – 57) +4 0 3 12
Value Type
Total 19 60
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PHYSICS Max Marks: 60
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 4 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases. Section 1 (Max Marks: 12)
Section 1 contains Four questions
Each Question has Four Options and Only One of these four will be the correct answer.
For each question, choose the option corresponding to the correct answer
The Marking scheme to evaluate Answer to each question will be :
Full Marks: +3 (If the answer is correct)
Zero Marks: 0 (If the question is unanswered)
Negative Marks: -1 (In all other cases)
1. A uniform rod AB of mass M is attached to a hinge at one end A, and released from the
horizontal position. The rod rotates about A, and when it reaches the vertical position the
rod strikes a sphere of mass m and radius r initially at rest on the smooth horizontal
surface as shown in the adjacent figure. The impact is along the horizontal direction and
perfectly elastic.
If at the moment of impact, the lowest end of the rod is very close to the smooth
horizontal surface. After the impact, the sphere moves along the horizontal and the rod,
subsequently rises to a maximum of 600 with the vertical. Choose the correct statement(s)
from the following, taking into account the information given above. The length of the
6 2
rod equals 2 r. r m (take g 10 m / s 2 )
10
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2. A solid cube is placed on rough horizontal surface. The coefficient of friction between
1
them is , where . A variable horizontal force is applied on the cube’s upper face
2
perpendicular to one edge and passing through midpoint of that edge. The maximum
acceleration with which it can move without toppling is
[Acceleration due to gravity ‘g’]
D) g
1
A) g B) 2 g C) g 1 2
2
A) 4 2v0 5 3v B) 8v0 5 3v C) 5v 0 8 3v D) v v0
4. A uniform rod of length L, moving down with linear velocity v0 and zero angular
velocity, collides with a horizontal surface. Just after collision, the linear velocity of its
centre of mass becomes v in the upward direction as shown in the figure. The angular
velocity of the rod just after the impact is
v0
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6 v v0 cos 2 v0 v cos
A) B)
L 3L
3 v v 0 cos 6 v 0 v cos
C) D)
2L L
SECTION 2
This section contains THREE (03) questions stems.
There are TWO (02) questions corresponding to each question stem.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the on-screen
virtual numeric keypad.
If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks:0 in all other cases
9. The angular velocity of each dumb-bell just after the first collision in (rad/s) is
10. If first collision occurs at t = 0 and second collision occurs at t = t sec, then the value of
t (in sec) is
SECTION 3
This section contains SIX (06) questions.
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct answer(s).
For each question, choose the option(s) corresponding to (all) the correct answer(s).
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen,
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct:
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If unanswered;
Negative Marks: -2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to the correct answer, then
Choosing ONLY (A), (B) and (D) will get +4 marks;
Choosing ONLY (A), will get +1 mark;
Choosing ONLY (B), will get +1 mark;
Choosing ONLY (D), will get +1 mark;
Choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
Choosing any other option(s) will get -2 marks.
11. Two equal uniform rods P and Q each of length move with the same velocity v as
shown in the figure. The second rod has an angular velocity ( 6v / l and clockwise)
about its centre of gravity G1 in addition to v.
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A) If the ends A and A ' are suddenly fixed simultaneously, both the rods will start to
rotate with the same angular velocity.
B) If the ends A and A ' are suddenly fixed simultaneously, the rod Q will start to rotate
with greater angular velocity.
C) If the ends B and B ' are suddenly fixed simultaneously, both rods will start to rotate
with the same angular velocity.
D) If the ends B and B ' are suddenly fixed simultaneously, the rod P will start to rotate
with greater angular velocity.
12. A rod of mass m and length 2R can rotate about an axis passing through O in vertical
R
plane. A disc of mass m and radius is hinged to the other end P of the rod and can
2
freely rotate about P . When disc is at lowest point both rod and disc has angular velocity
9g 3g 1 g g
A) B) C) D)
16R 23R 3 R R
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13. A rod AC Of length and mass m is kept on a horizontal smooth plane. It is free to rotate
and move. A particle of same mass m moving on the plane with velocity v strikes rod at
point B making angle 370 with the rod. The collision is elastic. After collision:
B l/4
A 37 0 C
72V
A) The angular velocity of the rod will be
55
B) The centre of the rod will travel a distance in the time in which it makes half
3
rotation.
24mV
C) Impulse of the impact force is
55
p
D) The centre of the rod will travel a distance in the time in which it makes 1/4th
8
rotation
14. A rod of mass ‘m’ lengths ‘l’ is in equilibrium in the position shown. The ground is rough
enough to prevent slipping.
60°
B
mg
A) The normal force N1 at B is (Before cutting the string)
2
7 mg
B) The normal force N 2 at B immediately after cutting the string is
16
3mg
C) The friction force at point B is after cutting
16
D) The friction force at point B is zero before cutting the string.
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15. A particle of mass m is attached to an end of a uniform rod of mass M = 2m and length
' l ' which is suspended through its mid point by an inextensible string as shown. Initially
the rod is in horizontal position and at rest. The system is released from this position. Just
after the release.
6g
A) The angular acceleration of the system is
5l
2g
B) The angular acceleration of the system is
5l
12
C) The tension in the string is mg
5
2
D) The tension in the string is mg
5
16. A uniform solid cylinder is placed on a horizontal board. The coefficient of friction
between them is 0.3. The board is imparted a constant acceleration of a 6m / s 2 in a
horizontal direction at right angles of the cylindrical axis. Then (take g 10m / s 2 )
A) The acceleration of the cylinder axis in the absence of slipping will be 1.5 m / s 2 .
B) The acceleration of the cylinder axis in the absence of slipping will be 2 m / s 2
C) The limiting value of ‘ a ’ for which there will be no slipping is 12 m / s 2
D) The limiting value of ‘ a ’ for which there will be no slipping is 9 m / s 2
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SECTION 4
This section contains THREE (03) question.
The answer to each question is a NON-NEGATIVE INTEGER.
For each question, enter the correct integer corresponding to the answer the using the mouse and the on-screen virtual numeric keypad in the
place designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.
17. A hollow straight tube of length L and mass m can turn freely about its centre normal to
its length on a smooth horizontal table. Another smooth uniform rod of same length and
mass is fitted into the tube so that their centers coincide. The system is set in motion with
an initial angular velocity 0 . The angular velocity of the rod at an instant when the rod
g 10 m / s2
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N2 N2 N2 N2 O2
(i) (ii) (iii) O2
O N2 N O2
(iv) O2 2
(v) 2 (vi) O2
A) (i) and (ii) B) (iii) and (v) C) (iii) and(iv) D) (v) and (ii)
21. Which of the following molecules / ions can exist?
A) H 4 S B) OF4 C) KHF2 D) BeF53
22. Which of the following element have electron affinity greater than ‘F’.
A) O B) S C) Se D) Cl
23. Match the species with their respective ionic size
Column – I Column - II
P Mg 2 1 1.26A0
Q O 2 2 1.16A0
R F 3 1.19 A0
S Na 4 0.72 A0
A) P-4; Q-1; R-2; S-3 B) P-1;Q-4;R-2;S-3
C) P-2; Q-3; R-1; S-4 D) P-4 ; Q-1; R-3;S-2;
SECTION 2
This section contains THREE (03) questions stems.
There are TWO (02) questions corresponding to each question stem.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the on-screen
virtual numeric keypad.
If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.
For A g IE 1 + IE2 value is equal to 950 KJ / mole.
The value of the H eg of A2( g ) in KJ / mole is –a. Then find the value of
a
24. in
120
KJ / mole.
25. The value of IE1 of A g is x KJ / mole and IE of A ( g ) is y KJ / mole. The hydration
x y
energy of A2( g ) is –Z KJ / mole. Then the value of is equal to____
z
Question Stem for Question Nos. 26 and 27
Question Stem
In the poly atomic molecules the bond energy of similar bond may differ due to the
difference in the chemical environment around central atom. Bond order is given by the
number of bonds between the two atoms in a molecule. Iso electronic molecules and ions
will have identical bond orders . In general as bond order increases the bond energy
increases and bond length decreases.
26. In the following the number species are having less bond order than O 2 and
paramagnetic.
CN , CO , N 2 , N 2 , O 2 , O 2 , O 22 , F2 , CO
27. In the following the number of species with fractional bond order is/are
H 2 ,H 2 , H 2 , He 2 , He 2 , B 2 , C 2 , O 2 , O 2 , O 2 , O 3 , BF3 , CO 32 , C 6H 6 (Only C – C bond)
Question Stem for Question Nos. 28 and 29
Question Stem
In ABnE x type molecules, as the electronegativity of A increases, the bond pairs come
closer towards the central atom and the repulsion between then increases. On the other
hand as electronegativity of AB increases, the bond pairs get farther and repulsion
decreases (A,B are the different elements A is the central atom and B is the bonded atom
and E=number of lone pairs)
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28. In the following how many species are orientation of hybride orbitals and shape of
species is same.
NH3 ,
ClO 4 , SO 42 , XeO 3 , XeF4 , ClF3 , BeCl 2 , CH3 , CH 3 , SnCl 2 , NH 4 , I3
29. In the following, how many species with dipolemoment zero.
1, 2 – dichloro benzene, 1, 3 – dichloro benzene
1, 4 - dichloro benzene cis – 2 – butene, Trans – 2- butene
C H3 H H
C= C C= C
H HCl
, ,
1, 4 – dihydroxybenzene, 1, 4 – dicyanobenzene
SECTION 3
This section contains SIX (06) questions.
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct answer(s).
For each question, choose the option(s) corresponding to (all) the correct answer(s).
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen,
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct:
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If unanswered;
Negative Marks: -2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to the correct answer, then
Choosing ONLY (A), (B) and (D) will get +4 marks;
Choosing ONLY (A), will get +1 mark;
Choosing ONLY (B), will get +1 mark;
Choosing ONLY (D), will get +1 mark;
Choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
Choosing any other option(s) will get -2 marks.
30. Which of the following molecules/ions has unpaired electrons in antibonding molecular
orbitals?
A) NO B) O2 C) O2 D) O2
31. Which combination of compounds, their geometry and hybridization is correct?
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33. In which of the following sets of elements having more similarities in their properties
is/are
A) S, Na B) Li, Mg C) Be, Al D) Zr, Hf
34. Which of the following is / are correct relation? (in general)
1
A) Bond energy polarity of the bond
B) Bond energy (S – character of hybrid orbitals)
1
C) Bond energy Atomic radius
1
D) Bond energy Bond order
36. Number of lone pair – bond pair repulsion at 900 are P in ICl2 .
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39. Let A,B,C,D are four coplanar points in 3D – space and 3OA 2OB 4OC OD 0
Then the ratio made by AB on the join of CD is
A) 5 : 4 B) 1 : 4 C) 1 : 1 D) 4 : 5
40. Let A (0, 0, 0), B (1, 1, 1), C (1, -1, 1) then the circum radius of the ABC , is _____
2 2 1 3 3
A) B) C) D)
3 2 2 2 2
41. Which of the following is/are FALSE?
A) Let a , b , c are three non-coplanar vectors and r .a r .b r . c 0 then r 0.
C) If a . c 0 then a b c , a b c are perpendicular
D) If a , b , c , d are four coplanar vectors then a b c d 0
x 1 y 2 z 2
42. The plane containing the line making maximum distance from
1 2 1
O (0 ,0 ,0) is “p” Then “6 p 2 ” = ______
A) 5 B) 1 C) 8 D) 4
SECTION 2
This section contains THREE (03) questions stems.
There are TWO (02) questions corresponding to each question stem.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the on-screen
virtual numeric keypad.
If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks: 0 In all other cases.
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49. Let OA a , OB b , OC c , OD d and tan a 2 tan b 2 tan c d , also
the points A, B, C, D are coplanar then which of the following options is/are correct?
1
A) The maximum value of tan 2 tan 2 tan 2
4
1
B) The minimum value of tan 2 tan 2 tan 2
9
1 5
C) At the time of tan 2 tan 2 tan 2 then tan tan tan
9 9
1 5
D) At the time of tan 2 tan 2 tan 2 then tan tan tan
4 4
50. Consider Three planes
ax by cz 0, bx cy az 0, cx ay bz 0and A (a b c) ,
B (a 2 b 2 c 2 ab bc ca)
which of the following options is/are correct?
A) If A = 0, B = 0 then the locus of (x, y, z) lie on a straight line
B) If A = 0, B 0 then the locus of (x, y, z) lie on a straight line
C) If A 0 , B = 0 then the locus of (x, y, z) lie on a plane
D) If A 0 , B 0 then the locus of (x, y, z) lie on a plane
51. Let PQRS be a unit Square folded along the Diagonal PR , so that ‘Q’ Reaches at Q 1 and
planes PRQ 1, PRS are perpendicular to one other then which of the following options
is/are correct?
1
A) QQ 1
2
B) QQ 1 1
2
C) Shortest distance between PQ 1, RS
3
2
D) Shortest distance between PQ 1, RS
3
52. Consider a unit cube with the edges has its line segments of unit length then which of the
following options is/are correct?
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A) The maximum value of the minimum distance between any two edges of a cube is
1unit
B) The maximum value of the minimum distance between any two edges of a cube is
2 unit
C) The maximum value of the minimum distance between any two face diagonals of the
cube is 1unit
D) The maximum value of the minimum distance between any two face diagonals of the
cube 2 unit
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2 2 2
56 let a, b, c Three unit vectors then the maximum value of a b b c c a
57. The locus of the centroid of a tetrahedron of constant volume ‘64c.c’ formed by three
co-ordinate planes and a variable plane is ‘ xyz ’ then the value of ' ' ____
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