Sec: SR.

IIT _*CO-SC(MODEL-A&APEX) Date: 17-08-25

Time: 3 Hrs Max. Marks: 180
17-08-25_SR.IIT_STAR CO-SC(MODEL-A&APEX)_JEE ADV_PTA-3_SYLLABUS
MATHEMATICS: PRESENT WEEK (100%): CONTINUITY & DIFFERENTIABILITY,
DIFFERENTIATION

PHYSICS: PRESENT WEEK (100%): ELECTROSTATICS + GAUSS LAW +

GRAVITATION

CHEMISTRY: PRESENT WEEK (100%): HYDROCARBON AND BENZENE

Narayana IIT Academy 17-08-25_SR.STAR CO-SC(MODEL-A&APEX)_JEE-ADV_PTA-3_QP
TIME:3hrs IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I (Q.N : 1 – 3) +4 -2 3 12
(partial marking scheme) (+1,0)
Sec – II (Q.N : 4 – 7) Questions with Single Correct Options +3 -1 4 12
Sec – III (Q.N : 8 – 13) Questions with Non-Negative Integer type +4 0 6 24
Sec – IV (Q.N : 14 – 17) Questions with MATRIX MATCH +3 -1 4 12
Total 17 60

PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I (Q.N : 18 – 20) +4 -2 3 12
(partial marking scheme) (+1,0)
Sec – II (Q.N : 21 – 24) Questions with Single Correct Options +3 -1 4 12
Sec – III (Q.N : 25 – 30) Questions with Non-Negative Integer type +4 0 6 24
Sec – IV (Q.N : 31 – 34) Questions with MATRIX MATCH +3 -1 4 12
Total 17 60

CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I (Q.N : 35 – 37) +4 -2 3 12
(partial marking scheme) (+1,0)
Sec – II (Q.N : 38 – 41) Questions with Single Correct Options +3 -1 4 12
Sec – III (Q.N : 42 – 47) Questions with Non-Negative Integer type +4 0 6 24
Sec – IV (Q.N : 48 –51) Questions with MATRIX MATCH +3 -1 4 12
Total 17 60

SR_IIT_*CO SC Page. No. 2

Narayana IIT Academy 17-08-25_SR.STAR CO-SC(MODEL-A&APEX)_JEE-ADV_PTA-3_QP
MATHEMATICS MAX.MARKS: 60
SECTION - I (Maximum Marks : 12)
This section contains THREE (03) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
1. Let a function be represented parametrically by the equations
1  log e t 3  2 log e t
x ; y  ; then which of the following statements is/are true?
t2 t

 dy d2y 
 where y '  ; y "  
 dx dx 2 

A) y " x  2 y ' x   y B) yy '  2 x  y '   1

2

C) xy '  2 y  y '  2 D) y "  y  4 xy '    y '

2 2

dny
2. Let y  e  x cos x and yn  kn y  0 ,  n  N where yn  and k n are constant n  N ,
dx n
then identify the correct statement(s)

A) k4  4 B) k8  16 C) k12  20 D) k16  24

3. Let f be a function defined on  0,   as

 x  a 2 sin x, 0  x   / 4

f  x    2 x cot x  b,  / 4  x   / 2
a cos 2 x  b sin x,  / 2  x  


If f is continuous on  0,   then identify the correct statement(s)

A) a   / 6 B) b   / 12 C) a   / 12 D) b   / 6

SR_IIT_*CO SC Page. No. 3

Narayana IIT Academy 17-08-25_SR.STAR CO-SC(MODEL-A&APEX)_JEE-ADV_PTA-3_QP
SECTION–II (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
4. Let y  f  x  be a continuous function from R  R and attains only irrational values,
100
then  f  r  is equal to
r 1

99 100 100 50
A)  f  r  B)  f  2r  C)   f  2r   1 D)  f r
r 1 r 1 r 1 r 1

dy
 4e2 x 2 y , then 1  log e  2 x   
2
For x  1 , Let  x, y  satisfy  2 x 
2y
5. is equal to
dx

x.log e  2 x   log e 2
A) B) log e  2 x 
x

x.log e  2 x   log e 2
C) D) x log e  2 x 
x

dy
6. If sin y  x sin  a  y  , then is equal to:
dx

sin a sin 2  a  y  sin 2  a  y 

A) B) C) sin a. sin  a  y 
2
D)
sin  a  y 
2
sin a sin a

 3  
 x cos  x 4 sin , x  0
7. Let f  x    2x x
 0, x0


be a function then f is

A) differentiable at x = 0 and x = 1

B) differentiable at x = 0 not differentiable at x = 2

C) differentiable at x = 2 and not differentiable at x = 1

D) differentiable neither at x = 0 nor at x = 2.

SR_IIT_*CO SC Page. No. 4

Narayana IIT Academy 17-08-25_SR.STAR CO-SC(MODEL-A&APEX)_JEE-ADV_PTA-3_QP
SECTION-III (Maximum Marks : 24)
This section contains SIX (06) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
 2 1
 x sin  x   2 x
   , x0
8. Let f  x    1
 1  x  x  e
 /e x0


If f  x  is continuous at x  0 , then the value of  is :

d2y
     dy
2 2
1 2 2
9. If y  tan x and x 1  2 x x  1  k , then the value of k, is :
dx 2 dx

 ax3  bx 2  cx  d
 , x0
10. Let f  x    x be a continuous function where a, b, c, d are in
2, x0


arithmetic progression (in order). Then the number of points where f  x  is non

derivable is.

4x
Let f : R  R be defined as f  x    2 x  3  
3
11.  cos x and g  f 1 , then the value of
3
7 g '  2   3 g "  2  is .

12. Let f  x   x, g  x   1  f  x  , h  x   2  g  x  , L  x   h  x   h  x  . The number of

points where L  x  is non-differentiable is.

13. Two cubic function f  x   x3  ax 2  bx  c and g  x   cx3  bx 2  ax  1 satisfy the

following conditions.
(I) f  3  0, g  4   0

f  x
(II) The value of lim exists for all p  R  4
x p g  x

f  x  g  x
The value of lim is
x1 x 1

SR_IIT_*CO SC Page. No. 5

Narayana IIT Academy 17-08-25_SR.STAR CO-SC(MODEL-A&APEX)_JEE-ADV_PTA-3_QP
SECTION-IV
(Maximum Marks : 12)
This section contains FOUR (04) Matching List Sets. Each set has ONE Multiple Choice Question
Each set has TWO lists: List-I and List-II. List-I has Four entries (P), (Q), (R) and (S) and
List-II has Five entries (1), (2), (3), (4) and (5).
FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these
four options satisfies the condition asked in the Multiple Choice Question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3ONLYif the option corresponding to the correct combination is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: – 1 in all other cases.
14. Column-I has the equation with at least one root in the interval of column-II
COLUMN-I COLUMN-II
 1
I) sin x  x  1  0 P)  2, 2 

x2 [0, 1]
II)  sin  x  2 / 3  0 Q)
4
x3  3 
III)  sin  x  2 / 3  0 R) 0, 2 
4
IV) 2 x  3x  0 S) [2, 2]
T) [2, 0]
A) I-T, II-P, III-S, IV-T B) I-R, II-P, III-S, IV-Q
C) I-R, II-P, III-T, IV-T D) I-Q, II-P, III-S, IV-T
15. Column-I has curve equation in parametric form (parameter t)
Column-II has differentiation (second order and 3rd order) of the curves in column-I at
the indicated points of the parameter is given
COLUMN-I COLUMN-II
2
d y 4
2 
I) x  a cos t , y  a sin t P) t   / 3  
dx a

d2y
II) 3
x  a cos t , y  a sin t 3
Q)  t   / 6  0
dx 2

d2y 1
2 
III) 2
x  a cos t , y  a sin t 2
R) t   / 2  
dx a

d3y 16
3 
IV) x  a  t  sin t  , y  a 1  cos t  S) t   / 4   2
dx 3a

A) I-Q, II-S, III-R, IV-P B) I-S, II-R, III-P, IV-Q

C) I-R, II-S, III-Q, IV-P D)I-P, II-R, III-Q, IV-S
SR_IIT_*CO SC Page. No. 6
Narayana IIT Academy 17-08-25_SR.STAR CO-SC(MODEL-A&APEX)_JEE-ADV_PTA-3_QP
16. The relation in (I) to (IV) satisfies

COLUMN-I COLUMN-II
1 1
I) xy  log y  1 P) xy2  y1  y  0
2 4

II)  
y  sin 1 x / 1  x 2 Q) 1  x  y
2
1  xy  1

III) y  2 x  x2 R) y 2   xy  1 y1  0

IV) ye x
 e x
S) y 3 y2  1  0

dy d2y
(Note: y1  , y2  2 )
dx d x

A) I-R, II-Q, III-S, IV-P B) I-R, II-Q, III-P, IV-S

C) I-S, II-R, III-Q, IV-P D) I-Q, II-R, III-S, IV-P

17. Match the following columns for the function and their derivatives.

COLUMN-I COLUMN-II
2
I) If f  x   2 tan 1 x, then f '  x  is: P) ; x 1
1  x2

 2x  2
II) If f  x   tan 1  2 
, then f '  x  is: Q) ; x0
1 x  1  x2

 2x  2
III) If f  x   sin 1  2 
, then f '  x  is: R) ; x 1
1 x  1  x2

 1  x2  2
IV) If f  x   cos 1  2 
, then f '  x  is: S) ; x 1
 1  x  1  x2

2
T) ; xR
1  x2

A) I-T; II-R; III-S; IV-Q B) I-T; II-Q; III-S; IV-Q

C) I-S; II-P; III-P; IV-Q D) I-T; II-Q; III-P; IV-Q

SR_IIT_*CO SC Page. No. 7

Narayana IIT Academy 17-08-25_SR.STAR CO-SC(MODEL-A&APEX)_JEE-ADV_PTA-3_QP
PHYSICS MAX.MARKS: 60
SECTION - I (Maximum Marks : 12)
This section contains THREE (03) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
18. A charged particle of charge  q and mass m is projected with initial velocity
qQ
v0  from a distance a from the fixed charge Q at an angle of α  60 with the
4 0 am
line joining the charges as shown in the figure. It is found that the particle moves on an
elliptical orbit with the charge Q at one of its foci.
Neglect gravity and any gravitational interaction between particles.

A) The length of the semi-major axis of the ellipse is a

B) The length of the semi-major axis of the ellipse is 2a
C) The area of the ellipse orbit is 3 a 2
3 2
D) The area of the ellipse orbit is a
2

19. Two thin conducting spherical shells of radii R and 2R are concentric. The outer shell
carries a uniform charge +Q and inner shell is neutral. A switch S can connect the inner
shell to earth.
A) When S is open, the potential of a point at a distance of 1.5R from centre is same as
that of the inner shell.
B) After S is closed, the potential of a point at a distance of 1.5R from centre is same as
that of the inner shell.
C) After S is closed, the charge on the inner shell is –0.5Q.
D) After S is closed, the potential of the outer shell is increased.

SR_IIT_*CO SC Page. No. 8

Narayana IIT Academy 17-08-25_SR.STAR CO-SC(MODEL-A&APEX)_JEE-ADV_PTA-3_QP
20. Consider two particles each of mass m at a distance r from each other. One of them is
given a velocity v perpendicular to line joining them and the other is simultaneously
released from rest. For which of the following values of v, the masses would be bound in
orbital motion under their mutual gravitational forces?

Gm 9Gm 9Gm 9Gm

A) B) C) D)
r 5r 4r 2r

SECTION–II (Maximum Marks: 12)

This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
21. Two infinitely large charged planes having uniform surface charge density  and 
are placed along x  y plane and y  z plane respectively as shown in the figure. Then the
nature of electric lines of forces in x  z plane is given by

A) B) C) D)

22. A point charge q is placed at some distance D from centre on the axis of uniformly
charged annular disc of internal radius R and external radius 2R of surface charge
density  . The flux due to the point charge though the plane of the periphery of the disc
(circle of radius 2R) is  . The electrostatic force on the point charge exerted by the disc
is of magnitude [D >> R]

 4 3
A)  B) C) D)
2 3 4

SR_IIT_*CO SC Page. No. 9

Narayana IIT Academy 17-08-25_SR.STAR CO-SC(MODEL-A&APEX)_JEE-ADV_PTA-3_QP
23. A very long hemi cylindrical surface of uniform surface charge density  is as shown.
Radius of the cylinder OA  R where O is midpoint of its axis and A is a point just inside
its surface. B is a point just outside on OA extended. Electric field at

 
A) point O is B) point O is
 0 20

C) point B is along OB D) point A is along OA

24. Inside a satellite orbiting very close to earth's surface, water does not fall out of a glass
when it is inverted. Which of the following is the best explanation w.r.t. an observer on
the earth?
A) The earth does not exert any force on the water
B) The earth's force of gravity on the water is exactly balanced by the gravitational force
of attraction by satellite + glass
C) The water & the glass have same acceleration towards the centre of the earth & hence
there is no relative motion between them
D) The earth's force of gravity on the water is exactly balanced by the centrifugal force
on the water.

SECTION-III (Maximum Marks : 24)

This section contains SIX (06) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
25. A ball of radius R carries a positive charge whose volume charge density depends on the

distance r form the centre as    0 1   where 0 is constant. Assume permittivity of

r
 R

the material of the ball to be 1. The distance from centre at which electric field intensity
is maximum, is nR. Find the value 12n.

SR_IIT_*CO SC Page. No. 10

Narayana IIT Academy 17-08-25_SR.STAR CO-SC(MODEL-A&APEX)_JEE-ADV_PTA-3_QP
26. A uniform ring of mass m and radius R is placed freely in a gravity free region. Half of
the ring is positively charged with uniform linear charge density  . and other half is
negatively charged with uniform charged density  . A uniform electric field E is
switched on along the normal to the plane of the ring. If the angular speed of the ring
 E 
when it turns through an angle 90° is n   , find the value of n.

 m 

27. A non-conducting solid cylinder of infinite length having charge density  and radius of
cylinder is 5R. A, B, C, D are four points on surface of the cylinder with sides AD & BC
parallel to axis of cylinder. If the flux passing through the rectangular surface ABCD as
 R3
shown in figure is . Find the value of  .
0

28. Coordinate of A are (0, 0, 0) and B (1, 0, 0). The shaded region is charge free and
vacuum. Volume charge density of A is  and that of B is   . Find the electric
potential (in V) at point C the point of intersection of the two spheres. Radius of large
sphere is 0.7 m and that of smaller sphere is 0.4 m. [All quantities are in S.I. units,
  200 0 ]

SR_IIT_*CO SC Page. No. 11

Narayana IIT Academy 17-08-25_SR.STAR CO-SC(MODEL-A&APEX)_JEE-ADV_PTA-3_QP
29. Consider a uniformly charged hemispherical shell having charge per unit area  . E1 is
the electric field at P1 (which is at a distance R from the centre of the hemispherical
shell and lying on an imaginary sphere having same radius as the given hemisphere (see
adjacent diagram), E2 is the magnitude of electric field at P2 (which is a point just inside
the hemispherical shell) and E3 is the magnitude of electric field at P3 (which is a point
E3
just outside the hemispherical shell). The value of is nearly _____ .
E2

30. A small spherical uniform moon of radius r and mass m is orbiting circularly around a
planet (uniform sphere) of mass M while keeping the same face towards the planet. Any
object on the moon’s surface closest to the planet experiences weightlessness if radius of
1
 aM  b
the orbit of moon is r   . Find the value of a  b .
 m 

SECTION-IV
(Maximum Marks : 12)
This section contains FOUR (04) Matching List Sets. Each set has ONE Multiple Choice Question
Each set has TWO lists: List-I and List-II. List-I has Four entries (P), (Q), (R) and (S) and
List-II has Five entries (1), (2), (3), (4) and (5).
FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these
four options satisfies the condition asked in the Multiple Choice Question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3ONLYif the option corresponding to the correct combination is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: – 1 in all other cases.
 
31. Two small electric dipoles of dipole moment P1 and P2 are oriented in two ways as

shown. Assuming dipole of dipole moment P2 to be placed at the origin and dipole of

moment P1 is at distance d from origin. Then:

SR_IIT_*CO SC Page. No. 12

Narayana IIT Academy 17-08-25_SR.STAR CO-SC(MODEL-A&APEX)_JEE-ADV_PTA-3_QP

Column-I Column-II
 1 2 P1 P2
P) Torque experienced by P1 in figure A 1) 4 0 d 3

Q) Torque experienced by P1 in figure B 2) Zero
 1 P1 P2
R) Force experienced by P1 in figure A 3) 4 0 d 3
 1 6 P1 P2
S) Torque experienced by P2 in figure A 4) 4 0 d 4

A) P  2; Q  3; R  4; S  2 B) P  2; Q  1; R  4; S  2

C) P  2; Q  1; R  4; S  3 D) P  3; Q  2; R  4; S  3

32. Two concentric conducting shells of radii R and 2R having charges q A and qB and
potential 2v and 3v / 2 respectively. (Assume potential to be zero at infinity). Now shell
B is earth by closing switch Sω . Let charge on spherical shell A & B become q A  and

qB  , and potential are vA  and vB  respectively.

SR_IIT_*CO SC Page. No. 13

Narayana IIT Academy 17-08-25_SR.STAR CO-SC(MODEL-A&APEX)_JEE-ADV_PTA-3_QP

Column-I Column-II
qB
P) 1) 0
qA
qB 
Q) 2) 1
qA 
vA
R) 3) 2
vA 
vB 
S) 4) 4
vB
A) P  3, Q  2, R  4, S  1 B) P  2, Q  3, R  4, S  1
C) P  2, Q  3, R  1, S  4 D) P  3, Q  2, R  1, S  4

33. Consider a system of five large conducting plates of area A. The charge on plate 1,2, 3,
4, 5 are given as Q, 2Q, 3Q, 4Q and 5Q respectively. Initially the two switches are
opened. Area of each plate is A. The distance between every successive plate is very
very small equal to d.

Column-I Column-II
P) The charge on surface b before closing switches is 1) 0.7 Q

After both the switches S1 and S2 are closed, the

potential difference between plate 2 and 3,  V2  V3 

Q) 2) 0.6 Q
 d 
is ____ ×  
 A 0 

SR_IIT_*CO SC Page. No. 14

Narayana IIT Academy 17-08-25_SR.STAR CO-SC(MODEL-A&APEX)_JEE-ADV_PTA-3_QP
The charge on surface b after closing both switches
R) 3) 1.3 Q
is

S) The charge on surface f after closing switches is 4) 6.5 Q

A) P  4, Q  1, R  2, S  3 B) P  4, Q  1, R  3, S  2

C) P  2, Q  3, R  1, S  4 D) P  4, Q  1, R  3, S  2

34. A space vehicle moving in a circular orbit of radius r1 transfer to a larger circular orbit
of radius r2 by means of an elliptical path between A and B. The transfer is
accomplished by a burst of speed vA at A and a second burst of speed vB at B. Then
match the following. g is acceleration due to gravity on the surface of the planet.

Column - I Column - II

2g r2
P) Speed at A in a circular orbit of radius r1 1) R
r1  r1  r2 

2g r1
Q) Speed at A in elliptical orbit 2) R
r2  r1  r2 

g  2r1 
R) Speed at B in elliptical orbit 3) R 1  
r2  r1  r2 

g
S) vB  4) R
r1

A) P  1; Q  4; R  3; S  2 B) P  1; Q  2; R  3; S  4
C) P  4; Q  1; R  2; S  3 D) P  1; Q  3; R  2; S  4

SR_IIT_*CO SC Page. No. 15

Narayana IIT Academy 17-08-25_SR.STAR CO-SC(MODEL-A&APEX)_JEE-ADV_PTA-3_QP
CHEMISTRY MAX.MARKS: 60
SECTION - I (Maximum Marks : 12)
This section contains THREE (03) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
35. Which of the following statement(s) is/are correct?
CMe 3

+Me CCOCl 

3
AlCl3
Δ  CO   HCl
 
A) ΔS for the rearrangement of Me3C CO to Me3 C is positive
 
B) Me3 C is more stable than Me3C CO 
NO2

C) Solvent used for Friedel Craft acylation is .

CHO
CHO

D) If the same reaction is carried out for product obtained will be CMe 3

36. Select the reactions in which the correct orientations have been mentioned for the major
product.
CH3 CH3
NO2
HNO3 + H2SO4
A)

Cl Cl

CH3 CH3
Br
B) Br2 / FeBr3

NHCOCH3 NHCOCH3

SR_IIT_*CO SC Page. No. 16

Narayana IIT Academy 17-08-25_SR.STAR CO-SC(MODEL-A&APEX)_JEE-ADV_PTA-3_QP
CHO CHO

Br2 / FeBr3
C)
OH Br OH

NO2+
D) O2 N

NO2 NO2

37. The correct statement(s) about X,Y& Z in the following reaction is/are ?
H2SO 4 dil
X (Consider only major products)

1) Hg(OAC) 2
(CH 3)3C-CH=CH 2 Y
2) NaBH 4

1) BH 3.THF
Z
2) NaOH, H 2O 2

A) X is optically inactive.
B) Y is obtained as racemic mixture.
C) Z is optically inactive.
D) Rearrangement of carbon skeleton is observed in formation of X & Y.

SECTION–II (Maximum Marks: 12)

This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
38. Mark the order of dipole moment of the following compounds:

(I) cis-1,2-Dichloroethene (II) trans-1,2-Dichloroethene

(III) 1,1-Dichloroethene (IV) Chloroethene

A) III > IV > I > II B) III > I > IV > II

C) I > III  IV > II D) IV > I > III > II

SR_IIT_*CO SC Page. No. 17

Narayana IIT Academy 17-08-25_SR.STAR CO-SC(MODEL-A&APEX)_JEE-ADV_PTA-3_QP
39. Arrange following alkanes in decreasing order of their Boiling point:

(I) n-Pentane (II) n-Butane (III) 2 -methyl propane

(IV) 2-methyl Butane (V) Neo pentane

A) I > II > IV > III > V B) I > IV > V > II > III

C) V > III > IV > II > I D) III > II > V > IV > I

O
40. Cl C Cl (A), Product (A) is:
AlCl3

O
A) B) C O C) C O D) Ph C Ph

C O
Cl
Cl
Cl

O
O Cl CH3
41.

(I) (II) (III) (IV) (V)

Correct order for electrophilic addition reaction of given compound follows

A) I > II > III > IV > V B) III > V > II > IV > I

C) III > IV > V > II > I D) I > IV > III > II > V

SR_IIT_*CO SC Page. No. 18

Narayana IIT Academy 17-08-25_SR.STAR CO-SC(MODEL-A&APEX)_JEE-ADV_PTA-3_QP
SECTION-III (Maximum Marks : 24)
This section contains SIX (06) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
42. How many optically active dienes on catalytic hydrogenation with 2 moles of hydrogen
will produce 1,4-Dimethylcyclohexane ?

43. Total number of dichloro product (excluding stereo) obtained on dichlorination of

methylcyclopropane.

44. How many of the positions are correct for major product of nitration in given molecules.

45. If CH3  C  C  CH  CH 2 is treated will 2 moles of Br2 , how many different isomers of
major product would be obtained?

46. How many of the following have an activated aromatic ring for electrophilic substitution
reaction as compared to benzene ?

(I) (II) (III)

N O
H
O
C O C6H5
NHC6H5 C
(IV) (V)
O

(VI) (VII) (VIII)

N

CHO
(IX)

SR_IIT_*CO SC Page. No. 19

Narayana IIT Academy 17-08-25_SR.STAR CO-SC(MODEL-A&APEX)_JEE-ADV_PTA-3_QP
47. Consider the alkyne isomers of C4 H6 . On addition of HBr (excess) to each of the

isomers, find the sum of position of Br atoms in the major products corresponding to

each isomer according to the IUPAC nomenclature.

SECTION-IV
(Maximum Marks : 12)
This section contains FOUR (04) Matching List Sets. Each set has ONE Multiple Choice Question
Each set has TWO lists: List-I and List-II. List-I has Four entries (P), (Q), (R) and (S) and
List-II has Five entries (1), (2), (3), (4) and (5).
FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these
four options satisfies the condition asked in the Multiple Choice Question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3ONLYif the option corresponding to the correct combination is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: – 1 in all other cases.
48. Find the correct match.
LIST-I LIST-II
(Reactions) (facts related to product of List-I)
I) nCH 2  CH 2 
Zieglar Natta
Catalyst
? P) Non aromatic product

II) n CH  CH 
Zieglar Natta
Catalyst
? Q) Aromatic product

 
III) 4CH  CH 
THF at  P  ?
Ni CN anhy
2
R) Used to make Toys, pipes etc

Ozonolysis gives glyoxal as one of the

IV) 3CH3  C  CH 
Re d hot Fe
Tube
? S)
product

T) Used as electrodes in Batteries

A) I  PRS, II  PS, III  PST, IV  QST

B) I  RST, II  RS, III  QS, IV  QS
C) I  PRST, II  PT, III  QS, IV  PS
D) I  PR, II  PST, III  PS, IV  Q

SR_IIT_*CO SC Page. No. 20

Narayana IIT Academy 17-08-25_SR.STAR CO-SC(MODEL-A&APEX)_JEE-ADV_PTA-3_QP
49. Consider the electrophilic addition reactions of List-I and match them with the
properties of products from List-II
List-I List-II

Cyclic intermediate is
I) 1) O3 P)
  formed
2) Zn  H 2O

Br2 Atleast one cyclic product is

II)  Q)
CCl4 formed

Product molecule(s) have

III) 1) O3 R) lesser carbons than starting
 
2) Zn  H 2O
material

Product or Product mixture

1) HgSO4  H 2 SO4
IV)   S) has two different functional
groups
A) I-P,Q,R,S; II-P,Q; III-PQ; IV-R,S B) I-Q,R,S; II-P; III-P,Q; IV-P,S
C) I-P,Q,R,S; II-P,Q; III-PS; IV-P D) I-Q,R,S; II-P; III-P,Q; IV-P,R,S
50. Consider the two lists: list-I contains compounds and list-II contains properties
associated with the compounds. Select the appropriate match.
List-I List-II
Reaction with HBr (assume sufficient wherever
I) But-1-yne P) required) produces major product with Br atoms not
on same carbon atom
Reaction with HBr (assume sufficient wherever
II) But-2-yne Q) required) produces major product with Br atoms on
the same carbon atom
III) Buta-1,3-diene R) Highest Heat of Hydrogenation (Magnitude)
IV) Allyl Bromide S) Lowest Heat of Hydrogenation (Magnitude)
T) Gives white precipitate with ammoniacal AgNO3
A) I-Q,R,T; II-Q; III-P; IV-P,S B) I-Q,R; II-Q,T; III-P; IV-P,S
C) I-Q,T; II-Q; III-P,R; IV-Q,S D) I-Q; II-Q,T; III-P,R; IV-Q,S
SR_IIT_*CO SC Page. No. 21
Narayana IIT Academy 17-08-25_SR.STAR CO-SC(MODEL-A&APEX)_JEE-ADV_PTA-3_QP
51. The unbalanced chemical reactions given in list-I has missing reagent or condition (?)
Which are provided in List II. Match List-I with List-II and select the correct option.

LIST-I LIST-II

I) 
?
 P) Zn in dil.HCl

II) 
?
 Q) Zn in dry ether

III) Cl

?
 R) Anhy AlCl3 / HCl

Mo2O3 over Al2O3

IV) Cl

?
S)
773K, 10-20 atm

A) I – R, II – S, III – Q, IV – P B) I – S, II – R, III – P, IV - Q

C) I – S, II – R, III – Q, IV – P D) I – R, II – S, III – P, IV – Q

SR_IIT_*CO SC Page. No. 22