1st Year Series of Exercises
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ScribdTranslations1st Year Series of Exercises
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ScribdTranslationsPHYSICAL CHEMISTRY 1bac S M/EX Otmane AITHISSI
EXERCISE 1:
A body (S) assumed to be point-like, with mass m = 100 g, is launched from point A, with a speed
VA= 4m/s slides inside a track ABCD consisting of two parts:
- Rectilinear segment of length 80 cm and inclined at an angle α = 30°
relative to the horizontal.
Circular BCD with a radius r = 35cm. Negligible friction on
the ABC part.
We choose the horizontal plane passing through point C as the reference state.
of gravitational potential energy.
1- Give the expression for the potential energy at point A, calculate it.
Deduct Em(A).
2- Calculate the value of the potential energy at point C, deduce Ec(C)etVc.
3-Let F be a point of the part AB or E c(F) = 7 Epp(F), Calculate the distance AF.
4-On the CD part, the friction is not negligible and E m(D)=1.053J.
a- Calculate the amount of heat released during the displacement CD.
b- Give the expression for the intensity of the friction force, give its value.
c- Determine the expression for the velocity VDto calculate its value.
EXERCISE 2 :
A homogeneous rod (AB), of length L = 40 cm and mass m = 0.5 kg, is susceptible
to rotate in a vertical plane around a horizontal axis (Δ) passing through it
Endpoint A. its moment of inertia relative to (Δ) is J.Δ=3.10-2kg.m2We consider
the stable equilibrium position as the reference state of potential energy of
gravity.
We move the bar away from its equilibrium position by an angle θ.mand let it go without speed
initial. All friction is neglected.
1- Establish the expression of Epp at a moment when the position of the bar is marked
by any angular coordinate θ.
2- Write the expression of its mechanical energy.
3- Calculate the value of the angular velocity ω of the rod at the moment it passes through its position.
of stable equilibrium.
4- Determine the angle θ1where the kinetic energy of the Bar and its potential energy of
gravitational forces equalize.
5- Graphically plot the energy curves Em, Eppand Ecdepending on
death.
EXERCISE 3 :
We wind a pulley, with a mass M=5 kg and a radius r = 10 cm, with a thread whose
The other end is attached to a solid (S) with a mass of 500g. We start the
pulley motor, the solid (S) slides without initial velocity from O upwards
that :α=30°.
The moment of inertia of the pulley JΔ = M We neglect friction, and we
consider that the thread is inextensible and has negligible mass. We choose the plane
horizontal passing through the reference of gravitational potential energy
OA=d=1m.
1- Express ʋ 2depending on dex.
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PHYSICAL CHEMISTRY 1bac S M/EX Otmane AITHISSI
2- Express the kinetic energy EcThe solid as a function of dex and m.
3- Express the kinetic energy EcFrom the pulley in terms of dex and M. Calculate its value.
when the solid is at point A.
4- Determine ΔEmbetween O and A, deduce the tension of the wire.
5- Determine the motor torque during movement OA.
6-When the solid arrives at position A, it detaches from the net and continues its movement then
The pulley stops after 10 turns due to the effect of friction torque.
a- Express EmThe mechanical energy at position A as a function of g, d, and α.
Knowing that mechanical energy is conserved on section AB, calculate E.m(B) the energy
Mechanics from position S to position B. Deduce the distance AB.
c- Determine Mcthe moment of friction torque.
EXERCISE 4:
2+ −
We mix 100 ml of calcium chloride solution. ( )+ ( ) et100 ml of solution of
silver nitrate + 3 − The
( )+ two solutions have the same molar concentration in solute.
( )
brought C=C (CaCl2) =C(AgNO3= 1,0.10-2mol. L-1The ions −( ) +
( ) precipitate for
give silver chloride.
1-Write the precipitation equation.
2-Calculate the concentrations of the ions present. − + in the initial state.
( ) ( )
3-Calculate the quantities of matter of the reactants − + in the initial state.
( ) ( )
4- Establish the advancement table of the precipitation reaction.
5-What is the mass of the precipitate obtained in the final state of the system?
6-What are the effective concentrations of the ions in solution in the final state of the system?
EXERCISE 5 :
We consider the reaction between hydrochloric acid solution and
magnesium modeled by the following equation:
+ +
( )+ ( ) → ( ) + ( )
The graph below shows the evolution of the quantities of the reactants.
function of the progress of the reaction.
1-Determine the quantity of matter of the reactants in the initial state.
2-Determine the maximum progress of the reaction and reactant
limiting.
3-Make the material balance.
4-Represent the evolution of the quantity of material of the products on the same graph.
5-Define the stoichiometric mixture, determine the mass of magnesium (Mg) so that the
stoichiometric mixture.
Data: molar mass M(Mg) = 24 g/mol.
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