Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Sr.Super60, Elite,Target & LIIT BT's Paper -1(Adv-2022-P1-Model) Date: 16-03-2025
Time: 09.00Am to 12.00Pm GTA-21 Max. Marks:$180
16-03-2025_ Sr.Super60, Elite, Target & LIIT BT's_Jee-Adv(2022-P1) _GTA-21_Syllabus

MATHEMATICS : TOTAL SYLLABUS

PHYSICS : TOTAL SYLLABUS

CHEMISTRY : TOTAL SYLLABUS

Name of the Student: ___________________ H.T. NO:

 Sri Chaitanya IIT Academy 16-03-2025_Sr.Super60, Elite, Target & LIIT BT's_ Jee-Adv(2022-P1) _GTA-21_Q.P

JEE-ADVANCE-2022-P1-Model
Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Numerical Value
Sec – I(Q.N : 1 – 8) +3 0 8 24
Answer Type
Questions with Multiple Correct
Sec – II(Q.N : 9 – 14) +4 -2 6 24
Choice with partial mark
Sec – III(Q.N : 15 – 18) Matching Type +3 -1 4 12
Total 18 60

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Numerical Value
Sec – I(Q.N : 19 – 26) +3 0 8 24
Answer Type
Questions with Multiple Correct Choice
Sec – II(Q.N : 27 – 32) +4 -2 6 24
with partial mark
Sec – III(Q.N : 33 – 36) Matching Type +3 -1 4 12
Total 18 60

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Numerical Value
Sec – I(Q.N : 37 – 44 +3 0 8 24
Answer Type
Questions with Multiple Correct Choice
Sec – II(Q.N : 45 – 50) +4 -2 6 24
with partial mark
Sec – III(Q.N : 51 – 54) Matching Type +3 -1 4 12
Total 18 60

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MATHEMATICS Max Marks: 60
SECTION – I
(NUMERICAL VALUE TYPE)
This section contains EIGHT (08) questions.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer. If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 ONLY if the correct numerical value is entered;
Partial Mark: 0 In all other cases.

1. Let I n  
sin 2 n
d , n  N , then the value of
 I 2024  I 2025 
will be ____
2 100
0 sin 
2. The mean height of 36 students of a class is 150.5cm . Later on, it was detected that the
height of one student was wrongly copied as 165cm instead of 156cm . The correct mean
height of 36 students will be ___(in mt).
3. The probability that a randomly selected calculator from a store is of brand ' r ' is
proportional to ' r '  r  1,2,3,4,5,6  . Further the probability of a calculator of brand ' r '
7r
being defective is ,  r  1,2,3,4,5,6 . If the probability that a calculator randomly
21
p
selected from the store being defective is , where p and q are co-prime, then the
q
value of  p  q  is ______________(Consider 6 brands available)
2 1
n k 
an 2
4. If 4 1 bn2  cn  1 , then the value of  a  b  c is __
2
k 1 k 
4
5. Two equal chords AB and AC of the circle x 2  y 2  6 x  8 y  24  0 are drawn from
the point A  
33  3, 0 . Another chord PQ is drawn intersecting AB and AC at point R
and S respectively given that AR  SC  7 and R B  A S  3, then the value of
PR  QS 
 
sin x sin  2025 x   cos  2024 x  I
6. If I   x
dx and J   x
dx , then
J

0 0

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7. The sum of order and degree of the differential equation given by
2026 1
 dy  3  d 3 y  2029
 2023  2024   2027 
 dx3 
 will be ____
 dx   
8. If area bounded by max  x  y , x  y   2 is ‘k’ sq.units, then the value of ‘k’ is ___
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: –2 In all other cases.
9. Given points A  a  , B  b  , C  c  , where
   
a  2024i  2025 j  2022k ,
   
b  2 2022 3 2023 i  3 20215 2025 j  k ,

then which of the following options is/are correct?(where O is origin)

 2023  1 
A) The point C  c   a b lies inside of triangle formed by O, A, B as vertices
2024 4048
 2024  3 
B) The point C  c   a b lies outside of triangle formed by O, A, B as
2025 2025
vertices, but lies inside of  AOB

 2  x2  1 
C) The point C  c   a b lies outside of triangle formed by O, A, B as
2 2
x 1 x 1
vertices, but lies inside of  OAB  x  R

 2  x2 
D) The point C  c   a b lies outside of triangle formed by O, A, B as
x2  1 x2  1
vertices, but lies inside of  OBA  x  R

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ex e x
10. Let I   dx and J   dx . Then which of the following is/are CORRECT?
e4 x  1 e4 x  1

1  2x 
1 e  1
A) I  J  tan  C
2  2e x 
 

1 e2 x  2e x  1 
B) I  J  ln  C
2 2  e2 x  2e x  1 

1  1  e 2 x  1  1  e 2 x  2e x  1  
C) I   tan    ln    C
2 2   2e x  2  e 2 x  2e x  1  
   

1   1  e 2 x  1  1  e 2 x  2e x  1  
D) J   tan    ln    C
2 2   2e x  2  e 2 x  2e x  1  
   
1 1
11. The number of ordered pairs  x, y  such that sin3 x  sin y and cos3 x  cos y ,
2 2
where x 0,2  and y  0,4  is not less than
A) 32 B) 4 C) 16 D) 8
12. Let P be any point on ellipse 3 x 2  4 y 2  12 and S , S ' are its foci, then the locus of
centroid of the triangle PSS ' is a conic C. Which of the following is/are correct?
A) Length of latus rectum of conic C is 10 unit
B) The equation satisfying the locus of point of intersection of perpendicular tangents of
7
conic C is x 2  y 2 
9
4
C) Equation satisfying the auxiliary circle of conic C is x 2  y 2 
9
D) Area of quadrilateral formed by tangents at the extremities of latus rectum is
100 sq.units

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13. If three 3  3 invertible matrices A, B, C are Idempotent, Involutory and Orthogonal
matrices respectively, then which of the following is/are CORRECT?

 
1 T
A)  ABC   ABT C


1
B) adj 2 AB C  8 
1 1
C) If  ABC    CBA , then BC  CB

 1 T 

D) adj 3 A BC
1 1
  9adj   C B

T
A  
 

n 1
x x2 x4 x2
14. Given f ( x)     ...   ....infinite terms , 0  x  1
2 4 8 2n
1 x 1 x 1 x 1 x

1 2 4 2n
and g ( x)     .......  n , x  R  .
2 4
x 1 x 1 x 1 x2  1
Which of the following is/are CORRECT?
x
A) f ( x)  B) f   1    1
1 x  2  3

1 2n1
C) g ( x)   D) g (0)  2 n 1  1
x  1 x2n1  1
SECTION – III
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists: List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosed (i.e. the question is unanswered);
Negative Marks: –1 In all other cases.

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15. Let E1   x  R : x  1 and x 

 0  and
 x 1 
   x  
E2   x  E1 : sin 1  ln    is a real number 
   x 1 
(Here, the inverse trigonometric function sin 1 x assumes values in   ,   )
 2 2

Let f : E1  R be the function defined by f  x   ln  x  and

x 1  
  x 
g : E2  R be the function defined by g  x   sin 1  ln  
  x 1 
Column-I Column-II
(I) The range of f is (P)  1   e 
  ,   , 
 1 e e 1 
(II) The range of g contains (Q)  0,1
(III) The domain of f contains (R)  1 1 
 2 , 2 
(IV) The domain of g is (S)  ,0    0,  
(T)  e 
  ,
 e  1 
The correct option is:
A) I S; II Q; III P; IV P B) I  R; II  R; III  T ; IV  S
C) I  S ; II  R; III  T ; IV  P D) I R; II Q; III P; IV S
16. Let p , q , r be non-zero real numbers that are, respectively, the 10th ,100th ,1000th terms of
a harmonic progression respectively. Consider the system of linear equations:
x  y  z 1,
10x 100y 1000z  0,
x y z
   0.
p q r

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Column-I Column-II
(I) q (P) 10  1 
If  10, then the system of linear  x , y , z    0, ,  can be
r  9 9 
equations has a solution
(II) p (Q) 10  1 
If  100, then the system of linear  x , y , z    , , 0  can be
r  9 9 
equations has a solution
(III) p (R) Infinitely many solutions
If  10, then the system of linear
q
equations has
(IV) p (S) No solution
If  10, then the system of linear
q
equations has
(T) Atleast one solution
Which of the following is CORRECT?
A) I R; II Q; III P; IV S B) I Q; II S; III S; IV R
C) I P; II Q; III R; IV S D) I Q; II T; III P; IV R
17.
List-I List-II
(P) P  A | C   P  B | C   P  A  B  | C  (1)

P A |  B C 
   
(Q) P A  B | C  P   A  B  | C   (2) P A | C

(R) 1  P  A   P  B  C   P  A   B  C   (3) P  A  B  | C 

1 PB  C
(S) PA  B PA  B (4) 1
A) (P) – (4), (Q) – (3), (R) – (1), (S) – (2)
B) (P) – (3), (Q) – (2), (R) – (1), (S) – (4)
C) (P) – (4), (Q) – (3), (R) – (2), (S) – (1)
D) (P) – (3), (Q) – (4), (R) – (2), (S) – (1)

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18.  
The equation of a straight line is L : r  iˆ  ˆj  kˆ   iˆ  ˆj  kˆ , where   R. P1 is the

plane containing line L and perpendicular to vector v1  iˆ  ˆj. P2 is another plane

containing L and passing through the point whose position vector is v2   ˆj.

The distance of plane P1 from M 1,2,3 is equal to a.

Let A  1, 2, 1 be a point in space and B be a point on line L, then the sum of

coordinates of B for which the vector AB is parallel to the plane 2x  y  3z 1 is b .

1  p
The acute angle between planes P1 and P2 is tan   , HCF  p, q   1.
 q 
Column-I Column-II
(I) 4a 2  8b  (P) 5

(II) 2a 2  4b  (Q) 4

(III) pq (R) 2


11
(IV) p  6q  (S) 1

(T) 3
Which of the following options is correct?
A) I  Q; II  S ; III  R; IV  P
B) I  P; II  Q; III  R; IV  S
C) I  Q; II  P; III  S ; IV  R
D) I  Q; II  R; III  R; IV  S

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PHYSICS Max Marks: 60
SECTION – I
(NUMERICAL VALUE TYPE)
This section contains EIGHT (08) questions.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer. If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 ONLY if the correct numerical value is entered;
Partial Mark: 0 In all other cases.
19. A large concave mirror with radius of curvature of 0.5 m is placed on a horizontal plate.
We pour a small amount of water into the mirror and place on it a plano-convex lens with
radius of curvature of 1.0m whose plane side just covers the water. Then we place a point
light source above this set-up at a height of 0.3m. The distance (in cm) from the object
where the final image is formed will be___. (Given that the refractive index of water is
4 3
and the refractive index of glass is ).
3 2
20. A radioactive sample contains two nuclides A and B having decay constant
hr 1and 2hr 1. Initially 25% of total decay comes from A. How long (in hr) will it
take before 75% of total decay comes from A. [Take   ln 3 ]
21. A solid cylinder of radius R and length l  5R is located coaxially in a vertical cylindrical
cavity filled with a viscous liquid of viscosity  as shown in the figure. The clearance
between the solid cylinder and the cavity is h( R) except the base. If the torque
required to rotate the solid cylinder with a constant angular velocity  about its vertical
 K R4 
axis is   . Find the value of K.
 h 
 


R
l  5R

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22. A cylinder of mass M and radius R moves with constant speed v through a region of
space that contains dust particles of mass m which is at rest. There are n number of
particles per unit volume. The cylinder moves in a direction perpendicular to its axis.
Assume m  M , and assume the particles do not interact with each other. All the
collision takes place is perfectly elastic and the surface of the cylinder is smooth. The
drag force per unit length of the cylinder require to maintain the speed v constant for the
K
cylinder is nmRv 2 . Find the value of K?
3
R        
       
       
v
       
       
M        

23. Two cars A and B are moving towards each other with the same speed u  25 m/ s along a
straight road as shown in the figure. The wind is blowing with a velocity   5 m / s in
the direction of velocity of the car A. The car A emits a sound of frequency
f  310 Hz and the velocity of sound relative to air is v  330 m/ s . Find the frequency (in
Hz) of the reflected back sound from the car B received by the driver of the car A.


A u u B
   

24. The distance between the centres of two stars of masses 4MS and 12MS is 36R. Here R is
the mean distance between the centres of the Earth and the Sun and MS is the mass of the
Sun. The two stars orbit around their common centre of mass in circular orbits with a
time period T , where T is the time period of Earth’s revolution around the Sun. Find the
value of n.

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25. Nuclei of deuterium can fuse according to the following reaction to produce a proton and
a tritium atom.
3
2 2
1 H 1 H 
 1 H 11 P
The binding energy per nucleon of deuterium and tritium are 1 MeV and 2.8 MeV
respectively and neglect the kinetic energy of the nuclei before the fusion. If the kinetic
energies of the proton and the tritium produced in the above nuclear reaction are K1

and K2 respectively. Find the value of ( K1  3K2 ) in MeV.

26. Two capacitors with capacitance values C1  (10  0.10)F and C2  (40  0.20)F are

connected in Series. The voltage applied across this combination is V  (8.00  0.02)volt.
Percentage error in measuring the total energy stored in capacitors is
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: –2 In all other cases.

27. Nucleus A decays to B with decay constant 1 and B decays with constant 2. Initially

number of nuclei of A and B are 2N0 and N0 respectively. At t  t0, number of nuclei of
3N0
B stop changing. If at this instant number of nuclei of B are .
2

A) The value of t0 is 1 ln 4 1 B) The value of t0 is 1 ln 4 1

1 3 2 2 3 2

C) The value of NA at t0 is 3 N 0  2 D) The value of NA at t0 is 3 N 0  2

4 1 2 1

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28. Consider a bob of mass m and having charge q attached with a light string of length  and
pivoted at point O. It is released at rest at 600 with vertical. There are two regions-
Region-I (left of line PQ) has a uniform and constant magnetic field B directed inside
plane of paper. Region-II (right of line PQ) has a constant and uniform electric field E
directed vertically up as shown. Consider no effect of gravity in both the regions.
P
Region - I E  const
Region - II
O
l

600
m,q

B
Q
2ml
A) Time taken by particle to cross region-I for 1st time is 
5qE
2 ml
B) Time taken by particle to cross region-I for 2nd time is 
13qE
5qE
C) Angular speed of 1st revolution in magnetic field is
2ml
13qE
D) Angular speed of 2nd revolution in magnetic field is 
ml
29. ABCD is a wire frame of identical wires in which point D is given velocity v as shown in
figure. Choose the correct statement(s)
y

x
A

B 300
D v

C
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A) Velocity of point A along x-axis will be v/2
B) Speed of point A will be v
C) Speed of point A along y-axis will v/2
D) Velocity of point A will be equal to velocity of point C
30. A wire frame ABCDEF is kept as shown in figure. I is the current in the wire frame.
Y
a B
a
A
P
C D
2a
O
Q X
2a
F E
Z 2a

 iˆ  ˆj 
A) The direction of magnetic field at ‘O’ due to the wire frame will be along  
 2 
B) The direction of magnetic field at P(0, a,0) due to wire CD and EF will be along  ĵ
C) The direction of magnetic field at Q(a,0,0) due to wire CD and EF will be along (  ˆj )

D) The direction of magnetic field at P(0, a,0) due to wire CD and EF will be along (  iˆ )

31. Which of the following represents a progressive harmonic wave?

A) A( ax  bt ) B) A tan(t  kx) C) A cos(vt  x) D) A cos kx sin t
32. A small body of mass ‘m’ & radius r is released from rest in a viscous liquid of
coefficient of viscosity  and density half of that of ball. Choose the correct option(s)
A) The ball initially accelerates and then decelerates.
mln 2
B) After time t  the velocity of ball will be half of the terminal velocity
6 r
 6 r 
t
C) The instantaneous velocity of ball at a time t is given by v  vT 1  e m 

 
 
D) Ball comes to rest in short interval of time.
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SECTION – III
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists: List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosed (i.e. the question is unanswered);
Negative Marks: –1 In all other cases.
33. A particle of mass m=0.8kg is rigidly attached to the circumference of a uniform circular
ring of same mass m=0.8kg and radius R which is placed on a rough horizontal surface as
shown in the figure. Initially, the line joining the centre of the ring and the particle makes
an angle   300 with the horizontal and the system is released from rest. The ring starts
rolling without slipping on the rough horizontal surface. When the particle is getting at
the right end of the horizontal diameter of the ring. Match each entry in List-I with an
appropriate value from List-II and choose the correct option.(Given g  10 m / s 2 and
R  20cm )
m,R
m
0
30


Rough surface
List-I List-II(in newton)
P) The normal force acting on the ring due to the 1) 3
horizontal surface in Newton
Q) The frictional force acting on the ring due to the 2) 5.5
horizontal surface in Newton
R) The horizontal component of the force acting on 3) 13.5
the particle due to the ring in Newton
S) The vertical component of the force acting on 4) 0.5
the particle due to ring in Newton
5) 2.5
The correct option is:
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A) ( P )  (3) (Q)  (1) ( R )  (4) ( S )  (2)
B) ( P )  (3) (Q)  (4) ( R )  (2) ( S )  (1)
C) ( P )  (4) (Q )  (2) ( R )  (1) ( S )  (5)
D) ( P )  (5) (Q )  (1) ( R )  (2) ( S )  (3)
34. A circuit shown in the adjoining figure is connected to an ac source of 120 sin(100t) volt.
Match each entry in List-I with an appropriate value from List-II and choose the correct
option.

L  0.2 H R1  20
A B

L0  0.3H C  500 F R2  20

R3  10

  120sin(100t )volt
List-I List-II(in newton)
P) The peak current (in Amp) through the source 1) 40 2
Q) The peak current (in Amp) through the resistor R2  20 2) 40
R) The peak potential drop (in Volt) between the 3) 80
points A and B
S) The average power (in Watt) dissipated in the 4) 20 2
resistor R3  10
5) 2
The correct option is:
A) ( P )  (4) (Q )  (2) ( R )  (5) ( S )  (1)
B) ( P )  (5) (Q )  (2) ( R )  (1) ( S )  (3)
C) ( P )  (4) (Q )  (5) ( R )  (1) ( S )  (2)
D) ( P)  (2) (Q)  (4) ( R)  (3) ( S )  (1)

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35. Three identical small balls A, B and C each of mass m = 2 kg are connected by two
massless inextensible strings and placed on a smooth horizontal surface as shown in the

figure. Initially the angle between the strings AB and BC is   600 and the ball A is
imparted an initial horizontal velocity u  30 m / s parallel to the string BC. Match each
entry in List-I with an appropriate value from List-II and choose the correct option.

(Take 13  3.6 )

A u

  60
C B
List-I List-II(in newton)
P) The initial velocity acquired by the ball B just 1) 2
after string gets taut in m/s
Q) The initial velocity acquired by the ball C just 2) 4
after string gets taut in m/s
R) The impulse due to tension in the string 3) 7.2
S) The impulse due to tension in the string BC in N-s 4) 16
5) 3.6
The correct option is:
A) ( P )  (2) (Q )  (5) ( R )  (4) ( S )  (3)
B) ( P )  (3) (Q)  (1) ( R )  (4) ( S )  (2)
C) ( P )  (3) (Q)  (5) ( R )  (2) ( S )  (5)
D) ( P )  (4) (Q )  (2) ( R )  (5) ( S )  (1)

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
36. A point electric dipole with dipole moment P is located between two uniformly charged
long threads with linear charge densities 1 and 2 at distances r1 and r2 from the
threads as shown in the figure. List-I provides the different value of 1, 2 ,r1 and r2 and
List-II provides the respective magnitudes of the net electric force experienced by the
point electric dipole. Match each entry in List-I with an appropriate value from List-II
and choose the correct option.
1 2

P
r1 r2

List-I List-II(in newton)

P) d d 1) 17 P
1  2 , 2   , r1  and r2 
2 2  0d 2
Q) d d 2) P
1  2, 2   , r1  and r2 
2 2  0d 2
R) d d 3) 2 P
1   , 2  2 , r1  and r2 
4 3  0d 2
S) d d 4) 5 P
1   , 2  2 , r  and r2 
4 3  0d 2
5) 6 P
 0d 2
The correct option is:
A) ( P)  (5) (Q )  (3) ( R)  (2) ( S )  (1)
B) ( P )  (4) (Q )  (3) ( R )  (4) ( S )  (2)
C) ( P)  (3) (Q)  (5) ( R )  (2) ( S )  (4)
D) ( P )  (5) (Q )  (3) ( R )  (1) ( S )  (2)

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CHEMISTRY Max Marks: 60
SECTION – I
(NUMERICAL VALUE TYPE)
This section contains EIGHT (08) questions.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer. If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 ONLY if the correct numerical value is entered;
Partial Mark: 0 In all other cases.
37. If photon having wavelength 6.2 nm was allowed to strike a metal plate having work
function 50 eV then Uncertainity in wavelength (in meter) of emitted electron

with KEmax , if uncertainity in the momentum is 1.8  1027 kg m / s .

(given h  6  1034 J -sec )

Fill your answer by multiplying 1015

38. Calculate Suniv (in J/K) for the chemical reaction: C (graphite)  2 H 2 ( g )  CH 4 ( g ) ;

H 300  75.0 kJ . The standard entropies of C (graphite), H 2 ( g ) and CH 4 ( g ) are 6.0,
130.6 and 186.2 J/K-mol, respectively.
39. What is the ratio of moles of Mg (OH ) 2 and Al (OH )3 present in 1 lit saturated aqueous

solution of Mg (OH ) 2 and Al (OH )3 ( K SP of Mg (OH ) 2  4  1012 and

K SP of Al (OH )3  1  1033 ) . Give answer by multiplying by 1016 .

40.

i ) mCPBA
  (A) major product
ii ) NaN3
iii ) a. LiAlH 4 / THF
b. aq. NH 4Cl
iv ) aq. NaNO2  HCl

If X = number of carbon present in the ring structure of the product A

Y = degree of unsaturation in the product of A. then find the value of (x+y)

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41. Find the net charge of the peptide Tyrosine-Alanine-Arginine-Glycine at pH 5
(neglect the sign)
Ag i ) Hg /(OAC ) / H O i ) PCl
CH 3  CCl3 
 A 
2 2  B 
5  C (major product )
 ii ) NaBH 4 ii ) AlC.KOH , 
iii ) NBS (1 eq.)
iv ) AlC . KOH , 
42.
If x is the degree of unsaturation in the product C and y is the molecular weight of the
product C then find the value of (x+y).
(NOTE: Consider major product in each step)
43. 1.3 g of ferric chloride on reacting with 2.232 g of potassium hexacyanidoferrate(II)
produces ‘x’ g of a blue precipitate. The value of ‘x’(in g) is____
(Given that : AW of Fe=56, K=39, Cl=35.5)
44. How many of the following statement(s) is/are correct?
A) Single N – N bond is stronger than the single P – P bond
B) PH 3 can act as a ligand in the formation of coordination compounds with transition
metals or metal ions.
C) NO2 is paramagnetic in nature in gaseous form
D) Covalency of nitrogen in N 2O5 is five
E) SnO and SnO2 are amphoteric
F) N 2O4 is more acidic oxide among the oxides of nitrogen
G) SnO is more reactive towards acids than SnO2
H) Silicones are very inert polymers because both Si-O and Si-C-bond energies are very
high
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: –2 In all other cases.
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45.  2 NO2 ( g ) , the value of K P is 50 atm at 400 K and

For the reaction N 2O4 ( g ) 
1700 atm at 500K. Which of the following option(s) is/are correct? (All the four
statements given in the options are independent statements )
A) The reaction is endothermic
B) The reaction is exothermic
C) If NO2 ( g ) and N 2O4 ( g ) are mixed at 400 K at partial pressures 20 bar and 2 bar
respectively. More N 2O4 ( g ) will be formed.
D) The entropy of the system increases
46. The vapour pressures of pure liquids A, B and C are 75, 22 and 10 torr respectively.
Which of the following is/are possible values of vapour pressure of binary or ternary
solutions having equimolar amounts of these liquids? Assuming ideal behaviour.
A) 53.5 torr B) 35.67 torr C) 48.5 torr D) 16 torr
47. The correct statement about the following reaction sequence is
i )O / h CHCl
Cumene(C9 H12 ) 
2

P 
3  Q ( major )  R (minor)
ii ) H 3O aq.NaOH

NaOH
Q 
S
PhCH 2 Br

A) Q is steam volatile
B) Q given dark violet coloration with 1% aqueous FeCl3 solutions.
C) S readily cleaved by HI
D) S gives dark violet coloration with 1% aqueous FeCl3 solution.
48. Choose the correctly matched order?
COOH COOH

OH OH
OH

A) (Acidic strength)

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OH OH

NO2

(Acidic strength)
B) NO2

Aniline  ortho Toluidine

C) (Basic strength)

N N

CH3

<

D) (Basic strength)

49. Which of the following compound(s) does not have a bridging oxo linkage
( X  O  X ) among the following?
A) Na2 S2O5 B) Cl2O7 C) N 2O4 D) C3O2
50. Complete and balance the following reactions and answer the question:
H H
(i) PbS  H 2O2 
 (ii) MnO4  H 2O2 

(iii) AlCl3  H 2O  (iv) Ca3 N 2  H 2O 
Then identify the correct option(s)?
Given that:

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I. ‘x’ moles of H 2O is obtained as one of the product in reaction (i)
II. ‘y’ moles of O2 is obtained as one of the product in reaction (ii)
III. ‘p’ moles of Al containing compound is obtained as one of the product in
reaction (iii)
IV. ‘q’ moles of calcium containing compound is obtained as one of the product in
reaction (iv)
V. Assume in reaction (iv) the other product(in addition to ‘q’) is a gaseous
compound.
A) x  4 B) y  5 C) p  1 D) q  5
SECTION – III
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists: List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosed (i.e. the question is unanswered);
Negative Marks: –1 In all other cases.
51. 10 ml sample of H 2 SO4 solution (sp.gr. of solution= 1.47) is treated with 10 gm impure
Kl solution. The final mixture is neutralized by 20 ml of 8%(w/v) NaOH solution for left
H 2 SO4 . The liberated I 2 is divided into two parts
Evolved I 2
Part-I Part-II
Passed through 20 ml, Na2 S3O3 Passed through excess KCl
solution yielded 0.3 g NaI gives 0.497 g of Cl2
Reactions:
8 KI  5 H 2 SO4  4 K 2 SO4  4 I 2  H 2 S  4 H 2O
H 2 SO4  2 NaOH  Na2 SO4  2 H 2O
I 2  2 Na2S 2O3  2 NaI  Na2 S4O6
I 2  2 KCl  2 KI  Cl2

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Column-I Column-II
A) M Na S O P) 26.56
2 2 3
B) %(w/W) of H 2 SO4 Q) 100  103
C) % purity of KI R) 8  103
D) Total moles of I 2 evolved S) 20
A) A  R, B  S , C  P, D  Q B) A  Q, B  P, C  S , D  R
C) A  R, B  P, C  S , D  Q D) A  Q, B  S , C  P , D  R
52.
Column – I Column – II
(Reaction) (Statement)
A) P) One of the products used
3(i ) HNO / H SO , (ii ) Sn / HCl

2 4  to form Novalac
(iii ) NaNO2 / HCl , (iv ) H 2O, Boil

B) Q) One of the products used

3 (i ) CH COCl / AlCl , (ii ) Zn  Hg / HCl

3 
to form Melamine
(iii ) Cl2 , hv, (iv ) Alc, KOH , (v ) O3 / Zn, H 2O

C) (i) Red hot Fe tube, (ii) C H Cl / Anhydrous AlCl R) One of the products used
HC  CH 
3 7 3
(iii) O2 ,hv (iv) dil.H2SO4 to form Bakelite
D) CH3 S) One of the products used
to form Dacron

(i ) CH COCl / AlCl , (ii ) Zn  Hg / HCl


3

3 
(iii ) KMnO4 / O H , (iv ) dil. H 2 SO4

T) One of the products is

soluble in aq. NaOH
A) (A-PRT) (B-PQR) (C-PRT) (D-ST) B) (A-PRT) (B-PQRS) (C-PRT) (D-ST)
C) (A-PRT) (B-PQR) (C-PQRT) (D-ST) D) (A-PRT) (B-PQR) (C-PRT) (D-T)
53. Based on VSEPR model, match the compounds given in List I with the corresponding
geometries and the number of lone pairs on central atom given in List II and choose the
correct option:

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List I List II
I) ClF3 P) Trigonal bipyramidal and three lone pairs
II) I 3 Q) Tetrahedral and two lone pairs
III) I 3 R) Trigonal bipyramidal and two lone pairs
IV) XeF4 S) Octahedral and two lone pairs
T) Tetrahedral and zero lone pairs

A) I  P; II  R; III  S ; IV  Q B) I  R; II  P; III  Q; IV  S
C) I  P; II  S ; III  R; IV  Q D) I  Q; II  S ; III  R; IV  P
54. Match the complexes given in List I with their properties given in List II and choose the
correct option:
List I List II
I) 3 P) Paramagnetic
Cr  NH 3  
 6
II) 2 Q) Diamagnetic
 Ni  NH 3  
 6
III) 3 R) d 3 species
 Rh  H 2O  
 6
IV)
CrF6 3 S) Spin only magnetic moment = 1.732BM

T) Metal ion is in +2 oxidation state

A) I  Q; II  R; III  S ; IV  T B) I  P; II  S ; III  R; IV  T
C) I  PR; II  PT ; III  Q; IV  PR D) I  P; II  S ; III  T ; IV  R

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 Sri Chaitanya IIT Academy 16-03-2025_Sr.Super60, Elite, Target & LIIT BT's_ Jee-Adv(2022-P1) _GTA-21_Q.P

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