Conforms to UN GHS Classification

SAFETY DATA SHEET

TROYMAX ANTISKIN B

Section 1. Identification
GHS product identifier : TROYMAX ANTISKIN B
Code : 60086
Chemical name : 2-butanone oxime
Other means of : Not available.
identification
Product type : Liquid.
Material uses : Other non-specified industry: Anti-skinning agent

Supplier's details : Troy Siam Company Limited

242 Soi Chalongkrung 31,
Ladkrabang Industrial Estate
Lamplathew, Ladkrabang
Bangkok 10520 Thailand
Tel: 66-2-705-7500
Fax: 66-2-705-7599

Emergency Contact name:

Uraiwan Photichai-Logistics Manager
Direct Line: 662 7057517
Tel: 662 7057500 ext. 7517
Hand Phone: 66-892055951

Emergency telephone : +32 (0) 14 58 45 45 (24/7)

number (with hours of
operation)

Section 2. Hazards identification

Classification of the : FLAMMABLE LIQUIDS - Category 4
substance or mixture ACUTE TOXICITY (oral) - Category 5
ACUTE TOXICITY (dermal) - Category 4
SKIN CORROSION/IRRITATION - Category 3
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
SKIN SENSITIZATION - Category 1
TOXIC TO REPRODUCTION (Fertility) - Category 2
TOXIC TO REPRODUCTION (Unborn child) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (blood and
spleen) - Category 2
AQUATIC HAZARD (ACUTE) - Category 2

GHS label elements

Hazard pictograms :

Signal word : Danger

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Section 2. Hazards identification

Hazard statements : Combustible liquid.
Harmful in contact with skin.
May be harmful if swallowed.
Causes serious eye damage.
Causes mild skin irritation.
May cause an allergic skin reaction.
Suspected of damaging fertility or the unborn child.
May cause respiratory irritation.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure. (blood,
spleen)
Toxic to aquatic life.
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions
have been read and understood. Wear protective gloves. Wear eye or face
protection. Wear protective clothing. Keep away from flames and hot surfaces. -
No smoking. Use only outdoors or in a well-ventilated area. Avoid release to the
environment. Do not breathe vapor. Contaminated work clothing should not be
allowed out of the workplace.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove person to fresh air and keep comfortable for
breathing. Call a POISON CENTER or physician if you feel unwell. IF
SWALLOWED: Call a POISON CENTER or physician if you feel unwell. IF ON
SKIN: Wash with plenty of soap and water. Call a POISON CENTER or physician if
you feel unwell. Take off contaminated clothing and wash it before reuse. If skin
irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Immediately call a POISON CENTER or physician.
Storage : Store locked up. Store in a well-ventilated place. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national
and international regulations.

Other hazards which do not : None known.

result in classification

Section 3. Composition/information on ingredients

Substance/mixture : Substance
Chemical name : 2-butanone oxime
Other means of : Not available.
identification

CAS number/other identifiers

CAS number : 96-29-7
EC number : 202-496-6

Ingredient name % CAS number

2-butanone oxime >99 96-29-7
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

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Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately
flush eyes with plenty of water, occasionally lifting the upper and lower eyelids.
Check for and remove any contact lenses. Continue to rinse for at least 10 minutes.
Chemical burns must be treated promptly by a physician.
Inhalation : Get medical attention immediately. Call a poison center or physician. Remove
victim to fresh air and keep at rest in a position comfortable for breathing. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
It may be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie,
belt or waistband. In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
Skin contact : Get medical attention immediately. Call a poison center or physician. Wash with
plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly
by a physician. In the event of any complaints or symptoms, avoid further exposure.
Wash clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out
mouth with water. Remove dentures if any. Remove victim to fresh air and keep at
rest in a position comfortable for breathing. If material has been swallowed and the
exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Chemical burns must be treated
promptly by a physician. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or
waistband.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Skin contact : Harmful in contact with skin. Causes mild skin irritation. May cause an allergic skin
reaction.
Ingestion : May be harmful if swallowed. Can cause central nervous system (CNS) depression.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations

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Section 4. First aid measures

Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
stomach pains
reduced fetal weight
increase in fetal deaths
skeletal malformations

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Combustible liquid. In a fire or if heated, a pressure increase will occur and the
from the chemical container may burst, with the risk of a subsequent explosion. The vapor/gas is
heavier than air and will spread along the ground. Vapors may accumulate in low or
confined areas or travel a considerable distance to a source of ignition and flash
back. Runoff to sewer may create fire or explosion hazard. This material is toxic to
aquatic life. Fire water contaminated with this material must be contained and
prevented from being discharged to any waterway, sewer or drain.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

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Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate.
Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air). Water polluting material.
May be harmful to the environment if released in large quantities.

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilled product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in
which this product is used. Avoid exposure - obtain special instructions before use.
Avoid exposure during pregnancy. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not
breathe vapor or mist. Do not ingest. Avoid release to the environment. Use only
with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately
ventilated. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Store and use away from
heat, sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use only non-sparking tools.
Empty containers retain product residue and can be hazardous. Do not reuse
container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

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Section 7. Handling and storage

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved
including any area. Store in original container protected from direct sunlight in a dry, cool and well-
incompatibilities ventilated area, away from incompatible materials (see Section 10) and food and
drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing
materials. Keep container tightly closed and sealed until ready for use. Containers
that have been opened must be carefully resealed and kept upright to prevent
leakage. Do not store in unlabeled containers. Use appropriate containment to
avoid environmental contamination.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
None.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering controls
also need to keep gas, vapor or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be
required instead.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately
estimated.
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

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Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Color : Clear. Colorless.
Odor : Ethereal.
Odor threshold : Not available.
pH : 7 to 8.5
Melting point/freezing point : -29.5°C (-21.1°F)
Initial boiling point and : 152°C (305.6°F)
boiling range
Flash point : Closed cup: 63°C (145.4°F) [Setaflash.]
Burning time : Not applicable.
Burning rate : Not applicable.
Evaporation rate : >1 (butyl acetate = 1)
Flammability (solid, gas) : Not available.
Upper/lower flammability or : Not available.
explosive limits
Vapor pressure : 0.27 kPa (2 mm Hg) [room temperature]
Vapor density : 3 [Air = 1]
Relative density : 0.91 to 0.95
Solubility : Soluble in the following materials: cold water and hot water.
Dispersibility properties : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
SADT : Not available.
Viscosity : Not available.

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.

Incompatible materials : Reactive or incompatible with the following materials:

oxidizing materials

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.

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Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
2-butanone oxime LC50 Inhalation Vapor Rat >4.8 mg/l 4 hours
LD50 Dermal Rabbit 1000 to 1800 -
mg/kg
LD50 Oral Rat 2326 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
2-butanone oxime Eyes - Severe irritant Rabbit - - -
Sensitization
Product/ingredient name Route of Species Result
exposure
2-butanone oxime skin Guinea pig Sensitizing

Mutagenicity
Not available.
Carcinogenicity
Not available.
Reproductive toxicity
Product/ingredient name Maternal Fertility Development Species Dose Exposure
toxicity toxin
2-butanone oxime - Negative - Rat Oral -
Teratogenicity
Product/ingredient name Result Species Dose Exposure
2-butanone oxime Negative - Oral Rat - -
Negative - Oral Rabbit - -
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
2-butanone oxime Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
2-butanone oxime Category 2 Not determined blood and spleen
Aspiration hazard
Not available.

Information on the likely : Not available.

routes of exposure
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.

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Section 11. Toxicological information

Skin contact : Harmful in contact with skin. Causes mild skin irritation. May cause an allergic skin
reaction.
Ingestion : May be harmful if swallowed. Can cause central nervous system (CNS) depression.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
stomach pains
reduced fetal weight
increase in fetal deaths
skeletal malformations

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Product/ingredient name Result Species Dose Exposure
2-butanone oxime Sub-chronic LOAEL Oral Rat 25 mg/kg 13 weeks
Sub-chronic NOEL Oral Rat 13 mg/kg 13 weeks
Sub-chronic NOEL Inhalation Rat 25 ppm 4 weeks
Gas.
General : May cause damage to organs through prolonged or repeated exposure. Once
sensitized, a severe allergic reaction may occur when subsequently exposed to very
low levels.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : Suspected of damaging the unborn child.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : Suspected of damaging fertility.
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Section 11. Toxicological information

Numerical measures of toxicity

Acute toxicity estimates
Not available.

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
2-butanone oxime Acute LC50 750 mg/l Daphnia 48 hours
Acute LC50 48 mg/l Fish 96 hours

Persistence and degradability

Product/ingredient name Aquatic half-life Photolysis Biodegradability
2-butanone oxime - - Inherent

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
2-butanone oxime 0.4 - low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible. This material and
its container must be disposed of in a safe way. Care should be taken when
handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Vapor from product residues
may create a highly flammable or explosive atmosphere inside the container. Do
not cut, weld or grind used containers unless they have been cleaned thoroughly
internally. Avoid dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers.

Section 14. Transport information

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Section 14. Transport information

UN IMDG IATA
UN number Not regulated. Not regulated. Not regulated.

UN proper - - -
shipping name
Transport hazard - - -
class(es)

Packing group - - -
Environmental No. No. No.
hazards
Additional - - -
information

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Transport in bulk according : Not available.

to Annex II of MARPOL and
the IBC Code

Section 15. Regulatory information

Safety, health and : No known specific national and/or regional regulations applicable to this product
environmental regulations (including its ingredients).
specific for the product
Product registration : United States inventory (TSCA 8b): All components are listed or exempted.
Australia inventory (AICS): All components are listed or exempted.
Canada inventory: All components are listed or exempted.
China inventory (IECSC): All components are listed or exempted.
Europe inventory: All components are listed or exempted.
Japan inventory (ENCS): All components are listed or exempted.
Japan inventory (ISHL): Not determined.
Malaysia Inventory (EHS Register): Not determined.
New Zealand Inventory of Chemicals (NZIoC): All components are listed or
exempted.
Philippines inventory (PICCS): All components are listed or exempted.
Korea inventory: All components are listed or exempted.
Taiwan Chemical Substances Inventory (TCSI): All components are listed or
exempted.
Turkey inventory: Not determined.

Section 16. Other information

History
Date of printing : 9/2/2016
Date of issue/Date of : 8/31/2016
revision
Date of previous issue : 12/3/2015
Version : 2

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Section 16. Other information

Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-
named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described herein,
we cannot guarantee that these are the only hazards that exist.

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