SAFETY DATA SHEET

Regulation (EC) No 1907/2006 (REACH), Article 31 Revision date: 11-Jun-2018

According to Article 31 of the Regulation (EC) No 1907/2006 (REACH), a Version: 4

Safety Data Sheet (SDS) must be provided for hazardous substances or
mixtures. This product does not meet the classification criteria of the
Regulation (EC) No 1272/2008 (CLP) . Therefore such document is outside
the scope of Article 31 of REACH and the requirements for content in each
section do not apply.

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

1.1. Product Identifier

Product code: TS530

Product name: CAB-O-SILÒTS-530 Fumed Silica

REACH Registration Number: See Section 3
Synonyms: Silicon Dioxide, Synthetic Amorphous Silica, Pyrogenic (Fumed) Amorphous Silica

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended use: Various, Rheological control, Flow agent, Thickening agent, Reinforcing agent in: Coatings,
Adhesives and/or sealants, Inks and toners, Silicone Elastomer, Rubber products,
Dispersion, Suspension, Paints, Cosmetics, Hygiene and sanitary products, Other

Uses advised against: No information available.

1.3. Details of the supplier of the safety data sheet

Cabot EMEA* Headquarters

CABOT SWITZERLAND GmbH
Mühlentalstrasse 36
8200 Schaffhausen
Switzerland
Tel.: +41 (0) 52 630 3838
Fax: +41 (0) 52 630 3810

Cabot EMEA* Business Service Center

101 Mukusalas Street
LV-1004 Riga
Latvia
Tel.: +371 67050700

* Europe, Middle East and Africa

E-mail address: [email protected]

1.4. Emergency telephone number

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Emergency Telephone Number: 24H/7d service

GERMANY: CHEMTREC 0800-181-7059
UK: CHEMTREC: (+44)-870-8200418
US: CHEMTREC: 1-800-424-9300 or 1-703-527-3887
CHEMTREC China: 4001-204937
International CHEMTREC: +1 703-741-5970 or +1-703-527-3887

2. HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture

Not a hazardous substance according to Regulation (EC) 1272/2008 (CLP), its various amendments and adaptations.

2.2. Label Elements

Pictogram:
None

Signal Word:
None

Hazard statements:
None

Precautionary statements:
None

2.3. Other Hazards

This substance is classified as hazardous as a combustible dust by the United States 2012 OSHA Hazard Communication
Standard (29 CFR 1910.1200) and the Canadian Hazardous Products Regulation (HPR) 2015. The signal word, hazard
statement and precautionary statements in the United States and Canada are: WARNING May form combustible dust
concentrations in air. Keep away from all ignition sources including heat, sparks and flame. Prevent dust accumulations to
minimize explosion hazard.

Do not expose to temperatures above 150°C. Hazardous products of combustion can include carbon monoxide, carbon
dioxide and nitrogen oxides (NOx).

Principle Routes of Exposure: Inhalation, Skin Contact, Eye contact

Eye Contact: May cause mechanical irritation. Avoid contact with eyes.

Skin Contact: May cause mechanical irritation and skin drying. Avoid contact with skin. No cases of
sensitization in humans have been reported.

Inhalation: Dust may be irritating to respiratory tract. Provide appropriate exhaust ventilation at
machinery and at places where dust can be generated. See also Section 8.

Ingestion: Adverse health effects are not expected. See Section 11.

Carcinogenicity: Does not contain any substances greater than 0.1% listed by IARC (International Agency
for Research on Cancer), NTP (National Toxicology Program), OSHA (Occupational Safety
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and Health Administration), ACGIH (American Conference for Governmental Industrial

Hygienists) or EU (European Union). See also Section 11.

Target Organ Effects: Lungs, See Section 11

Medical Conditions Aggravated by Asthma, Respiratory disorder

Exposure:

Potential Environmental Effects: None known. See Section 12.

3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances

Chemical name EC No: CAS No weight-% Classification Classification according REACH

according to to Regulation (EC) No. registration
Directive 1272/2008 [CLP] number
67/548/EEC or
1999/45/EC
Silanamine, 272-697-1 68909-20-6 100 - - *
1,1,1-trimethyl-N-(t
rimethylsilyl)-,
hydrolysis products
with silica

Other Information:
The hyphen (-) means "not applicable"

REACH registration number:

Synthetic Amorphous Silica: 01-2119379499-16; Surface Treating Agent: Hexamethyldisilazane 01-2119438176-38

4. FIRST AID MEASURES

4.1. Description of first aid measures

Skin Contact Wash thoroughly with soap and water. Seek medical attention if symptoms develop.

Eye contact Flush eyes immediately with large amounts of water for 15 minutes. Seek medical
attention if symptoms develop.

Inhalation If cough, shortness of breath or other breathing problems occur, move to fresh air. Seek
medical attention if symptoms persist. If necessary, restore normal breathing through
standard first aid measures.

Ingestion Do not induce vomiting. If conscious, give several glasses of water. Never give anything
by mouth to an unconscious person.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms: The most important known symptoms and effects are described in Section 2 and/or in

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Section 11.

4.3. Indication of any immediate medical attention and special treatment needed

Note to physicians: Treat symptomatically.

5. FIRE-FIGHTING MEASURES
5.1. Extinguishing media

Suitable Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment. Use foam, carbon dioxide (CO2), dry chemical or water spray.
A fog is recommended if water is used.

Unsuitable Extinguishing Media: DO NOT USE high pressure media which could cause formation of a potentially explosible
dust-air mixture.

5.2. Special hazards arising from the substance or mixture

Specific hazards arising from the None.

chemical:

Hazardous combustion products: Carbon monoxide (CO). Carbon dioxide (CO2). Nitrogen oxides (NOx).

5.3. Advice for firefighters

Special protective equipment for Wear suitable protective equipment. In the event of fire, wear self-contained breathing
fire-fighters apparatus.

Risk of Dust Explosion: Dust may form explosive mixture in air. See also Section 9.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions: Avoid dust formation. Ensure adequate ventilation. Use personal protective equipment.
See also Section 8.

For emergency responders: Use personal protection recommended in Section 8.

6.2. Environmental precautions

Environmental Precautions: Contain spilled product on land, if possible. Local authorities should be advised if
significant spillages cannot be contained.

6.3. Methods and material for containment and cleaning up

Methods for containment: Prevent further leakage or spillage if safe to do so.

Methods for cleaning up: If the spilled material contains dust or has the potential to create dust, use
explosion-proof vacuums and/or cleaning systems suitable for combustible dusts. Use of
a vacuum with high efficiency particulate air (HEPA) filtration is recommended. Do not
create a dust cloud by using a brush or compressed air. Dry sweeping is not
recommended. See Section 13.

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6.4. Reference to other sections

Reference to other sections See section 8 for more information. See section 13 for more information.

7. HANDLING AND STORAGE

7.1. Precautions for safe handling

Advice on safe handling: Avoid contact with skin and eyes. Avoid dust formation. Do not breathe dust. Provide
appropriate exhaust ventilation at machinery and at places where dust can be generated.
Do not create a dust cloud by using a brush or compressed air. Dust may form explosible
mixture in air.

Take precautionary measures against static discharges. All metal parts of the mixing and
processing equipment must be earthed/grounded. Ensure all equipment is electrically
earthed/grounded before beginning transfer operations. Fine dust is capable of
penetrating electrical equipment and may cause electrical shorts.

General hygiene considerations: Handle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions: Keep containers tightly closed in a dry and well-ventilated place. Do not store together
with volatile chemicals as they may be adsorbed onto product. Store at ambient
conditions. Keep away from heat and sources of ignition. Keep in properly labeled
containers.

Dust deposits should not be allowed to accumulate on surfaces, as these may form an
explosible mixture if they are released in the atmosphere in sufficient concentrations.

Incompatible materials: None known.

7.3. Specific end use(s)

Risk Management Measures (RMM) Per Article 14.4 of the REACH Regulation no exposure scenario has been developed as the
substance is not hazardous.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Exposure guidelines: The table below is a summary. Please see the specific legislation for complete
information.

Amorphous Silica, The regulatory Australia: 2 mg/m³, TWA, Respirable

exposure limits are found under the Austria MAK 4 mg/m³, TWA, Inhalable fraction
general silica, CAS RN 7631-86-9: Finland: 5 mg/m³
Germany TRGS 900:
4 mg/m³, TWA, Inhalable fraction
India: 10 mg/m³, TWA
Ireland: 2.4 mg/m³, TWA, Respirable dust
Norway: 1.5 mg/m³, TWA, Respirable dust
Switzerland:4 mg/m³, TWA
UK WEL: 6 mg/m³, TWA, Inhalable fraction
2.4 mg/m³, TWA, Respirable fraction
US OSHA PEL: 6mg/m³ (54 FR2701)
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Dust, or Particulates Not Otherwise Belgium: 10 mg/m³, TWA, Inhalable

Specified: 3 mg/m³ TWA, Respirable

China: 8 mg/m³, TWA

10 mg/m³, STEL

France: 10 mg/m³, TWA Inhalable dust

5 mg/m³, TWA Respirable dust

Italy: 10 mg/m³, TWA, Inhalable

3 mg/m³, TWA, Respirable

Malaysia: 10 mg/m³, TWA, Inhalable

3 mg/m³, TWA, Respirable

Spain: 10 mg/m³, VLA, Inhalable

3 mg/m³, VLA, Respirable

US ACGIH - PNOS: 10 mg/m³, TWA, Inhalable

3 mg/m³, TWA, Respirable

US OSHA - PEL: 15 mg/m³, TWA, Total dust

5 mg/m³, TWA, Respirable

NOTE:

In its facilities globally, Cabot Corporation manages silica to the Germany TRGS 900 occupational exposure limit of 4 mg/m³,
TWA, Inhalable fraction

MAK: Maximale Arbeitsplatzkonzentration (Maximum Workplace Concentration)

PEL: Permissible Exposure Limit
PNOS: Particulate Not Otherwise Specified
STEL: Short Term Exposure Limit
TRGS: Technische Regeln für Gefahrstoffe (Technical Rule for Hazardous Materials)
TWA: Time Weighted Average
US ACGIH: United States American Conference of Governmental Industrial Hygienists
US OSHA: United States Occupational Safety and Health Administration
VLA: Valore Límite Ambientales (Environmental Limit Value)
WEL: Workplace Exposure Limit

Derived No Effect Level (DNEL): Synthetic Amorphous Silica: As required under the EU Registration, Evaluation and
Authorization of Chemicals (REACH) Regulation, the Synthetic Amorphous Silica REACH
Consortium (of which Cabot Corporation is a member) developed a Derived No Effect
Level (DNEL) for Synthetic Amorphous Silica of 4 mg/m3 inhalable (Germany TRGS 900
occupational exposure limit).

8.2. Exposure controls

Engineering Controls: Ensure adequate ventilation to maintain exposures below occupational limits. Provide
appropriate local exhaust ventilation at machinery and at places where dust can be
generated.

Personal protective equipment [PPE]

Respiratory Protection: Approved respirator may be necessary if local exhaust ventilation is not adequate.
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Hand Protection: Wear protective gloves to prevent skin drying. Use protective barrier cream before
handling the product. Wash hands and other exposed skin with mild soap and water.

Eye/face Protection: Wear eye/face protection. Wear safety glasses with side shields (or goggles).

Skin and Body Protection: Wear suitable protective clothing. Wash clothing daily. Work clothing should not be
allowed out of the workplace.

Other: Handle in accordance with good industrial hygiene and safety practice. Emergency
eyewash and safety shower should be located nearby.

Environmental exposure controls: In accordance with all local legislation and permit requirements as applicable for dusts.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Physical State: Solid Odor: None.

Appearance: Powder Odor threshold: No information available
Color: White

Property Values Rema rks•Met hod

pH: No information available
Melting point/freezing point: 1700 °C NIOSH Pocket Guide to Chemical Hazards
Boiling point / boiling range: 2230 °C NIOSH Pocket Guide to Chemical Hazards
Evaporation Rate: Not Applicable
Vapor pressure: Not Applicable
Vapor Density: Not Applicable
Density: 2.2-2.3 g/cm3 @ 20 °C
Bulk Density: <5 lbs/ft3 DIN/ISO 787:11

Specific Gravity at 20°C: 2.2-2.3

Water solubility: No information available
Solubility(ies): No information available
Partition Coefficient Not Applicable
(n-octanol/water):
Decomposition temperature: > 321 °C Bulk Powder test- Diffusion cell
Viscosity: Not Applicable
Kinematic viscosity: Not Applicable
Dynamic viscosity: Not Applicable
Oxidizing Properties: No oxidizing properties
Softening point: Not Applicable
VOC content (%): Not Applicable
% Volatile (by Volume): Not Applicable
% Volatile (by Weight): Not Applicable

Surface Tension: Not Applicable

Explosive properties: Dust may form explosible mixture in air

Flash Point: Not Applicable

Flammability (solid, gas): No information available
Flammability Limit in Air:
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Explosion Limits in Air - Upper (g/m3): No information available

Explosion Limits in Air - Lower (g/m3): 600<MEC<800 ASTM E-1515 (MEC - Minimum Explosible Concentration)
g/m3
Autoignition Temperature: 725 °C ASTM E-1491 Dust cloud (MAIT - Minimum Auto-Ignition
Temperature)
Minimum Ignition Temperature: >450 °C ASTM E-2021, Dust layer. Neither of the tests conducted at a
temperature of 450°C (the upper limit of the apparatus) met
the criteria for ignition based on temperature rise. For this
reason, the MIT was reported as > 450°C

Minimum Ignition Energy: > 10 J BS 5958 (Part 1, 1991)

Ignition Energy: No information available
Maximum Absolute Explosion Pressure: 4.62 bar ASTM E-1226 (20-L Sphere Test)
Maximum Rate of Pressure Rise: 66 bar/sec ASTM E-1226 (20-L Sphere Test)
Burn Velocity: No information available
Kst Value: 18 ASTM E-1226 (20-L Sphere Test)
bar.meter/second
Dust Explosion Classification: ST1 Weak Explosion; ASTM E-1226

End point is listed "not applicable" due to the inherent properties of the substance
"No information available" indicates testing has not been performed

9.2. Other information

None

10. STABILITY AND REACTIVITY

10.1. Reactivity

Reactivity: Not reactive.

10.2. Chemical stability

Stability: Stable under recommended handling and storage conditions. Bulk Powder test- Diffusion
cell. Onset Temperature: 321 °C.

Explosion data

Sensitivity to Mechanical Impact: None

Sensitivity to Static Discharge: Dust may form explosible mixture in air. Avoid dust formation. Do not create a dust cloud
by using a brush or compressed air. Take precautionary measures against static
discharges. All metal parts of the mixing and processing equipment must be
earthed/grounded. Ensure all equipment is electrically earthed/grounded before
beginning transfer operations.

10.3. Possibility of hazardous reactions

Hazardous polymerization: Hazardous polymerization does not occur.

Possibility of hazardous reactions: None under normal processing.

10.4. Conditions to avoid

Conditions to avoid: Do not expose to temperatures above 150°C. Keep away from heat and sources of

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ignition. Avoid dust formation.

10.5. Incompatible materials

Incompatible materials: None known

10.6. Hazardous decomposition products

Hazardous decomposition products: Carbon monoxide (CO), Carbon dioxide (CO2), Nitrogen oxides (NOx)

11. TOXICOLOGICAL INFORMATION

Information given is based on data obtained from this substance or from similar substances.

11.1. Information on toxicological effects

Acute toxicity

Oral LD50: LD50/oral/rat = > 5000 mg/kg. No deaths occurred and no signs of toxicity were seen
during the observation periods after single oral administration of the substance. (OECD
423).

Inhalation LC50: Due to the product's physical characteristics, no suitable testing procedure is available

Dermal LD50: No data are available on the product itself

Synthetic Amorphous Silica LD50/dermal/rabbit = > 2000 mg/kg Very slight transient
erythema in one animal. No signs of systemic or organ toxicity (OECD 402)

Skin corrosion/irritation: Primary irritation index = 0.0 @ 24 hr. Not classified as an irritant (OECD 404).

Serious eye damage/eye irritation: Not classified as an irritant in rabbit studies (OECD 405). High dust concentrations may
cause mechanical irritation.

Sensitization: No experimental animal data are available. No cases of sensitization in humans have been
reported.

Mutagenicity: Not mutagenic in Ames test. Negative in the chromosome aberration test in Chinese
hamster ovary (CHO) cells.

Carcinogenicity: No data are available on the product itself.

Synthetic Amorphous Silica. No evidence of carcinogenicity was observed in multiple

animal species following repeated oral or inhalation exposure to amorphous silica.
Similarly, epidemiology studies show no evidence of carcinogenicity in workers who
manufacture amorphous silica.

Reproductive and Developmental No effects on reproductive organs or fetal development have been reported in animal
Toxicity: toxicity studies.

STOT - single exposure: Specific target organ toxicity is not expected after single oral, single inhalation, or single
dermal exposure.

STOT - repeated exposure: No data are available on the product itself.

Treated Synthetic Amorphous Silica: Repeated dose toxicity: oral (rat), 28-d, diet, no
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significant treatment-related adverse effects at the doses tested. Derived No Adverse

Effects Level (NOAEL) in the range of 1000 mg/kg/d.

Synthetic Amorphous Silica: Repeated dose toxicity: oral (rat), 2 weeks to 6 months, no
significant treatment-related adverse effects at doses of up to 8% silica in the diet.
Repeated dose toxicity: inhalation (rat), 13 weeks, Lowest Observed Effect Level (LOEL) =
1.3 mg/m3 based on mild reversible effects in the lungs.
Repeated dose toxicity: inhalation (rat), 90 days, LOEL = 1 mg/m3 based on reversible
effects in the lungs and effects in the nasal cavity.

Based on available data, a STOT-RE classification is not warranted.

Aspiration Hazard: Based on industrial experience and available data, no aspiration hazard is expected.

12. ECOLOGICAL INFORMATION

Information given is based on data from similar substances.

12.1. Toxicity

Aquatic Toxicity: Fish (Brachydanio rerio) LC50 (96 h): > 10,000 mg/l; (Method: OECD 203). No acute
toxicity to Daphnia with EL and EL50 ranging from >1000 to 10,000 mg/L (OECD 202).

12.2. Persistence and degradability

The methods for determining biodegradability are not applicable to inorganic substances

12.3. Bioaccumulative potential

Not expected due to physicochemical properties of the substance.

12.4. Mobility in soil

Mobility: Not expected to migrate.

12.5. Results of PBT and vPvB

assessment

No information available.

12.6. Other adverse effects

No information available.

13. DISPOSAL CONSIDERATIONS

Disclaimer: Information in this section pertains to the product as shipped in its intended composition as described in Section 3
of this SDS. Contamination or processing may change waste characteristics and requirements. Regulations may also apply to

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empty containers, liners or rinsate. State/provincial and local regulations may be different from federal regulations. The person
generating waste must determine its proper classification

List of Wastes Code: Not Applicable

13.1. Waste treatment methods

Waste from residues/unused Disposal should be in accordance with applicable regional, national and local laws and
products: regulations.

14. TRANSPORT INFORMATION

DOT
14.1 UN/ID no Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Hazard Class Not regulated
14.4 Packing group Not regulated

IMDG
14.1 UN/ID no Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Hazard Class Not regulated
14.4 Packing group Not regulated

RID
14.1 UN/ID no Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Hazard Class Not regulated
14.4 Packing group Not regulated

ADR
14.1 UN/ID no Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Hazard Class Not regulated
14.4 Packing group Not regulated

ICAO (air)
14.1 UN/ID no Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Hazard Class Not regulated
14.4 Packing group Not regulated

IATA
14.1 UN/ID no Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Hazard Class Not regulated
14.4 Packing group Not regulated

15. REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

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European Union

Indication of danger: Not a hazardous substance according to Regulation (EC) 1272/2008 (CLP), its various amendments and
adaptations and Directive 67/548/EEC.

National Regulations

Germany Water hazard class (WGK): nwg (not water endangering) WGK ID Nr.: 1429

Swiss Poison class:

Not determined

International Inventories

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory Complies
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List Complies
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Complies
Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances Complies
IECSC - China Inventory of Existing Chemical Substances Complies
KECL - Korean Existing and Evaluated Chemical Substances Complies
PICCS - Philippines Inventory of Chemicals and Chemical Substances Complies
AICS - Australian Inventory of Chemical Substances Complies
NZIoC - New Zealand Inventory of Chemicals Complies
TCSI - Taiwan Chemical Substance Inventory Complies

15.2. Chemical safety assessment

EU Chemical Safety Assessment: A Chemical Safety Assessment has been carried out for Synthetic Amorphous Silica.

EU Exposure Scenarios: Per Article 14.4 of the REACH Regulation no exposure scenario has been developed as the substance is
not hazardous.

16. OTHER INFORMATION

Pharmaceutical Use:
Not permitted

Food Additive Use:

Not permitted

References: NIOSH Pocket Guide to Chemical Hazards, September 2005. "Silica, amorphous". DHHS (NIOSH) Publication No.
2005-149. National Technical Information Service, Springfield, VA. p. 277

Contacts:

Cabot Corporation Cabot GmbH Cabot Carbon, Ltd.

157 Concord Road Kronenstrasse 2 Sully Moors Road
Billerica, MA 01821 79618 Rheinfelden Sully, Vale of Glamorgan CF64 5RP
UNITED STATES GERMANY Wales, UNITED KINGDOM
Tel: 1-978-663-3455 Tel (+49) 7623.707.0 Tel: (+44) 1446.736999
Fax: 1-978-670-6955 Fax: (+49) 7623.707.530 Fax: (+44) 1446.737123
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Cabot Corporation Cabot Bluestar Ltd. Cabot Corporation

700 E U.S. Highway 36 Xinghuo Industrial Garden 3603 South Saginaw Road
Tuscola, IL 61953-9643 Yongxiu County, Jiujiang City 330319 Midland, MI 48640
UNITED STATES Jiangxi Province, CHINA UNITED STATES
Tel:1-217-253-3370 Tel: (86-792) 3171616 Tel: 1-989-495-0030
Fax: 1-217-253-5530 Fax: (86-792) 3170320 Fax: 1-989-495-2139

Disclaimer:
The information set forth is based on information that Cabot Corporation believes to be accurate. No warranty, expressed or
implied, is intended. The information is provided solely for your information and consideration and Cabot assumes no legal
responsibility for use or reliance thereon. In the event of a discrepancy between the information on the non-English document
and its English counterpart, the English version shall supersede.

Prepared by: Cabot Corporation - Safety, Health and Environmental Affairs

Revision date: 11-Jun-2018

Version: 4

All names annotated with the Òor Ô symbol are trademarks of the Cabot Corporation or its affiliates

End of Safety Data Sheet

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